Abstract: Ulexite (Na2O.2CaO.5B2O3.16H2O) is boron mineral
that is found in large quantities in the Turkey and world. In this
study, the dissolution of this mineral in the disodium hydrogen
phosphate solutions has been studied. Temperature, concentration,
stirring speed, solid liquid ratio and particle size were selected as
parameters. The experimental results were successfully correlated by
linear regression using Statistica program. Dissolution curves were
evaluated shrinking core models for solid-fluid systems. It was
observed that increase in the reaction temperature and decrease in the
solid/liquid ratio causes an increase the dissolution rate of ulexite.
The activation energy was found to be 63.4 kJ/mol. The leaching of
ulexite was controlled by chemical reaction.
Abstract: In the present work, Electrochemical Impedance
Spectrocopy (EIS) is applied to study the transport of different metal
cations through a cation-exchange membrane. This technique enables
the identification of the ionic-transport characteristics and to
distinguish between different transport mechanisms occurring at
different current density ranges. The impedance spectra are
dependent on the applied dc current density, on the type of cation and
on the concentration.
When the applied dc current density increases, the diameter of the
impedance spectra loops increases because all the components of
membrane system resistance increase. The diameter of the impedance
plots decreases in the order of Na(I), Ni(II) and Cr(III) due to the
increased interactions between the negatively charged sulfonic
groups of the membrane and the cations with greater charge. Nyquist
plots are shifted towards lower values of the real impedance, and its
diameter decreases with the increase of concentration due to the
decrease of the solution resistance.
Abstract: Coal fly ash is formed as a solid waste product from
the combustion of coal in coal fired power stations. Huge amounts of
fly ash are produced globally every year and are predicted to
increase. Nowadays, less than half of the fly ash is used as a raw
material for cement manufacturing, construction and the rest of it is
disposed as a waste causing yet another environmental concern. For
this reason, the recycling of this kind of slurries into useful materials
is quite important in terms of economical and environmental aspects.
The purpose of this study is to evaluate the Orhaneli and
Tuncbilek coal fly ashes for utilization in some industrial
applications. Therefore the mineralogical and chemical compositions
of these fly ashes were analyzed by X-ray fluorescence spectroscopy,
ourier-transform infrared spectrometer, and X-ray diffraction. The
silicon (Si) and aluminum (Al) in the fly ashes were activated by
alkali fusion technique with sodium hydroxide. The obtained extracts
were analyzed for Si and Al content by inductively coupled plasma
optical emission spectrometry.
Abstract: This study was carried out to investigate the adverse
effect of industrial wastewater on surface water quality in Gebeng
industrial estate, Pahang, Malaysia. Surface water was collected from
six sampling stations. Physicochemical parameters were
characterized based on in-situ and ex-situ analysis according to
standard methods by American Public Health Association (APHA).
Selected heavy metals were determined by using Inductively Coupled
Plasma Mass Spectrometry (ICP MS). The results revealed that the
concentration of heavy metals such as Pb, Cu, Cd, Cr and Hg were
high in samples. The results also showed that the value of Pb and Hg
were higher in the wet season in comparison to dry season.
According to Malaysia National Water Quality Standard (NWQS)
and Water Quality Index (WQI) all the sampling station were
categorized as class IV (highly polluted). The present study revealed
that the adverse effects of careless disposal of wastes and directly
discharge of effluents affected on surface water quality. Therefore,
the authorities should implement the laws to ensure the proper
practices of wastewater management for environmental sustainability
around the study area.
Abstract: Chrome tannery wastewater causes serious environmental hazard due to its high pollution potential. As a result, rigorous treatment is necessary for abatement of pollution from this type of wastewater. There are many research studies on chrome tannery wastewater treatment in the field of physical, chemical, and biological methods. In general, biological treatment process is found ineffective for direct application because of adverse effects by toxic chromium, sulphide, chloride etc. However, biological methods were employed mainly for a few sub processes generating significant amount of organic matter and without chromium, chlorides etc. In this context the present paper reviews the characteristics feature and pollution potential of wastewater generated from chrome tannery units and treatment of the same. The different biological processes used earlier and their chronological development for treatment of the chrome tannery wastewater are thoroughly reviewed in this paper. In this regard, the scope of hybrid bioreactor - an advanced technology option has also been explored, as this kind of treatment is well suited for the wastewater having inhibitory substances.
Abstract: In this paper static scheme of under-frequency based load shedding is considered for chemical and petrochemical industries with islanded distribution networks relying heavily on the primary commodity to ensure minimum production loss, plant downtime or critical equipment shutdown. A simplistic methodology is proposed for in-house implementation of this scheme using underfrequency relays and a step by step guide is provided including the techniques to calculate maximum percentage overloads, frequency decay rates, time based frequency response and frequency based time response of the system. Case study of FFL electrical system is utilized, presenting the actual system parameters and employed load shedding settings following the similar series of steps. The arbitrary settings are then verified for worst overload conditions (loss of a generation source in this case) and comprehensive system response is then investigated.
Abstract: Lignocellolusic material is a substance that is resistant to be degraded by microorganisms or hydrolysis enzymes. To be used as materials for biofuel production, it needs pretreatment process to improve efficiency of hydrolysis. In this work, chemical pretreatments on rice straw using three diluted organic acids, including acetic acid, citric acid, oxalic acid, were optimized. Using Response Surface Methodology (RSM), the effect of three pretreatment parameters, acid concentration, treatment time, and reaction temperature, on pretreatment efficiency were statistically evaluated. The results indicated that dilute oxalic acid pretreatment led to the highest enhancement of enzymatic saccharification by commercial cellulase and yielded sugar up to 10.67 mg/ml when using 5.04% oxalic acid at 137.11 oC for 30.01 min. Compared to other acid pretreatment by acetic acid, citric acid, and hydrochloric acid, the maximum sugar yields are 7.07, 6.30, and 8.53 mg/ml, respectively. Here, it was demonstrated that organic acids can be used for pretreatment of lignocellulosic materials to enhance of hydrolysis process, which could be integrated to other applications for various biorefinery processes.
Abstract: The paper is focused on the identification of limiting
environmental factors of individual industrial floors on which newly
developed polymer protection and repair systems with the use of
secondary raw materials will be used. These mainly include floors
with extreme stresses and special requirements for materials used. In
relation to the environment of a particular industrial floor, it is
necessary to ensure, for example, chemical stability, resistance to
higher temperatures, resistance to higher mechanical stress, etc. for
developed materials, which is reflected in the demands for the
developed material systems. The paper describes individual
environments and, in relation to them, also requirements for
individual components of the developed materials and for the
developed materials as a whole.
Abstract: Although, lanthanum carbonate has not been approved
by the FDA for treatment of hyperphosphatemia, we prospectively
evaluated the efficacy of the combination of Calcium hydroxyapatite
(CHAp) and Lanthanum Carbonate (LaC) for the treatment of
hyperphosphatemia on mice. CHAp was prepared by co-precipitation
method using Ca(OH)2, H3PO4, NH4OH with calcination at 1200ºC.
Lanthanum carbonate was prepared by chemical method using
NaHCO3 and LaCl3 at low pH environment, below 4.0. The
structures were characterized by FTIR spectra and SEM -EDX
analysis. The study group included 16 subjects-mice divided into four
groups according to the administered substance: lanthanum carbonate
(group A), CHAp (group B), lanthanum carbonate + CHAp (group C)
and salt water (group D). The results indicate a phosphate decrease
when subjects (mice) were treated with CHAp and lanthanum
carbonate (0.5% CMC), in a single dose of 1500 mg/kg. Serum
phosphate concentration decreased [(from 4.5 ± 0.8 mg/dL) to
4.05 ± 0.2 mg/dL), P < 0.01] in group A and in group C (to 3.6
± 0.2 mg/dL) at 12 hours from the administration. The combination
of CHAp and lanthanum carbonate is a suitable regimen for
hyperphosphatemia treatment because it avoids both the
hypercalcemia of CaCO3 and the adverse effects of CHAp.
Abstract: Activated carbon is an amorphous carbon chain which
has extremely extended surface area. High surface area of activated
carbon is due to the porous structure. Activated carbon, using a
variety of materials such as coal and cellulosic materials; can be
obtained by both physical and chemical methods. The prepared
activated carbon can be used for decolorize, deodorize and also can
be used for removal of organic and non-organic pollution. In this
study, pomegranate peel was subjected to 800W microwave power
for 1 to 4 minutes. Also fresh pomegranate peel was used for the
reference material. Then ZnCl2 was used for the chemical activation
purpose. After the activation process, activated pomegranate peels
were used for the adsorption of Zn metal (40 ppm) in the waste water.
As a result of the adsorption experiments, removal of heavy metals
ranged from 89% to 85%.
Abstract: Feed oil samples which are used as mixed feed raw
material were taken from six different feed factories in March, May
and July. All factories make production in Konya, Turkey and all of
the samples were crude soybean oils. Physical and chemical analyses,
free radical scavenger effect, and total phenol content were
determined on these oil samples. Moisture (M) content was found
between 0.10-22.23%, saponification number (SF) was determined
143.13 to 167.93 KOH/kg, free fatty acidity (FFA) was varied 0.73 to
35.00%, peroxide value (PV) was found between 1.53 and 28.43
meq/kg, unsaponifiable matter (USM) was determined from 0.40 to
17.10%, viscosity (V) was found between 34.30 and 625.67 mPas,
sediment (S) amount was determined between 0.60-18.16%, free
radical scavenger effect (FRSE) was varied 20.7 to 43.04% inhibition
of the extract and total phenol (TPC) content was found between 1.20
and 2.69mg/L extract. Different results were found between months
and factories.
Abstract: The textile industry plays a major role in the economy
of India and on the other side of the coin it is the major source for
water pollution. As azo dyes is the largest dye class they are
extensively used in many fields such as textile industry, leather
tanning industry, paper production, food, color photography,
pharmaceuticals and medicine, cosmetic, hair colorings, wood
staining, agricultural, biological and chemical research etc. In
addition to these, they can have acute and/or chronic effects on
organisms depending on their concentration and length of exposure
when they discharged as effluent in the environment. The aim of this
study was to assess the genotoxic and histotoxic potentials of
environmentally relevant concentrations of C. I. Reactive Red 120
(RR 120) on Catla catla, important edible freshwater fingerlings. For
this, healthy Catla catla fingerlings were procured from the
Government Fish Farm and acclimatized in 100 L capacity and
continuously aerated glass aquarium in laboratory for 15 days.
According to APHA some physic-chemical parameters were
measured and maintained such as temperature, pH, dissolve oxygen,
alkalinity, total hardness. Water along with excreta had been changed
every 24 hrs. All fingerlings were fed artificial food palates once a
day @ body weight. After 15 days fingerlings were grouped in 5 (10
in each) and exposed to various concentrations of RR 120 (Control,
10, 20, 30 and 40 mg.l-1) and samples (peripheral blood and gills,
kidney) were collected and analyzed at 96 hrs. All results were
compared with the control. Micronuclei (MN), nuclear buds (NB),
fragmented-apoptotic (FA) and bi-nucleated (BN) cells in blood
smears and in tissues (gills and kidney cells) were observed.
Prominent histopathological alterations were noticed in gills such as
aneurism, hyperplasia, degenerated central axis, lifting of gill
epithelium, curved secondary gill lamellae etc. Similarly kidney
showed some detrimental changes like shrunken glomeruli with
increased periglomerular space, degenerated renal tubules etc. Both
haematological and histopathological changes clearly reveal the toxic
potential of RR 120. This work concludes that water pollution
assessment can be done by these two biomarkers which provide
baseline to the further chromosomal or molecular work.
Abstract: Depositional environment and source potential of the
different organic-rich levels of Devonian age (up to 990m thick) from
the onshore EC-1 well (Southern Tunisia) were investigated based on
the analysis of more than 130 cutting samples by different
geochemical techniques (Rock-Eval pyrolysis, GC-MS). The
obtained results including Rock Eval Pyrolysis data and biomarker
distribution (terpanes, steranes and aromatics) have been used to
describe the depositional environment and to assess the thermal
maturity of the Devonian organic matter. These results show that the
Emsian deposits exhibit poor to fair TOC contents. The associated
organic matter is composed of mixed kerogen (type II/III), as
indicated by the predominance of C29 steranes over C27 and C28
homologous, that was deposited in a slightly reduced environment
favoring organic matter preservation. Thermal maturity assessed from
Tmax, TNR and MPI-1 values shows a mature stage of organic
matter. The Middle Devonian (Eifelian) shales are rich in type II
organic matter that was deposited in an open marine depositional
environment. The TOC values are high and vary between 2 and 7%
indicating good to excellent source rock. The relatively high HI
values (reaching 547 mg HC/g TOC) and the low values of t19/t23
tricyclic terpane ratio (< 0.2) confirm the marine origin of the organic
matter (type II). During the Upper Devonian, the organic matter was
deposited under variable redox conditions, oxic to suboxic which is
clearly indicated by the low C35/C34 hopanes ratio, immature to
marginally mature with the vitrinite reflectance ranging from 0.5 to
0.7 Ro and Tmax value of 426°C-436 °C and the TOC values range
between 0.8% to 4%.
Abstract: Non-water based fixed abrasive polishing was adopted
to manufacture LBO crystal for nano precision surface quality because
of its deliquescent. Ethyl alcohol was selected as the non-water based
slurry solvent and ethanediamine, lactic acid, hydrogen peroxide was
added in the slurry as a chemical additive, respectively. Effect of
different additives with non-water based slurry on material removal
rate, surface topography, microscopic appearances, and surface
roughness were investigated in fixed abrasive polishing of LBO
crystal. The results show the best surface quality of LBO crystal with
surface roughness Sa 8.2 nm and small damages was obtained by
non-water based slurry with lactic acid. Non-water based fixed
abrasive polishing can achieve nano precision surface quality of LBO
crystal with high material removal.
Abstract: It is well known that in recent years magnetic
materials have received increased attention due to their properties.
For this reason a significant number of patents that were published
during the last decade are oriented towards synthesis and study of
such materials. The aim of this work is to create and study ferrite
nanocrystalline materials with spinel structure, using sol-gel
technology with participation of auto-combustion. This method is
perspective in that it is a cheap and low-temperature technique that
allows for the fine control on the product’s chemical composition.
Abstract: The biodegradable family of polymers
polyhydroxyalkanoates is an interesting substitute for convectional
fossil-based plastics. However, the manufacturing and environmental
impacts associated with their production via intracellular bacterial
fermentation are strongly dependent on the raw material used and on
energy consumption during the extraction process, limiting their
potential for commercialization. Industrial wastewater is studied in
this paper as a promising alternative feedstock for waste valorization.
Based on results from laboratory and pilot-scale experiments, a
conceptual process design, techno-economic analysis and life cycle
assessment are developed for the large-scale production of the most
common type of polyhydroxyalkanoate, polyhydroxbutyrate.
Intracellular polyhydroxybutyrate is obtained via fermentation of
microbial community present in industrial wastewater and the
downstream processing is based on chemical digestion with
surfactant and hypochlorite. The economic potential and
environmental performance results help identifying bottlenecks and
best opportunities to scale-up the process prior to industrial
implementation. The outcome of this research indicates that the
fermentation of wastewater towards PHB presents advantages
compared to traditional PHAs production from sugars because the
null environmental burdens and financial costs of the raw material in
the bioplastic production process. Nevertheless, process optimization
is still required to compete with the petrochemicals counterparts.
Abstract: Phelipanche ramosa is the most damaging obligate
flowering parasitic weed on wide species of cultivated plants. The
semi-arid regions of the world are considered the main centers of this
parasitic plant that causes heavy infestation. This is due to its
production of high numbers of seeds (up to 200,000) that remain
viable for extended periods (up to 20 years). In this study, 13
treatments for the control of Phelipanche were carried out, which
included agronomic, chemical, and biological treatments and the use
of resistant plant methods. In 2014, a trial was performed at the
Department of Agriculture, Food and Environment, University of
Foggia (southern Italy), on processing tomato (cv ‘Docet’) grown in
pots filled with soil taken from a field that was heavily infested by P.
ramosa). The tomato seedlings were transplanted on May 8, 2014,
into a sandy-clay soil (USDA). A randomized block design with 3
replicates (pots) was adopted. During the growing cycle of the
tomato, at 70, 75, 81 and 88 days after transplantation, the number of
P. ramosa shoots emerged in each pot was determined. The tomato
fruit were harvested on August 8, 2014, and the quantitative and
qualitative parameters were determined. All of the data were
subjected to analysis of variance (ANOVA) using the JMP software
(SAS Institute Inc. Cary, NC, USA), and for comparisons of means
(Tukey's tests). The data show that each treatment studied did not
provide complete control against P. ramosa. However, the virulence
of the attacks was mitigated by some of the treatments tried: radicon
biostimulant, compost activated with Fusarium, mineral fertilizer
nitrogen, sulfur, enzone, and the resistant tomato genotype. It is
assumed that these effects can be improved by combining some of
these treatments with each other, especially for a gradual and
continuing reduction of the “seed bank” of the parasite in the soil.
Abstract: The convective heat and mass transfer in nanofluid
flow through a porous media due to a permeable stretching sheet with
magnetic field, viscous dissipation, chemical reaction and Soret
effects are numerically investigated. Two types of nanofluids, namely
Cu-water and Ag-water were studied. The governing boundary layer
equations are formulated and reduced to a set of ordinary differential
equations using similarity transformations and then solved
numerically using the Keller box method. Numerical results are
obtained for the skin friction coefficient, Nusselt number and
Sherwood number as well as for the velocity, temperature and
concentration profiles for selected values of the governing
parameters. Excellent validation of the present numerical results has
been achieved with the earlier linearly stretching sheet problems in
the literature.
Abstract: Gypsum (CaSO4.2H2O) is a mineral that is found in
large quantities in the Turkey and in the World. In this study, the
dissolution of this mineral in the diammonium hydrogen phosphate
solutions has been studied. The dissolution and dissolution kinetics of
gypsum in diammonium hydrogen phosphate solutions will be useful
for evaluating of solid wastes containing gypsum. Parameters such as
diammonium hydrogen phosphate concentration, temperature and
stirring speed affecting on the dissolution rate of the gypsum in
diammonium hydrogen phosphate solutions were investigated. In
experimental studies have researched effectiveness of the selected
parameters. The dissolution of gypsum were examined in two parts at
low and high temperatures. The experimental results were
successfully correlated by linear regression using Statistica program.
Dissolution curves were evaluated shrinking core models for solidfluid
systems. The activation energy was found to be 34.58 kJ/mol
and 44.45 kJ/mol for the low and the high temperatures. The
dissolution of gypsum was controlled by chemical reaction both low
temperatures and high temperatures.
Abstract: Essential oils have a significant antimicrobial activity.
These oils can successfully replace the antibiotics. So, the
microorganisms show their inefficiencies resistant for the antibiotics.
For this reason, we study the physicochemical analysis and
antimicrobial activity of the essential oil of Daucus carota. The
extraction is done by steam distillation of water which brought us a
very significant return of 4.65%. The analysis of the essential oil is
performed by GC / MS and has allowed us to identify 32 compounds
in the oil of D. carota flowering tops of Bouira. Three of which are in
the majority are the α-Pinene (22.3%), the carotol (21.7%) and the
limonene (15.8%).