Abstract: NiFe2O4 (nickel ferrite), ZnFe2O4 (zinc ferrite) and
Ni0.5Zn0.5Fe2O4 (nickel-zinc ferrite) were prepared by
mechanochemical route in a planetary ball mill starting from mixture
of the appropriate quantities of the Ni(OH)2/Fe(OH)3,
Zn(OH)2/Fe(OH)3 and Ni(OH)2/Zn(OH)2/Fe(OH)3 hydroxide
powders. In order to monitor the progress of chemical reaction and
confirm phase formation, powder samples obtained after 25 h, 18 h
and 10 h of milling were characterized by X-ray diffraction (XRD),
transmission electron microscopy (TEM), IR, Raman and Mössbauer
spectroscopy. It is shown that the soft mechanochemical method, i.e.
mechanochemical activation of hydroxides, produces high quality
single phase ferrite samples in much more efficient way. From the IR
spectroscopy of single phase samples it is obvious that energy of
modes depends on the ratio of cations. It is obvious that all samples
have more than 5 Raman active modes predicted by group theory in
the normal spinel structure. Deconvolution of measured spectra
allows one to conclude that all complex bands in the spectra are made
of individual peaks with the intensities that vary from spectrum to
spectrum. The deconvolution of Raman spectra allows to separate
contributions of different cations to a particular type of vibration and
to estimate the degree of inversion.
Abstract: This study focuses on the hydro-geology and chemical
constituents analysis of Ikogosi Warm Spring waters in South West
Nigeria. Ikogosi warm spring is a global tourist attraction because it
has both warm and cold spring sources. Water samples from the cold
spring, warm spring and the meeting point were collected, analyzed
and the result shows close similarity in temperature, hydrogen iron
concentration (pH), alkalinity, hardness, Calcium, Magnesium,
Sodium, Iron, total dissolved solid and heavy metals. The measured
parameters in the water samples are within World Health
Organisation standards for fresh water. The study of the geology of
the warm spring reveals that the study area is underlain by a group of
slightly migmatised to non-migmatised paraschists and meta-igneous
rocks. Also, concentration levels of selected heavy metals, (Copper,
Cadmium, Zinc, Arsenic and Cromium) were determined in the water
(ppm) samples. Chromium had the highest concentration value of
1.52ppm (an average of 49.67%) and Cadmium had the lowest
concentration with value of 0.15ppm (an average of 4.89%).
Comparison of these results showed that, their mean levels are within
the standard values obtained in Nigeria. It can be concluded that both
warm and spring water are safe for drinking.
Abstract: The ferrites ZnFe2O4, CdFe2O4 and CuFe2O4 are
synthesized in laboratory conditions using ceramic technology. Their
homogeneity and structure are proven by X-Ray diffraction analysis
and Mössbauer spectroscopy. The synthesized ferrites are subjected
to strong acid and high temperature leaching with solutions of H2SO4,
HCl and HNO3. The results indicate that the highest degree of
leaching of Zn, Cd and Cu from the ferrites is achieved by use of
HCl. The charging of five zinc sulfide concentrates was optimized using
the criterion of minimal amount of zinc ferrite produced when
roasting the concentrates in a fluidized bed. The results obtained are
interpreted in terms of the hydrometallurgical zinc production and
maximum recovery of zinc, copper and cadmium from initial zinc
concentrates after their roasting.
Abstract: The study investigated efficiency cassava peel carbon
and Zinc Chloride activated cassava peel carbon at 1:3, 2:3 and 1:1
activation levels in the removal of nitrates from oxidized cassava
processing wastewater. Results showed that the CPC and CPAC were
effective in adsorption of nitrates. A summary of results from the
study revealed that CPAC at 1:3 exhibited the highest initial
decontamination (69.5% after 2 hrs) while CPAC at 1:1 activation
ratio showed a slower initial decontamination rate. The CPC &
CPAC exhibited Langmuir Rα values of 0.15, 0.11, 0.09, and 0.07 for
the 0:1, 1:3, 2:3 and 1:1 confirming its suitability as adsorption
material.
Abstract: Zinc borate is an important inorganic hydrate borate
material, which can be used as a flame retardant agent and corrosion
resistance material. This compound can loss its structural water
content at higher than 290°C. Due to thermal stability; Zinc Borate
can be used as flame retardant at high temperature process of plastic
and gum. In this study, the ultrasonic reaction of zinc borates were
studied using hydrozincite (Zn5(CO3)2·(OH)6) and boric acid
(H3BO3) raw materials. Before the synthesis raw materials were
characterized by X-Ray Diffraction (XRD) and Fourier Transform
Infrared Spectroscopy (FT-IR). Ultrasonic method is a new
application on the zinc borate synthesis. The synthesis parameters
were set to 90°C reaction temperature and 55 minutes of reaction
time, with 1:1, 1:2, 1:3, 1:4 and 1:5 molar ratio of starting materials
(Zn5(CO3)2·(OH)6 : H3BO3). After the zinc borate synthesis, the
products were analyzed by XRD and FT-IR. As a result, optimum
molar ratio of 1:5 is determined for the synthesis of zinc borates with
ultrasonic method.
Abstract: In this work, the plastic behaviour of cold-rolled zinc
coated dual-phase steel sheets DP600 and DP800 grades is firstly
investigated with the help of uniaxial, hydraulic bulge and Forming
Limit Curve (FLC) tests. The uniaxial tensile tests were performed in
three angular orientations with respect to the rolling direction to
evaluate the strain-hardening and plastic anisotropy. True stressstrain
curves at large strains were determined from hydraulic bulge
testing and fitted to a work-hardening equation. The limit strains are
defined at both localized necking and fracture conditions according to
Nakajima’s hemispherical punch procedure. Also, an elasto-plastic
localization model is proposed in order to predict strain and stress
based forming limit curves. The investigated dual-phase sheets
showed a good formability in the biaxial stretching and drawing FLC
regions. For both DP600 and DP800 sheets, the corresponding
numerical predictions overestimated and underestimated the
experimental limit strains in the biaxial stretching and drawing FLC
regions, respectively. This can be attributed to the restricted failure
necking condition adopted in the numerical model, which is not
suitable to describe the tensile and shear fracture mechanisms in
advanced high strength steels under equibiaxial and biaxial stretching
conditions.
Abstract: The use of titanium fluoride and iron fluoride
(TiF3/FeF3) catalysts in combination with polutetrafluoroethylene
(PTFE) in plain zinc- dialkyldithiophosphate (ZDDP) oil is important
for the study of engine tribocomponents and is increasingly a strategy
to improve the formation of tribofilm and provide low friction and
excellent wear protection in reduced phosphorus plain ZDDP oil. The
influence of surface roughness and the concentration of
TiF3/FeF3/PTFE were investigated using bearing steel samples
dipped in lubricant solution at 100°C for two different heating time
durations. This paper addresses the effects of water drop contact
angle using different surface; finishes after treating them with
different lubricant combination. The calculated water drop contact
angles were analyzed using Design of Experiment software (DOE)
and it was determined that a 0.05 μm Ra surface roughness would
provide an excellent TiF3/FeF3/PTFE coating for antiwear resistance
as reflected in the Scanning electron microscopy (SEM) images and
the tribological testing under extreme pressure conditions. Both
friction and wear performance depend greatly on the PTFE/and
catalysts in plain ZDDP oil with 0.05 % phosphorous and on the
surface finish of bearing steel. The friction and wear reducing effects,
which was observed in the tribological tests, indicated a better micro
lubrication effect of the 0.05 μm Ra surface roughness treated at
100°C for 24 hours when compared to the 0.1 μm Ra surface
roughness with the same treatment.
Abstract: Nanotechnology has become the world attention in
various applications including the solar cells devices due to the
uniqueness and benefits of achieving low cost and better
performances of devices. Recently, thin film solar cells such as
Cadmium Telluride (CdTe), Copper-Indium-Gallium-diSelenide
(CIGS), Copper-Zinc-Tin-Sulphide (CZTS), and Dye-Sensitized
Solar Cells (DSSC) enhanced by nanotechnology have attracted
much attention. Thus, a compilation of nanotechnology devices
giving the progress in the solar cells has been presented. It is much
related to nanoparticles or nanocrystallines, carbon nanotubes, and
nanowires or nanorods structures.
Abstract: RF magnetron sputtering is used on the ceramic targets,
each of which contains zinc oxide (ZnO), zinc oxide doped with
aluminum (AZO) and zinc oxide doped with gallium (GZO). The XRD
analysis showed a preferred orientation along the (002) plane for ZnO,
AZO, and GZO films. The AZO film had the best electrical properties;
it had the lowest resistivity of 6.6 × 10-4 cm, the best sheet resistance of
2.2 × 10-1 Ω/square, and the highest carrier concentration of 4.3 × 1020
cm-3, as compared to the ZnO and GZO films.
Abstract: In present global scenario, aluminum alloys are
coining the attention of many innovators as competing structural
materials for automotive and space applications. Comparing to other
challenging alloys, especially, 7xxx series aluminum alloys have
been studied seriously because of benefits such as moderate strength;
better deforming characteristics and affordable cost. It is expected
that substitution of aluminum alloys for steels will result in great
improvements in energy economy, durability and recyclability.
However, it is necessary to improve the strength and the formability
levels at low temperatures in aluminum alloys for still better
applications. Aluminum–Zinc–Magnesium with or without other
wetting agent denoted as 7XXX series alloys are medium strength
heat treatable alloys. In addition to Zn, Mg as major alloying
additions, Cu, Mn and Si are the other solute elements which
contribute for the improvement in mechanical properties by suitable
heat treatment process. Subjecting to suitable treatments like age
hardening or cold deformation assisted heat treatments; known as low
temperature thermomechanical treatments (LTMT) the challenging
properties might be incorporated. T6 is the age hardening or
precipitation hardening process with artificial aging cycle whereas T8
comprises of LTMT treatment aged artificially with X% cold
deformation. When the cold deformation is provided after solution
treatment, there is increase in hardness related properties such as
wear resistance, yield and ultimate strength, toughness with the
expense of ductility. During precipitation hardening both hardness
and strength of the samples are increasing. The hardness value may
further improve when room temperature deformation is positively
supported with age hardening known as thermomechanical treatment.
It is intended to perform heat treatment and evaluate hardness, tensile
strength, wear resistance and distribution pattern of reinforcement in
the matrix. 2 to 2.5 and 3 to 3.5 times increase in hardness is reported
in age hardening and LTMT treatments respectively as compared to
as-cast composite. There was better distribution of reinforcements in
the matrix, nearly two fold increase in strength levels and up to 5
times increase in wear resistance are also observed in the present
study.
Abstract: For this study, a town based soil database created in
Gümüsçay District of Biga Town, Çanakkale, Turkey. Crop and
livestock production are major activities in the district. Nutrient
management is mainly based on commercial fertilizer application
ignoring the livestock manure. Within the boundaries of district, 122
soil sampling points determined over the satellite image. Soil samples
collected from the determined points with the help of handheld
Global Positioning System. Labeled samples were sent to a
commercial laboratory to determine 11 soil parameters including
salinity, pH, lime, organic matter, nitrogen, phosphorus, potassium,
iron, manganese, copper and zinc. Based on the test results soil maps
for mentioned parameters were developed using remote sensing, GIS,
and geostatistical analysis. In this study we developed a GIS database
that will be used for soil nutrient management. Methods were
explained and soil maps and their interpretations were summarized in
the study.
Abstract: Optimal feeding, including optimal micronutrient
intake, becomes one of the ways to overcome the long-term
consequences of undernutrition. Macronutrient and micronutrient
intake were important to a rapid growth and development of young
children. The study objective was to assess macro and micronutrient
intake and its adequacy in children aged 12-23 months. This survey
was a cross-sectional study, involving 83 caregivers with children
aged 12-23 months old in Senen Sub-district, Central Jakarta selected
through simple random sampling. Data on nutrient intake was
obtained through interview using single 24-hour recall. Repeated 24-
hour recall to sub-sample was done to estimate the proportion of
nutrient inadequacy. The highest prevalence of nutrient inadequacy
was iron (52.4%), followed by vitamin C (30.9%) and zinc (28.8%).
Almost 12% children had inadequate energy intake. More than half
of children (62.6%) were anemic (25.3% were severely anemic).
Micronutrient inadequacy, especially iron, was more problematic
than macronutrient inadequacy in the study area.
Abstract: The addition of lime as Ca(OH)2 to sewage sludge to
destroy pathogens (Escherichia coli), was evaluated also in relation
to heavy metal bioavailability.
The obtained results show that the use of calcium hydroxide at the
dose of 3% effectively destroyed pathogens ensuring the stability at
high pH values over long period and the duration of the sewage
sludge stabilization. In general, lime addition decreased the total
extractability of heavy metals indicating a reduced bioavailability of
these elements. This is particularly important for a safe utilization in
agricultural soils to reduce the possible transfer of heavy metals to
the food chain.
Abstract: The concentrations of heavy metals in sediments of
Qua Iboe River Estuary (QIRE) were monitored at four different
sampling locations in wet and dry seasons. A preliminary survey to
determine the four sampling stations along the river continuum
showed that the area spanned between
Abstract: We investigated the structure and electronic properties
of the compound Mg1-xBixO with varying concentrations of 0, ¼, ½,
and ¾ x bismuth in the the cesium chloride (CsCl), zinc-blende
(ZnS), nickel arsenide (NiAs) NaCl (rock-salt) and WZ (wurtzite)
phases. We calculated. The calculations were performed using the
first-principles pseudo-potential method within the framework of spin
density functional theory (DFT).
Abstract: A field study was conducted to evaluate the efficacy
of lavender for phytoremediation of contaminated soils. The
experiment was performed on an agricultural fields contaminated by
the Non-Ferrous-Metal Works near Plovdiv, Bulgaria. The
concentrations of Pb, Zn and Cd in lavender (roots, stems, leaves and
inflorescences) and in the essential oils of lavender were determined.
Lavender is a plant which is tolerant to heavy metals and can be
grown on contaminated soils, and which can be referred to the
hyperaccumulators of lead and the accumulators of cadmium and
zinc, and can be successfully used in the phytoremediation of heavy
metal contaminated soils. Favorable is also the fact that heavy metals
do not influence the development of the lavender, as well as on the
quality and quantity of the essential oil. The possibility of further
industrial processing will make lavender economically interesting
crops for farmers of phytoextraction technology.
Abstract: The capability of exploiting the electronic charge and
spin properties simultaneously in a single material has made diluted
magnetic semiconductors (DMS) remarkable in the field of
spintronics. We report the designing of DMS based on zinc-blend
ZnO doped with Cr impurity. The full potential linearized augmented
plane wave plus local orbital FP-L(APW+lo) method in density
functional theory (DFT) has been adapted to carry out these
investigations. For treatment of exchange and correlation energy,
generalized gradient approximations have been used. Introducing Cr
atoms in the matrix of ZnO has induced strong magnetic moment
with ferromagnetic ordering at stable ground state. Cr:ZnO was found
to favor the short range magnetic interaction that
reflect tendency of Cr clustering. The electronic structure of ZnO is
strongly influenced in the presence of Cr impurity atoms where
impurity bands appear in the band gap.
Abstract: Activated carbon is an amorphous carbon chain which
has extremely extended surface area. High surface area of activated
carbon is due to the porous structure. Activated carbon, using a
variety of materials such as coal and cellulosic materials; can be
obtained by both physical and chemical methods. The prepared
activated carbon can be used for decolorize, deodorize and also can
be used for removal of organic and non-organic pollution. In this
study, pomegranate peel was subjected to 800W microwave power
for 1 to 4 minutes. Also fresh pomegranate peel was used for the
reference material. Then ZnCl2 was used for the chemical activation
purpose. After the activation process, activated pomegranate peels
were used for the adsorption of Zn metal (40 ppm) in the waste water.
As a result of the adsorption experiments, removal of heavy metals
ranged from 89% to 85%.
Abstract: Zinc oxide (ZnO) is one of the light emitting materials in ultraviolet (UV) region. In addition, ZnO nanostructures are also attracting increasing research interest as buildingblocks for UV optoelectronic applications. We have succeeded in synthesizing vertically-aligned ZnO nanostructures by laser interference patterning, which is catalyst-free and non-contact technique. In this study, vertically-aligned ZnO nanowall arrays were synthesized using two-beam interference. The maximum height and average thickness of the ZnO nanowalls were about 4.5µm and 200 nm, respectively.UV lasing from a piece of the ZnO nanowall was obtained under the third harmonic of a Q-switched Nd:YAG laser excitation, and the estimated threshold power density for lasing was about 150 kW/cm2. Furthermore, UV lasing from the vertically-aligned ZnO nanowall was also achieved. The results indicate that ZnO nanowalls can be applied to random laser.
Abstract: The concentration levels of six heavy metals (Cd, Cr,
Fe, Ni, Pb and Zn) and two mineral elements (Ca and Mg) were
determined in soil samples collected from the vicinity of two auto
mechanic workshops in Sabon-Gari, Kaduna state, Nigeria, using
Atomic Absorption Spectrometry (AAS), in order to compare the
gradation of their concentrations with distance and depth of soil from
the workshop sites. At site 1, concentrations of Lead, Chromium, Iron
and Zinc were generally found to be above the World Health
Organization limits, while those of Nickel and Cadmium fell within
the limits. Iron had the highest concentration with a range of 176.274
ppm to 489.127 ppm at depths of 5 cm to 15 cm and a distance range
of 5 m to 15 m, while the concentration of cadmium was least with a
range of 0.001 ppm to 0.008 ppm at similar depth and distance
ranges. In addition, there was more of calcium (11.521 ppm to
121.709 ppm), in all the samples, than magnesium (11.293 ppm to
21.635 ppm). Similar results were obtained for site II. The
concentrations of all the metals analyzed showed a downward
gradient with increase in depth and distance from both workshop sites
except for iron and zinc at site 2. The immediate and remote
implications of these findings on the biota are discussed.