Abstract: Coal tar is a liquid by-product of coal pyrolysis
processes. This liquid oil mixture contains various kinds of useful
compounds such as benzoic aromatic compounds and phenolic
compounds. These compounds are widely used as raw material for
insecticides, dyes, medicines, perfumes, coloring matters, and many
others. The coal tar was collected by pyrolysis process of coal
obtained from PT Kaltim Prima Coal and Arutmin-Kalimantan. The
experiments typically occurred at the atmospheric pressure in a
laboratory furnace at temperatures ranging from 300 to 550oC with a
heating rate of 10oC/min and a holding time of 1 hour at the pyrolysis
temperature. The Gas Chromatography-Mass Spectroscopy (GC-MS)
was used to analyze the coal tar components. The obtained coal tar
has the viscosity of 3.12 cp, the density of 2.78 g/cm3, the calorific
value of 11,048.44 cal/g, and the molecular weight of 222.67. The
analysis result showed that the coal tar contained more than 78
chemical compounds such as benzene, cresol, phenol, xylene,
naphtalene, etc. The total phenolic compounds contained in coal tar
are 33.25% (PT KPC) and 17.58% (Arutmin-Kalimantan). The total
naphtalene compounds contained in coal tar is 14.15% (PT KPC) and
17.13% (Arutmin-Kalimantan).