Abstract: Sodium formate is the chemical substance used for
food additive. Catalase is the important antioxidative enzyme in
protecting the cell from oxidative damage by reactive oxygen species
(ROS). The resultant level of oxidative stress in sodium formatetreated
lymphocytes was investigated. The sodium formate
concentrations of 0.05, 0.1, 0.2, 0.4 and 0.6 mg/mL were treated in
human lymphocytes for 12 hours. After 12 treated hours, catalase
activity change was measured in sodium formate-treated
lymphocytes. The results showed that the sodium formate
concentrations of 0.4 and 0.6 mg/mL significantly decreased catalase
activities in lymphocytes (P < 0.05). The change of catalase activity
in sodium formate-treated lymphocytes may be the oxidative damage
marker for detect sodium formate exposure in human.
Abstract: This paper presents results of compressive strength,
capillary water absorption, and density tests conducted on concrete
containing recycled aggregate (RCA) which is obtained from
structural waste generated by the construction industry in Turkey. In
the experiments, 0%, 15%, 30%, 45% and 60% of the normal
(natural) coarse aggregate was replaced by the recycled aggregate.
Maximum aggregate particle sizes were selected as 16 mm, 22,4 mm
and 31,5 mm; and 0,06%, 0,13% and 0,20% of air-entraining agent
(AEA) were used in mixtures. Fly ash and superplasticizer were used
as a mineral and chemical admixture, respectively. The same type
(CEM I 42.5) and constant dosage of cement were used in the study.
Water/cement ratio was kept constant as 0.53 for all mixture. It was
concluded that capillary water absorption, compressive strength, and
density of concrete decreased with increasing RCA ratio. Increasing
in maximum aggregate particle size and amount of AEA also affect
the properties of concrete significantly.
Abstract: Due to the resultant leachate from waste
decomposition in landfills has polluter potential hundred times
greater than domestic sewage, this is considered a problem related to
the depreciation of environment requiring pre-disposal treatment.In
seeking to improve this situation, this project proposes the treatment
of landfill leachate using natural fibers intercropped with advanced
oxidation processes. The selected natural fibers were palm, coconut
and banana fiber.These materials give sustainability to the project
because, besides having adsorbent capacity, are often part of waste
discarded. The study was conducted in laboratory scale.In trials, the
effluents were characterized as Chemical Oxygen Demand (COD),
Turbidity and Color. The results indicate that is technically
promising since that there were extremely oxidative conditions, the
use of certain natural fibers in the reduction of pollutants in leachate
have been obtained results of COD removals between 67.9% and
90.9%, Turbidity between 88.0% and 99.7% and Color between
67.4% and 90.4%.The expectation generated is to continue evaluating
the association of efficiency of other natural fibers with other landfill
leachate treatment processes.
Abstract: A comparison of activity and stability of the as-formed
Pt/C, Pt-Co and Pt-Pd/C electrocatalysts, prepared by a combined
approach of impregnation and seeding, was performed. According to
the activity test in a single Proton Exchange Membrane (PEM) fuel
cell, the Oxygen Reduction Reaction (ORR) activity of the Pt-M/C
electrocatalyst was slightly lower than that of Pt/C. The j0.9 V and
E10 mA/cm2 of the as-prepared electrocatalysts increased in the order of
Pt/C > Pt-Co/C > Pt-Pd/C. However, in the medium-to-high current
density region, Pt-Pd/C exhibited the best performance. With regard to
their stability in a 0.5 M H2SO4 electrolyte solution, the
electrochemical surface area decreased as the number of rounds of
repetitive potential cycling increased due to the dissolution of the
metals within the catalyst structure. For long-term measurement, Pt-
Pd/C was the most stable than the other three electrocatalysts.
Abstract: This work studies the effect of chemical composition
on the activity and selectivity of γ–alumina supported CuO/
MnO2/Cr2O3 catalysts toward deep oxidation of CO, dimethyl ether
(DME) and methanol. The catalysts were prepared by impregnation
of the support with an aqueous solution of copper nitrate, manganese
nitrate and CrO3 under different conditions. Thermal, XRD and TPR
analysis were performed. The catalytic measurements of single
compounds oxidation were carried out on continuous flow equipment
with a four-channel isothermal stainless steel reactor. Flow-line
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions that mimic closely the industrial
ones was used. The reactant and product gases were analyzed by
means of on-line gas chromatographs.
On the basis of XRD analysis it can be concluded that the active
component of the mixed Cu-Mn-Cr/γ–alumina catalysts consists of at
least six compounds – CuO, Cr2O3, MnO2, Cu1.5Mn1.5O4,
Cu1.5Cr1.5O4 and CuCr2O4, depending on the Cu/Mn/Cr molar ratio.
Chemical composition strongly influences catalytic properties, this
influence being quite variable with regards to the different processes.
The rate of CO oxidation rapidly decrease with increasing of
chromium content in the active component while for the DME was
observed the reverse trend. It was concluded that the best
compromise are the catalysts with Cu/(Mn + Cr) molar ratio 1:5 and
Mn/Cr molar ratio from 1:3 to 1:4.
Abstract: In this work new macroporous Ni electrodes modified
with Au nanoparticles for hydrogen production have been developed.
The supporting macroporous Ni electrodes have been obtained by
means of the electrodeposition at high current densities. Then, the Au
nanoparticles were synthesized and added to the electrode surface.
The electrocatalytic behaviour of the developed electrocatalysts was
studied by means of pseudo-steady-state polarization curves,
electrochemical impedance spectroscopy (EIS) and hydrogen
discharge curves. The size of the Au synthetized nanoparticles shows
a monomodal distribution, with a very sharp band between 10 and 50
nm. The characteristic parameters d10, d50 and d90 were 14, 20 and
31 nm respectively. From Tafel polarization data has been concluded
that the Au nanoparticles improve the catalytic activity of the
developed electrodes towards the HER respect to the macroporous Ni
electrodes. EIS permits to obtain the electrochemically active area by
means of the roughness factor value. All the developed electrodes
show roughness factor values in the same order of magnitude. From
the activation energy results it can be concluded that the Au
nanoparticles improve the intrinsic catalytic activity of the
macroporous Ni electrodes.
Abstract: Mobil Producing Nigeria Unlimited (MPNU), a
subsidiary of ExxonMobil and the highest crude oil & condensate
producer in Nigeria has its operational base and an oil terminal, the
Qua Iboe terminal (QIT) located at Ibeno, Nigeria. Other oil
companies like Network Exploration and Production Nigeria Ltd,
Frontier Oil Ltd; Shell Petroleum Development Company Ltd; Elf
Petroleum Nigeria Ltd and Nigerian Agip Energy, a subsidiary of the
Italian ENI E&P operate onshore, on the continental shelf and in deep
offshore of the Atlantic Ocean, respectively with the coastal waters of
Ibeno, Nigeria as the nearest shoreline. This study was designed to
delineate the oil-polluted sites in Ibeno, Nigeria using
microbiological and physico-chemical characterization of soils,
sediments and ground and surface water samples from the study area.
Results obtained revealed that there have been significant recent
hydrocarbon inputs into this environment as observed from the high
counts of hydrocarbonoclastic microorganisms in excess of 1% at all
the stations sampled. Moreover, high concentrations of THC, BTEX
and heavy metals contents in all the samples analyzed corroborate the
high recent crude oil input into the study area. The results also
showed that the pollution of the different environmental media
sampled were of varying degrees, following the trend: ground water
> surface water > sediments > soils.
Abstract: Rice bran is normally used as a raw material for rice
bran oil production or sold as feed with a low price. Conventionally,
the protein in defatted rice bran was extracted using alkaline
extraction and acid precipitation, which involves in chemical usage
and lowering some nutritious component. This study was conducted
in order to extract of rice bran protein concentrate (RBPC) from
defatted rice bran using enzymes and employing polysaccharides in a
precipitating step. The properties of RBPC obtained will be compared
to those of a control sample extracted using a conventional method.
The results showed that extraction of protein from rice bran using
enzymes exhibited the higher protein recovery compared to that
extraction with alkaline. The extraction conditions using alcalase 2%
(v/w) at 50 C, pH 9.5 gave the highest protein (2.44%) and yield
(32.09%) in extracted solution compared to other enzymes. Rice bran
protein concentrate powder prepared by a precipitation step using
alginate (protein in solution: alginate 1:0.016) exhibited the highest
protein (27.55%) and yield (6.84%). Precipitation using alginate was
better than that of acid. RBPC extracted with alkaline (ALK) or
enzyme alcalase (ALC), then precipitated with alginate (AL)
(samples RBP-ALK-AL and RBP-ALC-AL) yielded the precipitation
rate of 75% and 91.30%, respectively. Therefore, protein
precipitation using alginate was then selected. Amino acid profile of
control sample, and sample precipitated with alginate, as compared to
casein and soy protein isolated, showed that control sample showed
the highest content among all sample. Functional property study of
RBP showed that the highest nitrogen solubility occurred in pH 8-10.
There was no statically significant between emulsion capacity and
emulsion stability of control and sample precipitated by alginate.
However, control sample showed a higher of foaming capacity and
foaming stability compared to those of sample precipitated with
alginate. The finding was successful in terms of minimizing
chemicals used in extraction and precipitation steps in preparation of
rice bran protein concentrate. This research involves in a production
of value-added product in which the double amount of protein (28%)
compared to original amount (14%) contained in rice bran could be
beneficial in terms of adding to food products e.g. healthy drink with
high protein and fiber. In addition, the basic knowledge of functional
property of rice bran protein concentrate was obtained, which can be
used to appropriately select the application of this value-added
product from rice bran.
Abstract: Continuous upflow filters can combine the nutrient
(nitrogen and phosphate) and suspended solid removal in one unit
process. The contaminant removal could be achieved chemically or
biologically; in both processes the filter removal efficiency depends
on the interaction between the packed filter media and the influent. In
this paper a residence time distribution (RTD) study was carried out
to understand and compare the transfer behaviour of contaminants
through a selected filter media packed in a laboratory-scale
continuous up flow filter; the selected filter media are limestone and
white dolomite. The experimental work was conducted by injecting a
tracer (red drain dye tracer –RDD) into the filtration system and then
measuring the tracer concentration at the outflow as a function of
time; the tracer injection was applied at hydraulic loading rates
(HLRs) (3.8 to 15.2 m h-1). The results were analysed according to
the cumulative distribution function F(t) to estimate the residence
time of the tracer molecules inside the filter media. The mean
residence time (MRT) and variance σ2 are two moments of RTD that
were calculated to compare the RTD characteristics of limestone with
white dolomite. The results showed that the exit-age distribution of
the tracer looks better at HLRs (3.8 to 7.6 m h-1) and (3.8 m h-1) for
limestone and white dolomite respectively. At these HLRs the
cumulative distribution function F(t) revealed that the residence time
of the tracer inside the limestone was longer than in the white
dolomite; whereas all the tracer took 8 minutes to leave the white
dolomite at 3.8 m h-1. On the other hand, the same amount of the
tracer took 10 minutes to leave the limestone at the same HLR. In
conclusion, the determination of the optimal level of hydraulic
loading rate, which achieved the better influent distribution over the
filtration system, helps to identify the applicability of the material as
filter media. Further work will be applied to examine the efficiency
of the limestone and white dolomite for phosphate removal by
pumping a phosphate solution into the filter at HLRs (3.8 to 7.6 m h-1).
Abstract: In recent years a new method of combination
treatment for cancer has been developed and studied that has led to
significant advancements in the field of cancer therapy. Hyperthermia
is a traditional therapy that, along with a creation of a medically
approved level of heat with the help of an alternating magnetic AC
current, results in the destruction of cancer cells by heat. This paper
gives details regarding the production of the spherical nanocomposite
PVA/γ-Fe2O3 in order to be used for medical purposes such as tumor
treatment by hyperthermia. To reach a suitable and evenly distributed
temperature, the nanocomposite with core-shell morphology and
spherical form within a 100 to 200 nanometer size was created using
phase separation emulsion, in which the magnetic nano-particles γ-
Fe2O3 with an average particle size of 20 nano-meters and with
different percentages of 0.2, 0.4, 0.5 and 0.6 were covered by
polyvinyl alcohol. The main concern in hyperthermia and heat
treatment is achieving desirable specific absorption rate (SAR) and
one of the most critical factors in SAR is particle size. In this project
all attempts has been done to reach minimal size and consequently
maximum SAR. The morphological analysis of the spherical
structure of the nanocomposite PVA/γ-Fe2O3 was achieved by SEM
analyses and the study of the chemical bonds created was made
possible by FTIR analysis. To investigate the manner of magnetic
nanocomposite particle size distribution a DLS experiment was
conducted. Moreover, to determine the magnetic behavior of the γ-
Fe2O3 particle and the nanocomposite PVA/γ-Fe2O3 in different
concentrations a VSM test was conducted. To sum up, creating
magnetic nanocomposites with a spherical morphology that would be
employed for drug loading opens doors to new approaches in
developing nanocomposites that provide efficient heat and a
controlled release of drug simultaneously inside the magnetic field,
which are among their positive characteristics that could significantly
improve the recovery process in patients.
Abstract: The Figaro AM-1 sensor module which employs TGS
2600 model gas sensor in air quality assessment was used. The
system was coupled with a microprocessor that enables sensor
module to create warning message via telephone. This low cot sensor
system’s performance was compared with a DiagNose II commercial
electronic nose system. Both air quality sensor and electronic nose
system employ metal oxide chemical gas sensors. In the study
experimental setup, data acquisition methods for electronic nose
system, and performance of the low cost air quality system were
evaluated and explained.
Abstract: This study aimed to determine the possible protective effects of L‐carnitine against gentamicin‐induced nephrotoxicity. Forty male albino rats were divided into 4 groups (10 rats each); Group 1: normal control, group 2: induced nephrotoxicity (gentamicin 50 mg/kg/day S.C; 8 days), group 3: treated with L‐ carnitine (40 mg/kg/d SC for 12 days) and group 4: treated with L‐ carnitine 4 days before and for 8 days in concomitant with gentamicin. Gentamicin‐induced nephrotoxicity (group 2): caused significant increase in serum urea, creatinine, urinary N‐acetyl‐B‐D‐ glucosaminidase (NAG), gamma glutamyl transpeptidase (GGT), urinary total protein and kidney tissue malondialdehyde (MDA) with significant decrease in serum superoxide dismutase (SOD), serum catalase and creatinine clearance and marked tubular necrosis in the proximal convoluted tubules with interruption in the basement membrane around the necrotic tubule compared to the normal control group. L‐carnitine 4 days before and for 8 days in concomitant with gentamicin (group 4) offered marked decrease in serum urea, serum creatinine, urinary NAG, urinary GGT, urinary proteins and kidney tissue MDA, with marked increase in serum SOD, serum catalase and creatinine clearance with marked improvement in the tubular damage compared to gentamicin‐induced nephrotoxicity group. L‐carnitine administered for 12 days produced no change in the parameters mentioned above as compared to the normal control group. In conclusion: L‐carnitine could reduce most of the biochemical parameters and also improve the histopathological features of kidney asscociated with gentamicin induced‐nephrotoxicity.
Abstract: Experimental investigations of the DC electric field effect on thermal decomposition of biomass, formation of the axial flow of volatiles (CO, H2, CxHy), mixing of volatiles with swirling airflow at low swirl intensity (S ≈ 0.2-0.35), their ignition and on formation of combustion dynamics are carried out with the aim to understand the mechanism of electric field influence on biomass gasification, combustion of volatiles and heat energy production. The DC electric field effect on combustion dynamics was studied by varying the positive bias voltage of the central electrode from 0.6 kV to 3 kV, whereas the ion current was limited to 2 mA. The results of experimental investigations confirm the field-enhanced biomass gasification with enhanced release of volatiles and the development of endothermic processes at the primary stage of thermochemical conversion of biomass determining the field-enhanced heat energy consumption with the correlating decrease of the flame temperature and heat energy production at this stage of flame formation. Further, the field-enhanced radial expansion of the flame reaction zone correlates with a more complete combustion of volatiles increasing the combustion efficiency by 3% and decreasing the mass fraction of CO, H2 and CxHy in the products, whereas by 10% increases the average volume fraction of CO2 and the heat energy production downstream the combustor increases by 5-10%
Abstract: The crude methanol extracts of five indigenous vegetables namely, Amarathus tricolor, Basella rubra L., Chochurus olitorius L., Ipomea batatas, and Momordica chuchinensis L., were examined for their phytochemical profile and antioxidant activity using 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical. The values for DPPH radical scavenging activity ranged from 7.6-89.53% with B. rubra and I. batatas having the lowest and highest values, respectively. The total flavonoid content of all five indigenous vegetables ranged from 74.65-277.3 mg quercetin equivalent per gram of dried vegetable material while the total phenolic content ranged from 1.93-6.15 mg gallic acid equivalent per gram dried material. Phytochemical screening revealed the presence of steroids, flavonoids, saponins, tannins, carbohydrates and reducing sugars, which may also be associated with the antioxidant activity shown by these indigenous vegetables.
Abstract: The aim of this investigation is to elaborate nearinfrared
methods for testing and recognition of chemical components
and quality in “Pannon wheat” allied (i.e. true to variety or variety
identified) milling fractions as well as to develop spectroscopic
methods following the milling processes and evaluate the stability of
the milling technology by different types of milling products and
according to sampling times, respectively. These wheat categories
produced under industrial conditions where samples were collected
versus sampling time and maximum or minimum yields. The changes
of the main chemical components (such as starch, protein, lipid) and
physical properties of fractions (particle size) were analysed by
dispersive spectrophotometers using visible (VIS) and near-infrared
(NIR) regions of the electromagnetic radiation. Close correlation
were obtained between the data of spectroscopic measurement
techniques processed by various chemometric methods (e.g. principal
component analysis [PCA], cluster analysis [CA]) and operation
condition of milling technology. It is obvious that NIR methods are
able to detect the deviation of the yield parameters and differences of
the sampling times by a wide variety of fractions, respectively. NIR
technology can be used in the sensitive monitoring of milling
technology.
Abstract: In this study, we demonstrate the production of natural gas hydrates from permeable marine sediments with simultaneous mechanisms for methane recovery and methane-air or methane-air/carbon dioxide replacement. The simultaneous melting happens until the chemical potentials become equal in both phases as natural gas hydrate depletion continues and self-regulated methane-air replacement occurs over an arbitrary point. We observed certain point between dissociation and replacement mechanisms in the natural gas hydrate reservoir, and we call this boundary as critical methane concentration. By the way, when carbon dioxide was added, the process of chemical exchange of methane by air/carbon dioxide was observed in the natural gas hydrate. The suggested process will operate well for most global natural gas hydrate reservoirs, regardless of the operating conditions or geometrical constraints.
Abstract: Encapsulated O-rings are specifically designed to address the problem of sealing the most hostile chemicals and extreme temperature applications. Ultrasonic vibration hot embossing and ultrasonic welding techniques provide a fast and reliable method to fabricate encapsulated O-ring. This paper performs the design and analysis method of the acoustic horns with double extrusion to process tube double side flange simultaneously. The paper deals with study through Finite Element Method (FEM) of ultrasonic stepped horn used to process a capsulated O-ring, the theoretical dimensions of horns, and their natural frequencies and amplitudes are obtained through the simulations of COMOSOL software. Furthermore, real horns were fabricated, tested and verified to proof the practical utility of these horns.
Abstract: A dip-coating process has been used to form an
asymmetric silica membrane with improved membrane performance
and reproducibility. First, we deposited repeatedly silica on top of a
commercial alumina membrane support to improve its structural
make up. The membrane is further processed under clean room
conditions to avoid dust impurity and subsequent drying in an oven
for high thermal, chemical and physical stability. The resulting
asymmetric membrane exhibits a gradual change in the membrane
layer thickness. Compared to the support, the dual-layer process
improves the gas flow rates. For the scientific applications for natural
gas purification, CO2, CH4 and H2 gas flow rates were. In addition,
the membrane selectively separated hydrogen.
Abstract: Biomass briquette gasification is regarded as a
promising route for efficient briquette use in energy generation, fuels
and other useful chemicals. However, previous research has been
focused on briquette gasification in fixed bed gasifiers such as
updraft and downdraft gasifiers. Fluidised bed gasifier has the
potential to be effectively sized to medium or large scale. This study
investigated the use of fuel briquettes produced from blends of rice
husks and corn cobs biomass, in a bubbling fluidised bed gasifier.
The study adopted a combination of numerical equations and Aspen
Plus simulation software, to predict the product gas (syngas)
composition base on briquette density and biomass composition
(blend ratio of rice husks to corn cobs). The Aspen Plus model was
based on an experimentally validated model from the literature. The
results based on a briquette size 32 mm diameter and relaxed density
range of 500 to 650kg/m3, indicated that fluidisation air required in
the gasifier increased with increase in briquette density, and the
fluidisation air showed to be the controlling factor compared with the
actual air required for gasification of the biomass briquettes. The
mass flowrate of CO2 in the predicted syngas composition increased
with an increase in air flow, in the gasifier, while CO decreased and
H2 was almost constant. The ratio of H2 to CO for various blends of
rice husks and corn cobs did not significantly change at the designed
process air, but a significant difference of 1.0 was observed between
10/90 and 90/10 % blend of rice husks and corn cobs.
Abstract: It is the worldwide problem that the recycled PVB is
not recycled and it is wildly stored in landfills. However, PVB has
similar chemical properties such as PVC. Moreover, both of these
polymers are plasticized. Therefore, the study of thermal properties
of plasticized PVC and the recycled PVB obtained by recycling of
windshields is carried out. This work has done in order to find nondegradable
processing conditions applicable for both polymers.
Tested PVC contained 38% of plasticizer diisononyl phthalate
(DINP) and PVB was plasticized with 28% of triethylene glycol,
bis(2-ethylhexanoate) (3GO). The thermal and thermo-oxidative
decomposition of both vinyl polymers are compared by calorimetric
analysis and by tensile strength analysis.