Mass Transfer Modeling of Nitrate in an Ion Exchange Selective Resin
The rate of nitrate adsorption by a nitrate selective ion
exchange resin was investigated in a well-stirred batch experiments.
The kinetic experimental data were simulated with diffusion models including external mass transfer, particle diffusion and chemical
adsorption. Particle pore volume diffusion and particle surface diffusion were taken into consideration separately and simultaneously
in the modeling. The model equations were solved numerically using the Crank-Nicholson scheme. An optimization technique was
employed to optimize the model parameters. All nitrate concentration
decay data were well described with the all diffusion models. The
results indicated that the kinetic process is initially controlled by external mass transfer and then by particle diffusion. The external
mass transfer coefficient and the coefficients of pore volume diffusion and surface diffusion in all experiments were close to each
other with the average value of 8.3×10-3 cm/S for external mass
transfer coefficient. In addition, the models are more sensitive to the
mass transfer coefficient in comparison with particle diffusion. Moreover, it seems that surface diffusion is the dominant particle
diffusion in comparison with pore volume diffusion.
[1] C. Della Rocca, V. Belgiorno, S. Meriç, "Overview of in-situ applicable
nitrate removal processes," Desalination, 204, pp. 46-62, 2007.
[2] P.C. Mishra, R.K. Patel, "Use of agricultural waste for the removal of nitrate-nitrogen from aqueous medium," Journal of Environmental
Management, 90, pp. 519-522, 2009.
[3] S. Mossa Hosseini, B. Ataie-Ashtiani, M. Kholghi, "Nitrate reduction by
nano-Fe/Cu particles in packed column," Desalination, 276, pp. 214-
221, 2011.
[4] J.H.Winneberger, "Nitrogen, public health, and the environment," Ann
Arbor SciencePublishers Inc., Ann Arbor, Michigan, 1982.
[5] S. Samatya, N. Kabay, U. Yuksel, M. Arda, M. Yuksel, "Removal of nitrate from aqueous solution by nitrate selective ion exchange resins", Reactive & Functional Polymers, 66, pp. 1206-1214, 2006.
[6] S. N. Milmile, J. V. Pande, S. Karmakar, A. Bansiwal, T. Chakrabarti,
R. B. Biniwale, "Equilibrium isotherm and kinetic modeling of the adsorption of nitrates by anion exchange Indion NSSR resin,"
Desalination, 276, pp. 38-44, 2006.
[7] M. Chabani, A. Amrane, A. Bensmaili, "Kinetic modeling of the
adsorption of nitrates by ion exchange resin," Chemical Engineering
Journal, 125, pp. 111-117, 2006.
[8] M. Chabani, A. Bensmaili, "Kinetic modeling of the retention of nitrates
by Amberlite IRA 410," Desalination, 185, pp. 509-515, 2005.
[9] Z. Hubicki, A.Wołowicz, "Adsorption of palladium(II) from chloride
solutions on Amberlyst A 29 and Amberlyst A 21 resins,"
Hydrometallurgy 96, pp. 159-165, 2009.
[10] B. Aly├╝z, Sevil Veli, " Kinetics and equilibrium studies for the removal
of nickel and zinc from aqueous solutions by ion exchange resins,"
Journal of Hazardous Materials, 167, pp. 482-488 (2009).
[11] I. Yilmaz Ipek, R. Holdich, N. Kabay, M. Bryjak, M. Yuksel, "Kinetic
behaviour of boron selective resins for boron removal using seeded
microfiltration system," Reactive & Functional Polymers, 67, pp. 1628-
1634 (2007).
[12] K. Vankova, P. Acai, M. Polakovic, "Modelling of fixed-bed adsorption
of mono-, di-, and fructooligosaccharides on a cation-exchange resin,"
Biochemical Engineering Journal, 49, pp. 84-88, 2010.
[13] K. Miyabe, G. Guiochon, "Kinetic study of the mass transfer of bovine
serum albumin in anion-exchange chromatography," Journal of Chromatography, A, 866, pp. 147-171, 2000.
[14] A. A. Zagorodni, "Ion Exchange Materials Properties and Applications,"
Elsevier BV.,2007.
[15] V.M.T.M. Silva, A.E. Rodrigues, "Kinetic studies in a batch reactor
using ion exchange resin catalysts for oxygenates production: Role of
mass transfer mechanisms," Chemical Engineering Science, 61, pp. 316- 331, 2006.
[16] R. Leyva-Ramos, L.A. Bernal-Jacome, J. Mendoza-Barron, M.M.G.
Hernandez-Orta, "Kinetic modeling of pentachlorophenol adsorption
onto granular activated carbon," Journal of the Taiwan Institute of
Chemical Engineers 40, pp. 622-629, 2009.
[17] Geankoplis, C. J. and R. Leyva-Ramos, "Model Simulation and Analysis
of Surface Diffusion of Liquids in Porous Solids," Chem. Eng. Sci., 40 (5), 799, 1985.
[18] R. B. Garcia-Reyes, J. R. Rangel-Mendez, "Adsorption kinetics of chromium(III) ions on agro-waste materials," Bioresource Technology,
101, pp. 8099-8108, 2010.
[19] J. Beltran de Heredia, J.R. Dom─▒nguez, Y. Cano, I. Jimenez, Nitrate removal from groundwater using Amberlite IRN-78: Modeling the
system, Applied Surface Science, 252, pp. 6031-6035, 2006.
[20] N. Z. Misak, "Some aspects of the application of adsorption isotherms to
ion exchange reactions," Reactive & Functional Polymers, 43, pp. 153-
164, 2000.
[21] R. Ocampo-Perez, R. Leyva-Ramos, "P. Alonso-Davila, J. Rivera-
Utrilla, M. Sanchez-Polo, Modeling adsorption rate of pyridine onto granular activated carbon," Chemical Engineering Journal, 165, pp.133-141, 2010.
[22] Y. Rudich, R.K. Talukdar, A.R. Ravishankara, "Reactive uptake of NO3
on pure water ionic solutions," Journal of geophysical research, 101, pp.
21023-21031, 1996.
[23] "Diffusion coefficients of nitrate, chloride, sulphate and water in cracked
and uncracked Chalk," Journal of Soil Science, 35, pp. 27-33, 1984.
[24] P. Li, A.K. SenGupta, "Intraparticle diffusion during selective sorption
of trace contaminants: the effect of gel versus macroporous morphology," Environ. Sci. Technol., 34 (24), pp. 5193-5200, 2000.
[1] C. Della Rocca, V. Belgiorno, S. Meriç, "Overview of in-situ applicable
nitrate removal processes," Desalination, 204, pp. 46-62, 2007.
[2] P.C. Mishra, R.K. Patel, "Use of agricultural waste for the removal of nitrate-nitrogen from aqueous medium," Journal of Environmental
Management, 90, pp. 519-522, 2009.
[3] S. Mossa Hosseini, B. Ataie-Ashtiani, M. Kholghi, "Nitrate reduction by
nano-Fe/Cu particles in packed column," Desalination, 276, pp. 214-
221, 2011.
[4] J.H.Winneberger, "Nitrogen, public health, and the environment," Ann
Arbor SciencePublishers Inc., Ann Arbor, Michigan, 1982.
[5] S. Samatya, N. Kabay, U. Yuksel, M. Arda, M. Yuksel, "Removal of nitrate from aqueous solution by nitrate selective ion exchange resins", Reactive & Functional Polymers, 66, pp. 1206-1214, 2006.
[6] S. N. Milmile, J. V. Pande, S. Karmakar, A. Bansiwal, T. Chakrabarti,
R. B. Biniwale, "Equilibrium isotherm and kinetic modeling of the adsorption of nitrates by anion exchange Indion NSSR resin,"
Desalination, 276, pp. 38-44, 2006.
[7] M. Chabani, A. Amrane, A. Bensmaili, "Kinetic modeling of the
adsorption of nitrates by ion exchange resin," Chemical Engineering
Journal, 125, pp. 111-117, 2006.
[8] M. Chabani, A. Bensmaili, "Kinetic modeling of the retention of nitrates
by Amberlite IRA 410," Desalination, 185, pp. 509-515, 2005.
[9] Z. Hubicki, A.Wołowicz, "Adsorption of palladium(II) from chloride
solutions on Amberlyst A 29 and Amberlyst A 21 resins,"
Hydrometallurgy 96, pp. 159-165, 2009.
[10] B. Aly├╝z, Sevil Veli, " Kinetics and equilibrium studies for the removal
of nickel and zinc from aqueous solutions by ion exchange resins,"
Journal of Hazardous Materials, 167, pp. 482-488 (2009).
[11] I. Yilmaz Ipek, R. Holdich, N. Kabay, M. Bryjak, M. Yuksel, "Kinetic
behaviour of boron selective resins for boron removal using seeded
microfiltration system," Reactive & Functional Polymers, 67, pp. 1628-
1634 (2007).
[12] K. Vankova, P. Acai, M. Polakovic, "Modelling of fixed-bed adsorption
of mono-, di-, and fructooligosaccharides on a cation-exchange resin,"
Biochemical Engineering Journal, 49, pp. 84-88, 2010.
[13] K. Miyabe, G. Guiochon, "Kinetic study of the mass transfer of bovine
serum albumin in anion-exchange chromatography," Journal of Chromatography, A, 866, pp. 147-171, 2000.
[14] A. A. Zagorodni, "Ion Exchange Materials Properties and Applications,"
Elsevier BV.,2007.
[15] V.M.T.M. Silva, A.E. Rodrigues, "Kinetic studies in a batch reactor
using ion exchange resin catalysts for oxygenates production: Role of
mass transfer mechanisms," Chemical Engineering Science, 61, pp. 316- 331, 2006.
[16] R. Leyva-Ramos, L.A. Bernal-Jacome, J. Mendoza-Barron, M.M.G.
Hernandez-Orta, "Kinetic modeling of pentachlorophenol adsorption
onto granular activated carbon," Journal of the Taiwan Institute of
Chemical Engineers 40, pp. 622-629, 2009.
[17] Geankoplis, C. J. and R. Leyva-Ramos, "Model Simulation and Analysis
of Surface Diffusion of Liquids in Porous Solids," Chem. Eng. Sci., 40 (5), 799, 1985.
[18] R. B. Garcia-Reyes, J. R. Rangel-Mendez, "Adsorption kinetics of chromium(III) ions on agro-waste materials," Bioresource Technology,
101, pp. 8099-8108, 2010.
[19] J. Beltran de Heredia, J.R. Dom─▒nguez, Y. Cano, I. Jimenez, Nitrate removal from groundwater using Amberlite IRN-78: Modeling the
system, Applied Surface Science, 252, pp. 6031-6035, 2006.
[20] N. Z. Misak, "Some aspects of the application of adsorption isotherms to
ion exchange reactions," Reactive & Functional Polymers, 43, pp. 153-
164, 2000.
[21] R. Ocampo-Perez, R. Leyva-Ramos, "P. Alonso-Davila, J. Rivera-
Utrilla, M. Sanchez-Polo, Modeling adsorption rate of pyridine onto granular activated carbon," Chemical Engineering Journal, 165, pp.133-141, 2010.
[22] Y. Rudich, R.K. Talukdar, A.R. Ravishankara, "Reactive uptake of NO3
on pure water ionic solutions," Journal of geophysical research, 101, pp.
21023-21031, 1996.
[23] "Diffusion coefficients of nitrate, chloride, sulphate and water in cracked
and uncracked Chalk," Journal of Soil Science, 35, pp. 27-33, 1984.
[24] P. Li, A.K. SenGupta, "Intraparticle diffusion during selective sorption
of trace contaminants: the effect of gel versus macroporous morphology," Environ. Sci. Technol., 34 (24), pp. 5193-5200, 2000.
@article{"International Journal of Architectural, Civil and Construction Sciences:61656", author = "A. A. Hekmatzadeh and A. Karimi-Jashani and N. Talebbeydokhti", title = "Mass Transfer Modeling of Nitrate in an Ion Exchange Selective Resin", abstract = "The rate of nitrate adsorption by a nitrate selective ion
exchange resin was investigated in a well-stirred batch experiments.
The kinetic experimental data were simulated with diffusion models including external mass transfer, particle diffusion and chemical
adsorption. Particle pore volume diffusion and particle surface diffusion were taken into consideration separately and simultaneously
in the modeling. The model equations were solved numerically using the Crank-Nicholson scheme. An optimization technique was
employed to optimize the model parameters. All nitrate concentration
decay data were well described with the all diffusion models. The
results indicated that the kinetic process is initially controlled by external mass transfer and then by particle diffusion. The external
mass transfer coefficient and the coefficients of pore volume diffusion and surface diffusion in all experiments were close to each
other with the average value of 8.3×10-3 cm/S for external mass
transfer coefficient. In addition, the models are more sensitive to the
mass transfer coefficient in comparison with particle diffusion. Moreover, it seems that surface diffusion is the dominant particle
diffusion in comparison with pore volume diffusion.", keywords = "External mass transfer, pore volume diffusion, surface diffusion, mass action law isotherm.", volume = "6", number = "1", pages = "59-6", }
