Abstract: CTMA-bentonite and BTEA-Bentonite prepared by Na-bentonite cation exchanged with cetyltrimethylammonium(CTMA) and benzyltriethylammonium (BTEA). Products were characterized by XRD and IR techniques.The d001 spacing value of CTMA-bentonite and BTEA-bentonite are 7.54Å and 3.50Å larger than that of Na-bentonite at 100% cation exchange capacity, respectively. The IR spectrum showed that the intensities of OH stretching and bending vibrations of the two organoclays decreased greatly comparing to untreated Na-bentonite. Batch experiments were carried out at 303 K, 318 K and 333 K to obtain the sorption isotherms of Crystal violet onto the two organoclays. The results show that the sorption isothermal data could be well described by Freundlich model. The dynamical data for the two organoclays fit well with pseudo-second-order kinetic model. The adsorption capacity of CTMA-bentonite was found higher than that of BTEA-Bentonite. Thermodynamic parameters such as changes in the free energy (ΔG°), the enthalpy (ΔH°) and the entropy (ΔS°) were also evaluated. The overall adsorption process of Crystal violet onto the two organoclays were spontaneous, endothermic physisorption. The CTMA-bentonite and BTEA-Bentonite could be employed as low-cost alternatives to activated carbon in wastewater treatment for the removal of color which comes from textile dyes.
Abstract: Many states are now committed to implementing
international human rights standards domestically. In terms of
practical governance, how might effectiveness be measured? A facevalue
answer can be found in domestic laws and institutions relating
to human rights. However, this article provides two further tools to
help states assess their status on the spectrum of robust to fragile
human rights governance. The first recognises that each state has its
own 'human rights history' and the ideal end stage is robust human
rights governance, and the second is developing criteria to assess
robustness. Although a New Zealand case study is used to illustrate
these tools, the widespread adoption of human rights standards by
many states inevitably means that the issues are relevant to other
countries. This is even though there will always be varying degrees of
similarity-difference in constitutional background and developed or
emerging human rights systems.
Abstract: Accurate timing alignment and stability is important
to maximize the true counts and minimize the random counts in
positron emission tomography So signals output from detectors must
be centering with the two isotopes to pre-operation and fed signals
into four units of pulse-processing units, each unit can accept up to
eight inputs. The dual source computed tomography consist two units
on the left for 15 detector signals of Cs-137 isotope and two units on
the right are for 15 detectors signals of Co-60 isotope. The gamma
spectrum consisting of either single or multiple photo peaks. This
allows for the use of energy discrimination electronic hardware
associated with the data acquisition system to acquire photon counts
data with a specific energy, even if poor energy resolution detectors
are used. This also helps to avoid counting of the Compton scatter
counts especially if a single discrete gamma photo peak is emitted by
the source as in the case of Cs-137. In this study the polyenergetic
version of the alternating minimization algorithm is applied to the
dual energy gamma computed tomography problem.
Abstract: Truss spars are used for oil exploitation in deep and ultra-deep water if storage crude oil is not needed. The linear hydrodynamic analysis of truss spar in random sea wave load is necessary for determining the behaviour of truss spar. This understanding is not only important for design of the mooring lines, but also for optimising the truss spar design. In this paper linear hydrodynamic analysis of truss spar is carried out in frequency domain. The hydrodynamic forces are calculated using the modified Morison equation and diffraction theory. Added mass and drag coefficients of truss section computed by transmission matrix and normal acceleration and velocity component acting on each element and for hull section computed by strip theory. The stiffness properties of the truss spar can be separated into two components; hydrostatic stiffness and mooring line stiffness. Then, platform response amplitudes obtained by solved the equation of motion. This equation is non-linear due to viscous damping term therefore linearised by iteration method [1]. Finally computed RAOs and significant response amplitude and results are compared with experimental data.
Abstract: The urban centers within northeastern Brazil are
mainly influenced by the intense rainfalls, which can occur after long
periods of drought, when flood events can be observed during such
events. Thus, this paper aims to study the rainfall frequencies in such
region through the wavelet transform. An application of wavelet
analysis is done with long time series of the total monthly rainfall
amount at the capital cities of northeastern Brazil. The main
frequency components in the time series are studied by the global
wavelet spectrum and the modulation in separated periodicity bands
were done in order to extract additional information, e.g., the 8 and
16 months band was examined by an average of all scales, giving a
measure of the average annual variance versus time, where the
periods with low or high variance could be identified. The important
increases were identified in the average variance for some periods,
e.g. 1947 to 1952 at Teresina city, which can be considered as high
wet periods. Although, the precipitation in those sites showed similar
global wavelet spectra, the wavelet spectra revealed particular
features. This study can be considered an important tool for time
series analysis, which can help the studies concerning flood control,
mainly when they are applied together with rainfall-runoff
simulations.
Abstract: Synthetic aperture radar (SAR) imaging usually
requires echo data collected continuously pulse by pulse with certain
bandwidth. However in real situation, data collection or part of signal
spectrum can be interrupted due to various reasons, i.e. there will be
gaps in spatial spectrum. In this case we need to find ways to fill out
the resulted gaps and get image with defined resolution. In this paper
we introduce our work on how to apply iterative spatially variant
apodization (Super-SVA) technique to extrapolate the spatial
spectrum in both azimuthal and range directions so as to fill out the
gaps and get correct radar image.
Abstract: In this work, we address theoretically the influence of red and white Gaussian noise for electronic energies and eigenstates of cylindrically shaped quantum dots. The stochastic effect can be imagined as resulting from crystal-growth statistical fluctuations in the quantum-dot material composition. In particular we obtain analytical expressions for the eigenvalue shifts and electronic envelope functions in the k . p formalism due to stochastic variations in the confining band-edge potential. It is shown that white noise in the band-edge potential leaves electronic properties almost unaffected while red noise may lead to changes in state energies and envelopefunction amplitudes of several percentages. In the latter case, the ensemble-averaged envelope function decays as a function of distance. It is also shown that, in a stochastic system, constant ensembleaveraged envelope functions are the only bounded solutions for the infinite quantum-wire problem and the energy spectrum is completely discrete. In other words, the infinite stochastic quantum wire behaves, ensemble-averaged, as an atom.
Abstract: In this paper, a novel method for a biometric system based on the ECG signal is proposed, using spectral coefficients computed through linear predictive coding (LPC). ECG biometric systems have traditionally incorporated characteristics of fiducial points of the ECG signal as the feature set. These systems have been shown to contain loopholes and thus a non-fiducial system allows for tighter security. In the proposed system, incorporating non-fiducial features from the LPC spectrum produced a segment and subject recognition rate of 99.52% and 100% respectively. The recognition rates outperformed the biometric system that is based on the wavelet packet decomposition (WPD) algorithm in terms of recognition rates and computation time. This allows for LPC to be used in a practical ECG biometric system that requires fast, stringent and accurate recognition.
Abstract: A facile vapour deposition method of synthesis of vertically aligned ZnO nanowires on carbon seed layer was developed. The received samples were investigated on electronic microscope JSM-6490 LA JEOL and x-ray diffractometer X, pert MPD PRO. The photoluminescence spectra (PL) of obtained ZnO samples at a room temperature were studied using He-Cd laser (325 nm line) as excitation source.
Abstract: In this paper, a residue number arithmetic is used in
direct sequence spread spectrum system, this system is evaluated and
the bit error probability of this system is compared to that of non
residue number system. The effect of channel bandwidth, PN
sequences, multipath effect and modulation scheme are studied. A
Matlab program is developed to measure the signal-to-noise ratio
(SNR), and the bit error probability for the various schemes.
Abstract: The electromagnetic spectrum is a natural resource
and hence well-organized usage of the limited natural resources is the
necessities for better communication. The present static frequency
allocation schemes cannot accommodate demands of the rapidly
increasing number of higher data rate services. Therefore, dynamic
usage of the spectrum must be distinguished from the static usage to
increase the availability of frequency spectrum. Cognitive radio is not
a single piece of apparatus but it is a technology that can incorporate
components spread across a network. It offers great promise for
improving system efficiency, spectrum utilization, more effective
applications, reduction in interference and reduced complexity of
usage for users. Cognitive radio is aware of its environmental,
internal state, and location, and autonomously adjusts its operations
to achieve designed objectives. It first senses its spectral environment
over a wide frequency band, and then adapts the parameters to
maximize spectrum efficiency with high performance. This paper
only focuses on the analysis of Bit-Error-Rate in cognitive radio by
using Particle Swarm Optimization Algorithm. It is theoretically as
well as practically analyzed and interpreted in the sense of
advantages and drawbacks and how BER affects the efficiency and
performance of the communication system.
Abstract: –In this paper the damage in clamped-free, clampedclamped and free-free beam are analyzed considering samples
without and with structural modifications. The damage location is
investigated by the use of the bispectrum and wavelet analysis. The
mathematical models are obtained using 2D elasticity theory and the
Finite Element Method (FEM). The numerical and experimental data
are approximated using the Particle Swarm Optimizer (PSO) method
and this way is possible to adjust the localization and the severity of
the damage. The experimental data are obtained through
accelerometers placed along the sample. The system is excited using
impact hammer.
Abstract: The linear SEF (Spectral Edge Frequency) parameter
and spectrum analysis method can not reflect the non-linear of EEG.
This method can not contribute to acquire real time analysis and obtain
a high confidence in the clinic due to low discrimination. To solve the
problems, the development of a new index is carried out using the
bispectrum analyzing the EEG(electroencephalogram) including the
non-linear characteristic. After analyzing the bispectrum of the 2
dimension, the most significant power spectrum density peaks appeared abundantly at the specific area in awakening and anesthesia state. These points are utilized to create the new index since many
peaks appeared at the specific area in the frequency coordinate. The measured range of an index was 0-100. An index is 20-50 at an anesthesia, while the index is 90-60 at the awake. New index could afford to effectively discriminate the awake and anesthesia state.
Abstract: The analytical solutions for geodesic acoustic
eigenmodes in tokamak plasmas with circular concentric magnetic
surfaces are found. In the frame of ideal magnetohydrodynamics the
dispersion relation taking into account the toroidal coupling between
electrostatic perturbations and electromagnetic perturbations with
poloidal mode number |m| = 2 is derived. In the absence of such
a coupling the dispersion relation gives the standard continuous
spectrum of geodesic acoustic modes. The analysis of the existence
of global eigenmodes for plasma equilibria with both off-axis
and on-axis maximum of the local geodesic acoustic frequency is
performed.
Abstract: The advances in multimedia and networking technologies
have created opportunities for Internet pirates, who can easily
copy multimedia contents and illegally distribute them on the Internet,
thus violating the legal rights of content owners. This paper describes
how a simple and well-known watermarking procedure based on a
spread spectrum method and a watermark recovery by correlation can
be improved to effectively and adaptively protect MPEG-2 videos
distributed on the Internet. In fact, the procedure, in its simplest
form, is vulnerable to a variety of attacks. However, its security
and robustness have been increased, and its behavior has been
made adaptive with respect to the video terminals used to open
the videos and the network transactions carried out to deliver them
to buyers. In fact, such an adaptive behavior enables the proposed
procedure to efficiently embed watermarks, and this characteristic
makes the procedure well suited to be exploited in web contexts,
where watermarks usually generated from fingerprinting codes have
to be inserted into the distributed videos “on the fly", i.e. during the
purchase web transactions.
Abstract: 16-Mercaptohexadecanoic acid (MHDA) and tripeptide glutathione conjugated with gold nanoparticles (Au-NPs) are characterized by Fourier Transform InfaRared (FTIR) spectroscopy combined with Surface-enhanced Raman scattering (SERS) spectroscopy. Surface Plasmon Resonance (SPR) technique based on FTIR spectroscopy has become an important tool in biophysics, which is perspective for the study of organic compounds. FTIR-spectra of MHDA shows the line at 2500 cm-1 attributed to thiol group which is modified by presence of Au-NPs, suggesting the formation of bond between thiol group and gold. We also can observe the peaks originate from characteristic chemical group. A Raman spectrum of the same sample is also promising. Our preliminary experiments confirm that SERS-effect takes place for MHDA connected with Au-NPs and enable us to detected small number (less than 106 cm-2) of MHDA molecules. Combination of spectroscopy methods: FTIR and SERS – enable to study optical properties of Au- NPs and immobilized bio-molecules in context of a bio-nano-sensors.
Abstract: In the last decade digital watermarking procedures have
become increasingly applied to implement the copyright protection
of multimedia digital contents distributed on the Internet. To this
end, it is worth noting that a lot of watermarking procedures
for images and videos proposed in literature are based on spread
spectrum techniques. However, some scepticism about the robustness
and security of such watermarking procedures has arisen because
of some documented attacks which claim to render the inserted
watermarks undetectable. On the other hand, web content providers
wish to exploit watermarking procedures characterized by flexible and
efficient implementations and which can be easily integrated in their
existing web services frameworks or platforms. This paper presents
how a simple spread spectrum watermarking procedure for MPEG-2
videos can be modified to be exploited in web contexts. To this end,
the proposed procedure has been made secure and robust against some
well-known and dangerous attacks. Furthermore, its basic scheme
has been optimized by making the insertion procedure adaptive with
respect to the terminals used to open the videos and the network transactions
carried out to deliver them to buyers. Finally, two different
implementations of the procedure have been developed: the former
is a high performance parallel implementation, whereas the latter is
a portable Java and XML based implementation. Thus, the paper
demonstrates that a simple spread spectrum watermarking procedure,
with limited and appropriate modifications to the embedding scheme,
can still represent a valid alternative to many other well-known and
more recent watermarking procedures proposed in literature.
Abstract: The colonic tissue is a complicated dynamic system
and the colonic activities it generates are composed of irregular
segmental waves, which are referred to as erratic fluctuations or spikes.
They are also highly irregular with subunit fractal structure. The
traditional time-frequency domain statistics like the averaged
amplitude, the motility index and the power spectrum, etc. are
insufficient to describe such fluctuations. Thus the fractal
box-counting dimension is proposed and the fractal scaling behaviors
of the human colonic pressure activities under the physiological
conditions are studied. It is shown that the dimension of the resting
activity is smaller than that of the normal one, whereas the clipped
version, which corresponds to the activity of the constipation patient,
shows with higher fractal dimension. It may indicate a practical
application to assess the colonic motility, which is often indicated by
the colonic pressure activity.
Abstract: This paper analyses the non linear properties
exhibited by a drill string system under various un balanced mass
conditions. The drill string is affected by continuous friction in the
form of drill bit and well bore hole interactions. This paper proves
the origin of limit cycling and increase of non linearity with increase
in speed of the drilling in the presence of friction. The spectrum of
the frequency response is also studied to detect the presence of
vibration abnormalities arising during the drilling process.
Abstract: Bacterial cellulose, a biopolysaccharide, is produced by the bacterium, Gluconacetobacter xylinus. Static batch fermentation for bacterial cellulose production was studied in sucrose and date syrup solutions (Bx. 10%) at 28 °C using G. xylinus (PTCC, 1734). Results showed that the maximum yields of bacterial cellulose (BC) were 4.35 and 1.69 g/l00 ml for date syrup and sucrose medium after 336 hours fermentation period, respectively. Comparison of FTIR spectrum of cellulose with BC indicated appropriate coincidence which proved that the component produced by G. xylinus was cellulose. Determination of the area under X-ray diffractometry patterns demonstrated that the crystallinity amount of cellulose (83.61%) was more than that for the BC (60.73%). The scanning electron microscopy imaging of BC and cellulose were carried out in two magnifications of 1 and 6K. Results showed that the diameter ratio of BC to cellulose was approximately 1/30 which indicated more delicacy of BC fibers relative to cellulose.