A Multivariate Statistical Approach for Water Quality Assessment of River Hindon, India

River Hindon is an important river catering the demand of highly populated rural and industrial cluster of western Uttar Pradesh, India. Water quality of river Hindon is deteriorating at an alarming rate due to various industrial, municipal and agricultural activities. The present study aimed at identifying the pollution sources and quantifying the degree to which these sources are responsible for the deteriorating water quality of the river. Various water quality parameters, like pH, temperature, electrical conductivity, total dissolved solids, total hardness, calcium, chloride, nitrate, sulphate, biological oxygen demand, chemical oxygen demand, and total alkalinity were assessed. Water quality data obtained from eight study sites for one year has been subjected to the two multivariate techniques, namely, principal component analysis and cluster analysis. Principal component analysis was applied with the aim to find out spatial variability and to identify the sources responsible for the water quality of the river. Three Varifactors were obtained after varimax rotation of initial principal components using principal component analysis. Cluster analysis was carried out to classify sampling stations of certain similarity, which grouped eight different sites into two clusters. The study reveals that the anthropogenic influence (municipal, industrial, waste water and agricultural runoff) was the major source of river water pollution. Thus, this study illustrates the utility of multivariate statistical techniques for analysis and elucidation of multifaceted data sets, recognition of pollution sources/factors and understanding temporal/spatial variations in water quality for effective river water quality management.




References:
[1] V. Kumar, S. Arya, A. Dhaka, Minakshi, Chanchal, “A study on physiochemical
characteristics of Yamuna river around Hamirpur (UP),
Bundelkhand region central India,” International Multidisciplinary
Research Journal, Vol. 1, no.5, pp.14-16, 2011.
[2] F. Zhou, Y. Liu and H. Guo, “Application of multivariate statistical
methods to water quality assessment of the watercourses in northwestern
New Territories, Hong Kong,” Environmental Monitoring and
Assessment, vol. 132, pp. 1-13, 2007.
[3] S. R. Carpenter, N. F. Caraco, D. L. Correll, R. W. Howarth, A. N.
Sharpley, and V. H. Smith, “Nonpoint pollution of surface waters with
phosphorus and nitrogen,” Ecol Appl, vol. 8, no. 3, pp. 559–568, 1998.
[4] S. Yerel and H. Ankara, “Application of Multivariate Statistical
Techniques in the Assessment of Water Quality in Sakarya River,
Turkey,” Journal Geological Society of India, vol. 79, pp. 89-93, 2012.
[5] I. S. Babiker, A. A. Mohamed and T. Himaya, “Assessing groundwater
quality using GIS,” Water Resource Management, vol. 21, pp. 699–715,
2007.
[6] U. Kuruppu, A. Rahman, M. Haque and A. Sathasivan, “Water quality
investigation in the Hawkesbury-Nepean River in Sydney using
Principal Component Analysis,” in Proc 20th International Congress on
Modelling and Simulation, Adelaide, Australia,2013,pp. 2646- 2652.
[7] R. Bouza-Deaño, M. Ternero-Rodríguez and A. J. Fernández-Espinosa,
“Trend study and assessment of surface water quality in the Ebro River
(Spain),” J Hydrol, vol. 361, 227-239, 2008.
[8] O.O. Omo-Irabor , S. B. Olobaniyi, K. Oduyemi and, J. Akunna,
“Surface and ground water quality assessment using multivariate
analytical methods: a case study of the Western Niger Delta, Nigeria,”
Phys Chem Earth, vol. 33, pp. 663- 673, 2008.
[9] T. G. Kazi , M. B. Arain, M. K. Jamali, N. Jalbani, H. I. Afridi and R. A.
Sarfraz, “Assessment of water quality of polluted lake using multivariate
statistical techniques: A case study,” Ecotox Environ Safe, vol. 72, pp.
301-309, 2009.
[10] Y. Ouyang, “Evaluation of river water quality monitoring stations by
principal component analysis,” Water Res, vol. 39, pp. 2621-2635, 2005.
[11] B. Parinet, A. Lhote and B. Legube, “Principal component analysis: an
appropriate tool for water quality evaluation and management?
application to a tropical lake system,” Ecol Model, vol. 178, pp. 295-
311, 2004.
[12] S. Shrestha and F. Kazama, “Assessment of surface water quality using
multivariate statistical techniques: a case study of the Fuji river basin,
Japan,” Environ Modell Softw, vol. 22, pp. 464-475, 2007.
[13] S. Suthar, J. Sharma, M. Chabukdhara and A. K. Nema, “Water quality
assessment of river Hindon at Ghaziabad, India: impact of industrial and
urban wastewater,” Env. Mon and Assess, vol. 165, pp. 103–112, 2010.
[14] C. K. Jain, D. C. Singhal and M. K. Sharma, “Metal Pollution
Assessment of Sediment and Water in the River Hindon, India,” Env.
Mon and Assess, vol. 105, pp. 193-207, 2005.
[15] APHA. Standard methods for the examination of water and waste water,
19th. Ed, American Public Health Association, American Water Works
Association & Water Environment Federation, Washington, DC, 1998.
[16] A. Mustapha, A. Z. Aris, M. F. Ramli and H. Juahir, “Spatial-temporal
variation of surface water quality in the downstream region of the Jakara
River, north-western Nigeria: A statistical approach,” Journal of
Environmental Science and Health, vol. 47, pp. 1551–1560, 2012.
[17] G. Brumelis, L. Lapina, O. Nikodemus and G. Tabors, “Use of an
artificial model of monitoring data to aid interpretation of principal
component analysis,” Env. Mod. and Soft, vol. 15, no. 8, pp. 755-763,
2000.
[18] K. P. Singh, A. Malik, D. Mohan, and S. Sinha, “Multivariate statistical
techniques for the evaluation of spatial and temporal variations in water
quality of Gomti River (India): a case study,” Water Res, vol. 38, pp.
3980-3992, 2004.
[19] K. P. Singh, A. Malik, and S. Sinha, “Water quality assessment and
apportionment of pollution sources of Gomti river (India) using
multivariate statistical techniques: a case study,” Analytica Chimica
Acta, vol. 538, pp. 355-374, 2005.
[20] D. Love, D. Hallbauer, A. Amos, and R. Hranova, “Factor analysis as a
tool in groundwater quality management: two southern African case studies,” Physics and Chemistry of the Earth, vol. 29, pp. 1135-1143,
2004.
[21] S. A. Abdul-Wahab, C. S. Bakheit and S. M. Al-Alawi, “Principal
component and multiple regression analysis in modelling of groundlevel
ozone and factors affecting its concentrations” Env. Model and
Soft, vol. 20 no. 10, pp. 1263-1271, 2005.
[22] J. E. Jr. McKenna, “An enhanced cluster analysis program with
bootstrap significance testing for ecological community analysis,” Env.
Model and Soft, vol. 18, no. 3, pp. 205-220, 2003.
[23] M. Otto, Multivariate methods. In: R. Kellner, J. M. Mermet, M. Otto
and H. M. Widmer, Eds. Analytical Chemistry. Wiley-VCH: Weinheim,
1998.
[24] G. S. Rao and G. N. Rao, “Study of ground water quality in greater
Viskhapatnun city, Andhra Pradesh (India),” J. of Env. Sc. & Engg. Vol.
52, pp. 137-146, 2010
[25] S. Gholami and S. Srikantaswamy, “Analysis of agricultural impact on
the Cauvery river water around KRS Dam,” World applied Sciences
Journal, vol. 6, no. 8, pp. 1157-1169, 2009.
[26] A. O. Adebola, S. M. Adekolurejo and O. Osibanjo, “Water Quality
Assessment of River Ogun Using Multivariate Statistical Techniques,”
Journal of Environmental Protection, vol. 4, pp. 466-479, 2013.
[27] S. Ahmed, M. Hussain and W. Abderrahman, “Using multivariate factor
analysis to assess surface/logged water quality and source of
contamination at a large irrigation project at Al-Fadhli, Eastern
Province, Saudi Arabia,” Bulletin of Engineering Geology and the
Environment, vol. 64, pp. 232–315, 2005.
[28] S. M. Yidana, “Groundwater classification using multivariate statistical
methods: Southern Ghana,” J. Afr. Earth Sci, vol. 57, pp. 455–469 2010.
[29] A. H. Ismail, S. A. Basim and A. Q. Shahla, “Application of
Multivariate Statistical Techniques in the surface water quality
Assessment of Tigris River at Baghdad stretch,” Iraq Journal of Babylon
University/Engineering Sciences, vol. 22, no. 2, 2014.