Abstract: The study investigated efficiency cassava peel carbon
and Zinc Chloride activated cassava peel carbon at 1:3, 2:3 and 1:1
activation levels in the removal of nitrates from oxidized cassava
processing wastewater. Results showed that the CPC and CPAC were
effective in adsorption of nitrates. A summary of results from the
study revealed that CPAC at 1:3 exhibited the highest initial
decontamination (69.5% after 2 hrs) while CPAC at 1:1 activation
ratio showed a slower initial decontamination rate. The CPC &
CPAC exhibited Langmuir Rα values of 0.15, 0.11, 0.09, and 0.07 for
the 0:1, 1:3, 2:3 and 1:1 confirming its suitability as adsorption
material.
Abstract: The effects of wood ash from five common tropical
woods on the ignition point of four common tropical woods in
Nigeria were investigated. The ash and moisture contents of the wood
sawdust from Mahogany (Khaya ivorensis), Opepe (Sarcocephalus
latifolius), Abura (Mitragyna ciliata), Rubber (Heavea brasilensis)
and Poroporo (Sorghum bicolour) used, were determined using a
furnace (Vecstar furnaces, model ECF2, serial no. f3077) and oven
(Genlab laboratory oven, model MINO/040) respectively. The metal
contents of the five wood sawdust ash samples were determined
using a Perkin Elmer optima 3000 dv atomic absorption spectrometer
while the ignition points were determined using Vecstar furnaces
model ECF2. Poroporo had the highest ash content, 2.263g while
rubber had the least, 0.710g. The results for the moisture content
range from 2.971g to 0.903g. Magnesium metal had the highest
concentration of all the metals, in all the wood ash samples; with
mahogany ash having the highest concentration, 9.196ppm while
rubber ash had the least concentration of magnesium metal, 2.196
ppm. The ignition point results showed that the wood ashes from
mahogany and opepe increased the ignition points of the test wood
samples, Danta (Nesogordonia papaverifera), Ekpaya, Akomu
(Pycnanthus angolensis) and Oleku when coated on them while the
ashes from poroporo, rubber and abura decreased the ignition points
of the test wood samples when coated on them. However, Opepe saw
dust ash decreased the ignition point in one of the test wood samples,
suggesting that the metal content of the test wood sample was more
than that of the Opepe saw dust ash. Therefore, Mahogany and Opepe
saw dust ashes could be used in the surface treatment of wood to
enhance their fire resistance or retardancy. However, the caution to
be exercised in this application is that the metal content of the test
wood samples should be evaluated as well.
Abstract: Nonlinear evolution of broadband ultrasonic pulses
passed through the rock specimens is studied using the apparatus
“GEOSCAN-02M”. Ultrasonic pulses are excited by the pulses of Qswitched
Nd:YAG laser with the time duration of 10 ns and with the
energy of 260 mJ. This energy can be reduced to 20 mJ by some light
filters. The laser beam radius did not exceed 5 mm. As a result of the
absorption of the laser pulse in the special material – the optoacoustic
generator–the pulses of longitudinal ultrasonic waves are excited with
the time duration of 100 ns and with the maximum pressure
amplitude of 10 MPa. The immersion technique is used to measure
the parameters of these ultrasonic pulses passed through a specimen,
the immersion liquid is distilled water. The reference pulse passed
through the cell with water has the compression and the rarefaction
phases. The amplitude of the rarefaction phase is five times lower
than that of the compression phase. The spectral range of the
reference pulse reaches 10 MHz. The cubic-shaped specimens of the
Karelian gabbro are studied with the rib length 3 cm. The ultimate
strength of the specimens by the uniaxial compression is (300±10)
MPa. As the reference pulse passes through the area of the specimen
without cracks the compression phase decreases and the rarefaction
one increases due to diffraction and scattering of ultrasound, so the
ratio of these phases becomes 2.3:1. After preloading some horizontal
cracks appear in the specimens. Their location is found by one-sided
scanning of the specimen using the backward mode detection of the
ultrasonic pulses reflected from the structure defects. Using the
computer processing of these signals the images are obtained of the
cross-sections of the specimens with cracks. By the increase of the
reference pulse amplitude from 0.1 MPa to 5 MPa the nonlinear
transformation of the ultrasonic pulse passed through the specimen
with horizontal cracks results in the decrease by 2.5 times of the
amplitude of the rarefaction phase and in the increase of its duration
by 2.1 times. By the increase of the reference pulse amplitude from 5
MPa to 10 MPa the time splitting of the phases is observed for the
bipolar pulse passed through the specimen. The compression and
rarefaction phases propagate with different velocities. These features
of the powerful broadband ultrasonic pulses passed through the rock
specimens can be described by the hysteresis model of Preisach-
Mayergoyz and can be used for the location of cracks in the optically
opaque materials.
Abstract: The purpose of the present work was to develop an innovative food product with good textural and sensorial characteristics. The product, a new type of bread, was prepared with wheat (90%) and lupin (10%) flours, without the addition of any conservatives. Several experiences were also done to find the most appropriate proportion of lupin flour. The optimized product was characterized considering the rheological, physical-chemical and sensorial properties. The water absorption of wheat flour with 10% of lupin was higher than that of the normal wheat flours, and Wheat Ceres flour presented the lower value, with lower dough development time and high stability time. The breads presented low moisture but a considerable water activity. The density of bread decreased with the introduction of lupin flour. The breads were quite white, and during storage the colour parameters decreased. The lupin flour clearly increased the number of alveolus, but the total area increased significantly just for the Wheat Cerealis bread. The addition of lupin flour increased the hardness and chewiness of breads, but the elasticity did not vary significantly. Lupin bread was sensorially similar to wheat bread produced with WCerealis flour, and the main differences are the crust rugosity, colour and alveolus characteristics.
Abstract: The seriously damaged structures during earthquakes
show the need and importance of design of reinforced concrete
structures with high ductility. Reinforced concrete beam-column
joints have an important function in all structures. Under seismic
excitation, the beam column joint region is subjected to horizontal
and vertical shear forces whose magnitude is many times higher than
the adjacent beam and column. Strength and ductility of structures
depends mainly on proper detailing of the reinforcement in beamcolumn
joints and the old structures were found ductility deficient.
DSP materials are obtained by using high quantities of super
plasticizers and high volumes of micro silica. In the case of High
Performance Densified Small Particle Concrete (HPDSPC), since
concrete is dense even at the micro-structure level, tensile strain
would be much higher than that of the conventional SFRC, SIFCON
& SIMCON. This in turn will improve cracking behaviour, ductility
and energy absorption capacity of composites in addition to
durability. The fine fibers used in our mix are 0.3mm diameter and 10
mm which can be easily placed with high percentage. These fibers
easily transfer stresses and act as a composite concrete unit to take up
extremely high loads with high compressive strength. HPDSPC
placed in the beam column joints helps in safety of human life due to
prolonged failure.
Abstract: The main idea of this work is to investigate the effect
of knitted fabrics characteristics on moisture management properties.
Wetting and transport properties of single jersey, Rib 1&1 and
English Rib fabrics made out of cotton and blended Cotton/Polyester
yarns were studied. The dynamic water sorption of fabrics was
investigated under same isothermal and terrestrial conditions at
20±2°C-65±4% by using the Moisture Management Tester (MMT)
which can be used to quantitatively measure liquid moisture transfer
in one step in a fabric in multidirections: Absorption rate, moisture
absorbing time of the fabric's inner and outer surfaces, one-way
transportation capability, the spreading/drying rate, the speed of
liquid moisture spreading on fabric's inner and outer surfaces are
measured, recorded and discussed. The results show that fabric’s
composition and knit’s structure have a significant influence on those
phenomena.
Abstract: Ultraviolet photocatalytic oxidation (UV-PCO)
technology has been recommended as a green approach to health
indoor environment when it is integrated into mechanical ventilation
systems for inorganic and organic compounds removal as well as
energy saving due to less outdoor air intakes. Although much research
has been devoted to UV-PCO, limited information is available on the
UV-PCO behavior tested by the mixtures in literature. This project
investigated UV-PCO performance and by-product generation using a
single and a mixture of acetone and MEK at 100 ppb each in a
single-pass duct system in an effort to obtain knowledge associated
with competitive photochemical reactions involved in. The
experiments were performed at 20 % RH, 22 °C, and a gas flow rate of
128 m3/h (75 cfm). Results show that acetone and MEK mutually
reduced each other’s PCO removal efficiency, particularly negative
removal efficiency for acetone. These findings were different from
previous observation of facilitatory effects on the adsorption of
acetone and MEK on photocatalyst surfaces.
Abstract: In most existing buildings in hot climate, cooling
loads lead to high primary energy consumption and consequently
high CO2 emissions. These can be substantially decreased with
integrated renewable energy systems. Kuwait is characterized by its
dry hot long summer and short warm winter. Kuwait receives annual
total radiation more than 5280 MJ/m2 with approximately 3347 h of
sunshine. Solar energy systems consist of PV modules and parabolic
trough collectors are considered to satisfy electricity consumption,
domestic water heating, and cooling loads of an existing building.
This paper presents the results of an extensive program of energy
conservation and energy generation using integrated photovoltaic
(PV) modules and Parabolic Trough Collectors (PTC). The program
conducted on an existing institutional building intending to convert it
into a Net-Zero Energy Building (NZEB) or near net Zero Energy
Building (nNZEB). The program consists of two phases; the first
phase is concerned with energy auditing and energy conservation
measures at minimum cost and the second phase considers the
installation of photovoltaic modules and parabolic trough collectors.
The 2-storey building under consideration is the Applied Sciences
Department at the College of Technological Studies, Kuwait. Single
effect lithium bromide water absorption chillers are implemented to
provide air conditioning load to the building. A numerical model is
developed to evaluate the performance of parabolic trough collectors
in Kuwait climate. Transient simulation program (TRNSYS) is
adapted to simulate the performance of different solar system
components. In addition, a numerical model is developed to assess
the environmental impacts of building integrated renewable energy
systems. Results indicate that efficient energy conservation can play
an important role in converting the existing buildings into NZEBs as
it saves a significant portion of annual energy consumption of the
building. The first phase results in an energy conservation of about
28% of the building consumption. In the second phase, the integrated
PV completely covers the lighting and equipment loads of the
building. On the other hand, parabolic trough collectors of optimum
area of 765 m2 can satisfy a significant portion of the cooling load,
i.e about73% of the total building cooling load. The annual avoided
CO2 emission is evaluated at the optimum conditions to assess the
environmental impacts of renewable energy systems. The total annual
avoided CO2 emission is about 680 metric ton/year which confirms
the environmental impacts of these systems in Kuwait.
Abstract: In this paper, we study the optical nonlinearities of
Silver sulfide (Ag2S) nanostructures dispersed in the Dimethyl
sulfoxide (DMSO) under exposure to 532 nm, 15 nanosecond (ns)
pulsed laser irradiation. Ultraviolet–visible absorption spectrometry
(UV-Vis), X-ray diffraction (XRD), and transmission electron
microscopy (TEM) are used to characterize the obtained nanocrystal
samples. The band gap energy of colloid is determined by analyzing
the UV–Vis absorption spectra of the Ag2S NPs using the band
theory of semiconductors. Z-scan technique is used to characterize
the optical nonlinear properties of the Ag2S nanoparticles (NPs).
Large enhancement of two photon absorption effect is observed with
increase in concentration of the Ag2S nanoparticles using open Zscan
measurements in the ns laser regime. The values of the nonlinear
absorption coefficients are determined based on the local nonlinear
responses including two photon absorption. The observed aperture
dependence of the Ag2S NP limiting performance indicates that the
nonlinear scattering plays an important role in the limiting action of
the sample. The concentration dependence of the optical liming is
also investigated. Our results demonstrate that the optical limiting
threshold decreases with increasing the silver sulfide NPs in DMSO.
Abstract: Groundwater is vital to the livelihoods and health of the majority of the people, since it provides almost the entire water resource for domestic, agricultural and industrial uses. Groundwater quality comprises the physical, chemical and bacteriological qualities. The present investigation was carried out to determine the physicochemical and bacteriological quality of the ground water sources in the residential areas of Karakulam Grama Panchayath in Thiruvananthapuram district, Kerala state in India. Karakulam is located in the eastern suburbs of Thiruvananthapuram city. The major drinking water source of the residents in the study area is wells. The present study aims to assess the portability and irrigational suitability of groundwater in the study area. The water samples were collected from randomly selected dug wells and bore wells in the study area during post monsoon and pre monsoon seasons of the year 2014 after a preliminary field survey. The physical, chemical and bacteriological parameters of the water samples were analyzed following standard procedures. The concentration of heavy metals (Cd, Pb and Mn) in the acid digested water samples were determined by using an Atomic Absorption Spectrophotometer. The results showed that the pH of well water samples ranged from acidic to alkaline level. In majority of well water samples (>54 %) the iron and magnesium content were found high in both the seasons studied, and the values were above the permissible limits of WHO drinking water quality standards. Bacteriological analyses showed that 63% of the wells were contaminated with total coliforms in both the seasons studied. Irrigational suitability of groundwater was assessed by determining the chemical indices like Sodium Percentage (%Na), Sodium Adsorption Ratio (SAR), Residual Sodium Carbonate (RSC), Permeability Index (PI), and the results indicate that the well water in the study area are good for irrigation purposes. Therefore, the study reveals the degradation of drinking water quality groundwater sources in Karakulam Grama Panchayath in Thiruvananthapuram District, Keralain terms of its chemical and bacteriological characteristics, and is not potable without proper treatment. In the study, more than 1/3rdof the well water samples tested were positive for total coliforms, and the bacterial contamination may pose threat to public health. The study recommends the need for periodic well water quality monitoring in the study area and to conduct awareness programs among the residents.
Abstract: Nowadays, energy dissipation devices are commonly
used in structures. High rate of energy absorption during earthquakes
is the benefit of using such devices, which results in damage
reduction of structural elements, specifically columns. The hysteretic
damping capacity of energy dissipation devices is the key point that it
may adversely make analysis and design process complicated. This
effect may be generally represented by Equivalent Viscous Damping
(EVD). The equivalent viscous damping might be obtained from the
expected hysteretic behavior regarding to the design or maximum
considered displacement of a structure. In this paper, the hysteretic
damping coefficient of a steel Moment Resisting Frame (MRF),
which its performance is enhanced by a Buckling Restrained Brace
(BRB) system has been evaluated. Having foresight of damping
fraction between BRB and MRF is inevitable for seismic design
procedures like Direct Displacement-Based Design (DDBD) method.
This paper presents an approach to calculate the damping fraction for
such systems by carrying out the dynamic nonlinear time history
analysis (NTHA) under harmonic loading, which is tuned to the
natural system frequency. Two MRF structures, one equipped with
BRB and the other without BRB are simultaneously studied.
Extensive analysis shows that proportion of each system damping
fraction may be calculated by its shear story portion. In this way,
contribution of each BRB in the floors and their general contribution
in the structural performance may be clearly recognized, in advance.
Abstract: This study intends to show the influence of the
hydrolytic degradation on the properties of the e-PTFE/NOMEX®
membranes used in fire-protective clothing. The modification of
water vapour permeability, morphology and chemical structure was
examined by MOCON Permatran, electron microscopy scanning
(SEM), and ATR-FTIR, respectively. A decrease in permeability to
water vapour of the aged samples was observed following closure of
transpiration pores. Analysis of fiber morphology indicates the
appearance of defects at the fibers surface with the presence of micro
cavities. ATR-FTIR analysis reveals the presence of a new absorption
band attributed to carboxylic acid terminal groups generated during
the amide bond hydrolysis.
Abstract: High frequency automotive interior noise above 500
Hz considerably affects automotive passenger comfort. To reduce this
noise, sound insulation material is often laminated on body panels or
interior trim panels. For a more effective noise reduction, the sound
reduction properties of this laminated structure need to be estimated.
We have developed a new calculate tool that can roughly calculate the
sound absorption and insulation properties of laminate structure and
handy for designers. In this report, the outline of this tool and an
analysis example applied to floor mat are introduced.
Abstract: The composite flour blend consisting of corn, pearl
millet, black gram and wheat bran in the ratio of 80:5:10:5 was taken
to prepare the extruded product and their effect on physical properties
of extrudate was studied. The extrusion process was conducted in
laboratory by using twin screw extruder. The physical characteristics
evaluated include lateral expansion, bulk density, water absorption
index, water solubility index, and rehydration ratio and moisture
retention. The Central Composite Rotatable Design (CCRD) was
used to decide the level of processing variables i.e. feed moisture
content (%), screw speed (rpm), and barrel temperature (oC) for the
experiment. The data obtained after extrusion process were analyzed
by using response surface methodology. A second order polynomial
model for the dependent variables was established to fit the
experimental data. The numerical optimization studies resulted in
127°C of barrel temperature, 246 rpm of screw speed, and 14.5% of
feed moisture as optimum variables to produce acceptable extruded
product. The responses predicted by the software for the optimum
process condition resulted in lateral expansion 126%, bulk density
0.28 g/cm3, water absorption index 4.10 g/g, water solubility index
39.90%, rehydration ratio 544% and moisture retention 11.90% with
75% desirability.
Abstract: Synthesis of gold nanoparticles has attracted much
attention since the pioneering discovery of the high catalytic activity
of supported gold nanoparticles in the reaction of CO oxidation at
low temperature. In this research field, we used Na-montmorillonite
for gold nanoparticles stabilization; various gold loading percentage
1, 2 and 5% were used for gold nanoparticles preparation. The gold
nanoparticles were obtained using chemical reduction method using
NaBH4 as reductant agent. The obtained gold nanoparticles stabilized
in Na-montmorillonite were used as catalysts for the reduction of 4-
nitrophenol to aminophenol with sodium borohydride at room
temperature. The UV-Vis results confirmed directly the gold
nanoparticles formation. The XRD and N2 adsorption results showed
the formation of gold nanoparticles in the pores of montmorillonite
with an average size of 5 nm obtained on samples with 2% gold
loading percentage. The gold particles size increased with the
increase of gold loading percentage. The reduction reaction of 4-
nitrophenol into 4-aminophenol with NaBH4 catalyzed by Au-Namontmorillonite
catalyst exhibits remarkably a high activity; the
reaction was completed within 9 min for 1%Au-Na-montmorillonite
and within 3 min for 2%Au-Na-montmorillonite.
Abstract: In the present study, the properties of Al-Al2O3
nanocomposite hollow sphere structures were investigated. For this
reason, the Al-based nanocomposite hollow spheres with different
amounts of nano-alumina reinforcement (0-10wt %) and different
ratio of thickness to diameter (t/D: 0.06-0.3) were prepared via a
powder metallurgy method. Then, the effect of mentioned parameters
was studied on physical and quasi static mechanical properties of
their related prepared structures (open/closed cell) such as density,
hardness, strength, and energy absorption. It was found that, as the
t/D ratio increases the relative density, compressive strength and
energy absorption increase. The highest values of strength and energy
absorption were obtained from the specimen with 5 wt. % of
nanoparticle reinforcement, t/D of 0.3 (t=1 mm, D=400μm) as 22.88
MPa and 13.24 MJ/m3, respectively. The moderate specific strength
of prepared composites in the present study showed the good
consistency with the properties of others low carbon steel composite
with similar structure.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: In recent research copper and manganese systems
were found to be the most active in CO and organic compounds
oxidation among the base catalysts. The mixed copper manganese
oxide has been widely studied in oxidation reactions because of their
higher activity at low temperatures in comparison with single oxide
catalysts. The results showed that the formation of spinel
CuxMn3−xO4 in the oxidized catalyst is responsible for the activity
even at room temperature. That is why the most of the investigations
are focused on the hopcalite catalyst (CuMn2O4) as the best coppermanganese
catalyst. Now it’s known that this is true only for CO
oxidation, but not for mixture of CO and VOCs. The purpose of this
study is to investigate the alumina supported copper-manganese
catalysts with different Cu/Mn molar ratio in terms of oxidation of
CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of γ-Al2O3 with
copper and manganese nitrates and the catalytic activity
measurements were carried out in two stage continuous flow
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions closest possible to the industrial. Gas
mixtures on the input and output of the reactor were analyzed with a
gas chromatograph, equipped with FID and TCD detectors. The
texture characteristics were determined by low-temperature (- 196oС)
nitrogen adsorption in a Quantachrome Instruments NOVA 1200e
(USA) specific surface area & pore analyzer. Thermal, XRD and
TPR analyses were performed. It was established that the active component of the mixed Cu-
Mn/γ–alumina catalysts strongly depends on the Cu/Mn molar ratio.
Highly active alumina supported Cu-Mn catalysts for CO, methanol
and DME oxidation were synthesized. While the hopcalite is the best
catalyst for CO oxidation, the best compromise for simultaneous
oxidation of all components is the catalyst with Cu/Mn molar ratio
1:5.
Abstract: Present work deals with the possible use of fertigation
in agriculture and its impact on the availability of mineral nitrogen
(Nmin) in topsoil and subsoil horizons. The aim of the present study is
to demonstrate the effect of the organic matter presence in fertigation
on microbial transformation and availability of mineral nitrogen
forms. The main investigation reason is the potential use of pretreated
waste water, as a source of organic carbon (Corg) and residual
nutrients (Nmin) for fertigation. Laboratory experiment has been
conducted to demonstrate the effect of the arable land fertilization
method on the Nmin availability in different depths of the soil with
the usage of model experimental containers filled with soil from
topsoil and podsoil horizons that were taken from the precise area.
Tufted hairgrass (Deschampsia caespitosa) has been chosen as a
model plant. The water source protection zone Brezova nad Svitavou
has been a research area where significant underground reservoirs of
drinking water of the highest quality are located. From the second
half of the last century local sources of drinking water show
nitrogenous compounds increase that get here almost only from
arable lands. Therefore, an attention of the following text focuses on
the fate of mineral nitrogen in the complex plant-soil. Research
results show that the fertigation application with Corg in a
combination with mineral fertilizer can reduce the amount of Nmin
leached from topsoil horizon of agricultural soils. In addition, some
plants biomass production reduces may occur.
Abstract: This paper presents results of compressive strength,
capillary water absorption, and density tests conducted on concrete
containing recycled aggregate (RCA) which is obtained from
structural waste generated by the construction industry in Turkey. In
the experiments, 0%, 15%, 30%, 45% and 60% of the normal
(natural) coarse aggregate was replaced by the recycled aggregate.
Maximum aggregate particle sizes were selected as 16 mm, 22,4 mm
and 31,5 mm; and 0,06%, 0,13% and 0,20% of air-entraining agent
(AEA) were used in mixtures. Fly ash and superplasticizer were used
as a mineral and chemical admixture, respectively. The same type
(CEM I 42.5) and constant dosage of cement were used in the study.
Water/cement ratio was kept constant as 0.53 for all mixture. It was
concluded that capillary water absorption, compressive strength, and
density of concrete decreased with increasing RCA ratio. Increasing
in maximum aggregate particle size and amount of AEA also affect
the properties of concrete significantly.