Abstract: Biodiesel is one of the alternative fuels that promising
for substituting petro diesel as energy source which is advantage on
sustainability and ecofriendly. Due to the raw material that tend to
decompose during storage, biodiesel also have the same characteristic
that tend to decompose and formed higher acid value which is the
result of oxidation to double bond on a chain of ester. Decomposition of biodiesel due to oxidation reaction could
prevent by introduce a small amount of antioxidant. The origin of raw
materials and the process for producing biodiesel will determine the
effectiveness of antioxidant. The quality degradation on biodiesel
could evaluate by measuring iodine value and acid number of
biodiesel. Biodiesel made from high fatty acid Jatropha curcas oil by using
esterification and transesterification process will stand on the quality
by introduce 90 ppm pyrogallol powder on the biodiesel, which could
increase Induction period time from 2 hours to more than 6 hours in
rancimat test evaluation.
Abstract: Biodiesel, as an alternative renewable fuel, has been
receiving increasing attention due to the limited supply of fossil fuels
and the increasing need for energy. Microalgae are promising source
for lipids, which can be converted to biodiesel. The biodiesel
production from microalgae lipids using lipase catalyzed reaction in
supercritical CO2 medium has several advantages over conventional
production processes. However, identifying the optimum microalgae
lipid extraction and transesterification conditions is still a challenge.
In this study, the quality of biodiesel produced from lipids extracted
from Scenedesmus sp. and their enzymatic transesterification using
supercritical carbon dioxide have been investigated. At the optimum
conditions, the highest biodiesel production yield was found to be
82%. The fuel properties of the produced biodiesel, without any
separation step, at optimum reaction condition, were determined and
compared to ASTM standards. The properties were found to comply
with the limits, and showed a low glycerol content, without any
separation step.
Abstract: Biodiesel as an alternative diesel fuel is steadily gaining more attention and significance. However, there are some drawbacks while using biodiesel regarding its properties that requires it to be blended with petrol based diesel and/or additives to improve the fuel characteristics. This study analyses thermal cracking as an alternative technology to improve biodiesel characteristics in which, FAME based biodiesel produced by transesterification of castor oil is fed into a continuous thermal cracking reactor at temperatures range of 450-500°C and flowrate range of 20-40 g/hr. Experiments designed by response surface methodology and subsequent statistical studies show that temperature and feed flowrate significantly affect the products yield. Response surfaces were used to study the impact of temperature and flowrate on the product properties. After each experiment, the produced crude bio-oil was distilled and diesel cut was separated. As shorter chain molecules are produced through thermal cracking, the distillation curve of the diesel cut fitted more with petrol based diesel curve in comparison to the biodiesel. Moreover, the produced diesel cut properties adequately pose within property ranges defined by the related standard of petrol based diesel. Cold flow properties, high heating value as the main drawbacks of the biodiesel are improved by this technology. Thermal cracking decreases kinematic viscosity, Flash point and cetane number.
Abstract: Strong anion exchange resins with QN+OH-, have the
potential to be developed and employed as heterogeneous catalyst for
transesterification, as they are chemically stable to leaching of the
functional group. Nine different SIERs (SIER1-9) with QN+OH-were
prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene
(VBC-DVB) copolymers in the presence of n-heptane
(pore-forming agent). The amine group was successfully grafted into
the polymeric resin beads through functionalization with
trimethylamine. These SIERs are then used as a catalyst for the
transesterification of triacetin with methanol. A set of differential
equations that represents the Langmuir-Hinshelwood-Hougen-
Watson (LHHW) and Eley-Rideal (ER) models for the
transesterification reaction were developed. These kinetic models of
LHHW and ER were fitted to the experimental data. Overall, the
synthesized ion exchange resin-catalyzed reaction were welldescribed
by the Eley-Rideal model compared to LHHW models,
with sum of square error (SSE) of 0.742 and 0.996, respectively.
Abstract: The knowledge of biodiesel density over large ranges
of temperature and pressure is important for predicting the behavior
of fuel injection and combustion systems in diesel engines, and for
the optimization of such systems. In this study, cottonseed oil was
transesterified into biodiesel and its density was measured at
temperatures between 288 K and 358 K and pressures between 0.1
MPa and 30 MPa, with expanded uncertainty estimated as ±1.6 kg⋅m-
3. Experimental pressure-volume-temperature (pVT) cottonseed data
was used along with literature data relative to other 18 biodiesels, in
order to build a database used to test the correlation of density with
temperarure and pressure using the Goharshadi–Morsali–Abbaspour
equation of state (GMA EoS). To our knowledge, this is the first that
density measurements are presented for cottonseed biodiesel under
such high pressures, and the GMA EoS used to model biodiesel
density. The new tested EoS allowed correlations within 0.2 kg·m-3
corresponding to average relative deviations within 0.02%. The built
database was used to develop and test a new full predictive model
derived from the observed linear relation between density and degree
of unsaturation (DU), which depended from biodiesel FAMEs
profile. The average density deviation of this method was only about
3 kg.m-3 within the temperature and pressure limits of application.
These results represent appreciable improvements in the context of
density prediction at high pressure when compared with other
equations of state.
Abstract: The discarded clam shell waste, fossil and edible oil
as biolubricant feedstocks create environmental impacts and food
chain dilemma, thus this work aims to circumvent these issues by
using activated saltwater clam shell waste (SCSW) as solid catalyst
for conversion of Jatropha curcas oil as non-edible sources to ester
biolubricant. The characterization of solid catalyst was done by
Differential Thermal Analysis-Thermo Gravimetric Analysis (DTATGA),
X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD),
Brunauer-Emmett-Teller (BET), Field Emission Scanning Electron
Microscopy (FESEM) and Fourier Transformed Infrared
Spectroscopy (FTIR) analysis. The calcined catalyst was used in the
transesterification of Jatropha oil to methyl ester as the first step, and
the second stage was involved the reaction of Jatropha methyl ester
(JME) with trimethylolpropane (TMP) based on the various process
parameters. The formated biolubricant was analyzed using the
capillary column (DB-5HT) equipped Gas Chromatography (GC).
The conversion results of Jatropha oil to ester biolubricant can be
found nearly 96.66%, and the maximum distribution composition
mainly contains 72.3% of triester (TE).
Abstract: Various biomass based resources, which can be used
as an extender, or a complete substitute of diesel fuel may have very
significant role in the development of agriculture, industrial and
transport sectors in the energy crisis. Use of Karanja oil methyl ester
biodiesel in a CI DI engine was found highly compatible with engine
performance along with lower exhaust emission as compared to
diesel fuel but with slightly higher NOx emission and low wear
characteristics. The combustion related properties of vegetable oils
are somewhat similar to diesel oil. Neat vegetable oils or their blends
with diesel, however, pose various long-term problems in
compression ignition engines. These undesirable features of
vegetable oils are because of their inherent properties like high
viscosity, low volatility, and polyunsaturated character. Pongamia
methyl ester (PME) was prepared by transesterification process using
methanol for long term engine operations. The physical and
combustion-related properties of the fuels thus developed were found
to be closer to that of the diesel. A neat biodiesel (PME) was selected
as a fuel for the tribological study of biofuels.
Two similar new engines were completely disassembled and
subjected to dimensioning of various vital moving parts and then
subjected to long-term endurance tests on neat biodiesel and diesel
respectively. After completion of the test, both the engines were
again disassembled for physical inspection and wear measurement of
various vital parts. The lubricating oil samples drawn from both
engines were subjected to atomic absorption spectroscopy (AAS) for
measurement of various wear metal traces present. The additional
lubricating property of biodiesel fuel due to higher viscosity as
compared to diesel fuel resulted in lower wear of moving parts and
thus improved the engine durability with a bio-diesel fuel. Results
reported from AAS tests confirmed substantially lower wear and thus
improved life for biodiesel operated engines.
Abstract: In this study, fish bone waste was used as a new
catalyst for biodiesel production. Instead of discarding the fish bone
waste, it will be utilized as a source for catalyst that can provide
significant benefit to the environment. Also, it can be substitute as a
calcium oxide source instead of using eggshell, crab shell and snail
shell. The XRD and SEM analysis proved that calcined fish bone
contains calcium oxide, calcium phosphate and hydroxyapatite. The
catalyst was characterized using Scanning Electron Microscope
(SEM) and X-ray Diffraction (XRD).
Abstract: Jojoba oil-wax is extracted from the seeds of the jojoba (Simmondsia chinensis Link Schneider), a perennial shrub that grows in semi desert areas in Egypt and in some parts of the world. The main uses of jojoba oil-wax are in the cosmetics and pharmaceutical industry, but new uses could arise related to the search of new energetic crops. This paper summarizes a process to convert the jojoba oil-wax to biodiesel by transesterification with ethanol and a series of aliphatic alcohols using a more economic and energy saving method in a domestic microwave. The effect of time and power of the microwave on the extent of the transesterification using ethanol and other aliphatic alcohols has been studied. The separation of the alkyl esters from the fatty alcohols rich fraction has been done in a single crystallization step at low temperature (−18°C) from low boiling point petroleum ether. Gas chromatography has been used to follow up the transesterification process. All products have been characterized by spectral analysis.
Abstract: As the limited availability of petroleum-based fuel has been a major concern, biodiesel is one of the most attractive alternative fuels because it is renewable and it also has advantages over the conventional petroleum-base diesel. At Present, productions of biodiesel generally perform by transesterification of vegetable oils with low molecular weight alcohol, mainly methanol, using chemical catalysts. Methanol is petrochemical product that makes biodiesel producing from methanol to be not pure renewable energy source. Therefore, ethanol as a product produced by fermentation processes. It appears as a potential feed stock that makes biodiesel to be pure renewable alternative fuel. The research is conducted based on two biodiesel production processes by reacting soybean oils with methanol and ethanol. Life cycle assessment was carried out in order to evaluate the environmental impacts and to identify the process alternative. Nine mid-point impact categories are investigated. The results indicate that better performance on abiotic depletion potential (ADP) and acidification potential (AP) are observed in biodiesel production from methanol when compared with biodiesel production from ethanol due to less energy consumption during the production processes. Except for ADP and AP, using methanol as feed stock does not show any advantages over biodiesel from ethanol. The single score method is also included in this study in order to identify the best option between two processes of biodiesel production. The global normalization and weighting factor based on ecotaxes are used and it shows that producing biodiesel form ethanol has less environmental load compare to biodiesel from methanol.
Abstract: The performance, emission and combustion characteristics of a single cylinder four stroke variable compression ratio multi fuel engine when fueled with different blends of rice bran oil methyl ester and ethanol are investigated and compared with the results of standard diesel. Bio diesel produced from Rice bran oil by transesterification process has been used in this study. Experiment has been conducted at a fixed engine speed of 1500 rpm, 50% load and at compression ratios of 16.5:1, 17:1, 17.5:1 and 18:1. The impact of compression ratio on fuel consumption, brake thermal efficiency and exhaust gas emissions has been investigated and presented. Optimum compression ratio which gives best performance has been identified. The results indicate longer ignition delay, maximum rate of pressure rise, lower heat release rate and higher mass fraction burnt at higher compression ratio for waste cooking oil methyl ester when compared to that of diesel. The brake thermal efficiency at 50% load for Rice bran oil methyl ester blends and diesel has been calculated and the blend B40 is found to give maximum thermal efficiency. The blends when used as fuel results in reduction of carbon monoxide, hydrocarbon and increase in nitrogen oxides emissions.
Abstract: Transesterification reactions free of catalyst between
roasted chicken fat with methanol were carried out in a batch reactor
in order to produce biodiesel to temperatures from 120°C to 140°C.
Parameters related to the transesterification reactions, including
temperature, time and the molar ratio of chicken fat to methanol also
investigated. The maximum yield of the reaction was of 98% under
conditions of 140°C, 4 h of reaction time and a molar ratio of chicken
fat to methanol of 1:31. The biodiesel thus obtained exhibited a
viscosity of 6.3 mm2/s and a density of 895.9 kg/m3. The results
showed this process can be right choice to produce biodiesel since
this process does not use any catalyst. Therefore, the steps of
neutralization and washing are avoided, indispensables in the case of
the alkaline catalysis.
Abstract: Different vegetable oil based biodiesel (FAMES) were prepared by alkaline transesterification using refined oils as well as waste frying oil (WFO). Methanol and sodium hydroxide are used as catalyst under similar reaction conditions. To ensure the quality of biodiesel produced, a series of different ASTM Standard tests were carried out. In this context, various testwere done including viscosity, carbon residue, specific gravity, corrosion test, flash point, cloud point and pour point. Results revealed that characteristics of biodiesel depend on the feedstock and it is far better than petroleum diesel.
Abstract: Knowledge of food resource of the houbara which an
endangered species would be a important step toward the
preservation of this bird. Adequate study has not been done in this
field and therefore the food sources of the houbara during the
brooding season was studied in the central steppe of Iran. In order to
determine the density of insect in plant communities the pitfall trap
was used , positioned in five linear transects divided between plant
communities and in two repetitions. The results showed that the
among communities there was a significant difference in term of the
number beetles and ants ( p= 0.01, F2, 29= 4.66) collectively. Also
bush steppe habitat had a higher arthropoda density in comparison
with the shrub steppe habitat. Considering that most houbara nests
were found in the bush steppe habitat .It seems this habitat provides
the most available food supply for the houbara chicks.
Abstract: Antioxidants contribute to endogenous photoprotection
and are important for the maintenance of skin health. The study was carried out to compare the skin hydration and transepidermal
water loss (TEWL) effects of a stable cosmetic preparation
containing flavonoids, following two applications a day over a period
of tenth week. The skin trans-epidermal water loss and skin hydration
effect was measured at the beginning and up to the end of study period of ten weeks. Any effect produced was measured by Corneometer and TEWA meter (Non-invasive probe).
Two formulations were developed for this study design. Formulation one the control formulation in which no apple juice
extract( Flavonoids) was incorporated while second one was the active formulation in which the apple juice extract (3%) containing
flavonoids was incorporated into water in oil emulsion using Abil EM 90 as an emulsifier. Stable formulations (control and Active)
were applied on human cheeks (n = 12) for a study period of 10 weeks. Result of each volunteer of skin hydration and TEWL was
measured by corneometer and TEWA meter. By using ANOVA and Paired sample t test as a statistical evaluation, result of both base and
formulation were compared. Statistical significant results (p≤0.05)
were observed regarding skin hydration and TEWL when two creams, control and Formulation were compared. It showed that
desired formulation (Active) may have interesting application as an
active moisturizing cream on healthy skin.
Abstract: Commercially available lipases (Candida antarctica lipase B, Novozyme 435, Thermomyces lanuginosus lipase, and Lipozyme TL IM), as well as sol-gel immobilized lipases, have been screened for their ability to acylate regioselectively xylitol, sorbitol, and mannitol with a phenolic ester in a binary mixture of t-butanol and dimethylsulfoxide. HPLC and MALDI-TOF MS analysis revealed the exclusive formation of monoesters for all studied sugar alcohols. The lipases immobilized by the sol-gel entrapment method proved to be efficient catalysts, leading to high conversions (up to 60%) in the investigated acylation reactions. From a sequence of silane precursors with different nonhydrolyzable groups in their structure, the presence of octyl and i-butyl group was most beneficial for the catalytic activity of sol-gel entrapped lipases in the studied process.
Abstract: The aim of this study is to develop mathematical
relationships for the performance parameter brake thermal efficiency
(BTE) and emission parameter nitrogen oxides (NOx) for the various
esters of vegetable oils used as CI engine fuel. The BTE is an
important performance parameter defining the ability of engine to
utilize the energy supplied and power developed similarly it is
indication of efficiency of fuels used. The esters of cottonseed oil,
soybean oil, jatropha oil and hingan oil are prepared using
transesterification process and characterized for their physical and
main fuel properties including viscosity, density, flash point and
higher heating value using standard test methods. These esters are
tried as CI engine fuel to analyze the performance and emission
parameters in comparison to diesel. The results of the study indicate
that esters as a fuel does not differ greatly with that of diesel in
properties. The CI engine performance with esters as fuel is in line
with the diesel where as the emission parameters are reduced with the
use of esters.
The correlation developed between BTE and brake power(BP),
gross calorific value(CV), air-fuel ratio(A/F), heat carried away by
cooling water(HCW). Another equation is developed between the
NOx emission and CO, HC, smoke density (SD), exhaust gas
temperature (EGT). The equations are verified by comparing the
observed and calculated values which gives the coefficient of
correlation of 0.99 and 0.96 for the BTE and NOx equations
respectively.
Abstract: Nano-MgO was successfully deposited on titania using deposition-precipitation method. The catalyst produced was characterised using FTIR, XRD, BET and XRF and its activity was tested on the transesterification reaction of soybean oil to biodiesel. The catalyst activity improved when the reaction temperature was increasedfrom 150 and 225 OC. It was also observed that increasing the reaction time above 1h had no significant benefit on conversion. The stability fixed MgO on TiO2 was investigated using XRF and ICP-OES. It was observed that MgO loss during the reaction was between 0.5-2.3 percent and that there was no correlation between the reaction temperature and the MgO loss.
Abstract: Studying alternative raw materials for biodiesel production is of major importance. The use of mixtures with incorporation of wastes is an environmental friendly alternative and might reduce biodiesel production costs. The objective of the present work was: (i) to study biodiesel production using waste frying oil mixed with pork lard and (ii) to understand how mixture composition influences biodiesel quality. Biodiesel was produced by transesterification and quality was evaluated through determination of several parameters according to EN 14214. The weight fraction of lard in the mixture varied from 0 to 1 in 0.2 intervals. Biodiesel production yields varied from 81.7 to 88.0 (wt%), the lowest yields being the ones obtained using waste frying oil and lard alone as raw materials. The obtained products fulfilled most of the determined quality specifications according to European biodiesel quality standard EN 14214. Minimum purity (96.5 wt%) was closely obtained when waste frying oil was used alone and when 0.2% of lard was incorporated in the raw material (96.3 wt%); however, it ranged from 93.9 to 96.3 (wt%) being always close to the limit. From the evaluation of the influence of mixture composition in biodiesel quality, it was possible to establish a model to be used for predicting some parameters of biodiesel resulting from mixtures of waste frying oil with lard when different lard contents are used.
Abstract: This paper studied the synthesis of monoacylglycerol (monolaurin) by glycerolysis of coconut oil and crude glycerol, catalyzed by Carica papaya lipase. Coconut oil obtained from cold pressed extraction method and crude glycerol obtained from the biodiesel plant in Department of Chemistry, Uttaradit Rajabhat University, Thailand which used oils were used as raw materials for biodiesel production through transesterification process catalyzed by sodium hydroxide. The influences of the following variables were studied: (i) type of organic solvent, (ii) molar ratio of substrate, (iii) reaction temperature, (iv) reaction time, (v) lipase dosage, and (vi) initial water activity of enzyme. High yields in monoacylglycerol (58.35%) were obtained with molar ratio of glycerol to oil at 8:1 in ethanol, temperature was controlled at 45oC for 36 hours, the amount of enzyme used was 20 wt% of oil and initial water activity of enzyme at 0.53.