Abstract: Mixed convection in two-dimensional shallow rectangular enclosure is considered. The top hot wall moves with constant velocity while the cold bottom wall has no motion. Simulations are performed for Richardson number ranging from Ri = 0.001 to 100 and for Reynolds number keeping fixed at Re = 408.21. Under these conditions cavity encompasses three regimes: dominating forced, mixed and free convection flow. The Prandtl number is set to 6 and the effects of cavity inclination on the flow and heat transfer are studied for different Richardson number. With increasing the inclination angle, interesting behavior of the flow and thermal fields are observed. The streamlines and isotherm plots and the variation of the Nusselt numbers on the hot wall are presented. The average Nusselt number is found to increase with cavity inclination for Ri ³ 1 . Also it is shown that the average Nusselt number changes mildly with the cavity inclination in the dominant forced convection regime but it increases considerably in the regime with dominant natural convection.
Abstract: Combined conduction-free convection heat transfer in
vertical eccentric annuli is numerically investigated using a finitedifference
technique. Numerical results, representing the heat transfer
parameters such as annulus walls temperature, heat flux, and heat
absorbed in the developing region of the annulus, are presented for a
Newtonian fluid of Prandtl number 0.7, fluid-annulus radius ratio 0.5,
solid-fluid thermal conductivity ratio 10, inner and outer wall
dimensionless thicknesses 0.1 and 0.2, respectively, and
dimensionless eccentricities 0.1, 0.3, 0.5, and 0.7. The annulus walls
are subjected to thermal boundary conditions, which are obtained by
heating one wall isothermally whereas keeping the other wall at inlet
fluid temperature. In the present paper, the annulus heights required
to achieve thermal full development for prescribed eccentricities are
obtained. Furthermore, the variation in the height of thermal full
development as function of the geometrical parameter, i.e.,
eccentricity is also investigated.
Abstract: The ability of pomelo peel, a natural biosorbent, to remove Cd(II) ions from aqueous solution by biosorption was investigated. The experiments were carried out by batch method at 25 °C. The influence of solution pH, initial cadmium ion concentrations and contact times were evaluated. Cadmium ion removal increased significantly as the pH of the solution increased from pH 1 to pH 5. At pH 5, the cadmium ion removal reached a maximum value. The equilibrium process was described well by the Langmuir isotherm model, with a maximum biosorption capacity of 21.83 mg/g. The biosorption was relatively quick, (approx. 20 min). Biosorption kinetics followed a pseudo-second-order model. The result showed that pomelo peel was effective as a biosorbent for removing cadmium ions from aqueous solution. It is a low cost material that shows potential to be applied in wastewater technology for remediation of heavy metal contamination.
Abstract: The paper presents a numerical investigation on the
rapid gas decompression in pure nitrogen which is made by using the
one-dimensional (1D) and three-dimensional (3D) mathematical
models of transient compressible non-isothermal fluid flow in pipes.
A 1D transient mathematical model of compressible thermal multicomponent
fluid mixture flow in pipes is presented. The set of the
mass, momentum and enthalpy conservation equations for gas phase
is solved in the model. Thermo-physical properties of multicomponent
gas mixture are calculated by solving the Equation of
State (EOS) model. The Soave-Redlich-Kwong (SRK-EOS) model is
chosen. This model is successfully validated on the experimental data
[1] and shows a good agreement with measurements. A 3D transient
mathematical model of compressible thermal single-component gas
flow in pipes, which is built by using the CFD Fluent code (ANSYS),
is presented in the paper. The set of unsteady Reynolds-averaged
conservation equations for gas phase is solved. Thermo-physical
properties of single-component gas are calculated by solving the Real
Gas Equation of State (EOS) model. The simplest case of gas
decompression in pure nitrogen is simulated using both 1D and 3D
models. The ability of both models to simulate the process of rapid
decompression with a high order of agreement with each other is
tested. Both, 1D and 3D numerical results show a good agreement
between each other. The numerical investigation shows that 3D CFD
model is very helpful in order to validate 1D simulation results if the
experimental data is absent or limited.
Abstract: In this project cadmium ions were adsorbed from
aqueous solutions onto either date pits; a cheap agricultural and nontoxic
material, or chemically activated carbon prepared from date pits
using phosphoric acid. A series of experiments were conducted in a
batch adsorption technique to assess the feasibility of using the
prepared adsorbents. The effects of the process variables such as
initial cadmium ions concentration, contact time, solution pH and
adsorbent dose on the adsorption capacity of both adsorbents were
studied. The experimental data were tested using different isotherm
models such as Langmuir, Freundlich, Tempkin and Dubinin-
Radushkevich. The results showed that although the equilibrium data
could be described by all models used, Langmuir model gave slightly
better results when using activated carbon while Freundlich model,
gave better results with date pits.
Abstract: The paper presents the results of theoretical and
numerical modeling of propagation of shock waves in bubbly liquids
related to nonlinear effects (realistic equation of state, chemical
reactions, two-dimensional effects). On the basis on the Rankine-
Hugoniot equations the problem of determination of parameters of
passing and reflected shock waves in gas-liquid medium for
isothermal, adiabatic and shock compression of the gas component is
solved by using the wide-range equation of state of water in the
analitic form. The phenomenon of shock wave intensification is
investigated in the channel of variable cross section for the
propagation of a shock wave in the liquid filled with bubbles
containing chemically active gases. The results of modeling of the
wave impulse impact on the solid wall covered with bubble layer are
presented.
Abstract: The paper presents a one-dimensional transient
mathematical model of compressible non-isothermal multicomponent
fluid mixture flow in a pipe. The set of the mass,
momentum and enthalpy conservation equations for gas phase is
solved in the model. Thermo-physical properties of multi-component
gas mixture are calculated by solving the Equation of State (EOS)
model. The Soave-Redlich-Kwong (SRK-EOS) model is chosen. Gas
mixture viscosity is calculated on the basis of the Lee-Gonzales-
Eakin (LGE) correlation. Numerical analysis of rapid gas
decompression process in rich and base natural gases is made on the
basis of the proposed mathematical model. The model is successfully
validated on the experimental data [1]. The proposed mathematical
model shows a very good agreement with the experimental data [1] in
a wide range of pressure values and predicts the decompression in
rich and base gas mixtures much better than analytical and
mathematical models, which are available from the open source
literature.
Abstract: The Lattice Boltzmann Method (LBM) with double populations is applied to solve the steady-state laminar natural convective heat transfer in a triangular cavity filled with water. The bottom wall is heated, the vertical wall is cooled, and the inclined wall is kept adiabatic. The buoyancy effect was modeled by applying the Boussinesq approximation to the momentum equation. The fluid velocity is determined by D2Q9 LBM and the energy equation is discritized by D2Q4 LBM to compute the temperature field. Comparisons with previously published work are performed and found to be in excellent agreement. Numerical results are obtained for a wide range of parameters: the Rayleigh number from to and the inclination angle from 0° to 360°. Flow and thermal fields were exhibited by means of streamlines and isotherms. It is observed that inclination angle can be used as a relevant parameter to control heat transfer in right-angled triangular enclosures.
Abstract: The simulation of extrusion process is studied widely
in order to both increase products and improve quality, with broad
application in wire coating. The annular tube-tooling extrusion was
set up by a model that is termed as Navier-Stokes equation in
addition to a rheological model of differential form based on singlemode
exponential Phan-Thien/Tanner constitutive equation in a twodimensional
cylindrical coordinate system for predicting the
contraction point of the polymer melt beyond the die. Numerical
solutions are sought through semi-implicit Taylor-Galerkin pressurecorrection
finite element scheme. The investigation was focused on
incompressible creeping flow with long relaxation time in terms of
Weissenberg numbers up to 200. The isothermal case was considered
with surface tension effect on free surface in extrudate flow and no
slip at die wall. The Stream Line Upwind Petrov-Galerkin has been
proposed to stabilize solution. The structure of mesh after die exit
was adjusted following prediction of both top and bottom free
surfaces so as to keep the location of contraction point around one
unit length which is close to experimental results. The simulation of
extrusion process is studied widely in order to both increase products
and improve quality, with broad application in wire coating. The
annular tube-tooling extrusion was set up by a model that is termed
as Navier-Stokes equation in addition to a rheological model of
differential form based on single-mode exponential Phan-
Thien/Tanner constitutive equation in a two-dimensional cylindrical
coordinate system for predicting the contraction point of the polymer
melt beyond the die. Numerical solutions are sought through semiimplicit
Taylor-Galerkin pressure-correction finite element scheme.
The investigation was focused on incompressible creeping flow with
long relaxation time in terms of Weissenberg numbers up to 200. The
isothermal case was considered with surface tension effect on free
surface in extrudate flow and no slip at die wall. The Stream Line
Upwind Petrov-Galerkin has been proposed to stabilize solution. The
structure of mesh after die exit was adjusted following prediction of
both top and bottom free surfaces so as to keep the location of
contraction point around one unit length which is close to
experimental results.
Abstract: Carbon Capture & Storage (CCS) is one of the various
methods that can be used to reduce the carbon footprint of the
energy sector. This paper focuses on the absorption of CO2 from
flue gas using packed columns, whose efficiency is highly dependent
on the structure of the liquid films within the column. To study the
characteristics of liquid films a CFD solver, OpenFOAM is utilised
to solve two-phase, isothermal film flow using the volume-of-fluid
(VOF) method. The model was validated using existing experimental
data and the Nusselt theory. It was found that smaller plate inclination
angles, with respect to the horizontal plane, resulted in larger wetted
areas on smooth plates. However, only a slight improvement in
the wetted area was observed. Simulations were also performed
using a ridged plate and it was observed that these surface textures
significantly increase the wetted area of the plate. This was mainly
attributed to the channelling effect of the ridges, which helped to
oppose the surface tension forces trying to minimise the surface area.
Rivulet formations on the ridged plate were also flattened out and
spread across a larger proportion of the plate width.
Abstract: Laminar natural-convective heat transfer from a
horizontal cylinder is studied by solving the Navier-Stokes and
energy equations using higher order compact scheme in cylindrical
polar coordinates. Results are obtained for Rayleigh numbers of 1,
10, 100 and 1000 for a Prandtl number of 0.7. The local Nusselt
number and mean Nusselt number are calculated and compared with
available experimental and theoretical results. Streamlines, vorticity -
lines and isotherms are plotted.
Abstract: A vast array of biological materials, especially algae have received increasing attention for heavy metal removal. Algae have been proven to be cheaper, more effective for the removal of metallic elements in aqueous solutions. A fresh water algal strain was isolated from Zoo Lake, Johannesburg, South Africa and identified as Desmodesmus sp. This paper investigates the efficacy of Desmodesmus sp.in removing heavy metals contaminating the Wonderfonteinspruit Catchment Area (WCA) water bodies. The biosorption data fitted the pseudo-second order and Langmuir isotherm models. The Langmuir maximum uptakes gave the sequence: Mn2+>Ni2+>Fe2+. The best results for kinetic study was obtained in concentration 120 ppm for Fe3+ and Mn2+, whilst for Ni2+ was at 20 ppm, which is about the same concentrations found in contaminated water in the WCA (Fe3+115 ppm, Mn2+ 121 ppm and Ni2+ 26.5 ppm).
Abstract: The present study is concerned with the free
convective two dimensional flow and heat transfer, within the
framework of Boussinesq approximation, in anisotropic fluid filled
porous rectangular enclosure subjected to end-to-end temperature
difference have been investigated using Lattice Boltzmann method
fornon-Darcy flow model. Effects of the moving lid direction (top,
bottom, left, and right wall moving in the negative and positive x&ydirections),
number of moving walls (one or two opposite walls), the
sliding wall velocity, and four different constant temperatures
opposite walls cases (two surfaces are being insulated and the
twoother surfaces areimposed to be at constant hot and cold
temperature)have been conducted. The results obtained are discussed
in terms of the Nusselt number, vectors, contours, and isotherms.
Abstract: The cup method is applied for the measurement of water vapor transport properties of porous materials worldwide. However, in practical applications the experimental results are often used without taking into account some secondary effects which can play an important role under specific conditions. In this paper, the effect of temperature on water vapor transport properties of cellular concrete is studied, together with the influence of sample thickness. At first, the bulk density, matrix density, total open porosity and sorption and desorption isotherms are measured for material characterization purposes. Then, the steady state cup method is used for determination of water vapor transport properties, whereas the measurements are performed at several temperatures and for three different sample thicknesses.
Abstract: There are three possible effects of Special Theory of
Relativity (STR) on a thermodynamic system. Planck and Einstein
looked upon this process as isobaric; on the other hand Ott saw it as
an adiabatic process. However plenty of logical reasons show that the
process is isotherm. Our phenomenological consideration
demonstrates that the temperature is invariant with Lorenz
transformation. In that case process is isotherm, so volume and
pressure are Lorentz covariant. If the process is isotherm the Boyles
law is Lorentz invariant. Also equilibrium constant and Gibbs energy,
activation energy, enthalpy entropy and extent of the reaction became
Lorentz invariant.
Abstract: Natural convection heat transfer from a heated
horizontal semi-circular cylinder (flat surface upward) has been
investigated for the following ranges of conditions; Grashof number,
and Prandtl number. The governing partial differential equations
(continuity, Navier-Stokes and energy equations) have been solved
numerically using a finite volume formulation. In addition, the role of
the type of the thermal boundary condition imposed at cylinder
surface, namely, constant wall temperature (CWT) and constant heat
flux (CHF) are explored. Natural convection heat transfer from a
heated horizontal semi-circular cylinder (flat surface upward) has
been investigated for the following ranges of conditions; Grashof
number, and Prandtl number, . The governing partial differential
equations (continuity, Navier-Stokes and energy equations) have
been solved numerically using a finite volume formulation. In
addition, the role of the type of the thermal boundary condition
imposed at cylinder surface, namely, constant wall temperature
(CWT) and constant heat flux (CHF) are explored. The resulting flow
and temperature fields are visualized in terms of the streamline and
isotherm patterns in the proximity of the cylinder. The flow remains
attached to the cylinder surface over the range of conditions spanned
here except that for and ; at these conditions, a separated flow
region is observed when the condition of the constant wall
temperature is prescribed on the surface of the cylinder. The heat
transfer characteristics are analyzed in terms of the local and average
Nusselt numbers. The maximum value of the local Nusselt number
always occurs at the corner points whereas it is found to be minimum
at the rear stagnation point on the flat surface. Overall, the average
Nusselt number increases with Grashof number and/ or Prandtl
number in accordance with the scaling considerations. The numerical
results are used to develop simple correlations as functions of
Grashof and Prandtl number thereby enabling the interpolation of the
present numerical results for the intermediate values of the Prandtl or
Grashof numbers for both thermal boundary conditions.
Abstract: The rate of nitrate adsorption by a nitrate selective ion
exchange resin was investigated in a well-stirred batch experiments.
The kinetic experimental data were simulated with diffusion models including external mass transfer, particle diffusion and chemical
adsorption. Particle pore volume diffusion and particle surface diffusion were taken into consideration separately and simultaneously
in the modeling. The model equations were solved numerically using the Crank-Nicholson scheme. An optimization technique was
employed to optimize the model parameters. All nitrate concentration
decay data were well described with the all diffusion models. The
results indicated that the kinetic process is initially controlled by external mass transfer and then by particle diffusion. The external
mass transfer coefficient and the coefficients of pore volume diffusion and surface diffusion in all experiments were close to each
other with the average value of 8.3×10-3 cm/S for external mass
transfer coefficient. In addition, the models are more sensitive to the
mass transfer coefficient in comparison with particle diffusion. Moreover, it seems that surface diffusion is the dominant particle
diffusion in comparison with pore volume diffusion.
Abstract: The present work is concerned with the free
convective two dimensional flow and heat transfer, in isotropic fluid
filled porous rectangular enclosure with differentially heated walls for
steady state incompressible flow have been investigated for non-
Darcy flow model. Effects of Darcy number (0.0001 £Da£ 10),
Rayleigh number (10 £Ra£ 5000), and aspect ratio (0.25 £AR£ 4), for
a range of porosity (0.4 £e£ 0.9) with and without moving lower wall
have been studied. The cavity was insulated at the lower and upper
surfaces. The right and left heated surfaces allows convective
transport through the porous medium, generating a thermal
stratification and flow circulations. It was found that the Darcy
number, Rayleigh number, aspect ratio, and porosity considerably
influenced characteristics of flow and heat transfer mechanisms. The
results obtained are discussed in terms of the Nusselt number,
vectors, contours, and isotherms.
Abstract: The present study attempted to improve the Mercury
(Hg) sorption capacity of kanuma volcanic ash soil (KVAS) by
impregnating the cupper (Cu). Impregnation was executed by 1 and
5% Cu powder and sorption characterization of optimum Hg
removing Cu impregnated KVAS was performed under different
operational conditions, contact time, solution pH, sorbent dosage and
Hg concentration using the batch operation studies. The 1% Cu
impregnated KVAS pronounced optimum improvement (79%) in
removing Hg from water compare to control. The present
investigation determined the equilibrium state of maximum Hg
adsorption at 6 h contact period. The adsorption revealed a pH
dependent response and pH 3.5 showed maximum sorption capacity
of Hg. Freundlich isotherm model is well fitted with the experimental
data than that of Langmuir isotherm. It can be concluded that the Cu
impregnation improves the Hg sorption capacity of KVAS and 1%
Cu impregnated KVAS could be employed as cost-effective
adsorbent media for treating Hg contaminated water.
Abstract: Rice husk is a lignocellulosic source that can be
converted to ethanol. Three hundreds grams of rice husk was mixed
with 1 L of 0.18 N sulfuric acid solutions then was heated in an
autoclave. The reaction was expected to be at constant temperature
(isothermal), but before that temperature was achieved, reaction has
occurred. The first liquid sample was taken at temperature of 140 0C
and repeated every 5 minute interval. So the data obtained are in the
regions of non-isothermal and isothermal. It was observed that the
degradation has significant effects on the ethanol production. The
kinetic constants can be expressed by Arrhenius equation with the
frequency factors for hydrolysis and sugar degradation of 1.58 x 105
1/min and 2.29 x 108 L/mole/min, respectively, while the activation
energies are 64,350 J/mole and 76,571 J/mole. The highest ethanol
concentration from fermentation is 1.13% v/v, attained at 220 0C.