Ferrites of the MeFe2O4 System (Me – Zn, Cu, Cd) and Their Two Faces

The ferrites ZnFe2O4, CdFe2O4 and CuFe2O4 are
synthesized in laboratory conditions using ceramic technology. Their
homogeneity and structure are proven by X-Ray diffraction analysis
and Mössbauer spectroscopy. The synthesized ferrites are subjected
to strong acid and high temperature leaching with solutions of H2SO4,
HCl and HNO3. The results indicate that the highest degree of
leaching of Zn, Cd and Cu from the ferrites is achieved by use of
HCl. The charging of five zinc sulfide concentrates was optimized using
the criterion of minimal amount of zinc ferrite produced when
roasting the concentrates in a fluidized bed. The results obtained are
interpreted in terms of the hydrometallurgical zinc production and
maximum recovery of zinc, copper and cadmium from initial zinc
concentrates after their roasting.





References:
[1] B. Boyanov, A. Peltekov and V. Petkova, “Thermal behavior of zinc
sulfide concentrates with different iron content at oxidative roasting”,
Thermochim. Acta., vol. 586, June. 2014, pp. 9–16.
[2] T. Chen and J. E. Dutrizac, “Mineralogical changes occurring during the
fluid bed roasting of zinc sulfide concentrates”, JOM, vol. 56, Dec.
2004, pp. 46–51.
[3] A. R. Queiroz, R. J. Carvalho and F. J. Moura, “Oxidation of zinc
sulphide concentrate in a fluidized bed reactor – Part 2: The influence of
experimental variables on the kinetics”, Braz. J. Chem. Eng., vol. 22,
Jan./Mar. 2005, pp. 127–133.
[4] R. I. Dimitrov, N. I. Moldovanska, K. Bonev and Z. Zivkovic,
“Oxidation of marmatite”, Thermochim. Acta, vol. 362, Nov. 2000, pp.
145–151.
[5] J. W. Graydon and D. W. Kirk, “The mechanism of ferrite formation
from iron sulfides during zinc roasting”, Mett. Trans. B, vol. 19, Oct.
1988, pp. 777–785.
[6] A. C. Hee, M. Mehrali, H. S. C. Mtselaar, M. Mehrali and N. A. A.
Osman, “Comparison of nanostructured nickel zinc ferrite and
magnesium copper zinc ferrite prepared by water-in-oil microemulsion”,
Electr. Mater. Lett., vol. 8, Dec. 2012, pp. 639–642.
[7] L. B. Tahar, H. Basti, F. Herbst, L. S. Smiri, J. P Quisefit, N. Yaacoub,
J. M. Greneche and S. Ammar, “Co1-xZnxFe2O4 (0 ≤ x ≤ 1)
nanocrystalline solid solution prepared by the polyol method:
Characterization and magnetic properties”, Mater. Res. Bulletin, vol. 47,
Apr. 2012, pp. 2590–2598.
[8] V. L. O. Brito, L. F. A. Almeida, A. K. Hirata and A. C. C. Migliano,
“Evaluation of a Ni-Zn ferrite for use in temperature sensors”, PIER
Letters, vol. 13, Sept. 2010, pp. 103–112.
[9] H. Irakoso, K. Einosuke; W. Atanabe, B. Aba, R. Iichi; N. Aagai and T.
Adao, Fundamental studies of zinc ferrite, (Book). Hokkaido University
Collection of Scholarly and Academic Papers (HUSCAP), Hokkaido,
1955, pp. 39–57.
[10] A. M. Gismelseed, K. A. Mohammed, N. M. Widatallah, A. D. Al-
Rawas, M. E. Elzain and A. A. Yousif, “The structural and magnetic
behavior of the MgFe2−xCrxO4 spinel ferrite”, Hyperfine Interact., vol.
217, Jan. 2012, pp. 33–37.
[11] K. N. Harish, H. S. B. Naik, P. N. P. Kumar and R. Viswanath,
“Synthesis, enhanced optical and photocatalytic study of Cd-Zn ferrites
under sun light”, Catal. Sci. Technol., vol. 2, Jan. 2012, pp. 1033–1039.
[12] K. Ali, A. Iqbal, M. R. Ahmad, Y. Jamil, S. A. Khan, N. Amin, M. A.
Iqbal, and M. Z. M. Jafri, “Structural characterization of CuFe2O4
nanocomposites and synthesis by an economical method”, Sci. Int.
(Lahore), vol. 23, Mar. 2011, pp. 21−25.
[13] M. Chakrabarti, D. Sanyal and A. Chakrabarti, Preparation of
Zn(1−x)CdxFe2O4 (x = 0.0, 0.1, 0.3, 0.5, 0.7 and 1.0) ferrite samples and
their characterization by Mössbauer and positron annihilation
techniques”, J. Phys.: Condens. Matter, vol. 19, May 2007, pp. 236210–
236220.
[14] M. M. Rashad , R. M. Mohamed, M. A. Ibrahim, L. F. M. Ismail and E.
A. Abdel-Aal, “Magnetic and catalytic properties of cubic copper ferrite
nanopowders synthesized from secondary resources”, Adv. Powder
Technol., vol. 23, May 2012, pp. 315–323.
[15] M. G. Naseri, E. B. Saion, H. A. Ahangar and A. H. Shaari,
“Fabrication, characterization, and magnetic properties of copper ferrite
nanoparticles prepared by a simple, thermal-treatment method”, Mater.
Res. Bull., vol. 48, Apr. 2013, pp. 1439–1446.
[16] I. V. K. Viswanath, Y. L. N. Murthy, K. R. Tata and R. Singh,
“Synthesis and characterization of nano ferrites by citrate gel method”,
Int. J. Chem. Sci., vol. 11, Dec. 2013, pp. 64–72.
[17] H. Ehrhardt, S. J. Campbell and M. Hofmann, “Structural evolution of
ball-milled ZnFe2O4”, J. Alloys Compd., vol. 339, June 2002, pp. 255–
260.
[18] S. M. Ismail, Sh. Labib and S. S. Attallah1, Preparation and
Characterization of Nano-Cadmium Ferrite, J. Ceram., vol. 2013, Jan.
2013, pp. 1–8.
[19] W. Kim, S. W. Hyun, T. Kouh and C. S. Kim, “Local Magnetic
Properties of Spinel Cd0.9M0.1Fe2O4 (M=Zn, Ni) Investigated by Using External Magnetic Field Mӧssbauer Spectrometry”, J. Korean Chem.
Soc., vol. 59, Dec. 2011, pp. 3380−3384.
[20] A. Sutka, G. Mezinskis1, D. Jakovlevs and V. Korsaks, “Sol-gel
combustion synthesis of CdFe2O4 ferrite by using various reducing
agents”, J. Aust. Ceram. Soc., vol. 49, Jan. 2013, pp. 136–140.
[21] B. Boyanov, “Solid state interactions in the systems CaO(CaCO3)-Fe2O3
and CuFe2O4-CaO”, J. Min. Met., vol. 41 B, Jan. 2005, pp. 67–77.
[22] N. Leclerc, E. Meux and J. M. Lecuire, “Hydrometallurgical extraction
of zinc from zinc ferrites”, Hydrometallurgy, vol. 70, Mar. 2003, pp.
175–183.
[23] J. E. Dutrizac, “The Physical Chemistry of Iron Precipitation in the Zinc
Industry”, (Published Conference Proceedings style)”, in Proc. Lead-
Zinc-Tin '80, New York, 1980, pp. 532–564.
[24] S. Tsunoda, I. Maeshiro, M. Ewi, K. Sekine, The Construction and
Operation of the Iijima Electrolytic Zinc Plant, (Published Conference
Proceedings style)”, in Proc. AIME TMS, Chicago, 1973, pp. A73–65.
[25] Y. A. Naik, T. V. Venkatesha and P. V. Nayak, “Electrodeposition of
Zinc from Chloride Solution”, Turk. J. Chem., vol. 26, May 2002, pp.
725−733.
[26] D. S. Baik and D. J. Fray, “Electrodeposition of zinc from high acid zinc
chloride solutions”, J. Appl. Electrochem., vol. 31, Oct. 2001, pp.
1141−1147.
[27] B. S. Boyanov and A. B. Peltekov, “X-Ray, DTA and TGA analysis of
zinc sulfide concentrates and study of their charging for roasting in
fluidized bed furnace”, Bul. Chem. Communic., vol. 44, Oct. 2012, pp.
17–23.
[28] B. S. Boyanov and A. B. Peltekov, “Two-Face Zinc Ferrite (Published
Conference Proceedings style)”, in Proc. of ICCE-21, Tenerife, Canary
Islands, Spain, 2013, pp. 105–106.
[29] S. Nikolov, B. Boyanov, N. Moldovanska and R. Dimitrov, “Mössbauer
Spectroscopy Study on the Oxidation of Sulfide Zinc Concentrate Rich
in Marmatite”, Thermochim. Acta., vol. 380, Nov. 2001, pp. 37–41.
[30] C. N. Chinnasamy, A. Narayanasamy, N. Ponpandian, K.
Chattopadhyay, H. Guerault and J. M. Greneche, “Magnetic properties
of nanostructured ferrimagnetic zinc ferrite”, J. Phys. Condens. Matter.,
vol. 12, July 2000, pp. 7795−7505.
[31] N. M. Deraz and A. Alarifi, “Synthesis and Physicochemical Properties
of Nanomagnetic Zinc Ferrite System”, Int. J. Electrochem. Sci., vol. 7,
May 2012, pp. 3798−3808.
[32] M. P. Sandalski, B. S. Boyanov, P. G. Georgiev, and A. K. Sotirov,
“Web based expert system optimization for processes in chemical
technology (Published Conference Proceedings style)”, in Proc. of 42nd
IOC of Mining and Metallurgy, Bor, Serbia, 2010, pp. 569–572.