Influence of Synthetic Antioxidant in the Iodine Value and Acid Number of Jatropha Curcas Biodiesel
Biodiesel is one of the alternative fuels that promising
for substituting petro diesel as energy source which is advantage on
sustainability and ecofriendly. Due to the raw material that tend to
decompose during storage, biodiesel also have the same characteristic
that tend to decompose and formed higher acid value which is the
result of oxidation to double bond on a chain of ester. Decomposition of biodiesel due to oxidation reaction could
prevent by introduce a small amount of antioxidant. The origin of raw
materials and the process for producing biodiesel will determine the
effectiveness of antioxidant. The quality degradation on biodiesel
could evaluate by measuring iodine value and acid number of
biodiesel. Biodiesel made from high fatty acid Jatropha curcas oil by using
esterification and transesterification process will stand on the quality
by introduce 90 ppm pyrogallol powder on the biodiesel, which could
increase Induction period time from 2 hours to more than 6 hours in
rancimat test evaluation.
[1] IEA. U.S. Energy Information Administration. International Energy
Statistics - Biodiesel production.
[2] Renner A., Zelt T., Gerteiser S., From Aid to Market, the Global
Exchange for Social Investment, Global Market Study on Jatropha
(Final report-Abstract), Gexsi LLP, 2008.
[3] Barnwal S.K., Sharma M.P., Prospects of biodiesel production from
vegetable oils in India, Renewable and Sustainable Energy Reviews 9
(2004) 363–378. [4] Gui M.M., Lee K.T., Bhatia S., Feasibility of edible oil vs. non-edible
oil vs. waste edible oil as biodiesel feedstock, Energy 33 (2008) 1646 –
1653.
[5] Kiss A. A., Omota F., Dimian A.C., Rothenberg G., The heterogeneous
advantage: biodiesel by catalytic reactive distillation, Topics in Catalysis
40 (2006) 141–150.
[6] Tamunaidu P., Bhatia S., Catalytic cracking of palm oil for the
production of biofuels: Optimization studies, Bioresource Technology
98 (2007) 3593–3601.
[7] Prado C.M.R., Filho N.R.A., Production and characterization of the
biofuels obtained by thermal cracking and thermal catalytic cracking of
vegetable oils, Journal of Analytical and Applied Pyrolysis 86 (2009)
338–347.
[8] Motasemi F., Ani F.N., A review on microwave-assisted production of
biodiesel, Renewable and Sustainable Energy Reviews 16 (2012) 4719–
4733.
[9] Shahidi F., Bailey’s Industrial Oil and Fat Products, John Wiley & Sons,
2005, Sixth Edition.
[10] Dias, J.M., Araújo, J.M., Costa, J.F., Alvim-Ferraz, M.C.M., Almeida,
M.F. Biodiesel production from raw castor oil, Energy 53 (2013) 58 –
66.
[11] Akintayo E.T., Characteristics and composition of Parkia biglobbossa
and Jatropha curcas oils and cakes, Bioresource Technology 92 (2004)
307–310.
[12] Pimentel D., Patzek T.W., Ethanol Production Using Corn, Switch grass,
and Wood; Biodiesel Production Using Soybean and Sunflower, Natural
Resources Research 14 (2005) 65-76.
[13] Dias J.M., Alvim-Ferraz M.C.M., Almeida M.F., Production of biodiesel
from acid waste lard, Bioresource Technology 100 (2009) 6355 – 6361
[14] Salimon J., Abdullah R., Physicochemical Properties of Malaysian
Jatropha Curcas Seed Oil, Sain Malaysia 37 (2008) 379–382
[15] Encinar J.M., Gonzalez J.F., and Rodríguez-Reinares A., Biodiesel from
Used Frying Oil. Variables Affecting the Yields and Characteristics of
the Biodiesel, Industrial Engineering Chemical Resources 44 (2005)
5491–5499.
[16] Sarin A., Arora R., Singh N.P., Sharma M., Malhotra R.K., Influence of
metal contaminants on oxidation stability of Jatropha biodiesel, Energy
34 (2009) 1271–1275.
[17] Tang H., Wang A., Salley S.O., Simon Ng K.Y., The Effect of Natural
and Synthetic Antioxidants on the Oxidative Stability of Biodiesel,
Journal of the American Oil Chemists Society 85 (2008)373–382
[18] Dinkov R., Hristov G., Stratiev D., Aldayri V.B., Effect of commercially
available antioxidants over biodiesel/diesel blends stability, Fuel 88
(2009) 732–737.
[19] Knothe G., Some aspects of biodiesel oxidative stability, Fuel
Processing Technology 88 (2007) 669–677.
[20] Jain S., Sharma M.P., Stability of biodiesel and its blends: A review,
Renewable and Sustainable Energy Reviews 14 (2010) 667–678.
[1] IEA. U.S. Energy Information Administration. International Energy
Statistics - Biodiesel production.
[2] Renner A., Zelt T., Gerteiser S., From Aid to Market, the Global
Exchange for Social Investment, Global Market Study on Jatropha
(Final report-Abstract), Gexsi LLP, 2008.
[3] Barnwal S.K., Sharma M.P., Prospects of biodiesel production from
vegetable oils in India, Renewable and Sustainable Energy Reviews 9
(2004) 363–378. [4] Gui M.M., Lee K.T., Bhatia S., Feasibility of edible oil vs. non-edible
oil vs. waste edible oil as biodiesel feedstock, Energy 33 (2008) 1646 –
1653.
[5] Kiss A. A., Omota F., Dimian A.C., Rothenberg G., The heterogeneous
advantage: biodiesel by catalytic reactive distillation, Topics in Catalysis
40 (2006) 141–150.
[6] Tamunaidu P., Bhatia S., Catalytic cracking of palm oil for the
production of biofuels: Optimization studies, Bioresource Technology
98 (2007) 3593–3601.
[7] Prado C.M.R., Filho N.R.A., Production and characterization of the
biofuels obtained by thermal cracking and thermal catalytic cracking of
vegetable oils, Journal of Analytical and Applied Pyrolysis 86 (2009)
338–347.
[8] Motasemi F., Ani F.N., A review on microwave-assisted production of
biodiesel, Renewable and Sustainable Energy Reviews 16 (2012) 4719–
4733.
[9] Shahidi F., Bailey’s Industrial Oil and Fat Products, John Wiley & Sons,
2005, Sixth Edition.
[10] Dias, J.M., Araújo, J.M., Costa, J.F., Alvim-Ferraz, M.C.M., Almeida,
M.F. Biodiesel production from raw castor oil, Energy 53 (2013) 58 –
66.
[11] Akintayo E.T., Characteristics and composition of Parkia biglobbossa
and Jatropha curcas oils and cakes, Bioresource Technology 92 (2004)
307–310.
[12] Pimentel D., Patzek T.W., Ethanol Production Using Corn, Switch grass,
and Wood; Biodiesel Production Using Soybean and Sunflower, Natural
Resources Research 14 (2005) 65-76.
[13] Dias J.M., Alvim-Ferraz M.C.M., Almeida M.F., Production of biodiesel
from acid waste lard, Bioresource Technology 100 (2009) 6355 – 6361
[14] Salimon J., Abdullah R., Physicochemical Properties of Malaysian
Jatropha Curcas Seed Oil, Sain Malaysia 37 (2008) 379–382
[15] Encinar J.M., Gonzalez J.F., and Rodríguez-Reinares A., Biodiesel from
Used Frying Oil. Variables Affecting the Yields and Characteristics of
the Biodiesel, Industrial Engineering Chemical Resources 44 (2005)
5491–5499.
[16] Sarin A., Arora R., Singh N.P., Sharma M., Malhotra R.K., Influence of
metal contaminants on oxidation stability of Jatropha biodiesel, Energy
34 (2009) 1271–1275.
[17] Tang H., Wang A., Salley S.O., Simon Ng K.Y., The Effect of Natural
and Synthetic Antioxidants on the Oxidative Stability of Biodiesel,
Journal of the American Oil Chemists Society 85 (2008)373–382
[18] Dinkov R., Hristov G., Stratiev D., Aldayri V.B., Effect of commercially
available antioxidants over biodiesel/diesel blends stability, Fuel 88
(2009) 732–737.
[19] Knothe G., Some aspects of biodiesel oxidative stability, Fuel
Processing Technology 88 (2007) 669–677.
[20] Jain S., Sharma M.P., Stability of biodiesel and its blends: A review,
Renewable and Sustainable Energy Reviews 14 (2010) 667–678.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:70637", author = "Supriyono and Sumardiyono", title = "Influence of Synthetic Antioxidant in the Iodine Value and Acid Number of Jatropha Curcas Biodiesel", abstract = "Biodiesel is one of the alternative fuels that promising
for substituting petro diesel as energy source which is advantage on
sustainability and ecofriendly. Due to the raw material that tend to
decompose during storage, biodiesel also have the same characteristic
that tend to decompose and formed higher acid value which is the
result of oxidation to double bond on a chain of ester. Decomposition of biodiesel due to oxidation reaction could
prevent by introduce a small amount of antioxidant. The origin of raw
materials and the process for producing biodiesel will determine the
effectiveness of antioxidant. The quality degradation on biodiesel
could evaluate by measuring iodine value and acid number of
biodiesel. Biodiesel made from high fatty acid Jatropha curcas oil by using
esterification and transesterification process will stand on the quality
by introduce 90 ppm pyrogallol powder on the biodiesel, which could
increase Induction period time from 2 hours to more than 6 hours in
rancimat test evaluation.", keywords = "Acid value, antioxidant, biodiesel, iodine value.", volume = "9", number = "8", pages = "1018-4", }