Abstract: Brownfields are one of the most important problems
that must be solved by today's cities. The topic of this article is
description of developing a comprehensive transformation of postindustrial
area of the former iron factory national cultural heritage
lower Vítkovice. City of Ostrava used to be industrial superpower of
the Czechoslovak Republic, especially in the area of coal mining and
iron production, after declining industrial production and mining in
the 80s left many unused areas of former factories generally
brownfields and backfields. Since the late 90s we are observing how
the city officials or private entities seeking to remedy this situation.
Regeneration of brownfields is a very expensive and long-term
process. The area is now rebuilt for tourists and residents of the city
in the entertainment, cultural, and social center. It was necessary do
the reconstruction of the industrial monuments. Equally important
was the construction of new buildings, which helped reusing of the
entire complex. This is a unique example of transformation of
technical monuments and completion of necessary new objects, so
that the area could start working again and reintegrate back into the
urban system.
Abstract: A new fast growing trend in tourism is ecotourism, in
which tourists visit natural ecosystems under low impact, nonconsumptive
and locally oriented activities. Through these activities
species and habitats are maintained and typically, underdeveloped
regions are emphasized. Ecotourism provides a great alternative,
especially for rural and undeveloped area. At the same time, despite
its many benefits, it also poses many risks for the naturally protected
areas. If ecotourism is practiced improperly degradation and
irreversible damages could be the unwanted result. In addition, the
lack of MSc programs in the field of Ecotourism in Europe makes it a
necessity to be developed. Such an MSc program is being
implemented with the lead partner the Technical University of
Madrid. The entire partnership has six Universities, seven SMEs and
one National Park from seven different countries all over Europe.
The MSc will have 10 educational modules that will be available
online and will prepare professionals that will be able to implement
ecotourism in a sustainable way. Only through awareness and
education a sustainable ecotourism will be achieved in the protected
areas of Europe.
Abstract: In this paper, an experiment was conducted to assess
the impact of online deliberation on citizens’ attitudes. Specifically,
this research compared pre and post deliberation opinions of
participants who deliberated online via an asynchronous platform
regarding the issue of political opinion polls. Results indicate that
online deliberation had a positive effect on citizens’ attitudes since it
was found that following deliberation participants changed their
views regarding public opinion polls. Specifically, online deliberation
improved discussants perceptions regarding the reliability of polls,
while suppressing their negative views about the misuse of polls by
media, polling organizations and politicians.
Abstract: The reduction of phosphorus and sulfur in engine oil
are the main topics of this paper. Very reproducible boundary
lubrication tests were conducted as part of Design of Experiment
software (DOE) to study the behavior of fluorinated catalyst iron
fluoride (FeF3), and polutetrafluoroethylene or Teflon (PTFE) in
developing environmentally friendly (reduced P and S) anti-wear
additives for future engine oil formulations. Multi-component
Chevron fully formulated oil (GF3) and Chevron plain oil were used
with the addition of PTFE and catalyst to characterize and analyze
their performance. Lower phosphorus blends were the goal of the
model solution. Experiments indicated that new sub-micron FeF3
catalyst played an important role in preventing breakdown of the
tribofilm.
Abstract: The main objective of this study was to determine the
effects of Nitrogen fixing bacteria and manure application on the seed
yield and yield components in black cumin (Nigella sativa L.). The
experiment was carried out at the RAN Research Station in
Firouzkouh in 2012. A 4×4 factorial experiment, arranged in a
randomized complete blocks designed with three replications.
Nitrogen fixing bacteria at 4 levels (control, Azotobacter,
Azospirillum and Azotobacter + Azospirillum) and manure
application at 4 levels (0, 2.5, 5 and 7.5 ton ha-1) were used at this
investigation. The present results have shown that the highest height,
1000 seeds weight, seed number per follicle, follicle yield, seed yield
and harvest index were obtained after using Azotobacter and
Azospirillum, simultaneously. Manure application only effects on
follicle yield and by 5ton manure ha-1 the highest follicle yield
obtained. Results of this investigation showed that the maximum seed
yield obtained when Aotobacter+Azospirillum inoculated with black
cumin seeds and 5 ton manure ha-1 applied. According to the results
of this investigation the integrated management of Azotobacter and
Azospirillum with manure application is the best treatment for
achieving the maximum quantitative charactersitics of Black cumin.
Abstract: The paper provides a comprehensive analysis of the
sustainable development in the Belgrade Metropolitan Region - BMA
(level NUTS 2) preliminary evaluating the three chosen components:
1) economic growth and developmental changes; 2) competitiveness;
and 3) territorial concentration and industrial specialization. First, we
identified the main results of development changes and economic
growth by applying Shift-share analysis on the metropolitan level.
Second, the empirical evaluation of competitiveness in the BMA is
based on the analysis of absolute and relative values of eight
indicators by Spider method. Paper shows that the consideration of
the national share, industrial mix and metropolitan/regional share in
total Shift share of the BMA, as well as economic/functional
specialization of the BMA indicate very strong process of
deindustrialization. Allocative component of the BMA economic
growth has positive value, reflecting the above-average sector
productivity compared to the national average. Third, the important
positive role of metropolitan/regional component in decomposition of
the BMA economic growth is highlighted as one of the key results.
Finally, comparative analysis of the industrial territorial
concentration in the BMA in relation to Serbia is based on location
quotient (LQ) or Balassa index as a valid measure. The results
indicate absolute and relative differences in decrease of industry
territorial concentration as well as inefficiency of utilizing territorial
capital in the BMA. Results are important for the increase of regional
competitiveness and territorial distribution in this area as well as for
improvement of sustainable metropolitan and sector policies,
planning and governance on this level.
Abstract: There have been rigorous research and development
of unmanned aerial vehicles in the field of search and rescue (SAR)
operation recently. UAVs reduce unnecessary human risks while
assisting rescue efforts through aerial imagery, topographic mapping
and emergency delivery. The application of UAVs in offshore and
nearshore marine SAR missions is discussed in this paper. Projects
that integrate UAV technology into their systems are introduced to
highlight the great advantages and capabilities of UAVs. Scenarios
where UAVs could provide invaluable assistance are also suggested.
Abstract: Effect of sprue/metal head height on mould filling,
microstructure and mechanical properties of TWDI casting is studied.
Results show that metal/sprue height of 50 mm is not sufficient to
push the melt through the gating channel, but as it is increased from
100-350 mm, proper mould filling is achieved. However at higher
heights between 200 mm and 350 mm, defects associated with
incomplete solidification, carbide precipitation and turbulent flow are
evident. This research shows that superior UTS, hardness, nodularity
and nodule count are obtained at 100 mm sprue height.
Abstract: Si ion implantation was widely used to synthesize
specimens of SiO2 containing supersaturated Si and subsequent high
temperature annealing induces the formation of embedded
luminescent Si nanocrystals. In this work, the potentialities of excimer
UV-light (172 nm, 7.2 eV) irradiation and rapid thermal annealing
(RTA) to enhance the photoluminescence and to achieve low
temperature formation of Si nanocrystals have been investigated. The
Si ions were introduced at acceleration energy of 180 keV to fluence of
7.5 x 1016 ions/cm2. The implanted samples were subsequently
irradiated with an excimer-UV lamp. After the process, the samples
were rapidly thermal annealed before furnace annealing (FA).
Photoluminescence spectra were measured at various stages at the
process. We found that the luminescence intensity is strongly
enhanced with excimer-UV irradiation and RTA. Moreover, effective
visible photoluminescence is found to be observed even after FA at
900 oC, only for specimens treated with excimer-UV lamp and RTA.
We also prepared specimens of Si nanocrystals embedded in a SiO2 by
reactive pulsed laser deposition (PLD) in an oxygen atmosphere. We
will make clear the similarities and differences with the way of
preparation.
Abstract: This paper presents results of compressive strength,
capillary water absorption, and density tests conducted on concrete
containing recycled aggregate (RCA) which is obtained from
structural waste generated by the construction industry in Turkey. In
the experiments, 0%, 15%, 30%, 45% and 60% of the normal
(natural) coarse aggregate was replaced by the recycled aggregate.
Maximum aggregate particle sizes were selected as 16 mm, 22,4 mm
and 31,5 mm; and 0,06%, 0,13% and 0,20% of air-entraining agent
(AEA) were used in mixtures. Fly ash and superplasticizer were used
as a mineral and chemical admixture, respectively. The same type
(CEM I 42.5) and constant dosage of cement were used in the study.
Water/cement ratio was kept constant as 0.53 for all mixture. It was
concluded that capillary water absorption, compressive strength, and
density of concrete decreased with increasing RCA ratio. Increasing
in maximum aggregate particle size and amount of AEA also affect
the properties of concrete significantly.
Abstract: An Acoustic Micro-Energy Harvester (AMEH) is
developed to convert wasted acoustical energy into useful electrical
energy. AMEH is mathematically modeled using Lumped Element
Modelling (LEM) and Euler-Bernoulli beam (EBB) modelling. An
experiment is designed to validate the mathematical model and assess
the feasibility of AMEH. Comparison of theoretical and experimental
data on critical parameter value such as Mm, Cms, dm and Ceb showed
the variances are within 1% to 6%, which is reasonably acceptable.
Then, AMEH undergoes bandwidth tuning for performance
optimization. The AMEH successfully produces 0.9V/(m/s^2) and
1.79μW/(m^2/s^4) at 60Hz and 400kΩ resistive load which only
show variances about 7% compared to theoretical data. At 1g and
60Hz resonance frequency, the averaged power output is about
2.2mW which fulfilled a range of wireless sensors and
communication peripherals power requirements. Finally, the design
for AMEH is assessed, validated and deemed as a feasible design.
Abstract: Food poisoning and infection by bacteria are of public
health significance to both developing and developed countries.
Samples of ogi (akamu) prepared from white and yellow variety of
maize sold in Uturu and Okigwe were analyzed together with the
laboratory prepared ogi for bacterial quality using the standard
microbiological methods. The analyses showed that both white and
yellow variety had total bacterial counts (cfu/g) of 4.0 ×107 and 3.9 x
107 for the laboratory prepared ogi while the commercial ogi had 5.2
x 107 and 4.9 x107, 4.9 x107 and 4.5 x107, 5.4 x107 and 5.0 x107 for
Eke-Okigwe, Up-gate and Nkwo-Achara market respectively. The
Staphylococcal counts ranged from 2.0 x 102 to 5.0 x102 and 1.0 x
102 to 4.0 x102 for the white and yellow variety from the different
markets while Staphylococcal growth was not recorded on the
laboratory prepared ogi. The laboratory prepared ogi had no Coliform
growth while the commercially prepared ogi had counts of 0.5 x103
to 1.6 x 103 for white variety and 0.3 x 103 to 1.1 x103 for yellow
variety respectively. The Lactic acid bacterial count of 3.5x106 and
3.0x106 was recorded for the laboratory ogi while the commercially
prepared ogi ranged from 3.2x106 to 4.2x106 (white variety) and 3.0
x106 to 3.9 x106 (yellow). The presence of bacteria isolates from the
commercial and laboratory fermented ogi showed that Lactobacillus
sp, Leuconostoc sp and Citrobacter sp were present in all the
samples, Micrococcus sp and Klebsiella sp were isolated from Eke-
Okigwe and ABSU-up-gate markets varieties respectively, E. coli
and Staphylococcus sp were present in Eke-Okigwe and Nkwo-
Achara markets while Salmonella sp were isolated from the three
markets. Hence, there are chances of contracting food borne diseases
from commercially prepared ogi. Therefore, there is the need for
sanitary measures in the production of fermented cereals so as to
minimize the rate of food borne pathogens during processing and
storage.
Abstract: Psyllium gum alone and in combination with
sunflower oil was investigated as a possible alternative edible coating
for improvement of quality and shelf life of fresh-cut papaya.
Different concentrations including 0.5, 1 and 1.5 percent of psyllium
gum were used for coating of fresh-cut papaya. In some samples,
refined sunflower oil was used as a lipid component to increase the
effectiveness of coating in terms of water barrier properties. Soya
lecithin was used as an emulsifier in coatings containing oil.
Pretreatment with 1% calcium chloride was given to maintain the
firmness of fresh-cut papaya cubes. 1% psyllium gum coating was
found to yield better results. Further, addition of oil helped to
maintain the quality and acted as a barrier to water vapour, therefore,
minimizing the weight loss.
Abstract: The elastic properties and fracture of two-dimensional
graphene were calculated purely from the atomic bonding (stretching
and bending) based on molecular mechanics method. Considering the
representative unit cell of graphene under various loading conditions,
the deformations of carbon bonds and the variations of the interlayer
distance could be realized numerically under the geometry constraints
and minimum energy assumption. In elastic region, it was found that
graphene was in-plane isotropic. Meanwhile, the in-plane deformation
of the representative unit cell is not uniform along armchair direction
due to the discrete and non-uniform distributions of the atoms. The
fracture of graphene could be predicted using fracture criteria based on
the critical bond length, over which the bond would break. It was
noticed that the fracture behavior were directional dependent, which
was consistent with molecular dynamics simulation results.
Abstract: In this study, the feasibility of incorporating ceramic
waste from bricks (perforated brick and double hollow brick) and
extruded polystyrene (XPS) waste, is analysed.
Results show that it is possible to incorporate up to 25% of
ceramic waste and 4% of XPS waste over the weight of gypsum in a
gypsum matrix. Furthermore, with the addition of ceramic waste an
8% of surface hardness increase and a 25% of capillary water
absorption reduction can be obtained. On the other hand, with the
addition of XPS, a 26% reduction of density and a 37% improvement
of thermal conductivity can be obtained.
The obtained results are favorable to use these materials in order to
produce prefabricated gypsum and also as material for interior
cladding walls.
Abstract: Native American communities are struggling with unemployment and depressed economies. A major cause is a lack of business knowledge, education, and cultural desire. And yet, in the history of the American West, Native Americans were considered the best traders and negotiators for everything from furs to weapons to buffalo. To improve these economies, there has been an effort to reintroduce that heritage to todays and tomorrows generation of tribal members, such Crow, Cheyenne, and Blackfeet. Professors at the College of Business Montana State University-Billings (MSUB) teach tribal students in Montana to create business plans. These plans have won national small business plan competitions. The teaching and advising method used at MSUB is uniquely successful as theses business students are now five time national champions. This article reviews the environment and the method of learning to achieve a winning small business plan with Native American students. It discusses the five plans that became national champions. And it discusses the problems and solutions discovered in the process of achieving results. Students who participated in this endeavor have graduated and become CPAs, MBAs, and gainfully employed in their chosen professions. They have also worked to improve the economies of their native lands and homes. By educating members of these communities with business strategy and plan development, they are better able to impact their own economies.
Abstract: This work studies the effect of chemical composition
on the activity and selectivity of γ–alumina supported CuO/
MnO2/Cr2O3 catalysts toward deep oxidation of CO, dimethyl ether
(DME) and methanol. The catalysts were prepared by impregnation
of the support with an aqueous solution of copper nitrate, manganese
nitrate and CrO3 under different conditions. Thermal, XRD and TPR
analysis were performed. The catalytic measurements of single
compounds oxidation were carried out on continuous flow equipment
with a four-channel isothermal stainless steel reactor. Flow-line
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions that mimic closely the industrial
ones was used. The reactant and product gases were analyzed by
means of on-line gas chromatographs.
On the basis of XRD analysis it can be concluded that the active
component of the mixed Cu-Mn-Cr/γ–alumina catalysts consists of at
least six compounds – CuO, Cr2O3, MnO2, Cu1.5Mn1.5O4,
Cu1.5Cr1.5O4 and CuCr2O4, depending on the Cu/Mn/Cr molar ratio.
Chemical composition strongly influences catalytic properties, this
influence being quite variable with regards to the different processes.
The rate of CO oxidation rapidly decrease with increasing of
chromium content in the active component while for the DME was
observed the reverse trend. It was concluded that the best
compromise are the catalysts with Cu/(Mn + Cr) molar ratio 1:5 and
Mn/Cr molar ratio from 1:3 to 1:4.
Abstract: This paper aims to study the effect of cold work
condition on the microstructure of Cu-1.5wt%Ti, and Cu-3.5wt%Ti
and hence mechanical properties. The samples under investigation
were machined, and solution heat treated. X-ray diffraction technique
is used to identify the different phases present after cold deformation
by compression and also different heat treatment and also measuring
the relative quantities of phases present. The metallographic
examination is used to study the microstructure of the samples. The
hardness measurements were used to indicate the change in
mechanical properties. The results are compared with the mechanical
properties obtained by previous workers. Experiments on cold
compression followed by aging of Cu-Ti alloys have indicated that
the most efficient hardening of the material results from continuous
precipitation of very fine particles within the matrix. These particles
were reported to be β`-type, Cu4Ti phase. The β`-β transformation
and particles coarsening within the matrix as well as long grain
boundaries were responsible for the overaging of Cu-1.5wt%Ti and
Cu-3.5wt%Ti alloys. It is well known that plate-like particles are β –
type, Cu3Ti phase. Discontinuous precipitation was found to start at
the grain boundaries and expand into grain interior. At the higher
aging temperature, a classic Widmanstätten morphology forms giving
rise to a coarse microstructure comprised of α and the equilibrium
phase β. Those results were confirmed by X-ray analysis, which
found that a few percent of Cu3Ti, β precipitates are formed during
aging at high temperature for long time for both Cu- Ti alloys (i.e.
Cu-1.5wt%Ti and Cu-3.5wt%Ti).
Abstract: Amoxicillin is an antibiotic which is widely used to
treat various infections in both human beings and animals. However,
when amoxicillin is released into the environment, it is a major
problem. Amoxicillin causes bacterial resistance to these drugs and
failure of treatment with antibiotics. Liquid membrane is of great
interest as a promising method for the separation and recovery of the
target ions from aqueous solutions due to the use of carriers for the
transport mechanism, resulting in highly selectivity and rapid
transportation of the desired metal ions. The simultaneous processes
of extraction and stripping in a single unit operation of liquid
membrane system are very interesting. Therefore, it is practical to
apply liquid membrane, particularly the HFSLM for industrial
applications as HFSLM is proved to be a separation process with
lower capital and operating costs, low energy and extractant with
long life time, high selectivity and high fluxes compared with solid
membranes. It is a simple design amenable to scaling up for industrial
applications. The extraction and recovery for (Amoxicillin) through
the hollow fiber supported liquid membrane (HFSLM) using
aliquat336 as a carrier were explored with the experimental data. The
important variables affecting on transport of amoxicillin viz.
extractant concentration and operating time were investigated. The
highest AMOX- extraction percentages of 85.35 and Amoxicillin
stripping of 80.04 were achieved with the best condition at 6 mmol/L
[aliquat336] and operating time 100 min. The extraction reaction
order (n) and the extraction reaction rate constant (kf) were found to
be 1.00 and 0.0344 min-1, respectively.
Abstract: In this paper, the energy saving and human thermal
comfort in a typical office room are investigated. The impact of a
combined system of exhaust inlet air with light slots located at the
ceiling level in a room served by displacement ventilation system is
numerically modelled. Previous experimental data are used to
validate the Computational Fluid Dynamic (CFD) model. A case
study of simulated office room includes two seating occupants, two
computers, two data loggers and four lamps. The combined system is
located at the ceiling level above the heat sources. A new method of
calculation for the cooling coil load in Stratified Air Distribution
(STRAD) system is used in this study. The results show that 47.4%
energy saving of space cooling load can be achieved by combing the
exhaust inlet air with light slots at the ceiling level above the heat
sources.