Abstract: This study was carried out to investigate the adverse
effect of industrial wastewater on surface water quality in Gebeng
industrial estate, Pahang, Malaysia. Surface water was collected from
six sampling stations. Physicochemical parameters were
characterized based on in-situ and ex-situ analysis according to
standard methods by American Public Health Association (APHA).
Selected heavy metals were determined by using Inductively Coupled
Plasma Mass Spectrometry (ICP MS). The results revealed that the
concentration of heavy metals such as Pb, Cu, Cd, Cr and Hg were
high in samples. The results also showed that the value of Pb and Hg
were higher in the wet season in comparison to dry season.
According to Malaysia National Water Quality Standard (NWQS)
and Water Quality Index (WQI) all the sampling station were
categorized as class IV (highly polluted). The present study revealed
that the adverse effects of careless disposal of wastes and directly
discharge of effluents affected on surface water quality. Therefore,
the authorities should implement the laws to ensure the proper
practices of wastewater management for environmental sustainability
around the study area.
Abstract: Chrome tannery wastewater causes serious environmental hazard due to its high pollution potential. As a result, rigorous treatment is necessary for abatement of pollution from this type of wastewater. There are many research studies on chrome tannery wastewater treatment in the field of physical, chemical, and biological methods. In general, biological treatment process is found ineffective for direct application because of adverse effects by toxic chromium, sulphide, chloride etc. However, biological methods were employed mainly for a few sub processes generating significant amount of organic matter and without chromium, chlorides etc. In this context the present paper reviews the characteristics feature and pollution potential of wastewater generated from chrome tannery units and treatment of the same. The different biological processes used earlier and their chronological development for treatment of the chrome tannery wastewater are thoroughly reviewed in this paper. In this regard, the scope of hybrid bioreactor - an advanced technology option has also been explored, as this kind of treatment is well suited for the wastewater having inhibitory substances.
Abstract: In emerging economies, recycling is an opportunity
for the cities to increase the lifespan of sanitary landfills, reduce the
costs of the solid waste management, decrease the environmental
problems of the waste treatment through reincorporate waste in the
productive cycle and protect and develop people’s livelihoods of
informal waste pickers. However, few studies have analysed the
possibilities and strategies to integrate formal and informal sectors in
the solid waste management for the benefit of both. This study seek
to make a strength, weakness, opportunity, and threat (SWOT)
analysis in three recycling associations of Bogotá with the aim to
understand and determine the situation of recycling from perspective
of informal sector in its transition to enter as authorized waste
providers. Data used in the analysis are derived from multiple
strategies such as literature review, the Bogota’s recycling database,
focus group meetings, governmental reports, national laws and
regulations and specific interviews with key stakeholders. Results of
this study show as the main stakeholders of formal and informal
sector of waste management can identify the internal and internal
conditions of recycling in Bogotá. Several strategies were designed
based on the SWOTs determined, could be useful for Bogotá to
advance and promote recycling as a key strategy for integrated
sustainable waste management in the city.
Abstract: This paper presents a part of the project solving which
is dedicated to the identification of the hazardous waste with the most
critical production within the Czech Republic with the aim to study
and find the optimal composition of the cement matrix that will
ensure maximum content disposal of chosen hazardous waste. In the
first stage of project solving – which represents this paper – a specific
hazardous waste was chosen, its properties were identified and
suitable solidification agents were chosen. Consequently
solidification formulas and testing methodology was proposed.
Abstract: Activated carbon is an amorphous carbon chain which
has extremely extended surface area. High surface area of activated
carbon is due to the porous structure. Activated carbon, using a
variety of materials such as coal and cellulosic materials; can be
obtained by both physical and chemical methods. The prepared
activated carbon can be used for decolorize, deodorize and also can
be used for removal of organic and non-organic pollution. In this
study, pomegranate peel was subjected to 800W microwave power
for 1 to 4 minutes. Also fresh pomegranate peel was used for the
reference material. Then ZnCl2 was used for the chemical activation
purpose. After the activation process, activated pomegranate peels
were used for the adsorption of Zn metal (40 ppm) in the waste water.
As a result of the adsorption experiments, removal of heavy metals
ranged from 89% to 85%.
Abstract: Verification of vented wooden façade system with
bonded joints is presented in this paper. The potential of bonded
joints is studied and described in more detail. The paper presents the results of an experimental and theoretical research about the effects of freeze cycling on the bonded joint. For the purpose of tests spruce
timber profiles were chosen for the load bearing substructure. Planks from wooden plastic composite and Siberian larch are representing facade cladding. Two types of industrial polyurethane adhesives intended for structural bonding were selected. The article is focused on the preparation as well as on the subsequent curing and conditioning of test samples. All test samples were subjected to 15 cycles that represents sudden temperature changes, i.e. immersion in a water bath at (293.15 ± 3) K for 6 hours and subsequent freezing to (253.15 ± 2) K for 18 hours. Furthermore, the retention of bond strength between substructure and cladding wastested and strength in shear was determined under tensile stress.Research data indicate that little, if any, damage to the bond results from freezingcycles. Additionally, the suitability of selected group of adhesives in combination with timber substructure was confirmed.
Abstract: The biodegradable family of polymers
polyhydroxyalkanoates is an interesting substitute for convectional
fossil-based plastics. However, the manufacturing and environmental
impacts associated with their production via intracellular bacterial
fermentation are strongly dependent on the raw material used and on
energy consumption during the extraction process, limiting their
potential for commercialization. Industrial wastewater is studied in
this paper as a promising alternative feedstock for waste valorization.
Based on results from laboratory and pilot-scale experiments, a
conceptual process design, techno-economic analysis and life cycle
assessment are developed for the large-scale production of the most
common type of polyhydroxyalkanoate, polyhydroxbutyrate.
Intracellular polyhydroxybutyrate is obtained via fermentation of
microbial community present in industrial wastewater and the
downstream processing is based on chemical digestion with
surfactant and hypochlorite. The economic potential and
environmental performance results help identifying bottlenecks and
best opportunities to scale-up the process prior to industrial
implementation. The outcome of this research indicates that the
fermentation of wastewater towards PHB presents advantages
compared to traditional PHAs production from sugars because the
null environmental burdens and financial costs of the raw material in
the bioplastic production process. Nevertheless, process optimization
is still required to compete with the petrochemicals counterparts.
Abstract: Poly bag and mulch films for agricultural field caused
pose environmental problem due to the non-degradable plastics
wastes upon disposal. Thus, a degradable poly bag was designed with
hybrid sago starch (SS) and polyvinyl alcohol (PVA). Two Different
blended compositions of SS and PVA hybrid have been compounded.
Then, the hybrids blended are mixed with linear line density
polyethylene (LLDPE) resin to fabricate poly bag film through
conventional film blowing process. Samples of LLDPE, SS and PVA
hybrid film were exposed to UV light and soil burial. The weight
losses were determined during degradation process. Hybrid film by
degradation of starch was found to hydrolyze and hydroxyl groups
decrease on esterification upon exposure to soil burial and uv
radiation. It was found out that, the hybrid film for 60% of SS
composition showed greatest degradation in soil and UV radiation.
Abstract: Gypsum (CaSO4.2H2O) is a mineral that is found in
large quantities in the Turkey and in the World. In this study, the
dissolution of this mineral in the diammonium hydrogen phosphate
solutions has been studied. The dissolution and dissolution kinetics of
gypsum in diammonium hydrogen phosphate solutions will be useful
for evaluating of solid wastes containing gypsum. Parameters such as
diammonium hydrogen phosphate concentration, temperature and
stirring speed affecting on the dissolution rate of the gypsum in
diammonium hydrogen phosphate solutions were investigated. In
experimental studies have researched effectiveness of the selected
parameters. The dissolution of gypsum were examined in two parts at
low and high temperatures. The experimental results were
successfully correlated by linear regression using Statistica program.
Dissolution curves were evaluated shrinking core models for solidfluid
systems. The activation energy was found to be 34.58 kJ/mol
and 44.45 kJ/mol for the low and the high temperatures. The
dissolution of gypsum was controlled by chemical reaction both low
temperatures and high temperatures.
Abstract: Incineration of municipal solid waste (MSW) is one of
the key scopes in the global clean energy strategy. A computational
fluid dynamics (CFD) model was established in order to reveal these
features of the combustion process in a fixed porous bed of MSW.
Transporting equations and process rate equations of the waste bed
were modeled and set up to describe the incineration process,
according to the local thermal conditions and waste property
characters. Gas phase turbulence was modeled using k-ε turbulent
model and the particle phase was modeled using the kinetic theory of
granular flow. The heterogeneous reaction rates were determined
using Arrhenius eddy dissipation and the Arrhenius-diffusion
reaction rates. The effects of primary air flow rate and temperature in
the burning process of simulated MSW are investigated
experimentally and numerically. The simulation results in bed are
accordant with experimental data well. The model provides detailed
information on burning processes in the fixed bed, which is otherwise
very difficult to obtain by conventional experimental techniques.
Abstract: A three-dimensional numerical model of
thermoelectric generator (TEG) modules attached to a large chimney
plate is proposed and solved numerically using a control volume based
finite difference formulation. The TEG module consists of a
thermoelectric generator, an elliptical pin-fin heat sink, and a cold
plate for water cooling. In the chimney, the temperature of flue gases is
450-650K. Although the TEG hot-side temperature and thus the
electric power output can be increased by inserting an elliptical pin-fin
heat sink into the chimney tunnel to increase the heat transfer area, the
pin fin heat sink would cause extra pumping power at the same time.
The main purpose of this study is to analyze the effects of geometrical
parameters on the electric power output and chimney pressure drop
characteristics. The effects of different operating conditions, including
various inlet velocities (Vin= 1, 3, 5 m/s), inlet temperatures (Tgas = 450,
550, 650K) and different fin height (0 to 150 mm) are discussed in
detail. The predicted numerical data for the power vs. current (P-I)
curve are in good agreement (within 11%) with the experimental data.
Abstract: Silica was extracted from agriculture waste rice husk
ash (RHA) and was used as the silica source for synthesis of
RMCM-48 and RSBA-16. An alkali fusion process was utilized to
separate silicate supernatant and the sediment effectively. The
CTAB/Si and F127/Si molar ratio was employed to control the
structure properties of the obtained RMCM-48 and RSBA-16
materials. The N2 adsorption-desorption results showed the
micro-mesoporous RSBA-16 possessed high specific surface areas
(662-1001 m2/g). All the obtained RSBA-16 materials were applied as
the adsorbents for acetone adsorption. And the breakthrough tests
clearly revealed that the RSBA-16(0.004) materials could achieve the
highest acetone adsorption capacity of 181 mg/g under 1000 ppmv
acetone vapor concentration at 25oC, which was also superior to
ZSM-5 (71mg/g) and MCM-41 (157mg/g) under same test conditions.
This can help to reduce the solid waste and the high adsorption
performance of the obtained materials could consider as potential
adsorbents for acetone adsorption.
Abstract: The formulated problem of optimization of the
technological process of water treatment for thermal power plants is
considered in this article. The problem is of multiparametric nature.
To optimize the process, namely, reduce the amount of waste water, a
new technology was developed to reuse such water. A mathematical
model of the technology of wastewater reuse was developed.
Optimization parameters were determined. The model consists of a
material balance equation, an equation describing the kinetics of ion
exchange for the non-equilibrium case and an equation for the ion
exchange isotherm. The material balance equation includes a
nonlinear term that depends on the kinetics of ion exchange. A direct
problem of calculating the impurity concentration at the outlet of the
water treatment plant was numerically solved. The direct problem
was approximated by an implicit point-to-point computation
difference scheme. The inverse problem was formulated as relates to
determination of the parameters of the mathematical model of the
water treatment plant operating in non-equilibrium conditions. The
formulated inverse problem was solved. Following the results of
calculation the time of start of the filter regeneration process was
determined, as well as the period of regeneration process and the
amount of regeneration and wash water. Multi-parameter
optimization of water treatment process for thermal power plants
allowed decreasing the amount of wastewater by 15%.
Abstract: Peace education supports a holistic appreciation for
the value of life and the interdependence of all living systems. Peace
education aims to build a culture of peace. One way of building a
culture of peace is through environmental stewardship. This study
sought to find out the environmental stewardship practices in selected
Higher Education Institutions (HEIs) in the Philippines and how
these environmental stewardship practices lead to building a culture
of peace. The findings revealed that there is still room for
improvement in implementing environmental stewardship in schools
through academic service learning. In addition, the following
manifestations are implemented very satisfactorily in schools: 1)
waste reduction, reuse, and recycling, 2) community service, and 3)
clean and green surroundings. Administrators of schools in the study
lead their staff and students in implementing environmental
stewardship. It could be concluded that those involved in
environmental stewardship display an acceptable culture of peace,
particularly solidarity, respect for persons, and inner peace.
Abstract: Degradation of agricultural soils has increased rapidly
during the last 20 years due to the indiscriminate use of pesticides
and other anthropogenic activities. Currently, there is an urgent need
of soil restoration to increase agricultural production. Utilization of
sewage sludge or municipal solid waste is an important way to
recycle nutrient elements and improve soil quality. With these
amendments, nutrient availability in the aqueous phase might be
increased and production of healthier crops can be accomplished.
This research project aimed to achieve sustainable management of
tropical agricultural soils, specifically in Puerto Rico, through the
amendment of water treatment plant sludge’s. This practice avoids
landfill disposal of sewage sludge and at the same time results costeffective
practice for recycling solid waste residues. Coriander
sativum was cultivated in a compost-soil-sludge mixture at different
proportions. Results showed that Coriander grown in a mixture of
25% compost+50% Voladora soi+25% sludge had the best growth
and development. High chlorophyll content (33.01 ± 0.8) was
observed in Coriander plants cultivated in 25% compost+62.5%
Coloso soil+ 12.5% sludge compared to plants grown with no sludge
(32.59 ± 0.7). ICP-OES analysis showed variations in mineral
element contents (macro and micronutrients) in coriander plant
grown I soil amended with sludge and compost.
Abstract: In Jordan having deficit atmospheric precipitation, an
increase in water demand occurs during summer months. Jordan can
be regarded with a relatively high potential for wastewater recycling
and reuse. The main purpose of this paper was to investigate the
removal of total suspended solids (TSS) and chemical oxygen
demand (COD) for olive mill wastewater (OMW) by
electrocoagulation (EC) process. In the combination of
electrocoagulation by using coupled iron–aluminum electrodes, the
optimum working pH was found to be around 6. Results indicated
that the electrocoagulation process allowed removal of TSS and COD
of about 82.5% and 47.5%, respectively at 45 mA/cm2 after 70
minutes by using coupled iron–aluminum electrodes. It was
demonstrated that the maximum TSS and COD removals were
obtained at some optimum experimental parameters for current
density, pH, and reaction time.
Abstract: In this study, the Compressive strength of concretes
made with Ground Granulated Blast furnace Slag (GGBS),
Pulverised Fuel Ash (PFA), Rice Husk Ash (RHA) and Waste Glass
Powder (WGP) after they were exposed 7800C (exposure duration of
around 60 minutes) and then allowed to cool down gradually in the
furnace for about 280 minutes at water binder ratio of 0.50 was
investigated. GGBS, PFA, RHA and WGP were used to replace up to
20% Portland cement in the control concrete. Test for the
determination of workability, compressive strength and tensile
splitting strength of the concretes were carried out and the results
were compared with control concrete. The test results showed that the
compressive strength decreased by an average of around 30% after
the concretes were exposed to the heating and cooling scenario.
Abstract: Catalytic combustion of methane is imperative due to
stability of methane at low temperature. Methane (CH4), therefore,
remains unconverted in vehicle exhausts thereby causing greenhouse
gas GHG emission problem. In this study, heterogeneous catalysts of
palladium with bio-char (2 wt% Pd/Bc) and Al2O3 (2wt% Pd/ Al2O3)
supports were prepared by incipient wetness impregnation and then
subsequently tested for catalytic combustion of CH4. Support-porous
heterogeneous catalytic combustion (HCC) material were selected
based on factors such as surface area, porosity, thermal stability,
thermal conductivity, reactivity with reactants or products, chemical
stability, catalytic activity, and catalyst life. Sustainable and
renewable support-material of bio-mass char derived from palm shell
waste material was compared with those from the conventional
support-porous materials. Kinetic rate of reaction was determined for
combustion of methane on Palladium (Pd) based catalyst with Al2O3
support and bio-char (Bc). Material characterization was done using
TGA, SEM, and BET surface area. The performance test was
accomplished using tubular quartz reactor with gas mixture ratio of
3% methane and 97% air. The methane porous-HCC conversion was
carried out using online gas analyzer connected to the reactor that
performed porous-HCC. BET surface area for prepared 2 wt% Pd/Bc
is smaller than prepared 2wt% Pd/ Al2O3 due to its low porosity
between particles. The order of catalyst activity based on kinetic rate
on reaction of catalysts in low temperature was 2wt%
Pd/Bc>calcined 2wt% Pd/ Al2O3> 2wt% Pd/ Al2O3>calcined 2wt%
Pd/Bc. Hence agro waste material can successfully be utilized as an
inexpensive catalyst support material for enhanced CH4 catalytic
combustion.
Abstract: Solid waste management in steel industry is broadly
classified in “4 Rs” i.e. reduce, reuse, recycle and restore the
materials. Reuse and recycling the entire solid waste generated in the
process of steel making is a viable solution in targeting a clean, green
and zero waste technology leading to sustainable development of the
steel industry. Solid waste management has gained importance in
steel industry in view of its uncertainty, volatility and speculation due
to world competitive standards, rising input costs, scarcity of raw
materials and solid waste generated like in other sectors. The
challenges that the steel Industry faces today are the requirement of a
sustainable development by meeting the needs of our present
generation without compromising the ability of future generations.
Technologies are developed not only for gainful utilization of solid
wastes in manufacture of conventional products but also for
conversion of same in to completely new products.
Abstract: Hybrid bioreactor having both suspended-growth and
attached-growth bacteria is found a novel and excellent bioreactor
system for treating the municipal wastewater containing inhibitory
substrates too. In this reactor a fraction of substrate is used by
suspended biomass and the remaining by attached biomass resulting
in the competition between the two growths for the substrate. The
combination of suspended and attached growth provides the system
with enhanced biomass concentration and sludge age more than those
in ASP. Similar to attached growth system, the hybrid bioreactor
ensures considerable efficiency for treating toxic and refractory
substances in wastewater. For the process design of hybrid bioreactor
a suitable mathematical model is required. Although various
mathematical models were developed on hybrid bioreactor in due
course of time in earlier research works, none of them was found
having a specific simplified solution of the corresponding models and
without having any drawback. To overcome this drawback authors
already developed a simplified mathematical model for process
design of a hybrid bioreactor. The present paper briefly highlights on
the various aspects of process design of an aerobic hybrid bioreactor
for the treatment of municipal wastewater.