Abstract: Zinc borates are used as a multi-functional flame
retardant additive for its high dehydration temperature. In this study,
the method of ultrasonic mixing was used in the synthesis of zinc
borates. The reactants of zinc oxide (ZnO) and boric acid (H3BO3)
were used at the constant reaction parameters of 90°C reaction
temperature and 55 min of reaction time. Several molar ratios of
ZnO:H3BO3 (1:1, 1:2, 1:3, 1:4 and 1:5) were conducted for the
determination of the optimum reaction ratio. Prior to synthesis the
characterization of the synthesized zinc borates were made by X-Ray
Diffraction (XRD) and Fourier Transform Infrared Spectroscopy
(FT-IR). From the results Zinc Oxide Borate Hydrate
[Zn3B6O12.3.5H2O], were synthesized optimum at the molar ratio of
1:3, with a reaction efficiency of 95.2%.
Abstract: The purpose of this study is to analyze the temporal
and spatial variability of thermal conditions in the Republic of
Armenia. The paper describes annual fluctuations in air temperature.
Research has been focused on case study region of Armenia and
surrounding areas, where long–term measurements and observations
of weather conditions have been performed within the National
Meteorological Service of Armenia and its surrounding areas. The
study contains yearly air temperature data recorded between 1961-
2012. Mann-Kendal test and the autocorrelation function were
applied to detect the change trend of annual mean temperature, as
well as other parametric and non-parametric tests searching to find
the presence of some breaks in the long term evolution of
temperature. The analysis of all records reveals a tendency mostly
towards warmer years, with increased temperatures especially in
valleys and inner basins. The maximum temperature increase is up to
1,5°C. Negative results have not been observed in Armenia. The
patterns of temperature change have been observed since the 1990’s
over much of the Armenian territory. The climate in Armenia was
influenced by global change in the last 2 decades, as results from the
methods employed within the study.
Abstract: This first-attempt study revealed that decolorized
intermediates of azo dyes could act as redox mediators to assist
wastewater (WW) decolorization due to enhancement of
electron-transport phenomena. Electrochemical impedance spectra
indicated that hydroxyl and amino-substituent(s) were functional
group(s) as redox-mediator(s). As azo dyes are usually multiple
benzene-rings structured, their derived decolorized intermediates are
likely to play roles of electron shuttles due to lower barrier of energy
gap for electron shuttling. According to cyclic voltammetric profiles,
redox mediating characteristics of decolorized intermediates of azo
dyes (e.g., RBu171, RR198, RR141, RBk5) were clearly disclosed.
With supplementation of biodecolorized metabolites of RR141 and
198, decolorization performance of could be evidently augmented.
This study also suggested the optimal modes of microbial fuel cell
(MFC)-assisted WW decolorization would be plug-flow or batch
mode of operation with no mix. Single chamber-MFCs would be more
favourable than double chamber MFCs due to non-mixing contacting
reactor scheme for operation.
Abstract: River Hindon is an important river catering the
demand of highly populated rural and industrial cluster of western
Uttar Pradesh, India. Water quality of river Hindon is deteriorating at
an alarming rate due to various industrial, municipal and agricultural
activities. The present study aimed at identifying the pollution
sources and quantifying the degree to which these sources are
responsible for the deteriorating water quality of the river. Various
water quality parameters, like pH, temperature, electrical
conductivity, total dissolved solids, total hardness, calcium, chloride,
nitrate, sulphate, biological oxygen demand, chemical oxygen
demand, and total alkalinity were assessed. Water quality data
obtained from eight study sites for one year has been subjected to the
two multivariate techniques, namely, principal component analysis
and cluster analysis. Principal component analysis was applied with
the aim to find out spatial variability and to identify the sources
responsible for the water quality of the river. Three Varifactors were
obtained after varimax rotation of initial principal components using
principal component analysis. Cluster analysis was carried out to
classify sampling stations of certain similarity, which grouped eight
different sites into two clusters. The study reveals that the
anthropogenic influence (municipal, industrial, waste water and
agricultural runoff) was the major source of river water pollution.
Thus, this study illustrates the utility of multivariate statistical
techniques for analysis and elucidation of multifaceted data sets,
recognition of pollution sources/factors and understanding
temporal/spatial variations in water quality for effective river water
quality management.
Abstract: Over the last two decades, externally bonded fiber
reinforced polymer (FRP) composites bonded to concrete substrates
has become a popular method for strengthening reinforced concrete
(RC) highway and railway bridges. Such structures are exposed to
severe cyclic loading throughout their lifetime often resulting in
fatigue damage to structural components and a reduction in the
service life of the structure. Since experimental and numerical results
on the fatigue performance of FRP-to-concrete joints are still limited,
the current research focuses on assessing the fatigue performance of
externally bonded FRP-to-concrete joints using a direct shear test.
Some early results indicate that the stress ratio and the applied cyclic
stress level have a direct influence on the fatigue life of the externally
bonded FRP. In addition, a calibrated finite element model is
developed to provide further insight into the influence of certain
parameters such as: concrete strength, FRP thickness, number of
cycles, frequency, and stiffness on the fatigue life of the FRP-toconcrete
joints.
Abstract: In the present work, forming limit diagrams and strain
distribution profile diagrams for extra deep drawing steel at room and
elevated temperatures have been determined experimentally by
conducting stretch forming experiments by using designed and
fabricated warm stretchforming tooling setup. With the help of
forming Limit Diagrams (FLDs) and strain, distribution profile
diagrams the formability of Extra Deep Drawing steel has been
analyzed and co-related with mechanical properties like strain
hardening COEFFICIENT (n) and normal anisotropy (r−). Mechanical
properties of EDD steel from room temperature to 4500C were
determined and discussed the impact of temperature on the properties
like work hardening exponent (n) anisotropy (r-) and strength
coefficient of the material. In addition, the fractured surfaces after
stretching have undergone the some metallurgical investigations and
attempt has been made to co-relate with the formability of EDD steel
sheets. They are co-related and good agreement with FLDs at various
temperatures.
Abstract: Fluctuations of Schottky diode parameters in a
structure of the mixer are investigated. These fluctuations are
manifested in two ways. At the first, they lead to fluctuations in the
transfer factor that is lead to the amplitude fluctuations in the signal
of intermediate frequency. On the basis of the measurement data of
1/f noise of the diode at forward current, the estimation of a spectrum
of relative fluctuations in transfer factor of the mixer is executed.
Current dependence of the spectrum of relative fluctuations in
transfer factor of the mixer and dependence of the spectrum of
relative fluctuations in transfer factor of the mixer on the amplitude
of the heterodyne signal are investigated. At the second, fluctuations
in parameters of the diode lead to occurrence of 1/f noise in the
output signal of the mixer. This noise limits the sensitivity of the
mixer to the value of received signal.
Abstract: Sewage sludge is a biomass resource that can create a
solid fuel and electricity. Utilizing sewage sludge as a renewable
energy can contribute to the reduction of greenhouse gases. In Japan,
the "National Plan for the Promotion of Biomass Utilization" and the
“Priority Plan for Social Infrastructure Development" were approved
at cabinet meetings in December 2010 and August 2012, respectively,
to promote the energy utilization of sewage sludge. This study
investigated costs and greenhouse gas emission in different sewage
sludge treatments with technologies for energy from sewage sludge.
Expenses were estimated based on capital costs and O&M costs
including energy consumption of solid fuel plants and biogas power
generation plants for sewage sludge. Results showed that the cost of
sludge digestion treatment with solid fuel technologies was 8% lower
than landfill disposal. The greenhouse gas emission of sludge
digestion treatment with solid fuel technologies was also 6,390t as
CO2 smaller than landfill disposal. Biogas power generation reduced
the electricity of a wastewater treatment plant by 30% and the cost by
5%.
Abstract: This article developed an ion thruster optic system
sputter erosion depth numerical 3D model by IFE-PIC (Immersed
Finite Element-Particle-in-Cell) and Mont Carlo method, and
calculated the downstream surface sputter erosion rate of accelerator
grid; compared with LIPS-200 life test data. The results of the
numerical model are in reasonable agreement with the measured data.
Finally, we predicted the lifetime of the 20cm diameter ion thruster via
the erosion data obtained with the model. The ultimate result
demonstrated that under normal operating condition, the erosion rate
of the grooves wears on the downstream surface of the accelerator grid
is 34.6μm⁄1000h, which means the conservative lifetime until
structural failure occurring on the accelerator grid is 11500 hours.
Abstract: A Reconfigurable Wilkinson power divider is
proposed in this paper. In existing system only a limited number of
bandwidth is used at the output ports, in the proposed Wilkinson
power divider different band of frequencies are obtained by using
PIN diode. By tuning the PIN diode, different frequencies are
achieved. The size of the power divider is reduced for the operating
frequency and increases the fractional bandwidth.
Abstract: In the present research, whole meal barley flour
(WBF) was supplemented with gelatinized corn flour (GCF) in 0 and
30%. Whole meal wheat flour (WWF) was mixed with defatted rice
bran (DRB) to produce 0, 20, 25, and 30% replacement levels.
Rheological properties of dough were studied. Thermal properties
and starch crystallinity of flours were evaluated. Flat bread, balady
bread and pie were prepared from the different flour blends. The
different bakeries were sensory evaluated. Color of raw materials and
crust of bakery products were determined. Nutrients contents of raw
flours and food products were assessed. Results showed that addition
of GCF to WBF increased the viscosity and falling number of the
produced dough. Water absorption, dough development time and
dough stability increased with increasing the level of DRB in dough
while, weakening and mixing tolerance index decreased.
Extensibility and energy decreased, while, resistance to extension
increased as DRB level increased. Gelatinized temperature of WWF,
WBF, GCF, and DRB were 13.26, 35.09, 28.33, and 39.63,
respectively. Starch crystallinity was affected when DRB was added
to WWF. The highest protein content was present in balady bread
made from 70% WWF and 30% DRB. The highest calcium,
phosphorus, and potassium levels were present in products made
from 100% WBF. Sensory attributes of the products were slightly
affected by adding DRB and GCF. Conclusion: Addition of DRB or
GCF to WWF or WBF, respectively affect the physical, chemical,
rheological and sensory properties of balady bread, flat bread, and pie
while improved their nutritive values.
Abstract: Green and renewable energy is getting extraordinary
consideration today, because of ecological concerns made by blazing
of fossil powers. Photovoltaic and wind power generation are the
basic decisions for delivering power in this respects. Producing
power by the sun based photovoltaic systems is known to the world,
yet control makers may get confounded to pick between on-grid and
off-grid systems. In this exploration work, an endeavor is made to
compare the off-grid (stand-alone) and on-grid (grid-connected)
frameworks. The work presents relative examination, between two
distinctive PV frameworks situated at V.V.P. Engineering College,
Rajkot. The first framework is 100 kW remain solitary and the
second is 60 kW network joined. The real-time parameters compared
are; output voltage, load current, power in-flow, power output,
performance ratio, yield factor, and capacity factor. The voltage
changes and the power variances in both frameworks are given
exceptional consideration and the examination is made between the
two frameworks to judge the focal points and confinements of both
the frameworks.
Abstract: By using a fixed point theorem of a sum operator, the
existence and uniqueness of positive solution for a class of
boundary value problem of nonlinear fractional differential equation
is studied. An iterative scheme is constructed to approximate it.
Finally, an example is given to illustrate the main result.
Abstract: A Friction stir welding tool is a critical component to
the success of the process. The tool typically consists of a rotating
round shoulder and a threaded cylindrical pin that heats the work
piece, mostly by friction, and moves the softened alloy around it to
form the joint. In this research work, an attempt has been made to
investigate the relationship between FSW variables mainly tool
profile, rotating speed, welding speed and the mechanical properties
(tensile strength, yield strength, percentage elongation, and micro
hardness) of friction stir welded aluminum alloy 5083 joints. From
the experimental details, it can be assessed that the joint produced by
using Triflute profile tool has contribute superior mechanical and
structural properties as compared to Tapered unthreaded & Threaded
tool for 1000rpm.
Abstract: In this paper, a prototype PEM fuel cell vehicle
integrated with a 1 kW air-blowing proton exchange membrane fuel
cell (PEMFC) stack as a main power sources has been developed for
a lightweight cruising vehicle. The test vehicle is equipped with a
PEM fuel cell system that provides electric power to a brushed DC
motor. This vehicle was designed to compete with industrial
lightweight vehicle with the target of consuming least amount of
energy and high performance. Individual variations in driving style
have a significant impact on vehicle energy efficiency and it is well
established from the literature. The primary aim of this study was to
assesses the power and fuel consumption of a hydrogen fuel cell
vehicle operating at three difference driving technique (i.e. 25 km/h
constant speed, 22-28 km/h speed range, 20-30 km/h speed range).
The goal is to develop the best driving strategy to maximize
performance and minimize fuel consumption for the vehicle system.
The relationship between power demand and hydrogen consumption
has also been discussed. All the techniques can be evaluated and
compared on broadly similar terms. Automatic intelligent controller
for driving prototype fuel cell vehicle on different obstacle while
maintaining all systems at maximum efficiency was used. The result
showed that 25 km/h constant speed was identified for optimal
driving with less fuel consumption.
Abstract: Online measurement of the product quality is a
challenging task in cement production, especially in the production of
Celitement, a novel environmentally friendly hydraulic binder. The
mineralogy and chemical composition of clinker in ordinary Portland
cement production is measured by X-ray diffraction (XRD) and
X-ray fluorescence (XRF), where only crystalline constituents can be
detected. But only a small part of the Celitement components can be
measured via XRD, because most constituents have an amorphous
structure. This paper describes the development of algorithms
suitable for an on-line monitoring of the final processing step of
Celitement based on NIR-data. For calibration intermediate products
were dried at different temperatures and ground for variable
durations. The products were analyzed using XRD and
thermogravimetric analyses together with NIR-spectroscopy to
investigate the dependency between the drying and the milling
processes on one and the NIR-signal on the other side. As a result,
different characteristic parameters have been defined. A short
overview of the Celitement process and the challenging tasks of the
online measurement and evaluation of the product quality will be
presented. Subsequently, methods for systematic development of
near-infrared calibration models and the determination of the final
calibration model will be introduced. The application of the model on
experimental data illustrates that NIR-spectroscopy allows for a quick
and sufficiently exact determination of crucial process parameters.
Abstract: In this paper, we introduce a flexible box erecting
machine (BEM) that swiftly and automatically transforms cardboard
into a three dimensional box. Recently, the parcel service and
home-shopping industries have grown rapidly, and there is an
increasing need for various box types to ship various products.
However, workers cannot fold thousands of boxes manually in a day.
As such, automatic BEMs are garnering greater attention. This study
takes equipment operation into consideration as well as mechanical
improvements in order to design a BEM that is able to outperform its
conventional counterparts. We analyzed six dispatching rules – First In
First Out (FIFO), Shortest Processing Time (SPT), Earliest Due Date
(EDD), Setup Avoidance, EDD + SPT, and EDD + Setup Avoidance –
to determine which one was most suitable for BEM operation.
Consequently, SPT and Setup Avoidance were found to be the most
critical rules, followed by EDD + Setup Avoidance, EDD + SPT,
EDD, and FIFO. This hierarchy was valid for both our conventional
BEM and our new flexible BEM from the viewpoint of processing
time. We believe that this research can contribute to flexible BEM
management, which has the potential to increase productivity and
convenience.
Abstract: Fresh concrete has one of dynamic properties known
as slump. Slump of concrete is design to compatible with placing
method. Due to hydration reaction of cement, the slump of concrete
is loss through time. Therefore, delayed concrete probably get reject
because slump is unacceptable. In order to recover the slump of
delayed concrete the second dose of superplasticizer (naphthalene
based type F) is added into the system, the slump recovery can be
done as long as the concrete is not setting. By adding superplasticizer
as solution for recover unusable slump loss concrete may affects
other concrete properties. Therefore, this paper was observed setting
times and compressive strength of concrete after being re-dose with
chemical admixture type F (superplasticizer, naphthalene based) for
slump recovery. The concrete used in this study was fly ash concrete
with fly ash replacement of 0%, 30% and 50% respectively. Concrete
mix designed for test specimen was prepared with paste content (ratio
of volume of cement to volume of void in the aggregate) of 1.2 and
1.3, water-to-binder ratio (w/b) range of 0.3 to 0.58, initial dose of
superplasticizer (SP) range from 0.5 to 1.6%. The setting times of
concrete were tested both before and after re-dosed with different
amount of second dose and time of dosing. The research was
concluded that addition of second dose of superplasticizer would
increase both initial and final setting times accordingly to dosage of
addition. As for fly ash concrete, the prolongation effect was higher
as the replacement of fly ash increase. The prolongation effect can
reach up to maximum about 4 hours. In case of compressive strength,
the re-dosed concrete has strength fluctuation within acceptable range
of ±10%.
Abstract: This paper describes the development of new class of
epoxy based rice husk filled jute reinforced composites. Rice husk
flour is added in 0%, 1%, 3%, 5% by weight. Epoxy resin and
triethylenetetramine (T.E.T.A) is used as matrix and hardener
respectively. It investigates the mechanical properties of the
composites and a comparison is done for monolithic jute composite
and the filled ones. The specimens are prepared according to the
ASTM standards and experimentation is carried out using INSTRON
8801. The result shows that with the increase of filler percentage the
tensile properties increases but compressive and flexural properties
decreases.
Abstract: This study evaluated to facilitate separation of ABS
plastics from other waste plastics by froth flotation after surface
hydrophilization of ABS with heat treatment. The mild heat treatment
at 100oC for 60s could selectively increase the hydrophilicity of the
ABS plastics surface (i.e., ABS contact angle decreased from 79o to
65.8o) among other plastics mixture. The SEM and XPS results of
plastic samples sufficiently supported the increase in hydrophilic
functional groups and decrease contact angle on ABS surface, after
heat treatment. As a result of the froth flotation (at mixing speed 150
rpm and airflow rate 0.3 L/min) after heat treatment, about 85% of
ABS was selectively separated from other heavy plastics with 100%
of purity. The effect of optimum treatment condition and detailed
mechanism onto separation efficiency in the froth floatation was also
investigated. This research is successful in giving a simple, effective,
and inexpensive method for ABS separation from waste plastics.