Abstract: Nanocomposites of isotactic polypropylene (iPP) and
date wood fiber were prepared after modification of the host matrix
by reactive extrusion grafting of maleic anhydride. Chemical and
mechanical treatment of date wood flour (WF) was conducted to
obtain nanocrystalline cellulose. Layered silicates (clay) were
partially intercalated with date wood fiber, and the modified layered
silicate was used as filler in the PP matrix via a melt-blending
process. The tensile strength of composites prepared from wood fiber
modified clay was greater than that of the iPP-clay and iPP-WF
composites at a 6% filler concentration, whereas deterioration of
mechanical properties was observed when clay and WF were used
alone for reinforcement. The dispersion of the filler in the matrix
significantly decreased after clay modification with cellulose at
higher concentrations, as shown by X-ray diffraction (XRD) data.
Abstract: Inorganic nanoparticles filled polymer composites
have extended their multiple functionalities to various applications,
including mechanical reinforcement, gas barrier, dimensional
stability, heat distortion temperature, flame-retardant, and thermal
conductivity. Sodium stearate-modified calcium carbonate (CaCO3)
nanoparticles were prepared using surface modification method. The
results showed that sodium stearate attached to the surface of CaCO3
nanoparticles with the chemical bond. The effect of modified CaCO3
nanoparticles on thermal properties of polypropylene (PP) was
studied by means of differential scanning calorimetry (DSC) and
Thermogravimetric analysis (TGA). It was found that CaCO3
significantly affected the crystallization temperature and
crystallization degree of PP. Effect of the modified CaCO3 content on
mechanical properties of PP/CaCO3 nanocomposites was also
studied. The results showed that the modified CaCO3 can effectively
improve the mechanical properties of PP. In comparison with PP, the
impact strength of PP/CaCO3 nanocomposites increased by about
65% and the hardness increased by about 5%.