Abstract: The steady-state temperature for one-dimensional transpiration cooling system has been conducted experimentally and numerically to investigate the heat transfer characteristics of combined convection and radiation. The Nickel –Chrome (Ni-Cr) open-cellular porous material having porosity of 0.93 and pores per inch (PPI) of 21.5 was examined. The upper surface of porous plate was heated by the heat flux of incoming radiation varying from 7.7 - 16.6 kW/m2 whereas air injection velocity fed into the lower surface was varied from 0.36 - 1.27 m/s, and was then rearranged as Reynolds number (Re). For the report of the results in the present study, two efficiencies including of temperature and conversion efficiency were presented. Temperature efficiency indicating how close the mean temperature of a porous heat plate to that of inlet air, and increased rapidly with the air injection velocity (Re). It was then saturated and had a constant value at Re higher than 10. The conversion efficiency, which was regarded as the ability of porous material in transferring energy by convection after absorbed from heat radiation, decreased with increasing of the heat flux and air injection velocity. In addition, it was then asymptotic to a constant value at the Re higher than 10. The numerical predictions also agreed with experimental data very well.
Abstract: Microstructure, wetting behavior and interfacial
reactions between Sn–0.7Cu and Sn–0.3Ag–0.7Cu (SAC0307)
solders solidified on Ni coated Al substrates were compared and
investigated. Microstructure of Sn–0.7Cu alloy exhibited a eutectic
matrix composed of primary β-Sn dendrites with a fine dispersion of
Cu6Sn5 intermetallics whereas microstructure of SAC0307 alloy
exhibited coarser Cu6Sn5 and finer Ag3Sn precipitates of IMCs with
decreased tin dendrites. Contact angles ranging from 22° to 26° were
obtained for Sn–0.7Cu solder solidified on substrate surface whereas
for SAC0307 solder alloy contact angles were found to be in the
range of 20° to 22°. Sn–0.7Cu solder/substrate interfacial region
exhibited faceted (Cu, Ni)6Sn5 IMCs protruding into the solder matrix
and a small amount of (Cu, Ni)3Sn4 intermetallics at the interface.
SAC0307 solder/substrate interfacial region showed mainly (Cu,
Ni)3Sn4 intermetallics adjacent to the coating layer and (Cu,
Ni)6Sn5 IMCs in the solder matrix. The improvement in the
wettability of SAC0307 solder alloy on substrate surface is attributed
to the formation of cylindrical shape (Cu,Ni)6Sn5 and a layer of
(Cu, Ni)3Sn4 IMCs at the interface.
Abstract: Inconel 718, a nickel based super-alloy is an
extensively used alloy, accounting for about 50% by weight of
materials used in an aerospace engine, mainly in the gas turbine
compartment. This is owing to their outstanding strength and
oxidation resistance at elevated temperatures in excess of 5500 C.
Machining is a requisite operation in the aircraft industries for the
manufacture of the components especially for gas turbines. This
paper is concerned with optimization of the surface roughness when
turning Inconel 718 with cermet inserts. Optimization of turning
operation is very useful to reduce cost and time for machining. The
approach is based on Response Surface Method (RSM). In this work,
second-order quadratic models are developed for surface roughness,
considering the cutting speed, feed rate and depth of cut as the cutting
parameters, using central composite design. The developed models
are used to determine the optimum machining parameters. These
optimized machining parameters are validated experimentally, and it
is observed that the response values are in reasonable agreement with
the predicted values.
Abstract: Shape memory alloy (SMA) actuators have found a
wide range of applications due to their unique properties such as high
force, small size, lightweight and silent operation. This paper presents
the development of compact (SMA) actuator and cooling system in
one unit. This actuator is developed for multi-fingered hand. It
consists of nickel-titanium (Nitinol) SMA wires in compact forming.
The new arrangement insulates SMA wires from the human body by
housing it in a heat sink and uses a thermoelectric device for rejecting
heat to improve the actuator performance. The study uses
optimization methods for selecting the SMA wires geometrical
parameters and the material of a heat sink. The experimental work
implements the actuator prototype and measures its response.
Abstract: The presence of toxic heavy metals in industrial
effluents is one of the serious threats to the environment. Heavy
metals such as Cadmium, Chromium, Lead, Nickel, Zinc, Mercury,
Copper, Arsenic are found in the effluents of industries such as
foundries, electroplating, petrochemical, battery manufacturing,
tanneries, fertilizer, dying, textiles, metallurgical and metal finishing.
Tremendous increase of industrial copper usage and its presence in
industrial effluents has lead to a growing concern about the fate and
effects of Copper in the environment. Percolation of industrial
effluents through soils leads to contamination of ground water and
soils. The transport of heavy metals and their diffusion into the soils
has therefore, drawn the attention of the researchers.
In this study, an attempt has been made to delineate the
mechanisms of transport and fate of copper in terrestrial
environment. Column studies were conducted using perplex glass
square column of dimension side 15 cm and 1.35 m long. The soil
samples were collected from a natural drain near Mohali (India). The
soil was characterized to be poorly graded sandy loam. The soil was
compacted to the field dry density level of about 1.6 g/cm3. Break
through curves for different depths of the column were plotted. The
results of the column study indicated that the copper has high
tendency to flow in the soils and fewer tendencies to get absorbed on
the soil particles. The t1/2 estimates obtained from the studies can be
used for design copper laden wastewater disposal systems.
Abstract: The Ni/α-Al2O3 catalysts with different amounts of La
as promoter from 0 to 4 wt % were prepared, characterized and their
catalytic activity was investigated in syngas methanation reaction.
Effects of reaction temperature and lanthanum loading on carbon
oxides conversion and methane selectivity were also studied. Adding
certain amount of lanthanum to 10Ni /α-Al2O3 catalysts can decrease
the average NiO crystallite diameter which leads to higher activity and
stability while excessive addition would cause deactivation quickly.
Stability on stream towards deactivation was observed up to 800 min
at 500 °C, 0.1MPa and 600000 mL·g-1·h-1.
Abstract: In this paper a study on the vibration of thin
cylindrical shells with ring supports and made of functionally graded
materials (FGMs) composed of stainless steel and nickel is presented.
Material properties vary along the thickness direction of the shell
according to volume fraction power law. The cylindrical shells have
ring supports which are arbitrarily placed along the shell and impose
zero lateral deflections. The study is carried out based on third order
shear deformation shell theory (T.S.D.T). The analysis is carried out
using Hamilton-s principle. The governing equations of motion of
FGM cylindrical shells are derived based on shear deformation
theory. Results are presented on the frequency characteristics,
influence of ring support position and the influence of boundary
conditions. The present analysis is validated by comparing results
with those available in the literature.
Abstract: Vibration of thin cylindrical shells made of a
functionally gradient material composed of stainless steel and nickel
is presented. The effects of the FGM configuration are studied by
studying the frequencies of FG cylindrical shells. In this case FG
cylindrical shell has Nickel on its outer surface and stainless steel on
its inner surface. The study is carried out based on third order shear
deformation shell theory. The objective is to study the natural
frequencies, the influence of constituent volume fractions and the
effects of configurations of the constituent materials on the
frequencies. The properties are graded in the thickness direction
according to the volume fraction power-law distribution. Results are
presented on the frequency characteristics, the influence of the
constituent various volume fractions on the frequencies.
Abstract: In this paper a study on the vibration of thin
cylindrical shells with ring supports and made of functionally graded
materials (FGMs) composed of stainless steel and nickel is presented.
Material properties vary along the thickness direction of the shell
according to volume fraction power law. The cylindrical shells have
ring supports which are arbitrarily placed along the shell and impose
zero lateral deflections. The study is carried out based on third order
shear deformation shell theory (T.S.D.T). The analysis is carried out
using Hamilton-s principle. The governing equations of motion of
FGM cylindrical shells are derived based on shear deformation
theory. Results are presented on the frequency characteristics,
influence of ring support position and the influence of boundary
conditions. The present analysis is validated by comparing results
with those available in the literature.
Abstract: The aim of this research was to calculate the thermal
properties of Au3Ni Nanowire. The molecular dynamics (MD)
simulation technique was used to obtain the effect of radius size on
the energy, the melting temperature and the latent heat of fusion at
the isobaric-isothermal (NPT) ensemble. The Quantum Sutton-Chen
(Q-SC) many body interatomic potentials energy have been used for
Gold (Au) and Nickel (Ni) elements and a mixing rule has been
devised to obtain the parameters of these potentials for nanowire
stats. Our MD simulation results show the melting temperature and
latent heat of fusion increase upon increasing diameter of nanowire.
Moreover, the cohesive energy decreased with increasing diameter of
nanowire.
Abstract: The nickel and gold nanoclusters as supported
catalysts were analyzed by XAS, XRD and XPS in order to
determine their local, global and electronic structure. The present
study has pointed out a strong deformation of the local structure of
the metal, due to its interaction with oxide supports. The average
particle size, the mean squares of the microstrain, the particle size
distribution and microstrain functions of the supported Ni and Au
catalysts were determined by XRD method using Generalized Fermi
Function for the X-ray line profiles approximation. Based on EXAFS
analysis we consider that the local structure of the investigated
systems is strongly distorted concerning the atomic number pairs.
Metal-support interaction is confirmed by the shape changes of the
probability densities of electron transitions: Ni K edge (1s →
continuum and 2p), Au LIII-edge (2p3/2 → continuum, 6s, 6d5/2 and
6d3/2). XPS investigations confirm the metal-support interaction at
their interface.
Abstract: In this study, a nickel film with nano-crystalline grains,
high hardness and smooth surface was electrodeposited using a post
supercritical carbon dioxide (CO2) mixed Watts electrolyte. Although
the hardness was not as high as its Sc-CO2 counterpart, the thin coating
contained significantly less number of nano-sized pinholes. By
measuring the escape concentration of the dissolved CO2 in post
Sc-CO2 mixed electrolyte with the elapsed time, it was believed that
the residue of dissolved CO2 bubbles should closely relate to the
improvement in hardness and surface roughness over its conventional
plating counterpart. Therefore, shortening the duration of
electroplating with the raise of current density up to 0.5 A/cm2 could
effectively retain more post Sc-CO2 mixing effect. This study not only
confirms the roles of dissolved CO2 bubbles in electrolyte but also
provides a potential process to overcome most issues associated with
the cost in building high-pressure chamber for large size products and
continuous plating using supercritical method.
Abstract: The steam cracking reactions are always accompanied with the formation of coke which deposits on the walls of the tubular reactors. The investigation has attempted to control catalytic coking by the applying aluminum, zinc and ceramic coating like aluminum-magnesium by thermal spray and pack cementation method. Rate of coke formation during steam cracking of naphtha has been investigated both for uncoated stainless steel (with different alloys) and metal coating constructed with thermal Spray and pack cementation method with metal powders of Aluminum, Aluminum-Magnesium, zinc, silicon, nickel and chromium. The results of the study show that passivating the surface of SS321 with a coating of Aluminum and Aluminum-Magnesium can significantly reduce the rate of coke deposition during naphtha pyrolysis. SEM and EDAX techniques (Philips XL Series) were used to examine the coke deposits formed by the metal-hydrocarbon reactions. Our objective was to separate the different stages by identifying the characteristic morphologies.
Abstract: Study is on the vibration of thin cylindrical shells made of a functionally gradient material (FGM) composed of stainless steel and nickel is presented. The effects of the FGM configuration are studied by studying the frequencies of FG cylindrical shells. In this case FG cylindrical shell has Nickel on its inner surface and stainless steel on its outer surface. The study is carried out based on third order shear deformation shell theory. The objective is to study the natural frequencies, the influence of constituent volume fractions and the effects of configurations of the constituent materials on the frequencies. The properties are graded in the thickness direction according to the volume fraction power-law distribution. Results are presented on the frequency characteristics, the influence of the constituent various volume fractions on the frequencies.
Abstract: The aluminum bronze matrix alumina composites using hot press and resin infiltration were investigated to study their porosities, hardness, bending strengths, and microstructures. The experiment results show that the hardness of the sintered composites with the decrease of porosity increases. The composites without and with resin infiltration have about HRF 42-61 of about 34-40% of porosity and about HRF 62-83 of about 30-36% of porosity, respectively. Besides, the alumina composites contain a more amount of iron and nickel powders would cause a lower bending strength due to forming some weaker bonding among the iron, nickel, copper, aluminum under this hot pressing of shorter time.
Abstract: The main objective of this study was to remove and recover Ni, Cu and Fe from a mixed metal system using sodium hypophosphite as a reducing agent and nickel powder as seeding material. The metal systems studied consisted of Ni-Cu, Ni-Fe and Ni-Cu-Fe solutions. A 5 L batch reactor was used to conduct experiments where 100 mg/l of each respective metal was used. It was found that the metals were reduced to their elemental form with removal efficiencies of over 80%. The removal efficiency decreased in the order Fe>Ni>Cu. The metal powder obtained contained between 97-99% Ni and was almost spherical and porous. Size enlargement by aggregation was the dominant particulate process.
Abstract: This investigation examines the effect of the sintering
temperature curve in manufactured nickel powder capillary structure
(wick) for a loop heat pipe (LHP). The sintering temperature curve is
composed of a region of increasing temperature; a region of constant
temperature and a region of declining temperature. The most important
region is that in which the temperature increases, as an index in the
stage in which the temperature increases. The wick of nickel powder is
manufactured in the stage of fixed sintering temperature and the time
between the stage of constant temperature and the stage of falling
temperature. When the slope of the curve in the region of increasing
temperature is unity (equivalent to 10 °C/min), the structure of the
wick is complete and the heat transfer performance is optimal. The
result of experiment test demonstrates that the heat transfer
performance is optimal at 320W; the minimal total thermal resistance
is approximately 0.18°C/W, and the heat flux is 17W/cm2; the internal
parameters of the wick are an effective pore radius of 3.1 μm, a
permeability of 3.25×10-13m2 and a porosity of 71%.
Abstract: The Kowsar dam supply water for different usages
such as drinking, industrial, agricultural and aquaculture farms
usages and located next to the city of Dehdashat in Kohgiluye and
Boyerahmad province in southern Iran. There are some towns and
villages on the Kowsar dam watersheds, which Dehdasht and Choram
are the most important and populated cities in this area. The study
was undertaken to assess the status of water quality in the urban areas
of the Kowsar dam. A total of 28 water samples were collected from
6 stations on surface water and 1 station from groundwater on the
watershed of the Kowsar dam. All the samples were analyzed for Ni
concentration using standard procedures. The results were compared
with other national and international standards. Among the analyzed
samples, as the maximum value of Nickel (0.01 mg/L) was observed
on the station 2 at the autumn 2010, all the samples analyzed were
within the maximum admissible limits by the United States
Environmental Protection Agency, EU, WHO and the Iranian. In
general results of the present study have shown that a Ni mean value
of station No. 2 with 0.006 mg/L is higher than the other stations. Ni
level of all samples and stations have had normal values and this is an
indication of pollution potential and hazards because of human
activity and waste water of towns in the areas, which can effect on
human health implications in future. This research, therefore,
recommends the government and other responsible authorities to take
suitable improving measures in the Kowsar dam watersheds.
Abstract: The present work is concerned with sulfidation of Cu,
Zn and Ni containing plating wastewater with CaS. The sulfidation
experiments were carried out at a room temperature by adding solid
CaS to simulated metal solution containing either single-metal of Ni,
Zn and Cu, or Ni-Zn-Cu mixture. At first, the experiments were
conducted without pH adjustment and it was found that the complete
sulfidation of Zn and Ni was achieved at an equimolar ratio of CaS to a
particular metal. However, in the case of Cu, a complete copper
sulfidation was achieved at CaS to Cu molar ratio of about 2. In the
case of the selective sulfidation, a simulated plating solution
containing Cu, Zn and Ni at the concentration of 100 mg/dm3 was
treated with CaS under various pH conditions. As a result, selective
precipitation of metal sulfides was achieved by a sulfidation treatment
at different pH values. Further, the precipitation agents of NaOH,
Na2S and CaS were compared in terms of the average specific
filtration resistance and compressibility coefficients of metal sulfide
slurry. Consequently, based on the lowest filtration parameters of the
produced metal sulfides, it was concluded that CaS was the most
effective precipitation agent for separation and recovery of Cu, Zn and
Ni.
Abstract: The contamination of 15 ground water resources
of a selected region earmarked for the emergency supply
of population has been monitored. The resources have been selected
on the basis of previous assessment of natural conditions
and the exploitation of territory in their surroundings and infiltration
area. Two resources out of 15 have been excluded from further
exploitation, because they have not met some of the 72 assessed
hygienic indicators of extended analysis. The remaining 13 resources
have been the subject of health risk analysis in relation
to the contamination by arsenic, lead, cadmium, mercury, nickel and
manganese. The risk analysis proved that all 13 resources meet
health standards with regard to the above mentioned purposefully
selected elements and may thus be included into crisis plans. Water
quality of ground resources may be assessed in the same way
with regard to other contaminants.