Abstract: The increasing demand of gallium, indium and
rare-earth elements for the production of electronics, e.g. solid
state-lighting, photovoltaics, integrated circuits, and liquid crystal
displays, will exceed the world-wide supply according to current
forecasts. Recycling systems to reclaim these materials are not yet in
place, which challenges the sustainability of these technologies. This
paper proposes a multispectral imaging system as a basis for a vision
based recognition system for valuable components of electronics
waste. Multispectral images intend to enhance the contrast of images
of printed circuit boards (single components, as well as labels) for
further analysis, such as optical character recognition and entire
printed circuit board recognition. The results show, that a higher
contrast is achieved in the near infrared compared to ultraviolett and
visible light.
Abstract: Water contamination by toxic compound is one of the serious environmental problems today. These toxic compounds mostly originated from industrial effluents, agriculture, natural sources and human waste. These studies focus on modification of multiwalled carbon nanotube (MWCNTs) with nanoparticle of calixarene and explore the possibility of using this modification for the remediation of cadmium in water. The nanocomposites were prepared by dissolving calixarene in chloroform solution as solvent, followed by additional multiwalled carbon nanotube (MWCNTs) then sonication process for 3 hour and fabricated the nanocomposites on substrate by spin coating method. Finally, the nanocomposites were tested on cadmium ion (10 mg/ml). The morphology of nanocomposites was investigated by FESEM showing the formation of calixarene on the outer walls of carbon nanotube and cadmium ion also clearly seen from the micrograph. This formation was supported by using energy dispersive x-ray (EDX). The presence of cadmium ions in the films, leads to some changes in the surface potential and Fourier Transform Infrared spectroscopy (FTIR).The nanocomposites MWCNTs-calixarene have potential for development of sensor for pollutant monitoring and nanoelectronics devices applications.
Abstract: The adsorption efficiency of fired clayey pellets of 5
and 8 mm diameter size for Cu(II) and Zn(II) ion removal from a
waste printing developer was studied. In order to investigate the
influence of contact time, adsorbent mass and pellet size on the
adsorption efficiency the batch mode was carried out. Faster uptake
of copper ion was obtained with the fired clay pellets of 5 mm
diameter size within 30 minutes. The pellets of 8 mm diameter size
showed the higher equilibrium time (60 to 75 minutes) for copper and
zinc ion. The results pointed out that adsorption efficiency increases
with the increase of adsorbent mass. The maximal efficiency is
different for Cu(II) and Zn(II) ion due to the pellet size. Therefore,
the fired clay pellets of 5 mm diameter size present an effective
adsorbent for Cu(II) ion removal (adsorption efficiency is 63.6%),
whereas the fired clay pellets of 8 mm diameter size are the best
alternative for Zn(II) ion removal (adsorption efficiency is 92.8%)
from a waste printing developer.
Abstract: The development, operation and maintenance of
Integrated Waste Management Systems (IWMS) affects essentially
the sustainable concern of every region. The features of such systems
have great influence on all of the components of sustainability. In
order to reach the optimal way of processes, a comprehensive
mapping of the variables affecting the future efficiency of the system
is needed such as analysis of the interconnections among the
components and modeling of their interactions. The planning of a
IWMS is based fundamentally on technical and economical
opportunities and the legal framework. Modeling the sustainability
and operation effectiveness of a certain IWMS is not in the scope of
the present research. The complexity of the systems and the large
number of the variables require the utilization of a complex approach
to model the outcomes and future risks. This complex method should
be able to evaluate the logical framework of the factors composing
the system and the interconnections between them. The authors of
this paper studied the usability of the Fuzzy Cognitive Map (FCM)
approach modeling the future operation of IWMS’s. The approach
requires two input data set. One is the connection matrix containing
all the factors affecting the system in focus with all the
interconnections. The other input data set is the time series, a
retrospective reconstruction of the weights and roles of the factors.
This paper introduces a novel method to develop time series by
content analysis.
Abstract: In and around Erode District, it is estimated that more
than 1250 chemical and allied textile processing fabric industries are
affected, partially closed and shut off for various reasons such as poor
management, poor supplier performance, lack of planning for
productivity, fluctuation of output, poor investment, waste analysis,
labor problems, capital/labor ratio, accumulation of stocks, poor
maintenance of resources, deficiencies in the quality of fabric, low
capacity utilization, age of plant and equipment, high investment and
input but low throughput, poor research and development, lack of
energy, workers’ fear of loss of jobs, work force mix and work ethic.
The main objective of this work is to analyze the existing conditions
in textile fabric sector, validate the break even of Total Productivity
(TP), analyze, design and implement fuzzy sets and mathematical
programming for improvement of productivity and quality
dimensions in the fabric processing industry. It needs to be
compatible with the reality of textile and fabric processing industries.
The highly risk events from productivity and quality dimension were
found by fuzzy systems and results are wrapped up among the textile
fabric processing industry.
Abstract: Food as perishable goods represents a specific and
sensitive part in the supply chain theory, since changing physical or
chemical characteristics considerably influence the approach to stock
management. The most delicate phase of this process is
transportation, where it becomes difficult to ensure the stable
conditions which limit deterioration, since the value of the
deterioration rate could be easily influenced by the mode of
transportation. The fuzzy definition of variables allows one to take
these variations into account. Furthermore, an appropriate choice of
the defuzzification method permits one to adapt results to real
conditions as far as possible. In this article those methods which take
into account the relationship between the deterioration rate of
perishable goods and transportation by ship will be applied with the
aim of (a) minimizing the total cost function, defined as the sum of
the ordering cost, holding cost, disposing cost and transportation
costs, and (b) improving the supply chain sustainability by reducing
environmental impact and waste disposal costs.
Abstract: Currently, thorium fuel has been especially noticed
because of its proliferation resistance than long half-life alpha emitter
minor actinides, breeding capability in fast and thermal neutron flux
and mono-isotopic naturally abundant. In recent years, efficiency of
minor actinide burning up in PWRs has been investigated. Hence, a
minor actinide-contained thorium based fuel matrix can confront both
proliferation resistance and nuclear waste depletion aims. In the
present work, minor actinide depletion rate in a CANDU-type nuclear
core modeled using MCNP code has been investigated. The obtained
effects of minor actinide load as mixture of thorium fuel matrix on
the core neutronics has been studied with comparing presence and
non-presence of minor actinide component in the fuel matrix.
Depletion rate of minor actinides in the MA-contained fuel has been
calculated using different power loads. According to the obtained
computational data, minor actinide loading in the modeled core
results in more negative reactivity coefficients. The MA-contained
fuel achieves less radial peaking factor in the modeled core. The
obtained computational results showed 140 kg of 464 kg initial load
of minor actinide has been depleted in during a 6-year burn up in 10
MW power.
Abstract: The extermination and proper disposal of
pharmaceutical wastes from expired and unused medications remains
a disputable issue due to their specific nature and characteristics.
Even though the hazards from these wastes are already well known in
terms of environment and human health, people still treat them as
usual wastes. At a national level, in many countries the management
of pharmaceutical and medical wastes has been one of the main
objectives in order to protect people’s health and the environment.
Even though many legal regulations exist in this respect, there has not
been a single law that would clearly explain the procedures of
returning medicines, ways of selection, treatment and extermination
of pharmaceutical wastes. This paper aims at analyzing the practices
of pharmaceutical waste management and treatment in some
European countries as well as a review of the legislation and official
guidelines in managing these kinds of wastes and protecting the
environment and human health. A suitable treatment and
management of expired medications and other similar wastes would
be in the interest of public health in the first place, as well as in the
interest of healthcare institutions and other bodies engaged in
environment protection.
Abstract: Regardless of the manufacturing process used,
subtractive or additive, material, purpose and application, produced
components are conventionally solid mass with more or less complex
shape depending on the production technology selected. Aspects
such as reducing the weight of components, associated with the low
volume of material required and the almost non-existent material
waste, speed and flexibility of production and, primarily, a high
mechanical strength combined with high structural performance, are
competitive advantages in any industrial sector, from automotive,
molds, aviation, aerospace, construction, pharmaceuticals, medicine
and more recently in human tissue engineering. Such features,
properties and functionalities are attained in metal components
produced using the additive technique of Rapid Prototyping from
metal powders commonly known as Selective Laser Melting (SLM),
with optimized internal topologies and varying densities. In order to
produce components with high strength and high structural and
functional performance, regardless of the type of application, three
different internal topologies were developed and analyzed using
numerical computational tools. The developed topologies were
numerically submitted to mechanical compression and four point
bending testing. Finite Element Analysis results demonstrate how
different internal topologies can contribute to improve mechanical
properties, even with a high degree of porosity relatively to fully
dense components. Results are very promising not only from the
point of view of mechanical resistance, but especially through the
achievement of considerable variation in density without loss of
structural and functional high performance.
Abstract: A cleaner production project was implemented in a
bakery. The project is based on the substitution of the best available
technique for an obsolete leaven production technology. The new
technology enables production of durable, high-quality leavens.
Moreover, 25% of flour as the original raw material can be replaced
by pastry from the previous day production which has not been sold.
That pastry was previously disposed in a waste incineration plant.
Besides the environmental benefits resulting from less waste, lower
consumption of energy, reduction of sewage waters quantity and
floury dustiness there are also significant economic benefits. Payback
period of investment was calculated with help of static method of
financial analysis about 2.6 years, using dynamic method 3.5 years
and an internal rate of return more than 29%. The supposed annual
average profit after taxationin the second year of operation was
incompliance with the real profit.
Abstract: The present study was conducted to evaluate the
potential applicability of biological trickling filter system for the
treatment of simulated textile wastewater containing reactive azo
dyes with bacterial consortium under non-sterile conditions. The
percentage decolorization for the treatment of wastewater containing
structurally different dyes was found to be higher than 95% in all
trials. The stable bacterial count of the biofilm on stone media of the
trickling filter during the treatment confirmed the presence,
proliferation, dominance and involvement of the added microbial
consortium in the treatment of textile wastewater. Results of
physicochemical parameters revealed the reduction in chemical
oxygen demand (58.5-75.1%), sulphates (18.9-36.5%), and
phosphates (63.6-73.0%). UV-Visible and FTIR spectroscopy
confirmed decolorization of dye containing wastewater was ultimate
consequence of biodegradation. Toxicological studies revealed the
nontoxic nature of degradative metabolites.
Abstract: This work is focused on the study of valuation of
recycled concrete aggregates, by measuring certain properties of
concrete in the fresh and hardened state. In this study, rheological
tests and physic-mechanical characterization on concretes and
mortars were conducted with recycled concrete whose geometric
properties were identified aggregates. Mortars were elaborated with
recycled fine aggregate (0/5mm) and concretes were manufactured
using recycled coarse aggregates (5/12.5 mm and 12.5/20 mm). First,
a study of the mortars was conducted to determine the effectiveness
of polycarboxylate superplasticizer on the workability of these and
their action deflocculating of the recycled sand. The rheological
behavior of mortars based on fine aggregate recycled was
characterized. The results confirm that the mortars composed of
different fractions of recycled sand (0 /5) have a better mechanical
properties (compressive and flexural strength) compared to normal
mortar. Also, the mechanical strengths of concretes made with
recycled aggregates (5/12.5 mm and 12.5/20 mm), are comparable to
those of conventional concrete with conventional aggregates,
provided that the implementation can be improved by the addition of
a superplasticizer.
Abstract: This review summarizes the potential of starch
agroindustrial residues as substrate for biohydrogen production.
Types of potential starch agroindustrial residues, recent developments
and bio-processing conditions for biohydrogen production will be
discussed. Biohydrogen is a clean energy source with great potential
to be an alternative fuel, because it releases energy explosively in
heat engines or generates electricity in fuel cells producing water as
only by-product. Anaerobic hydrogen fermentation or dark
fermentation seems to be more favorable, since hydrogen is yielded
at high rates and various organic waste enriched with carbohydrates
as substrate result in low cost for hydrogen production. Abundant
biomass from various industries could be source for biohydrogen
production where combination of waste treatment and energy
production would be an advantage. Carbohydrate-rich nitrogendeficient
solid wastes such as starch residues can be used for
hydrogen production by using suitable bioprocess technologies.
Alternatively, converting biomass into gaseous fuels, such as
biohydrogen is possibly the most efficient way to use these
agroindustrial residues.
Abstract: India holds 17.5% of the world’s population but has
only 2% of the total geographical area of the world where 27.35% of
the area is categorized as wasteland due to lack of or less
groundwater. So there is a demand for excessive groundwater for
agricultural and non agricultural activities to balance its growth rate.
With this in mind, an attempt is made to find the groundwater
potential zone in Gomukhi Nadhi sub basin of Vellar River basin,
TamilNadu, India covering an area of 1146.6 Sq.Km consists of 9
blocks from Peddanaickanpalayam to Virudhachalam in the sub
basin. The thematic maps such as Geology, Geomorphology,
Lineament, Landuse and Landcover and Drainage are prepared for
the study area using IRS P6 data. The collateral data includes rainfall,
water level, soil map are collected for analysis and inference. The
digital elevation model (DEM) is generated using Shuttle Radar
Topographic Mission (SRTM) and the slope of the study area is
obtained. ArcGIS 10.1 acts as a powerful spatial analysis tool to find
out the ground water potential zones in the study area by means of
weighted overlay analysis. Each individual parameter of the thematic
maps are ranked and weighted in accordance with their influence to
increase the water level in the ground. The potential zones in the
study area are classified viz., Very Good, Good, Moderate, Poor with
its aerial extent of 15.67, 381.06, 575.38, 174.49 Sq.Km respectively.
Abstract: Supermarkets are the most electricity-intensive type of
commercial buildings. The unsuitable indoor environment of a
supermarket provided by abnormal HVAC operations incurs waste
energy consumption in refrigeration systems. This current study
briefly describes significantly solid backgrounds and proposes easyto-
use analysis terminology for investigating the impact of HVAC
operations on refrigeration power consumption using the field-test
data obtained from building automation system (BAS). With solid
backgrounds and prior knowledge, expected energy interactions
between HVAC and refrigeration systems are proposed through
Pearson’s correlation analysis (R value) by considering correlations
between equipment power consumption and dominantly independent
variables (driving force conditions).The R value can be conveniently
utilized to evaluate how strong relations between equipment
operations and driving force parameters are. The calculated R values
obtained from field data are compared to expected ranges of R values
computed by energy interaction methodology. The comparisons can
separate the operational conditions of equipment into faulty and
normal conditions. This analysis can simply investigate the condition
of equipment operations or building sensors because equipment could
be abnormal conditions due to routine operations or faulty
commissioning processes in field tests. With systematically solid and
easy-to-use backgrounds of interactions provided in the present
article, the procedures can be utilized as a tool to evaluate the proper
commissioning and routine operations of HVAC and refrigeration
systems to detect simple faults (e.g. sensors and driving force
environment of refrigeration systems and equipment set-point) and
optimize power consumption in supermarket buildings. Moreover,
the analysis will be used to further study the FDD research for
supermarkets in future.
Abstract: Recently, an increasing number of researchers have
been focusing on working out realistic solutions to sustainability
problems. As sustainability issues gain higher importance for
organisations, the management of such decisions becomes critical.
Knowledge representation is a fundamental issue of complex
knowledge based systems. Many types of sustainability problems
would benefit from models based on experts’ knowledge. Cognitive
maps have been used for analyzing and aiding decision making. A
cognitive map can be made of almost any system or problem. A
fuzzy cognitive map (FCM) can successfully represent knowledge
and human experience, introducing concepts to represent the essential
elements and the cause and effect relationships among the concepts to
model the behaviour of any system. Integrated waste management
systems (IWMS) are complex systems that can be decomposed to
non-related and related subsystems and elements, where many factors
have to be taken into consideration that may be complementary,
contradictory, and competitive; these factors influence each other and
determine the overall decision process of the system. The goal of the
present paper is to construct an efficient IWMS which considers
various factors. The authors’ intention is to propose an expert based
system design approach for implementing expert decision support in
the area of IWMSs and introduces an appropriate methodology for
the development and analysis of group FCM. A framework for such a
methodology consisting of the development and application phases is
presented.
Abstract: This paper involved the performance of a hightemperature
X-Ray powder diffraction analysis (XRD) of a sample of
chemical gypsum generated in the production of titanium white; this
gypsum originates by neutralizing highly acidic water with limestone
suspension. Specifically, it was gypsum formed in the first stage of
neutralization when the resulting material contains, apart from
gypsum, a number of waste products resulting from the
decomposition of ilmenite by sulphuric acid. So it can be described as
red titanogypsum. By conducting the experiment using XRD
apparatus Bruker D8 Advance with a Cu anode (λkα=1.54184 Å)
equipped with high-temperature chamber Anton Paar HTK 16, it was
possible to identify clearly in the sample each phase transition in the
system of CaSO4·xH2O.
Abstract: This paper focuses on the presentation of results
which were obtained as a part of the project FR-TI 3/742: “System of
Lightweight Materials for Finishing of Buildings with Waste Raw
Materials”. Attention was paid to the light weighting of polymermodified
mortars applicable as adhesives, screeds and repair mortars.
In terms of repair mortars, they were ones intended for the sanitation
of aerated concrete.
Abstract: The discarded clam shell waste, fossil and edible oil
as biolubricant feedstocks create environmental impacts and food
chain dilemma, thus this work aims to circumvent these issues by
using activated saltwater clam shell waste (SCSW) as solid catalyst
for conversion of Jatropha curcas oil as non-edible sources to ester
biolubricant. The characterization of solid catalyst was done by
Differential Thermal Analysis-Thermo Gravimetric Analysis (DTATGA),
X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD),
Brunauer-Emmett-Teller (BET), Field Emission Scanning Electron
Microscopy (FESEM) and Fourier Transformed Infrared
Spectroscopy (FTIR) analysis. The calcined catalyst was used in the
transesterification of Jatropha oil to methyl ester as the first step, and
the second stage was involved the reaction of Jatropha methyl ester
(JME) with trimethylolpropane (TMP) based on the various process
parameters. The formated biolubricant was analyzed using the
capillary column (DB-5HT) equipped Gas Chromatography (GC).
The conversion results of Jatropha oil to ester biolubricant can be
found nearly 96.66%, and the maximum distribution composition
mainly contains 72.3% of triester (TE).
Abstract: This paper deals with the issue of biomass and sorted
municipal waste gasification and cogeneration using hot-air turbo-set.
It brings description of designed pilot plant with electrical output 80
kWe. The generated gas is burned in secondary combustion chamber
located beyond the gas generator. Flue gas flows through the heat
exchanger where the compressed air is heated and consequently
brought to a micro turbine. Except description, this paper brings our
basic experiences from operating of pilot plant (operating parameters,
contributions, problems during operating, etc.). The principal
advantage of the given cycle is the fact that there is no contact
between the generated gas and the turbine. So there is no need for
costly and complicated gas cleaning which is the main source of
operating problems in direct use in combustion engines because the
content of impurities in the gas causes operation problems to the units
due to clogging and tarring of working surfaces of engines and
turbines, which may lead as far as serious damage to the equipment
under operation. Another merit is the compact container package
making installation of the facility easier or making it relatively more
mobile. We imagine, this solution of cogeneration from biomass or
waste can be suitable for small industrial or communal applications,
for low output cogeneration.