Abstract: Inorganic nanoparticles filled polymer composites
have extended their multiple functionalities to various applications,
including mechanical reinforcement, gas barrier, dimensional
stability, heat distortion temperature, flame-retardant, and thermal
conductivity. Sodium stearate-modified calcium carbonate (CaCO3)
nanoparticles were prepared using surface modification method. The
results showed that sodium stearate attached to the surface of CaCO3
nanoparticles with the chemical bond. The effect of modified CaCO3
nanoparticles on thermal properties of polypropylene (PP) was
studied by means of differential scanning calorimetry (DSC) and
Thermogravimetric analysis (TGA). It was found that CaCO3
significantly affected the crystallization temperature and
crystallization degree of PP. Effect of the modified CaCO3 content on
mechanical properties of PP/CaCO3 nanocomposites was also
studied. The results showed that the modified CaCO3 can effectively
improve the mechanical properties of PP. In comparison with PP, the
impact strength of PP/CaCO3 nanocomposites increased by about
65% and the hardness increased by about 5%.
Abstract: Plastics occupy wide place in the applications of
automotive, electronics and house goods. Especially reinforced
plastics become popular because of their high strength besides their
advantages of low weight and easy manufacturability. In this study,
mechanical and morphological properties of polypropylene (PP) and
high density polyethylene (HDPE) matrix composites reinforced with
surface modified nano titan dioxide (TiO2) particles were
investigated. Surface modification was made by coating the nano
powders with maleic anhydride grafted styrene ethylene butylene
styrene (SEBS-g-MA) and silane, respectively. After surface
modification, PP/TiO2 and HDPE/TiO2 composites were obtained by
using twin screw extruder at titan dioxide loading of 1 wt.%, 3 wt.%
and 5 wt.%. Effects of surface modification were determined by
thermal and morphological analysis. SEBS-g-MA provided bridging
effect between TiO2 particles and polymer matrix while silane was
effective as a dispersant. Depending on that, homogenous structures
without agglomeration were obtained. Mechanical tests were
performed on the injection moldings of the composites for obtaining
the impact strength, tensile strength, stress at break, elongation and
elastic modulus. Reinforced HDPE and PP moldings gave higher
tensile strength and elastic modulus due to the rigid structure of TiO2.
Slight increment was seen in stress at break. Elongation and impact
strength decreased due to the stiffness of the nano titan dioxide.
Abstract: Low silica type X (LSX) Zeolite is one of useful
material in many manufacturing due to the advantage properties
including high surface area, stability, microporous crystalline
aluminosilicates and positive ion in an extra–framework. The LSX
was used rice husk silica source which obtained by leaching with
hydrochloric acid and calcination at 500 C. To improve the
synthesis method, the LSX was crystallizated in Teflon–lined
autoclave will expedite deceasing of the amorphous particles. The
mixed gel with composition of 5.5 Na2O : 1.65 K2O : Al2O3 : 2.2
SiO2 : 122 H2O was crystallized in different container
(Polypropylene bottom and Teflon–lined autoclave). The obtained
powder was characterized by X–ray diffraction (XRD), X–ray
fluorescence spectrometry, N2 adsorption-desorption analysis BET
surface area Scanning electron microscopy (SEM) and Fourier
transform infrared spectroscopy to justify the quality of zeolite. The
results showed the crystallized zeolite in Teflon lined autoclave has
102.8 nm of crystal size, 286 m2/g of surface area and fewer amounts
of round amorphous particles when compared with the crystallized
zeolite in Polypropylene.
Abstract: Methanol-to-olefins coupled with transformation of
coal or natural gas to methanol gives an interesting and promising way
to produce ethylene and propylene. To investigate solid concentration
in gas-solid fluidized bed for methanol-to-olefins process catalyzed by
SAPO-34, a cold model experiment system is established in this paper.
The system comprises a gas distributor in a 300mm internal diameter
and 5000mm height acrylic column, the fiber optic probe system and
series of cyclones. The experiments are carried out at ambient
conditions and under different superficial gas velocity ranging from
0.3930m/s to 0.7860m/s and different initial bed height ranging from
600mm to 1200mm. The effects of radial distance, axial distance,
superficial gas velocity, initial bed height on solid concentration in the
bed are discussed. The effects of distributor shape and porosity on
solid concentration are also discussed. The time-averaged solid
concentration profiles under different conditions are obtained.
Abstract: The objective of the present study was to evaluate the
potential of hollow microneedles for enhancing the transdermal
delivery of Bovine Serum Albumin (MW~66,000 Da)-Fluorescein
Isothiocyanate (BSA-FITC) conjugate, a hydrophilic large molecular
compound. Moreover, the effect of different formulations was
evaluated. The series of binary mixtures composed of propylene
glycol (PG) and pH 7.4 phosphate buffer solution (PBS) was
prepared and used as a medium for BSA-FITC. The results showed
that there was no permeation of BSA-FITC solution across the
neonatal porcine skin without using hollow microneedles, whereas
the cumulative amount of BSA-FITC released at 8 h through the
neonatal porcine skin was about 60-70% when using hollow
microneedles. Furthermore, the results demonstrated that the higher
volume of PG in binary mixtures injected, the lower cumulative
amount of BSA-FITC released and release rate of BSA-FITC from
skin. These release profiles of BSA-FITC in binary mixtures were
expressed by Fick-s law of diffusion. These results suggest the
utilization of hollow microneedle to enhance transdermal delivery of
protein and provide useful information for designing an effective
hollow microneedle system.
Abstract: The phase diagrams and compositions of coexisting
phases have been determined for aqueous two-phase systems
containing poly(propylene glycol) with average molecular weight of
425 and sodium citrate at various pH of 3.93, 4.44, 4.6, 4.97, 5.1,
8.22. The effect of pH on the salting-out effect of poly (propylene
glycol) by sodium citrate has been studied. It was found that, an
increasing in pH caused the expansion of two-phase region.
Increasing pH also increases the concentration of PPG in the PPGrich
phase, while the salt-rich phase will be somewhat mole diluted.
Abstract: Methanol-to-olefins (MTO) coupled with
transformation of coal or natural gas to methanol gives an interesting
and promising way to produce ethylene and propylene. To investigate
solid concentration in gas-solid fluidized bed for methanol-to-olefins
process catalyzed by SAPO-34, a cold model experiment system is
established in this paper. The system comprises a gas distributor in a
300mm internal diameter and 5000mm height acrylic column, the
fiber optic probe system and series of cyclones. The experiments are
carried out at ambient conditions and under different superficial gas
velocity ranging from 0.3930m/s to 0.7860m/s and different initial bed
height ranging from 600mm to 1200mm. The effects of radial
distance, axial distance, superficial gas velocity, initial bed height on
solid concentration in the bed are discussed. The effects of distributor
shape and porosity on solid concentration are also discussed. The
time-averaged solid concentration profiles under different conditions
are obtained.
Abstract: The article presents findings from the study and
analysis of the results of an experimental programme focused on the
production of concrete and fibre reinforced concrete in which natural
aggregate has been substituted with brick or concrete recyclate. The
research results are analyzed to monitor the effect of mechanicalphysical
characteristics on the durability properties of tested
cementitious composites. The key parts of the fibre reinforced
concrete mix are the basic components: aggregates – recyclate,
cement, fly ash, water and fibres. Their specific ratios and the
properties of individual components principally affect the resulting
behaviour of fresh fibre reinforced concrete and the characteristics of
the final product. The article builds on the sources dealing with the
use of recycled aggregates from construction and demolition waste in
the production of fibre reinforced concrete. The implemented
procedure of testing the composite contributes to the building
sustainability in environmental engineering.
Abstract: This paper presents the experiment results of investigating the effects of adding various types and proportions of fibre on mechanical strength and permeability characteristics of recycled aggregate concrete (RAC), which was produced with treated coarse recycled concrete aggregate (RCA). Two types of synthetic fibres (i.e., barchip and polypropylene fibre) with various volume fractions were added to the RAC, which was calculated by the weight of the cement. The hardened RAC properties such as compressive strength, flexural strength, ultrasonic pulse velocity, water absorption and total porosity at the curing ages of 7 and 28 days were evaluated and compared with the properties of the control specimens. Results indicate that the treated coarse RCA enhances the mechanical strength and permeability properties of RAC and adding barchip fibre further optimises the results. Adding 1.2% barchip fibre has the best effect on the mechanical strength performance of the RAC.
Abstract: A kinetic model for propane dehydrogenation in an
industrial moving bed reactor is developed based on the reported
reaction scheme. The kinetic parameters and activity constant are
fine tuned with several sets of balanced plant data. Plant data at
different operating conditions is applied to validate the model and
the results show a good agreement between the model
predictions and plant observations in terms of the amount of main
product, propylene produced. The simulation analysis of key
variables such as inlet temperature of each reactor (Tinrx) and
hydrogen to total hydrocarbon ratio (H2/THC) affecting process
performance is performed to identify the operating condition to
maximize the production of propylene. Within the range of operating
conditions applied in the present studies, the operating condition to
maximize the propylene production at the same weighted average
inlet temperature (WAIT) is ΔTinrx1= -2, ΔTinrx2= +1, ΔTinrx3= +1 ,
ΔTinrx4= +2 and ΔH2/THC= -0.02. Under this condition, the surplus
propylene produced is 7.07 tons/day as compared with base case.
Abstract: Delayed wound healing in diabetes is primarily
associated with hyperglycemia, over-expression of inflammatory
marker, oxidative stress and delayed collagen synthesis. This
unmanaged wound is producing high economic burden on the
society. Thus research is required to develop new and effective
treatment strategies to deal with this emerging issue. Our present
study incorporates the evaluation of wound healing effects of 50%
ethanol extract of Ocimum sanctum (OSE) in streptozotocin
(45mg/kg)-induced diabetic rats with concurrent wound ulcer. The
animals showing diabetes (Blood glucose level >140 and
Abstract: Catalytic converters are used for minimizing the release of pollutants to the atmosphere. It is during the warm-up period that hydrocarbons are seen to be released in appreciable quantities from these converters. In this paper the conversion of a fast oxidizing hydrocarbon propylene is analysed using two numerical methods. The quasi steady state method assumes the accumulation terms to be negligible in the gas phase mass and energy balance equations, however this term is present in the solid phase energy balance. The unsteady state model accounts for the accumulation term to be present in the gas phase mass and energy balance and in the solid phase energy balance. The results derived from the two models for gas concentration, gas temperature and solid temperature are compared.
Abstract: This study has applied the L16 orthogonal array of the
Taguchi method to determine the optimized polymeric
Nanocomposite asphalt binder. Three control factors are defined as
polypropylene plastomer (PP), styrene-butadiene-styrene elastomer
(SBS) and Nanoclay. Four level of concentration contents are
introduced for prepared asphalt binder samples. all samples were
prepared with 4.5% of bitumen 60/70 content. Compressive strength
tests were carried out for defining the optimized sample via
QUALITEK-4 software. SBS with 3%, PP with 5 % and Nanoclay
with 1.5% of concentrations are defined as the optimized
Nanocomposite asphalt binders. The confirmation compressive
strength and also softening point tests showed that modification of
asphalt binders with this method, improved the compressive strength
and softening points of asphalt binders up to 55%.
Abstract: Alkali treated oil palm empty fruit bunch (EFB) fibres
(TEFBF) and untreated EFBF fibers (UEFBF) were incorporated in
polypropylene (PP) with and without malic anhydride grafted PP
(MAPP) and magnesium hydroxide as flame retardant (FR) to
produce TEFBF-PP and UEFBF-PP composites by the melt casting
method. The composites were characterized by mechanical and
burning tests along with a scanning electron microscope and Fourier
transform infrared spectroscopy. The significant improvement in
flexural modulus (133%) and flame retardant property (60%) of
TEFBF-PP composite with MAPP and FR is observed. The improved
mechanical property is discussed by the development of encapsulated
textures.
Abstract: Paper presents knowledge about types of test in area
of materials properties of selected methods of rapid prototyping
technologies. In today used rapid prototyping technologies for
production of models and final parts are used materials in initial state
as solid, liquid or powder material structure. In solid state are used
various forms such as pellets, wire or laminates. Basic range
materials include paper, nylon, wax, resins, metals and ceramics. In
Fused Deposition Modeling (FDM) rapid prototyping technology are
mainly used as basic materials ABS (Acrylonitrile Butadiene
Styrene), polyamide, polycarbonate, polyethylene and polypropylene.
For advanced FDM applications are used special materials as silicon
nitrate, PZT (Piezoceramic Material - Lead Zirconate Titanate),
aluminium oxide, hydroxypatite and stainless steel.
Abstract: High strength concrete has been used in situations
where it may be exposed to elevated temperatures. Numerous authors
have shown the significant contribution of polypropylene fiber to the
spalling resistance of high strength concrete.
When cement-based composite that reinforced by polypropylene
fibers heated up to 170 °C, polypropylene fibers readily melt and
volatilize, creating additional porosity and small channels in to the
matrix that cause the poor structure and low strength.
This investigation develops on the mechanical properties of mortar
incorporating polypropylene fibers exposed to high temperature.
Also effects of different pozzolans on strength behaviour of samples
at elevated temperature have been studied.
To reach this purpose, the specimens were produced by partial
replacement of cement with finely ground glass, silica fume and rice
husk ash as high reactive pozzolans. The amount of this replacement
was 10% by weight of cement to find the effects of pozzolans as a
partial replacement of cement on the mechanical properties of
mortars. In this way, lots of mixtures with 0%, 0.5%, 1% and 1.5% of
polypropylene fibers were cast and tested for compressive and
flexural strength, accordance to ASTM standard. After that
specimens being heated to temperatures of 300, 600 °C, respectively,
the mechanical properties of heated samples were tested.
Mechanical tests showed significant reduction in compressive
strength which could be due to polypropylene fiber melting. Also
pozzolans improve the mechanical properties of sampels.
Abstract: The term hybrid composite refers to the composite
containing more than one type of fiber material as reinforcing fillers.
It has become attractive structural material due to the ability of
providing better combination of properties with respect to single fiber
containing composite. The eco-friendly nature as well as processing
advantage, light weight and low cost have enhanced the attraction
and interest of natural fiber reinforced composite. The objective of
present research is to study the mechanical properties of jute-coir
fiber reinforced hybrid polypropylene (PP) composite according to
filler loading variation. In the present work composites were
manufactured by using hot press machine at four levels of fiber
loading (5, 10, 15 and 20 wt %). Jute and coir fibers were utilized at a
ratio of (1:1) during composite manufacturing. Tensile, flexural,
impact and hardness tests were conducted for mechanical
characterization. Tensile test of composite showed a decreasing trend
of tensile strength and increasing trend of the Young-s modulus with
increasing fiber content. During flexural, impact and hardness tests,
the flexural strength, flexural modulus, impact strength and hardness
were found to be increased with increasing fiber loading. Based on
the fiber loading used in this study, 20% fiber reinforced composite
resulted the best set of mechanical properties.
Abstract: This study presents the performance of membrane
bioreactor in treating high phosphate wastewater. The laboratory
scale MBR was operated at permeate flux of 25 L/m2.h with a hollow
fiber membrane (polypropylene, approx. pore size 0.01 - 0.2 μm) at
hydraulic retention time (HRT) of 12 hrs. Scanning electron
microscopy (SEM) and energy diffusive X-ray (EDX) analyzer were
used to characterize the membrane foulants. Results showed that the
removal efficiencies of COD, TSS, NH3-N and PO4
3- were 93, 98, 80
and 30% respectively. On average 91% of influent soluble microbial
products (SMP) were eliminated, with the eliminations of
polysaccharides mostly above 80%. The main fouling resistance was
cake resistance. It should be noted that SMP were found in major
portions of mixed liquor that played a relatively significant role in
membrane fouling. SEM and EDX analyses indicated that the
foulants covering the membrane surfaces comprises not only organic
substances but also inorganic elements including Mg, Ca, Al, K and
P.