Abstract: The primary objective of this work was to study the
effect of resin chemistry, pH and molarity of binding and elution
buffer on aggregate removal using Cation Exchange Chromatography
and find the optimum conditions which can give efficient aggregate
removal with minimum loss of yield. Four different resins were used
for carrying out the experiments: Fractogel EMD SO3
-(S), Fractogel EMD COO-(M), Capto SP ImpRes and S Ceramic HyperD. Runs
were carried out on the AKTA Avant system. Design of Experiments
(DOE) was used for analysis using the JMP software. The
dependence of the yield obtained using different resins on the
operating conditions was studied. Success has been achieved in
obtaining yield greater than 90% using Capto SP ImpRes and
Fractogel EMD COO-(M) resins. It has also been found that a change
in the operating conditions generally has different effects on the
yields obtained using different resins.
Abstract: In this article, a method is presented to effectively
estimate the deformed shape of a thick plate due to line heating. The
method uses a fifth order spline interpolation, with up to C3
continuity at specific points to compute the shape of the deformed
geometry. First and second order derivatives over a surface are the
resulting parameters of a given heating line on a plate. These
parameters are determined through experiments and/or finite element
simulations. Very accurate kriging models are fitted to real or virtual
surfaces to build-up a database of maps. Maps of first and second
order derivatives are then applied on numerical plate models to
evaluate their evolving shapes through a sequence of heating lines.
Adding an optimization process to this approach would allow
determining the trajectories of heating lines needed to shape complex
geometries, such as Francis turbine blades.
Abstract: As smartphones are equipped with various sensors,
there have been many studies focused on using these sensors to create
valuable applications. Human activity recognition is one such
application motivated by various welfare applications, such as the
support for the elderly, measurement of calorie consumption, lifestyle
and exercise patterns analyses, and so on. One of the challenges one
faces when using smartphone sensors for activity recognition is that
the number of sensors should be minimized to save battery power. In
this paper, we show that a fairly accurate classifier can be built that
can distinguish ten different activities by using only a single sensor
data, i.e., the smartphone accelerometer data. The approach that we
adopt to deal with this twelve-class problem uses various methods.
The features used for classifying these activities include not only the
magnitude of acceleration vector at each time point, but also the
maximum, the minimum, and the standard deviation of vector
magnitude within a time window. The experiments compared the
performance of four kinds of basic multi-class classifiers and the
performance of four kinds of ensemble learning methods based on
three kinds of basic multi-class classifiers. The results show that
while the method with the highest accuracy is ECOC based on
Random forest.
Abstract: One of the most critical decision points in the design of a
face recognition system is the choice of an appropriate face representation.
Effective feature descriptors are expected to convey sufficient, invariant
and non-redundant facial information. In this work we propose a set of
Hahn moments as a new approach for feature description. Hahn moments
have been widely used in image analysis due to their invariance, nonredundancy
and the ability to extract features either globally and locally.
To assess the applicability of Hahn moments to Face Recognition we
conduct two experiments on the Olivetti Research Laboratory (ORL)
database and University of Notre-Dame (UND) X1 biometric collection.
Fusion of the global features along with the features from local facial
regions are used as an input for the conventional k-NN classifier. The
method reaches an accuracy of 93% of correctly recognized subjects for
the ORL database and 94% for the UND database.
Abstract: A solar dish collector has been designed, fabricated
and tested for its performance on 10-03-2015 in Salem, Tamilnadu,
India. The experiments on cooking vessels of coated and un-coated
with 5 Liters capacity have been used for cooking Rice. The results
are shown in graphs. The solar cooker is always capable of cooking
food within the expected length of time and based on the solar
radiation levels. With minimum cooking power, the coated pressure
cooker of 5 Liters capacity cooks the food at faster manner. This is
due to the conductivity of the coating material provided in the cooker.
Abstract: Low Temperature Matrix Isolation - Electron
Paramagnetic Resonance (LTMI-EPR) Spectroscopy was utilized to
identify the species of iron oxide nanoparticles generated during the
oxidative pyrolysis of 1-methylnaphthalene (1-MN). The otherwise
gas-phase reactions of 1--MN were impacted by a polypropylenimine
tetra-hexacontaamine dendrimer complexed with iron (III) nitrate
nonahydrate diluted in air under atmospheric conditions. The EPR
fine structure of Fe (III)2O3 nanoparticles clusters, characterized by gfactors
of 2.00, 2.28, 3.76 and 4.37 were detected on a cold finger
maintained at 77 K after accumulation over a multitude of
experiments. Additionally, a high valence Fe (IV) paramagnetic
intermediate and superoxide anion-radicals, O2•- adsorbed on
nanoparticle surfaces in the form of Fe (IV) --- O2•- were detected
from the quenching area of Zone 1 in the gas-phase.
Abstract: The Northeast China (NEC) was the most important
agriculture areas and known as the Golden-Maize-Belt. Based on
observed crop data and crop model, we design four simulating
experiments and separate relative impacts and contribution under
climate change, planting date shift, and varieties change as well
change of varieties and planting date. Without planting date and
varieties change, maize yields had no significant change trend at
Hailun station located in the north of NEC, and presented significant
decrease by 0.2 - 0.4 t/10a at two stations, which located in the middle
and the south of NEC. With planting date change, yields showed a
significant increase by 0.09 - 0.47 t/10a. With varieties change, maize
yields had significant increase by 1.8~ 1.9 t/10a at Hailun and Huadian
stations, but a non-significant and low increase by 0.2t /10a at Benxi
located in the south of NEC. With change of varieties and planting
date, yields presented a significant increasing by 0.53- 2.0 t/10a. Their
contribution to yields was -25% ~ -55% for climate change, 15% ~
35% for planting date change, and 20% ~110% for varieties change as
well 30% ~135% for varieties with planting date shift. It found that
change in varieties and planting date were highest yields and were
responsible for significant increases in maize yields, varieties was
secondly, and planting date was thirdly. It found that adaptation in
varieties and planting date greatly improved maize yields, and
increased yields annual variability. The increase of contribution with
planting date and varieties change in 2000s was lower than in 1990s.
Yields with the varieties change and yields with planting date and
varieties change all showed a decreasing trend at Huadian and Benxi
since 2002 or so. It indicated that maize yields increasing trend
stagnated in the middle and south of NEC, and continued in the north
of NEC.
Abstract: Coal tar is a liquid by-product of coal pyrolysis
processes. This liquid oil mixture contains various kinds of useful
compounds such as benzoic aromatic compounds and phenolic
compounds. These compounds are widely used as raw material for
insecticides, dyes, medicines, perfumes, coloring matters, and many
others. The coal tar was collected by pyrolysis process of coal
obtained from PT Kaltim Prima Coal and Arutmin-Kalimantan. The
experiments typically occurred at the atmospheric pressure in a
laboratory furnace at temperatures ranging from 300 to 550oC with a
heating rate of 10oC/min and a holding time of 1 hour at the pyrolysis
temperature. The Gas Chromatography-Mass Spectroscopy (GC-MS)
was used to analyze the coal tar components. The obtained coal tar
has the viscosity of 3.12 cp, the density of 2.78 g/cm3, the calorific
value of 11,048.44 cal/g, and the molecular weight of 222.67. The
analysis result showed that the coal tar contained more than 78
chemical compounds such as benzene, cresol, phenol, xylene,
naphtalene, etc. The total phenolic compounds contained in coal tar
are 33.25% (PT KPC) and 17.58% (Arutmin-Kalimantan). The total
naphtalene compounds contained in coal tar is 14.15% (PT KPC) and
17.13% (Arutmin-Kalimantan).
Abstract: In this study, a multi objective optimization for end
milling of Al 6061 alloy has been presented to provide better
surface quality and higher Material Removal Rate (MRR). The input
parameters considered for the analysis are spindle speed, depth of cut
and feed. The experiments were planned as per Taguchis design of
experiment, with L27 orthogonal array. The Grey Relational Analysis
(GRA) has been used for transforming multiple quality responses
into a single response and the weights of the each performance
characteristics are determined by employing the Principal Component
Analysis (PCA), so that their relative importance can be properly and
objectively described. The results reveal that Taguchi based G-PCA
can effectively acquire the optimal combination of cutting parameters.
Abstract: A flow column has been innovatively used in the
design of a new electrocoagulation reactor (ECR1) that will reduce
the temperature of water being treated; where the flow columns work
as a radiator for the water being treated. In order to investigate the
performance of ECR1 and compare it to that of traditional reactors;
600 mL water samples with an initial temperature of 350C were
pumped continuously through these reactors for 30 min at current
density of 1 mA/cm2. The temperature of water being treated was
measured at 5 minutes intervals over a 30 minutes period using a
thermometer. Additional experiments were commenced to investigate
the effects of initial temperature (15-350C), water conductivity (0.15
– 1.2 S) and current density (0.5 -3 mA/cm2) on the performance of
ECR1.
The results obtained demonstrated that the ECR1, at a current
density of 1 mA/cm2 and continuous flow model, reduced water
temperature from 350C to the vicinity of 280C during the first 15
minutes and kept the same level till the end of the treatment time.
While, the temperature increased from 28.1 to 29.80C and from 29.8
to 31.90C in the batch and the traditional continuous flow models
respectively. In term of initial temperature, ECR1 maintained the
temperature of water being treated within the range of 22 to 280C
without the need for external cooling system even when the initial
temperatures varied over a wide range (15 to 350C). The influent
water conductivity was found to be a significant variable that affect
the temperature. The desirable value of water conductivity is 0.6 S.
However, it was found that the water temperature increased rapidly
with a higher current density.
Abstract: Chalcopyrite (CuFeS2) is the most common primary
mineral used for the commercial production of copper. The low
dissolution efficiency of chalcopyrite in sulfate media has prevented
an efficient industrial leaching of this mineral in sulfate media. Ferric
ions, bacteria, oxygen and other oxidants have been used as oxidizing
agents in the leaching of chalcopyrite in sulfate and chloride media
under atmospheric or pressure leaching conditions. Two leaching
methods were studied to evaluate chalcopyrite (CuFeS2) dissolution
in acid media. First, the conventional oxidative acid leaching method
was carried out using sulfuric acid (H2SO4) and potassium
dichromate (K2Cr2O7) as oxidant at atmospheric pressure. Second,
microwave-assisted acid leaching was performed using the
microwave accelerated reaction system (MARS) for same reaction
media. Parameters affecting the copper extraction such as leaching
time, leaching temperature, concentration of H2SO4 and
concentration of K2Cr2O7 were investigated. The results of
conventional acid leaching experiments were compared to the
microwave leaching method. It was found that the copper extraction
obtained under high temperature and high concentrations of oxidant
with microwave leaching is higher than those obtained
conventionally. 81% copper extraction was obtained by the
conventional oxidative acid leaching method in 180 min, with the
concentration of 0.3 mol/L K2Cr2O7 in 0.5M H2SO4 at 50 ºC, while
93.5% copper extraction was obtained in 60 min with microwave
leaching method under same conditions.
Abstract: An experimental investigation is carried out to
establish the performance characteristics of a compression ignition
engine while using cerium oxide nanoparticles as additive in neat
diesel and diesel-biodiesel blends. In the first phase of the
experiments, stability of neat diesel and diesel-biodiesel fuel blends
with the addition of cerium oxide nanoparticles is analyzed. After
series of experiments, it is found that the blends subjected to high
speed blending followed by ultrasonic bath stabilization improves the
stability. In the second phase, performance characteristics are studied
using the stable fuel blends in a single cylinder four stroke engine
coupled with an electrical dynamometer and a data acquisition
system. The cerium oxide acts as an oxygen donating catalyst and
provides oxygen for combustion. The activation energy of cerium
oxide acts to burn off carbon deposits within the engine cylinder at
the wall temperature and prevents the deposition of non-polar
compounds on the cylinder wall results reduction in HC emissions.
The tests revealed that cerium oxide nanoparticles can be used as
additive in diesel and diesel-biodiesel blends to improve complete
combustion of the fuel significantly.
Abstract: In recent years, fire accidents have been steadily
increased and the amount of property damage caused by the accidents
has gradually raised. Damaging building structure, fire incidents bring
about not only such property damage but also strength degradation and
member deformation. As a result, the building structure undermines its
structural ability. Examining the degradation and the deformation is
very important because reusing the building is more economical than
reconstruction. Therefore, engineers need to investigate the strength
degradation and member deformation well, and make sure that they
apply right rehabilitation methods. This study aims at evaluating
deformation characteristics of fire damaged and rehabilitated normal
strength concrete beams through both experiments and finite element
analyses. For the experiments, control beams, fire damaged beams and
rehabilitated beams are tested to examine deformation characteristics.
Ten test beam specimens with compressive strength of 21MPa are
fabricated and main test variables are selected as cover thickness of
40mm and 50mm and fire exposure time of 1 hour or 2 hours. After
heating, fire damaged beams are air-recurred for 2 months and
rehabilitated beams are repaired with polymeric cement mortar after
being removed the fire damaged concrete cover. All beam specimens
are tested under four points loading. FE analyses are executed to
investigate the effects of main parameters applied to experimental
study. Test results show that both maximum load and stiffness of the
rehabilitated beams are higher than those of the fire damaged beams.
In addition, predicted structural behaviors from the analyses also show
good rehabilitation effect and the predicted load-deflection curves are
similar to the experimental results. For the further, the proposed
analytical method can be used to predict deformation characteristics of
fire damaged and rehabilitated concrete beams without suffering from
time and cost consuming of experimental process.
Abstract: This study was conducted to determine sex
differentiation of laboratory reared Elm nymphalid (Nymphalis
polychloros Linnaeus, 1758) by examining the morphological
structure of pupal stage. Laboratory colony of elm nymphalid, reared
on pear leaves, was used to set up experiments. It was performed
with 5 replications having 8 pupae for each replication. Dorsal,
ventral and lateral parts of external morphological structures of pupae
were examined by Olympus SZX9 stereozoom microscope and
photographed. When fully grown, mature larvae wander the highest
part of the rearing cage and pupae were formed hanging by
cremaster. After completing prepupa stage about 1.5±0.3 days, they
all pupated. Pupal stage was completed at 24±1°C about 4.38±1.20
days. Pupal weights were 0.483±0.05 g in females and 0.392±0.08 g
(n=40) in males respectively. Pupal emergence rate was 95%, with
22 females and 16 males. Examinations of ventral parts of 8th, 9th,
and 10th abdominal segments revealed that anal opening were found
at 10th abdominal segment in both sexes, 3 lumps were determined at
9th abdominal segments then the specific opening structure at 8th
segment was only found on female pupae.
Abstract: Distillery spentwash contains high chemical oxygen
demand (COD), biological oxygen demand (BOD), color, total
dissolved solids (TDS) and other contaminants even after biological
treatment. The effluent can’t be discharged as such in the surface
water bodies or land without further treatment. Reverse osmosis (RO)
treatment plants have been installed in many of the distilleries at
tertiary level in many of the distilleries in India, but are not properly
working due to fouling problem which is caused by the presence of
high concentration of organic matter and other contaminants in
biologically treated spentwash. In order to make the membrane
treatment a proven and reliable technology, proper pre-treatment is
mandatory. In the present study, ultra-filtration (UF) for pretreatment
of RO at tertiary stage has been performed. Operating
parameters namely initial pH (pHo: 2–10), trans-membrane pressure
(TMP: 4-20 bars) and temperature (T: 15-43°C) were used for
conducting experiments with UF system. Experiments were
optimized at different operating parameters in terms of COD, color,
TDS and TOC removal by using response surface methodology
(RSM) with central composite design. The results showed that
removal of COD, color and TDS was 62%, 93.5% and 75.5%
respectively, with UF, at optimized conditions with increased
permeate flux from 17.5 l/m2/h (RO) to 38 l/m2/h (UF-RO). The
performance of the RO system was greatly improved both in term of
pollutant removal as well as water recovery.
Abstract: Biodiesel production from vegetable oil will produce
glycerol as by-product about 10% of the biodiesel production. The
amount of glycerol that was produced needed alternative way to
handling immediately so as to not become the waste that polluted
environment. One of the solutions was to process glycerol to
polyglycidyl nitrate (PGN). PGN is synthesized from glycerol by
three-step reactions i.e. nitration of glycerol, cyclization of 13-
dinitroglycerine and polymerization of glycosyl nitrate. Optimum
condition of nitration of glycerol with nitric acid has not been known.
Thermodynamic feasibility should be done before run experiments in
the laboratory. The aim of this study was to determine the parameters
those affect nitration of glycerol and nitric acid and chose the
operation condition. Many parameters were simulated to verify its
possibility to experiment under conditions which would get the
highest conversion of 1, 3-dinitroglycerine and which was the ideal
condition to get it. The parameters that need to be studied to obtain
the highest conversion of 1, 3-dinitroglycerine were mol ratio of
nitric acid/glycerol, reaction temperature, mol ratio of
glycerol/dichloromethane and pressure. The highest conversion was
obtained in the range of mol ratio of nitric acid /glycerol between 2/1
– 5/1, reaction temperature of 5-25oC and pressure of 1 atm. The
parameters that need to be studied further to obtain the highest
conversion of 1.3 DNG are mol ratio of nitric acid/glycerol and
reaction temperature.
Abstract: Artificial neural networks have gained a lot of interest
as empirical models for their powerful representational capacity,
multi input and output mapping characteristics. In fact, most feedforward
networks with nonlinear nodal functions have been proved to
be universal approximates. In this paper, we propose a new
supervised method for color image classification based on selforganizing
feature maps (SOFM). This algorithm is based on
competitive learning. The method partitions the input space using
self-organizing feature maps to introduce the concept of local
neighborhoods. Our image classification system entered into RGB
image. Experiments with simulated data showed that separability of
classes increased when increasing training time. In additional, the
result shows proposed algorithms are effective for color image
classification.
Abstract: Numerical investigations were conducted to study the
influence of flexural reinforcement ratio on the diagonal cracking
strength and ultimate shear strength of reinforced concrete (RC)
beams without stirrups. Three-dimensional nonlinear finite element
analyses (FEAs) of the beams with flexural reinforcement ratios
ranging from 0.58% to 2.20% subjected to a mid-span concentrated
load were carried out. It is observed that the load-deflection and loadstrain
curves obtained from the numerical analyses agree with those
obtained from the experiments. It is concluded that flexural
reinforcement ratio has a significant effect on the shear strength and
deflection capacity of RC beams without stirrups. The predictions of
diagonal cracking strength and ultimate shear strength of beams
obtained by using the equations defined by a number of codes and
researchers are compared with each other and with the experimental
values.
Abstract: It is necessary to predict a fatigue crack propagation
life for estimation of structural integrity. Because of an uncertainty
and a randomness of a structural behavior, it is also required to
analyze stochastic characteristics of the fatigue crack propagation life
at a specified fatigue crack size. The essential purpose of this study is to find the effect of load ratio
on probability distribution of the fatigue crack propagation life at a
specified grown crack size and to confirm the good probability
distribution in magnesium alloys under various fatigue load ratio
conditions. To investigate a stochastic crack growth behavior, fatigue
crack propagation experiments are performed in laboratory air under
several conditions of fatigue load ratio using AZ31. By Anderson-Darling test, a goodness-of-fit test for probability
distribution of the fatigue crack propagation life is performed. The
effect of load ratio on variability of fatigue crack propagation life is
also investigated.
Abstract: The reduction of phosphorus and sulfur in engine oil
are the main topics of this paper. Very reproducible boundary
lubrication tests were conducted as part of Design of Experiment
software (DOE) to study the behavior of fluorinated catalyst iron
fluoride (FeF3), and polutetrafluoroethylene or Teflon (PTFE) in
developing environmentally friendly (reduced P and S) anti-wear
additives for future engine oil formulations. Multi-component
Chevron fully formulated oil (GF3) and Chevron plain oil were used
with the addition of PTFE and catalyst to characterize and analyze
their performance. Lower phosphorus blends were the goal of the
model solution. Experiments indicated that new sub-micron FeF3
catalyst played an important role in preventing breakdown of the
tribofilm.