Abstract: Copper sulfide nanoparticles (CuS) were successfully synthesized by the pulsed plasma in liquid method, using two copper rod electrodes submerged in molten sulfur. Low electrical energy and no high temperature were applied for synthesis. Obtained CuS nanoparticles were then analyzed by means of X-ray diffraction, Low and High Resolution Transmission Electron Microscopy, Electron Diffraction, X-ray Photoelectron, Raman Spectroscopies and Field Emission Scanning Electron Microscopy. XRD analysis revealed peaks for CuS with hexagonal phase composition. TEM and HRTEM studies showed that sizes of CuS nanoparticles ranged between 10-60 nm, with the average size of about 20 nm. Copper sulfide nanoparticles have short nanorod-like structure. Raman spectroscopy found peak for CuS at 474.2cm-1of Raman region.
Abstract: The purpose of this research is to reduce the amount of incomplete coating of stainless steel washers in the electrodeposition painting process by using an experimental design technique. The surface preparation was found to be a major cause of painted surface quality. The influence of pretreating and painting process parameters, which are cleaning time, chemical concentration and shape of hanger were studied. A 23 factorial design with two replications was performed. The analysis of variance for the designed experiment showed the great influence of cleaning time and shape of hanger. From this study, optimized cleaning time was determined and a newly designed electrical conductive hanger was proved to be superior to the original one. The experimental verification results showed that the amount of incomplete coating defects decreased from 4% to 1.02% and operation cost decreased by 10.5%.
Abstract: This study is to investigate the electroencephalogram (EEG) differences generated from a normal and Alzheimer-s disease (AD) sources. We also investigate the effects of brain tissue distortions due to AD on EEG. We develop a realistic head model from T1 weighted magnetic resonance imaging (MRI) using finite element method (FEM) for normal source (somatosensory cortex (SC) in parietal lobe) and AD sources (right amygdala (RA) and left amygdala (LA) in medial temporal lobe). Then, we compare the AD sourced EEGs to the SC sourced EEG for studying the nature of potential changes due to sources and 5% to 20% brain tissue distortions. We find an average of 0.15 magnification errors produced by AD sourced EEGs. Different brain tissue distortion models also generate the maximum 0.07 magnification. EEGs obtained from AD sources and different brain tissue distortion levels vary scalp potentials from normal source, and the electrodes residing in parietal and temporal lobes are more sensitive than other electrodes for AD sourced EEG.
Abstract: SEMG (Surface Electromyogram) is one of the
bio-signals and is generated from the muscle. And there are many
research results that use forearm EMG to detect hand motions. In this
paper, we will talk about our developed the robot hand system that can
control grasping power by SEMG. In our system, we suppose that
muscle power is proportional to the amplitude of SEMG. The power is
estimated and the grip power of a robot hand is able to be controlled
using estimated muscle power in our system. In addition, to perform a
more precise control can be considered to build a closed loop feedback
system as an object to a subject to pressure from the edge of hand. Our
objectives of this study are the development of a method that makes
perfect detection of the hand grip force possible using SEMG patterns,
and applying this method to the man-machine interface.
Abstract: A gold coated copper rotating electrode was used to
eliminate surface oxidation effect. This study examined the effect of
electrode rotation on the ozone generation process and showed that an
ozonizer with an electrode rotating system might be a possible way to
increase ozone-synthesis efficiency. Two new phenomena appeared
during experiments with the rotating electrode. First was that ozone
concentration increased to about two times higher than that of the case
with no rotation. Second, input power and discharge area were found
to increase with the rotation speed. Both ozone concentration and
ozone production efficiency improved in the case of rotating electrode
compared to the case with a non-rotating electrode. One possible
reason for this was the increase in discharge length of
micro-discharges during electrode rotation. The rotating electrode
decreased onset voltage, while reactor capacitance increased with
rotation. Use of a rotating-type electrode allowed earlier observation
of the ozone zero phenomena compared with a non-rotating electrode
because, during rotation, the entire electrode surface was functional,
allowing nitrogen on the electrode surface to be evenly consumed.
Nitrogen demand increased with increasing rotation s
Abstract: In the present work, we have developed a symmetric electrochemical capacitor based on the nanostructured iron oxide (Fe3O4)-activated carbon (AC) nanocomposite materials. The physical properties of the nanocomposites were characterized by Scanning Electron Microscopy (SEM) and Brunauer-Emmett-Teller (BET) analysis. The electrochemical performances of the composite electrode in 1.0 M Na2SO3 and 1.0 M Na2SO4 aqueous solutions were evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The composite electrode with 4 wt% of iron oxide nanomaterials exhibits the highest capacitance of 86 F/g. The experimental results clearly indicate that the incorporation of iron oxide nanomaterials at low concentration to the composite can improve the capacitive performance, mainly attributed to the contribution of the pseudocapacitance charge storage mechanism and the enhancement on the effective surface area of the electrode. Nevertheless, there is an optimum threshold on the amount of iron oxide that needs to be incorporated into the composite system. When this optimum threshold is exceeded, the capacitive performance of the electrode starts to deteriorate, as a result of the undesired particle aggregation, which is clearly indicated in the SEM analysis. The electrochemical performance of the composite electrode is found to be superior when Na2SO3 is used as the electrolyte, if compared to the Na2SO4 solution. It is believed that Fe3O4 nanoparticles can provide favourable surface adsorption sites for sulphite (SO3 2-) anions which act as catalysts for subsequent redox and intercalation reactions.
Abstract: The operating control parameters of injection
flushing type of electrical discharge machining process on stainless
steel 304 workpiece using copper tools are being optimized
according to its individual machining characteristic i.e. Electrode
Wear Ratio (EWR). Higher EWR would give bad dimensional
precision for the EDM machined workpiece because of high
electrode wear. Hence, the quality characteristic for EWR is set to
lower-the-better to achieve the optimum dimensional precision for
the machined workpiece. Taguchi method has been used for the
construction, layout and analysis of the experiment for EWR
machining characteristic. The use of Taguchi method in the
experiment saves a lot of time and cost of preparing and machining
the experiment samples. Therefore, an L18 Orthogonal array
which was the fundamental component in the statistical design of
experiments has been used to plan the experiments and Analysis of
Variance (ANOVA) is used to determine the optimum machining
parameters for this machining characteristic. The control
parameters selected for this optimization experiments are polarity,
pulse on duration, discharge current, discharge voltage, machining
depth, machining diameter and dielectric liquid pressure. The
result had shown that negative polarity machining parameter
setting will decreases EWR.
Abstract: In recent times there has been a growing interest in the
development of quasi-two-dimensional niobium pentoxide (Nb2O5)
as a semiconductor for the potential electronic applications such as
capacitors, filtration, dye-sensitised solar cells and gas sensing
platforms. Therefore once the purpose is established, Nb2O5 can be
prepared in a number of nano- and sub-micron-structural
morphologies that include rods, wires, belts and tubes. In this study
films of Nb2O5 were prepared on gold plated silicon substrate using
spin-coating technique and subsequently by mechanical exfoliation.
The reason this method was employed was to achieve layers of less
than 15nm in thickness. The sintering temperature of the specimen
was 800oC. The morphology and structural characteristics of the
films were analyzed by Atomic Force Microscopy (AFM), Raman
Spectroscopy, X-ray Photoelectron Spectroscopy (XPS).
Abstract: To maximise furnace production it-s necessary to
optimise furnace control, with the objectives of achieving maximum
power input into the melting process, minimum network distortion
and power-off time, without compromise on quality and safety. This
can be achieved with on the one hand by an appropriate electrode
control and on the other hand by a minimum of AC transformer
switching.
Electrical arc is a stochastic process; witch is the principal cause
of power quality problems, including voltages dips, harmonic
distortion, unbalance loads and flicker. So it is difficult to make an
appropriate model for an Electrical Arc Furnace (EAF). The factors
that effect EAF operation are the melting or refining materials,
melting stage, electrode position (arc length), electrode arm control
and short circuit power of the feeder. So arc voltages, current and
power are defined as a nonlinear function of the arc length. In this
article we propose our own empirical function of the EAF and model,
for the mean stages of the melting process, thanks to the
measurements in the steel factory.
Abstract: In the paper the research of flat textile products for use
as electrodes was presented. Material-s resistance measurements were
carried out to determine the suitability of the textiles. Based on the received results of studies different types of textile electrodes were
designed. Textile electrodes tests were carried out on human
phantoms. The electro-conductive properties of human forearm
phantom were also described. Based on this results special electroconductive
hydrogels with electro-conductive particles were feasible. The hydrogel is an important element of the forearm-s phantom
model of a survey of electrodes for muscle electrostimulation. The
hydrogel is an equivalent human skin and tissue. The hydrogel should
have a permanence and recurrence of the electro-conductive properties.
Abstract: A power cable is widely used for power supply in
power distributing networks and power transmission lines. Due to
limitations in the production, delivery and setting up power cables,
they are produced and delivered in several separate lengths. Cable
itself, consists of two cable terminations and arbitrary number of
cable joints, depending on the cable route length. Electrical stress
control is needed to prevent a dielectric breakdown at the end of the
insulation shield in both the air and cable insulation. Reliability of
cable joint depends on its materials, design, installation and operating
environment. The paper describes design and performance results for
new modeled cable joints. Design concepts, based on numerical
calculations, must be correct. An Equivalent Electrodes
Method/Boundary Elements Method-hybrid approach that allows
electromagnetic field calculations in multilayer dielectric media,
including inhomogeneous regions, is presented.
Abstract: In this paper, we proposed the effects of Mo thickness
on the properties of AZO/Mo/AZO multilayer thin films for
opto-electronics applications. The structural, optical and electrical
properties of AZO/Mo/AZO thin films were investigated.
Optimization of the thin films coatings resulted with low resistivity of
9.98 × 10-5 )-cm, mobility of 12.75 cm2/V-s, carrier concentration of
1.05 × 1022 cm-3, maximum transmittance of 79.13% over visible
spectrum of 380 – 780 nm and Haacke figure of merit (FOM) are 5.95
× 10-2 )-1 under Mo layer thickness of 15 nm. These results indicate an
alternative candidate for use as a transparent electrode in solar cells
and various displays applications.
Abstract: We present a label-free biosensor based on
electrochemical impedance spectroscopy for the detection of proinflammatory
cytokine Tumor Necrosis Factor (TNF-α). Secretion of
TNF-α has been correlated to the onset of various diseases including
rheumatoid arthritis, Crohn-s disease etc. Gold electrodes were
patterned on a silicon substrate and self assembled monolayer of
dithiobis-succinimidyl propionate was used to develop the biosensor
which achieved a detection limit of ~57fM. A linear relationship was
also observed between increasing TNF-α concentrations and chargetransfer
resistance within a dynamic range of 1pg/ml – 1ng/ml.
Abstract: In this paper, a one-dimensional numerical approach is
used to study the effect of applying electrohydrodynamics on the
temperature and species mass fraction profiles along the microcombustor.
Premixed mixture is H2-Air with a multi-step chemistry
(9 species and 19 reactions). In the micro-scale combustion because
of the increasing ratio of area-to-volume, thermal and radical
quenching mechanisms are important. Also, there is a significant heat
loss from the combustor walls. By inserting a number of electrodes
into micro-combustor and applying high voltage to them corona
discharge occurs. This leads in moving of induced ions toward
natural molecules and colliding with them. So this phenomenon
causes the movement of the molecules and reattaches the flow to the
walls. It increases the velocity near the walls that reduces the wall
boundary layer. Consequently, applying electrohydrodynamics
mechanism can enhance the temperature profile in the microcombustor.
Ultimately, it prevents the flame quenching in microcombustor.
Abstract: As the increase of intraoral acidity due to ingestion of sweet foods and acidic beverages usually bring forth a dental caries and a erosion, the measurement of intraoral pH is essential in the study of oral environment. The indwelling intraoral pH telemetry for lasting longer than 24 hours in the mouth was developed to overcome the limits of conventional wire electrode method previously used for salivary and plaque pH measurement, and to assess its effectiveness.
Abstract: When a high DC voltage is applied to a capacitor with
strongly asymmetrical electrodes, it generates a mechanical force that
affects the whole capacitor. This is caused by the motion of ions generated around the smaller of the two electrodes and their subsequent interaction with the surrounding medium. If one of the electrodes is heated, it changes the conditions around the capacitor
and influences the process of ionisation, thus changing the value of the generated force. This paper describes these changes and gives
reasons behind them. Further the experimental results are given as proof of the ionic mechanism of the phenomenon.
Abstract: In the first part of the research work, an electrolyzer (10.16 cm dia and 24.13 cm height) to produce hydrogen and oxygen was constructed for single slice O2/H2 fuel cell using cation exchange membrane. The electrolyzer performance was tested with 23% NaOH, 30% NaOH, 30% KOH and 35% KOH electrolyte solution with current input 4 amp and 2.84 V from the rectifier. Rates of volume of hydrogen produced were 0.159 cm3/sec, 0.155 cm3/sec, 0.169 cm3/sec and 0.163 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution. Rates of volume of oxygen produced were 0.212 cm3/sec, 0.201 cm3/sec, 0.227 cm3/sec and 0.219 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution (1.5 L). In spite of being tested the increased concentration of electrolyte solution, the gas rate does not change significantly. Therefore, inexpensive 23% NaOH electrolyte solution was chosen to use as the electrolyte in the electrolyzer. In the second part of the research work, graphite serpentine flow plates, fiberglass end plates, stainless steel screen electrodes, silicone rubbers were made to assemble the single slice O2/H2 polymer electrolyte membrane fuel cell (PEMFC).
Abstract: The article deals with technical support of intracranial single unit activity measurement. The parameters of the whole measuring set were tested in order to assure the optimal conditions of extracellular single-unit recording. Metal microelectrodes for measuring the single-unit were tested during animal experiments. From signals recorded during these experiments, requirements for the measuring set parameters were defined. The impedance parameters of the metal microelectrodes were measured. The frequency-gain and autonomous noise properties of preamplifier and amplifier were verified. The measurement and the description of the extracellular single unit activity could help in prognoses of brain tissue damage recovery.
Abstract: In this work a surgical simulator is produced which
enables a training otologist to conduct a virtual, real-time prosthetic
insertion. The simulator provides the Ear, Nose and Throat surgeon
with real-time visual and haptic responses during virtual cochlear
implantation into a 3D model of the human Scala Tympani (ST). The
parametric model is derived from measured data as published in the
literature and accounts for human morphological variance, such as
differences in cochlear shape, enabling patient-specific pre- operative
assessment. Haptic modeling techniques use real physical data and
insertion force measurements, to develop a force model which
mimics the physical behavior of an implant as it collides with the ST
walls during an insertion. Output force profiles are acquired from the
insertion studies conducted in the work, to validate the haptic model.
The simulator provides the user with real-time, quantitative insertion
force information and associated electrode position as user inserts the
virtual implant into the ST model. The information provided by this
study may also be of use to implant manufacturers for design
enhancements as well as for training specialists in optimal force
administration, using the simulator. The paper reports on the methods
for anatomical modeling and haptic algorithm development, with
focus on simulator design, development, optimization and validation.
The techniques may be transferrable to other medical applications
that involve prosthetic device insertions where user vision is
obstructed.
Abstract: In this paper an attempt has been made to correlate the usefulness of electrodes made through powder metallurgy (PM) in comparison with conventional copper electrode during electric discharge machining. Experimental results are presented on electric discharge machining of AISI D2 steel in kerosene with copper tungsten (30% Cu and 70% W) tool electrode made through powder metallurgy (PM) technique and Cu electrode. An L18 (21 37) orthogonal array of Taguchi methodology was used to identify the effect of process input factors (viz. current, duty cycle and flushing pressure) on the output factors {viz. material removal rate (MRR) and surface roughness (SR)}. It was found that CuW electrode (made through PM) gives high surface finish where as the Cu electrode is better for higher material removal rate.