Abstract: The synthesis of CuFe2O4 spinel powders by an
optimized combustion-like process followed by calcination is
described herein. The samples were characterized using X-ray
diffraction (XRD), differential thermal analysis (TG/DTA), scanning
electron microscopy (SEM), dilatometry and 4-probe DC methods.
Different glycine to nitrate (G/N) ratios of 1 (fuel-deficient), 1.48
(stoichiometric) and 2 (fuel-rich) were employed. Calcining the asprepared
powders at 800 and 1000°C for 5 hours showed that the G/N
ratio of 2 results in the formation of the desired copper spinel single
phase at both calcination temperatures. For G/N=1, formation of
CuFe2O4 takes place in three steps. First, iron and copper nitrates
decompose to iron oxide and pure copper. Then, copper transforms to
copper oxide and finally, copper and iron oxides react with each other
to form a copper ferrite spinel phase. The electrical conductivity and
the coefficient of thermal expansion of the sintered pelletized
samples were 2 S.cm-1 (800°C) and 11×10-6 °C-1 (25-800°C),
respectively.
Abstract: Polyaniline is an indispensible component in lightemitting
devices (LEDs), televisions, cellular telephones, automotive,
corrosion-resistant coatings, actuators etc. The electrical conductivity
properties was found be increased by introduction of metal nano
particles. In the present study, an attempt has been made to utilize
platinum nano particles to achieve the improved electrical properties.
Polyaniline and Pt-polyaniline composite are synthesized by
electrochemical routes. X-ray diffractometer confirms the amorphous
nature of polyaniline. The Bragg’s diffraction peaks correspond to
platinum nanoparticles in Pt-polyaniline composite and
thermogravimetric analyzer indicates its decomposition at certain
temperature. The Scanning Electron Micrographs of colloidal
platinum nanoparticles were spherical, uniform shape in the
composite. The current-voltage (I-V) characteristics of the PANI and
composites were also studied which indicate a significant decreasing
resistivity than PANI-Platinum after introduction of pt nanoparticles
in the matrix of polyaniline (PANI).
Abstract: In recent years, fire accidents have been steadily
increased and the amount of property damage caused by the accidents
has gradually raised. Damaging building structure, fire incidents bring
about not only such property damage but also strength degradation and
member deformation. As a result, the building structure undermines its
structural ability. Examining the degradation and the deformation is
very important because reusing the building is more economical than
reconstruction. Therefore, engineers need to investigate the strength
degradation and member deformation well, and make sure that they
apply right rehabilitation methods. This study aims at evaluating
deformation characteristics of fire damaged and rehabilitated normal
strength concrete beams through both experiments and finite element
analyses. For the experiments, control beams, fire damaged beams and
rehabilitated beams are tested to examine deformation characteristics.
Ten test beam specimens with compressive strength of 21MPa are
fabricated and main test variables are selected as cover thickness of
40mm and 50mm and fire exposure time of 1 hour or 2 hours. After
heating, fire damaged beams are air-recurred for 2 months and
rehabilitated beams are repaired with polymeric cement mortar after
being removed the fire damaged concrete cover. All beam specimens
are tested under four points loading. FE analyses are executed to
investigate the effects of main parameters applied to experimental
study. Test results show that both maximum load and stiffness of the
rehabilitated beams are higher than those of the fire damaged beams.
In addition, predicted structural behaviors from the analyses also show
good rehabilitation effect and the predicted load-deflection curves are
similar to the experimental results. For the further, the proposed
analytical method can be used to predict deformation characteristics of
fire damaged and rehabilitated concrete beams without suffering from
time and cost consuming of experimental process.
Abstract: Transparent nickel doped cobalt sulfide was fabricated
on a SnO2:F electrode and tested as an efficient electrocatalyst and as
an alternative to the expensive platinum counter electrode. In order to
investigate how this electrode could affect the electrical
characteristics of a dye-sensitized solar cell, we manufactured cells
with the same TiO2 photoanode sensitized with dye (N719) and
employing the same quasi-solid electrolyte, altering only the counter
electrode used. The cells were electrically and electrochemically
characterized and it was observed that the ones with the Ni doped
CoS2 outperformed the efficiency of the cells with the Pt counter
electrode (3.76% and 3.44% respectively). Particularly, the higher
efficiency of the cells with the Ni doped CoS2 counter electrode (CE)
is mainly because of the enhanced photocurrent density which is
attributed to the enhanced electrocatalytic ability of the CE and the
low charge transfer resistance at the CE/electrolyte interface.
Abstract: In this paper, we present a new segmentation approach
for liver lesions in regions of interest within MRI (Magnetic
Resonance Imaging). This approach, based on a two-cluster Fuzzy CMeans
methodology, considers the parameter variable compactness
to handle uncertainty. Fine boundaries are detected by a local
recursive merging of ambiguous pixels with a sequential forward
floating selection with Zernike moments. The method has been tested
on both synthetic and real images. When applied on synthetic images,
the proposed approach provides good performance, segmentations
obtained are accurate, their shape is consistent with the ground truth,
and the extracted information is reliable. The results obtained on MR
images confirm such observations. Our approach allows, even for
difficult cases of MR images, to extract a segmentation with good
performance in terms of accuracy and shape, which implies that the
geometry of the tumor is preserved for further clinical activities (such
as automatic extraction of pharmaco-kinetics properties, lesion
characterization, etc.).
Abstract: These Monolayer and multilayer coatings of CrN and
AlCrN deposited on 100Cr6 (AISI 52100) substrate by PVD
magnetron sputtering system. The microstructures of the coatings
were characterized using atomic force microscopy (AFM). The AFM
analysis revealed the presence of domes and craters that are
uniformly distributed over all surfaces of the various layers.
Nanoindentation measurement of CrN coating showed maximum
hardness (H) and modulus (E) of 14 GPa and 190 GPa, respectively.
The measured H and E values of AlCrN coatings were found to be 30
GPa and 382 GPa, respectively. The improved hardness in both the
coatings was attributed mainly to a reduction in crystallite size and
decrease in surface roughness. The incorporation of Al into the CrN
coatings has improved both hardness and Young’s modulus.
Abstract: This work presents an improved single fiber pull-out
test for fiber/matrix interface characterization. This test has been
used to study the Inter-Facial Shear Strength ‘IFSS’ of hemp fibers
reinforced polypropylene (PP). For this aim, the fiber diameter
has been carefully measured using a tomography inspired method.
The fiber section contour can then be approximated by a circle
or a polygon. The results show that the IFSS is overestimated if
the circular approximation is used. The Influence of the molding
temperature on the IFSS has also been studied. We find that a molding
temperature of 183◦C leads to better interfacial properties. Above or
below this temperature the interface strength is reduced.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: Artificial neural networks have gained a lot of interest
as empirical models for their powerful representational capacity,
multi input and output mapping characteristics. In fact, most feedforward
networks with nonlinear nodal functions have been proved to
be universal approximates. In this paper, we propose a new
supervised method for color image classification based on selforganizing
feature maps (SOFM). This algorithm is based on
competitive learning. The method partitions the input space using
self-organizing feature maps to introduce the concept of local
neighborhoods. Our image classification system entered into RGB
image. Experiments with simulated data showed that separability of
classes increased when increasing training time. In additional, the
result shows proposed algorithms are effective for color image
classification.
Abstract: It is necessary to predict a fatigue crack propagation
life for estimation of structural integrity. Because of an uncertainty
and a randomness of a structural behavior, it is also required to
analyze stochastic characteristics of the fatigue crack propagation life
at a specified fatigue crack size. The essential purpose of this study is to find the effect of load ratio
on probability distribution of the fatigue crack propagation life at a
specified grown crack size and to confirm the good probability
distribution in magnesium alloys under various fatigue load ratio
conditions. To investigate a stochastic crack growth behavior, fatigue
crack propagation experiments are performed in laboratory air under
several conditions of fatigue load ratio using AZ31. By Anderson-Darling test, a goodness-of-fit test for probability
distribution of the fatigue crack propagation life is performed. The
effect of load ratio on variability of fatigue crack propagation life is
also investigated.
Abstract: In present global scenario, aluminum alloys are
coining the attention of many innovators as competing structural
materials for automotive and space applications. Comparing to other
challenging alloys, especially, 7xxx series aluminum alloys have
been studied seriously because of benefits such as moderate strength;
better deforming characteristics and affordable cost. It is expected
that substitution of aluminum alloys for steels will result in great
improvements in energy economy, durability and recyclability.
However, it is necessary to improve the strength and the formability
levels at low temperatures in aluminum alloys for still better
applications. Aluminum–Zinc–Magnesium with or without other
wetting agent denoted as 7XXX series alloys are medium strength
heat treatable alloys. In addition to Zn, Mg as major alloying
additions, Cu, Mn and Si are the other solute elements which
contribute for the improvement in mechanical properties by suitable
heat treatment process. Subjecting to suitable treatments like age
hardening or cold deformation assisted heat treatments; known as low
temperature thermomechanical treatments (LTMT) the challenging
properties might be incorporated. T6 is the age hardening or
precipitation hardening process with artificial aging cycle whereas T8
comprises of LTMT treatment aged artificially with X% cold
deformation. When the cold deformation is provided after solution
treatment, there is increase in hardness related properties such as
wear resistance, yield and ultimate strength, toughness with the
expense of ductility. During precipitation hardening both hardness
and strength of the samples are increasing. The hardness value may
further improve when room temperature deformation is positively
supported with age hardening known as thermomechanical treatment.
It is intended to perform heat treatment and evaluate hardness, tensile
strength, wear resistance and distribution pattern of reinforcement in
the matrix. 2 to 2.5 and 3 to 3.5 times increase in hardness is reported
in age hardening and LTMT treatments respectively as compared to
as-cast composite. There was better distribution of reinforcements in
the matrix, nearly two fold increase in strength levels and up to 5
times increase in wear resistance are also observed in the present
study.
Abstract: In recent research copper and manganese systems
were found to be the most active in CO and organic compounds
oxidation among the base catalysts. The mixed copper manganese
oxide has been widely studied in oxidation reactions because of their
higher activity at low temperatures in comparison with single oxide
catalysts. The results showed that the formation of spinel
CuxMn3−xO4 in the oxidized catalyst is responsible for the activity
even at room temperature. That is why the most of the investigations
are focused on the hopcalite catalyst (CuMn2O4) as the best coppermanganese
catalyst. Now it’s known that this is true only for CO
oxidation, but not for mixture of CO and VOCs. The purpose of this
study is to investigate the alumina supported copper-manganese
catalysts with different Cu/Mn molar ratio in terms of oxidation of
CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of γ-Al2O3 with
copper and manganese nitrates and the catalytic activity
measurements were carried out in two stage continuous flow
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions closest possible to the industrial. Gas
mixtures on the input and output of the reactor were analyzed with a
gas chromatograph, equipped with FID and TCD detectors. The
texture characteristics were determined by low-temperature (- 196oС)
nitrogen adsorption in a Quantachrome Instruments NOVA 1200e
(USA) specific surface area & pore analyzer. Thermal, XRD and
TPR analyses were performed. It was established that the active component of the mixed Cu-
Mn/γ–alumina catalysts strongly depends on the Cu/Mn molar ratio.
Highly active alumina supported Cu-Mn catalysts for CO, methanol
and DME oxidation were synthesized. While the hopcalite is the best
catalyst for CO oxidation, the best compromise for simultaneous
oxidation of all components is the catalyst with Cu/Mn molar ratio
1:5.
Abstract: In this paper air quality conditions in Makkah and
Leeds are compared. These two cities have totally different climatic
conditions. Makkah climate is characterised as hot and dry (arid)
whereas that of Leeds is characterised as cold and wet (temperate).
This study uses air quality data from 2012 collected in Makkah,
Saudi Arabia and Leeds, UK. The concentrations of all pollutants,
except NO are higher in Makkah. Most notable, the concentrations of
PM10 are much higher in Makkah than in Leeds. This is probably due
to the arid nature of climatic conditions in Makkah and not solely due
to anthropogenic emission sources, otherwise like PM10 some of the
other pollutants, such as CO, NO, and SO2 would have shown much
greater difference between Leeds and Makkah. Correlation analysis is
performed between different pollutants at the same site and the same
pollutants at different sites. In Leeds the correlation between PM10
and other pollutants is significantly stronger than in Makkah. Weaker
correlation in Makkah is probably due to the fact that in Makkah
most of the gaseous pollutants are emitted by combustion processes,
whereas most of the PM10 is generated by other sources, such as
windblown dust, re-suspension, and construction activities. This is in
contrast to Leeds where all pollutants including PM10 are
predominantly emitted by combustions, such as road traffic.
Furthermore, in Leeds frequent rains wash out most of the
atmospheric particulate matter and suppress re-suspension of dust.
Temporal trends of various pollutants are compared and discussed.
This study emphasises the role of climatic conditions in managing air
quality, and hence the need for region-specific controlling strategies
according to the local climatic and meteorological conditions.
Abstract: This paper aims to project the construction of a
prototype azimuthal thruster, mounted with materials of low cost and
easy access, testing in a controlled environment to measure their
performance, characteristics and feasibility of future projects. The
construction of the simulation of dynamic positioning software,
responsible for simulating a vessel and reposition it when necessary.
Validation tests were performed in the form of partial or complete
system. These tests validate the system manually or automatically.
The system provides an interface to the user and simulates the
conditions unfavorable positioning of a vessel, accurately calculates
the azimuth angle, the direction of rotation of the helix and the time
that this should be turned on so that the vessel back to position
original. A serial communication connects the Simulation Dynamic
Positioning System with Embedded System causing the usergenerated
data to simulate the DP system arrives in the form of
control signals to the motors of the propellant. This article addresses
issues in the marine industry employees.
Abstract: In light of the technological development and its
introduction into the field of education, an online course was
designed in parallel to the 'conventional' course for teaching the
''Qualitative Research Methods''. This course aimed to characterize
learning-teaching processes in a 'Qualitative Research Methods'
course studied in two different frameworks. Moreover, its objective
was to explore the difference between the culture of a physical
learning environment and that of online learning. The research
monitored four learner groups, a total of 72 students, for two years,
two groups from the two course frameworks each year. The courses
were obligatory for M.Ed. students at an academic college of
education and were given by one female-lecturer. The research was
conducted in the qualitative method as a case study in order to attain
insights about occurrences in the actual contexts and sites in which
they transpire. The research tools were open-ended questionnaire and
reflections in the form of vignettes (meaningful short pictures) to all
students as well as an interview with the lecturer. The tools facilitated
not only triangulation but also collecting data consisting of voices
and pictures of teaching and learning. The most prominent findings
are: differences between the two courses in the change features of the
learning environment culture for the acquisition of contents and
qualitative research tools. They were manifested by teaching
methods, illustration aids, lecturer's profile and students' profile.
Abstract: This study suggests the estimation method of stress
distribution for the beam structures based on TLS (Terrestrial Laser
Scanning). The main components of method are the creation of the
lattices of raw data from TLS to satisfy the suitable condition and
application of CSSI (Cubic Smoothing Spline Interpolation) for
estimating stress distribution. Estimation of stress distribution for the
structural member or the whole structure is one of the important
factors for safety evaluation of the structure. Existing sensors which
include ESG (Electric strain gauge) and LVDT (Linear Variable
Differential Transformer) can be categorized as contact type sensor
which should be installed on the structural members and also there are
various limitations such as the need of separate space where the
network cables are installed and the difficulty of access for sensor
installation in real buildings. To overcome these problems inherent in
the contact type sensors, TLS system of LiDAR (light detection and
ranging), which can measure the displacement of a target in a long
range without the influence of surrounding environment and also get
the whole shape of the structure, has been applied to the field of
structural health monitoring. The important characteristic of TLS
measuring is a formation of point clouds which has many points
including the local coordinate. Point clouds are not linear distribution
but dispersed shape. Thus, to analyze point clouds, the interpolation is
needed vitally. Through formation of averaged lattices and CSSI for
the raw data, the method which can estimate the displacement of
simple beam was developed. Also, the developed method can be
extended to calculate the strain and finally applicable to estimate a
stress distribution of a structural member. To verify the validity of the
method, the loading test on a simple beam was conducted and TLS
measured it. Through a comparison of the estimated stress and
reference stress, the validity of the method is confirmed.
Abstract: While choosing insulating oil, characteristic features
such as thermal cooling, endurance, efficiency and being
environment-friendly should be considered. Mineral oils are referred
as petroleum-based oil. In this study, vegetable oils investigated as an
alternative insulating liquid to mineral oil. Dissipation factor,
breakdown voltage, relative dielectric constant and resistivity
changes with the frequency and voltage of mineral, rapeseed and nut
oils were measured. Experimental studies were performed according
to ASTM D924 and IEC 60156 standards.
Abstract: This study aims to evaluate the effective size, section
and structural characteristics of circular hollow steel (CHS) damper.
CHS damper is among steel dampers which are used widely for
seismic energy dissipation because they are easy to install, maintain
and are inexpensive. CHS damper dissipates seismic energy through
metallic deformation due to the geometrical elasticity of circular shape
and fatigue resistance around connection part. After calculating the
effective size, which is found to be height to diameter ratio of √3,
nonlinear FE analyses were carried out to evaluate the structural
characteristics and effective section (diameter-to-ratio).
Abstract: The reduction of phosphorus and sulfur in engine oil
are the main topics of this paper. Very reproducible boundary
lubrication tests were conducted as part of Design of Experiment
software (DOE) to study the behavior of fluorinated catalyst iron
fluoride (FeF3), and polutetrafluoroethylene or Teflon (PTFE) in
developing environmentally friendly (reduced P and S) anti-wear
additives for future engine oil formulations. Multi-component
Chevron fully formulated oil (GF3) and Chevron plain oil were used
with the addition of PTFE and catalyst to characterize and analyze
their performance. Lower phosphorus blends were the goal of the
model solution. Experiments indicated that new sub-micron FeF3
catalyst played an important role in preventing breakdown of the
tribofilm.
Abstract: The main objective of this study was to determine the
effects of Nitrogen fixing bacteria and manure application on the seed
yield and yield components in black cumin (Nigella sativa L.). The
experiment was carried out at the RAN Research Station in
Firouzkouh in 2012. A 4×4 factorial experiment, arranged in a
randomized complete blocks designed with three replications.
Nitrogen fixing bacteria at 4 levels (control, Azotobacter,
Azospirillum and Azotobacter + Azospirillum) and manure
application at 4 levels (0, 2.5, 5 and 7.5 ton ha-1) were used at this
investigation. The present results have shown that the highest height,
1000 seeds weight, seed number per follicle, follicle yield, seed yield
and harvest index were obtained after using Azotobacter and
Azospirillum, simultaneously. Manure application only effects on
follicle yield and by 5ton manure ha-1 the highest follicle yield
obtained. Results of this investigation showed that the maximum seed
yield obtained when Aotobacter+Azospirillum inoculated with black
cumin seeds and 5 ton manure ha-1 applied. According to the results
of this investigation the integrated management of Azotobacter and
Azospirillum with manure application is the best treatment for
achieving the maximum quantitative charactersitics of Black cumin.