Abstract: The selective recovery of heavy metals of Cu, Zn, Ni and Cr from a mixed plating sludge by sulfidation and oxidation treatment was targeted in this study. At first, the mixed plating sludge was simultaneously subjected to an extraction and Cu sulfidation process at pH=1.5 to dissolve heavy metals and to precipitate Cu2+ as CuS. In the next step, the sulfidation treatment of Zn was carried out at pH=4.5 and the residual solution was subjected to an oxidation treatment of chromium with H2O2 at pH=10.0. After the experiments, the selectivity of metal precipitation and the chromium oxidation ratio were evaluated. As results, it was found that the filter cake obtained after selective sulfidation of Cu was composed of 96.6% of Cu (100% equals to the sum of Cu, Zn, Ni and Cr contents). Such findings confirmed that almost complete extraction of heavy metals was achieved at pH=1.5 and also that Cu could be selectively recovered as CuS. Further, the filter cake obtained at pH=4.5 was composed of 91.5% Zn and 6.83% of Cr. Regarding the chromium oxidation step, the chromium oxidation ratio was found to increase with temperature and the addition of oxidation agent of H2O2, but only oxidation ratio of 59% was achieved at a temperature of 60°C and H2O2 to Cr3+ equivalent ratio of 180.
Abstract: The present work is concerned with sulfidation of Cu,
Zn and Ni containing plating wastewater with CaS. The sulfidation
experiments were carried out at a room temperature by adding solid
CaS to simulated metal solution containing either single-metal of Ni,
Zn and Cu, or Ni-Zn-Cu mixture. At first, the experiments were
conducted without pH adjustment and it was found that the complete
sulfidation of Zn and Ni was achieved at an equimolar ratio of CaS to a
particular metal. However, in the case of Cu, a complete copper
sulfidation was achieved at CaS to Cu molar ratio of about 2. In the
case of the selective sulfidation, a simulated plating solution
containing Cu, Zn and Ni at the concentration of 100 mg/dm3 was
treated with CaS under various pH conditions. As a result, selective
precipitation of metal sulfides was achieved by a sulfidation treatment
at different pH values. Further, the precipitation agents of NaOH,
Na2S and CaS were compared in terms of the average specific
filtration resistance and compressibility coefficients of metal sulfide
slurry. Consequently, based on the lowest filtration parameters of the
produced metal sulfides, it was concluded that CaS was the most
effective precipitation agent for separation and recovery of Cu, Zn and
Ni.
Abstract: Regenerative Thermal Oxidizer (RTO) is one of the
best solutions for removal of Volatile Organic Compounds (VOC)
from industrial processes. In the RTO, VOC in a raw gas are usually
decomposed at 950-1300 K and the combustion heat of VOC is
recovered by regenerative heat exchangers charged with ceramic
honeycombs. The optimization of the treatment of VOC leads to the
reduction of fuel addition to VOC decomposition, the minimization of
CO2 emission and operating cost as well.
In the present work, the thermal efficiency of the RTO was
investigated experimentally in a pilot-scale RTO unit using toluene as
a typical representative of VOC. As a result, it was recognized that the
radiative heat transfer was dominant in the preheating process of a raw
gas when the gas flow rate was relatively low. Further, it was found
that a minimum heat exchanger volume to achieve self combustion of
toluene without additional heating of the RTO by fuel combustion was
dependent on both the flow rate of a raw gas and the concentration of
toluene. The thermal efficiency calculated from fuel consumption and
the decomposed toluene ratio, was found to have a maximum value of
0.95 at a raw gas mass flow rate of 1810 kg·h-1 and honeycombs height
of 1.5m.