Abstract: A gold coated copper rotating electrode was used to
eliminate surface oxidation effect. This study examined the effect of
electrode rotation on the ozone generation process and showed that an
ozonizer with an electrode rotating system might be a possible way to
increase ozone-synthesis efficiency. Two new phenomena appeared
during experiments with the rotating electrode. First was that ozone
concentration increased to about two times higher than that of the case
with no rotation. Second, input power and discharge area were found
to increase with the rotation speed. Both ozone concentration and
ozone production efficiency improved in the case of rotating electrode
compared to the case with a non-rotating electrode. One possible
reason for this was the increase in discharge length of
micro-discharges during electrode rotation. The rotating electrode
decreased onset voltage, while reactor capacitance increased with
rotation. Use of a rotating-type electrode allowed earlier observation
of the ozone zero phenomena compared with a non-rotating electrode
because, during rotation, the entire electrode surface was functional,
allowing nitrogen on the electrode surface to be evenly consumed.
Nitrogen demand increased with increasing rotation s