Abstract: A portable sensor for the analysis of phosphate in
aqueous samples has been developed. The sensor incorporates
microfluidic technology, colorimetric detection, and wireless
communications into a compact and rugged portable device. The
detection method used is the molybdenum yellow method, in which a
phosphate-containing sample is mixed with a reagent containing
ammonium metavanadate and ammonium molybdate in an acidic
medium. A yellow-coloured compound is generated and the
absorption of this compound is measured using a light emitting diode
(LED) light source and a photodiode detector. The absorption is
directly proportional to the phosphate concentration in the original
sample. In this paper we describe the application of this phosphate
sensor to the analysis of wastewater at a municipal wastewater
treatment plant in Co. Kildare, Ireland.
Abstract: MOC (method of cell) is a new method of investigating
wave propagating in material with periodic microstructure, and can
reflect the effect of microstructure. Wave propagation in periodically
laminated medium consisting of linearly elastic layers can be treated
as a special application of this method. In this paper, it was used to
simulate the dynamic response of carbon-phenolic to impulsive
loading under certain boundary conditions. From the comparison
between the results obtained from this method and the exact results
based on propagator matrix theory, excellent agreement is achieved.
Conclusion can be made that the oscillation periodicity is decided by
the thickness of sub-cells. In the end, the NHDMOC method, which
permits studying stress wave propagation with one dimensional strain,
was applied to study the one-dimensional stress wave propagation. In
this paper, the ZWT nonlinear visco-elastic constitutive relationship
with 7 parameters, NHDMOC, and corresponding equations were
deduced. The equations were verified, comparing the elastic stress
wave propagation in SHPB with, respectively, the elastic and the
visco-elastic bar. Finally the dispersion and attenuation of stress wave
in SHPB with visco-elastic bar was studied.
Abstract: The aim of this study was to synthesize the single
walled carbon nanotubes (SWCNTs) and determine their hydrogen
storage capacities. SWCNTs were firstly synthesized by chemical
vapor deposition (CVD) of acetylene (C2H2) on a magnesium oxide
(MgO) powder impregnated with an iron nitrate (Fe(NO3)3·9H2O)
solution. The synthesis parameters were selected as: the synthesis
temperature of 800°C, the iron content in the precursor of 5% and the
synthesis time of 30 min. Purification process of SWCNTs was
fulfilled by microwave digestion at three different temperatures (120,
150 and 200 °C), three different acid concentrations (0.5, 1 and 1.5
M) and for three different time intervals (15, 30 and 60 min). Nitric
acid (HNO3) was used in the removal of the metal catalysts. The
hydrogen storage capacities of the purified materials were measured
using volumetric method at the liquid nitrogen temperature and gas
pressure up to 100 bar. The effects of the purification conditions such
as temperature, time and acid concentration on hydrogen adsorption
were investigated.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: A novel interpolation scheme to extend usable spectrum
and upconvert in high performance D/A converters is addressed in this
paper. By adjusting the pulse width of cycle and the production circuit
of code, the expansion code is a null code or complementary code that
is interpolation process. What the times and codes of interpolation
decide DAC works in one of a normal mode or multi-mixer mode
so that convert the input digital data signal into normal signal or a
mixed analog signal having a mixer frequency that is higher than the
data frequency. Simulation results show that the novel scheme and
apparatus most extend the usable frequency spectrum into fifth to
sixth Nyquist zone beyond conventional DACs.
Abstract: This paper presents a formalisation of the different existing code mutation techniques (polymorphism and metamorphism) by means of formal grammars. While very few theoretical results are known about the detection complexity of viral mutation techniques, we exhaustively address this critical issue by considering the Chomsky classification of formal grammars. This enables us to determine which family of code mutation techniques are likely to be detected or on the contrary are bound to remain undetected. As an illustration we then present, on a formal basis, a proof-of-concept metamorphic mutation engine denoted PB MOT, whose detection has been proven to be undecidable.
Abstract: In this paper, a class of predator-prey-chain model with harvesting terms are studied. By using Mawhin-s continuation theorem of coincidence degree theory and some skills of inequalities, some sufficient conditions are established for the existence of eight positive periodic solutions. Finally, an example is presented to illustrate the feasibility and effectiveness of the results.
Abstract: The modified Claus process is commonly used in oil
refining and gas processing to recover sulfur and destroy
contaminants formed in upstream processing. A Claus furnace feed
containing a relatively low concentration of H2S may be incapable of
producing a stable flame. Also, incomplete combustion of
hydrocarbons in the feed can lead to deterioration of the catalyst in
the reactors due to soot or carbon deposition. Therefore, special
consideration is necessary to achieve the appropriate overall sulfur
recovery. In this paper, some configurations available to treat lean
acid gas streams are described and the most appropriate ones are
studied to overcome low H2S concentration problems. As a result,
overall sulfur recovery is investigated for feed preheating and hot gas
configurations.
Abstract: Application of pesticides in the paddy fields has
deleterious effects on non-target organisms including cyanobacteria
which are photosynthesizing and nitrogen fixing micro-organisms
contributing significantly towards soil fertility and crop yield.
Pesticide contamination in the paddy fields has manifested into a
serious global environmental concern. To study the effect of one such
pesticide, three cyanobacterial strains; Anabaena fertilissima,
Aulosira fertilissima and Westiellopsis prolifica were selected for
their stress responses to an Organochlorine insecticide - 6, 7, 8, 9, 10,
10-hexachloro-1, 5, 5a, 6, 9, 9a-hexahydro-6, 9-methano-2, 4, 3-
benzodioxathiepine-3-oxide, with reference to their photosynthesic
pigments-chlorophyll-a and carotenoids as well as accessory
pigments-phycobiliproteins (phycocyanin, allophycocyanin and
phycoerythrin), stress induced biochemical metabolites like
carbohydrates, proteins, amino acids, phenols and enzymes-nitrate
reductase, glutamine synthetase and succinate dehydrogenase. All
the three cyanobacterial strains were adversely affected by the
insecticide doses and inhibition was dose dependent. Reduction in
photosynthetic and accessory pigments, metabolites, nitrogen fixing
and respiratory enzymes of the test organisms were accompanied
with an initial increase in their total protein at lower Organochlorine
doses. On the other hand, increased amount of phenols in all the
insecticide treated concentrations was indicative of stressed activities
of the organisms.
Abstract: Electronic commerce is growing rapidly with on-line
sales already heading for hundreds of billion dollars per year. Due to
the huge amount of money transferred everyday, an increased
security level is required. In this work we present the architecture of
an intelligent speaker verification system, which is able to accurately
verify the registered users of an e-commerce service using only their
voices as an input. According to the proposed architecture, a
transaction-based e-commerce application should be complemented
by a biometric server where customer-s unique set of speech models
(voiceprint) is stored. The verification procedure requests from the
user to pronounce a personalized sequence of digits and after
capturing speech and extracting voice features at the client side are
sent back to the biometric server. The biometric server uses pattern
recognition to decide whether the received features match the stored
voiceprint of the customer who claims to be, and accordingly grants
verification. The proposed architecture can provide e-commerce
applications with a higher degree of certainty regarding the identity
of a customer, and prevent impostors to execute fraudulent
transactions.
Abstract: A lot of recent research have spoken on the relation
between the increase of the homocysteinemia and some kinds of
cancer . For that, our study was based on the research of a possible
relation between the increase of the concentration of this amino-acid
in the plasma and the appearance of the disease of the Acute
Lymphoblastic Leukaemia in a part of Algerian children with Berber
origin in the East of Algeria . The study has done on 47 ill persons
with an average age of (09±06 ) years , with whom the disease has
diagnosed by blood and marrow examination in the hospital of blood
diseases in the CHU of Batna, and on 194 healthy witnesses of the
same age. The two groups were benefited by a dosage of the
concentration of the homocysteine vitamin B9 ,vitamin B12 , and
also of the study of special polymorphisms of indispensable enzymes
in the metabolism of this acid , and that by the use of the method (
Light cycler ) Real time PCR , on the following enzymes : MS (
C2756G ), MSR ( A66G ) ,MTHFR1 ( C677T ) and MTHFR2
(A1298C). The obtained results have revealed that the rate of the
homozygote muted genotype is the less frequent in the two groups ,
and that exist at list one genotype of each enzyme in the ill group and
in which the percentage exceed with remarkable way the same
genotype in the healthy group and we notice specially the muted
genotype GG of -the methionine synthetase-and the form TT of the
enzyme – methyline tetra hydrofolate reductase – We notice the
existence of considerable number of genotypes in the ill group lied
with characteristic increase of this Amino-acid ,and that for the
reduction of the biologic activity of these enzymes which become
inefficient in the transfer of the homocysteine into the methionine
and cause the diminution of the biologic activity of these enzymes
and with consequence the reduction of the percentage of methylic
radicals in the DNA of studied genes and that lead to the increase of
the activity and the capacity of transcription , and it-s so probably
that this last one is one of the factors of this disease especially if we
know that the specific check-up of vitamins is normal and similar in
the two groups , which ovoid the hypothesis of the reduction of
vitamins . We notice also that the heterozygote genotype is the less in
the sick category except the MTHFR2. Wild genotype is more
frequent in the witness group except MSR. Even these results are
partials; they open a new way in the genetic diagnosis of this
malicious disease which allow a precocious diagnosis and the use of
an effective and appropriated treatment in the same time.
Abstract: Raw wood vinegar was purified by both standing and
filtering methods. Toxicity tests were conducted under laboratory
conditions by the topical application method (contact poison) and
feeding method (stomach poison). Larvicidal activities of wood
vinegar at four different concentrations (10, 15, 20, 25 and 30 %)
were studied against second instar larvae of housefly (Musca
domestica L.). Four replicates were maintained for all treatments and
controls. Larval mortality was recorded up to 96 hours and compared
with the larval survivability by two methods of larvicidal bioassay.
Percent pupation and percent adult emergence were observed in
treated M. domestica. The study revealed that the feeding method
gave higher efficiency compared with the topical application method.
Larval mortality increased with increasing concentration of wood
vinegar and the duration of exposure. No mortality was found in
treated M. domestica larvae at minimum 10% concentration of wood
vinegar through the experiments. The treated larvae were maintained
up to pupa and adult emergence. At 30% maximum concentration
larval duration was extended to 11 days in M. domestica for topical
application method and 9 days for feeding method. Similarly the
pupal durations were also increased with increased concentrations
(16 and 24 days for topical application method and feeding method
respectively at 30% concentration) of the treatments.
Abstract: Thrombosis can be life threatening, necessitating therefore its instant treatment. Hydergine, a nootropic agent is used as a cognition enhancer in stroke patients but relatively little is known about its anti-thrombolytic effect. To investigate this aspect, in vivo and ex vivo experiments were designed and conducted. Three groups of rats were injected 1.5mg, 3.0mg and 4.5mg hydergine intraperitonealy with and without prior exposure to fresh plasma. Positive and negative controls were run in parallel. Animals were sacrificed after 1.5hrs and BT, CT, PT, INR, APTT, plasma calcium levels were estimated. For ex vivo analyses, each 1ml blood aspirated was exposed to 0.1mg, 0.2mg, 0.3mg dose of hydergine with parallel controls. Parameters analyzed were as above. Statistical analysis was through one-way ANOVA. Dunken-s and Tukey-s tests provided intra-group variance. BT, CT, PT, INR and APTT increased while calcium levels dropped significantly (P
Abstract: In this paper, a new Genetic Algorithm (GA) based
methodology is proposed to optimize the Degree of Hybridization
(DOH) in a passenger parallel hybrid car. At first step, target
parameters for the vehicle are decided and then using ADvanced
VehIcle SimulatOR (ADVISOR) software, the variation pattern of
these target parameters, across the different DOHs, is extracted. At
the next step, a suitable cost function is defined and is optimized
using GA. In this paper, also a new technique has been proposed for
deciding the number of battery modules for each DOH, which leads
to a great improvement in the vehicle performance. The proposed
methodology is so simple, fast and at the same time, so efficient.
Abstract: In textile industry, besides the conventional textile
products, technical textile goods, that have been brought external
functional properties into, are being developed for technical textile
industry. Especially these products produced with weaving
technology are widely preferred in areas such as sports, geology,
medical, automotive, construction and marine sectors. These textile
products are exposed to various stresses and large deformations under
typical conditions of use. At this point, sufficient and reliable data
could not be obtained with uniaxial tensile tests for determination of
the mechanical properties of such products due to mainly biaxial
stress state. Therefore, the most preferred method is a biaxial tensile
test method and analysis. These tests and analysis is applied to fabrics
with different functional features in order to establish the textile
material with several characteristics and mechanical properties of the
product. Planar biaxial tensile test, cylindrical inflation and bulge
tests are generally required to apply for textile products that are used
in automotive, sailing and sports areas and construction industry to
minimize accidents as long as their service life. Airbags, seat belts
and car tires in the automotive sector are also subject to the same
biaxial stress states, and can be characterized by same types of
experiments. In this study, in accordance with the research literature
related to the various biaxial test methods are compared. Results with
discussions are elaborated mainly focusing on the design of a biaxial
test apparatus to obtain applicable experimental data for developing a
finite element model. Sample experimental results on a prototype
system are expressed.
Abstract: The paper presents the results of a series of
experiments conducted on physical models of Quarter-circle
breakwater (QBW) in a two dimensional monochromatic wave
flume. The purpose of the experiments was to evaluate the reflection
coefficient Kr of QBW models of different radii (R) for different
submergence ratios (d/hc), where d is the depth of water and hc is the
height of the breakwater crest from the sea bed. The radii of the
breakwater models studied were 20cm, 22.5cm, 25cm, 27.5cm and
submergence ratios used varied from 1.067 to 1.667. The wave
climate off the Mangalore coast was used for arriving at the various
model wave parameters. The incident wave heights (Hi) used in the
flume varied from 3 to 18cm, and wave periods (T) ranged from 1.2 s
to 2.2 s. The water depths (d) of 40cm, 45cm and 50cm were used in
the experiments. The data collected was analyzed to compute
variation of reflection coefficient Kr=Hr/Hi (where Hr=reflected wave
height) with the wave steepness Hi/gT2 for various R/Hi
(R=breakwater radius) values. It was found that the reflection
coefficient increased as incident wave steepness increased. Also as
wave height decreases reflection coefficient decreases and as
structure radius R increased Kr decreased slightly.
Abstract: This study discusses the effect of uncertainty on
production levels of a petrochemical complex. Uncertainly or
variations in some model parameters, such as prices, supply and
demand of materials, can affect the optimality or the efficiency of any
chemical process. For any petrochemical complex with many plants,
there are many sources of uncertainty and frequent variations which
require more attention. Many optimization approaches are proposed
in the literature to incorporate uncertainty within the model in order
to obtain a robust solution. In this work, a stability analysis approach
is applied to a deterministic LP model of a petrochemical complex
consists of ten plants to investigate the effect of such variations on
the obtained optimal production levels. The proposed approach can
determinate the allowable variation ranges of some parameters,
mainly objective or RHS coefficients, before the system lose its
optimality. Parameters with relatively narrow range of variations, i.e.
stability limits, are classified as sensitive parameters or constraints
that need accurate estimate or intensive monitoring. These stability
limits offer easy-to-use information to the decision maker and help in
understanding the interaction between some model parameters and
deciding when the system need to be re-optimize. The study shows
that maximum production of ethylene and the prices of intermediate
products are the most sensitive factors that affect the stability of the
optimum solution
Abstract: Chitosan is a biopolymer composed of glucosamine
and N-acetyl glucosamine. Solubility and viscosity pose problems in
some applications. These problems can be overcome with unique
modifications. In this study, firstly, chitosan was modified by caffeic
acid and thioglycolic acid, separately. Then, growing effects of these
modified polymers was observed in U937 cell line. Caffeic acid is a
phenolic compound and its modifications act carcinogenic inhibitors
in drugs. Thiolated chitosans are commonly being used for drugdelivery
systems in various routes, because of enhancing
mucoadhesiveness property. U937 cell line was used model cell for
leukaemia. Modifications were achieved by 1 – 15 % binding range.
Increasing binding ratios showed higher radical-scavenging activity
and reducing cell growth, in compared to native chitosan. Caffeic
acid modifications showed higher radical-scavenging activity than
thiolated chitosans at the same concentrations. Caffeic acid and
thioglycolic acid modifications inhibited growth of U937, effectively.
Abstract: This study investigated climatic factors associated
with influenza cases in Southern Thailand. The main aim for use
regression analysis to investigate possible causual relationship of
climatic factors and variability between the border of the Andaman
Sea and the Gulf of Thailand. Southern Thailand had the highest
Influenza incidences among four regions (i.e. north, northeast, central
and southern Thailand). In this study, there were 14 climatic factors:
mean relative humidity, maximum relative humidity, minimum
relative humidity, rainfall, rainy days, daily maximum rainfall,
pressure, maximum wind speed, mean wind speed, sunshine duration,
mean temperature, maximum temperature, minimum temperature,
and temperature difference (i.e. maximum – minimum temperature).
Multiple stepwise regression technique was used to fit the statistical
model. The results indicated that the mean wind speed and the
minimum relative humidity were positively associated with the
number of influenza cases on the Andaman Sea side. The maximum
wind speed was positively associated with the number of influenza
cases on the Gulf of Thailand side.
Abstract: The product development process (PDP) in the
Technology group plays a very important role in the launch of any
product. While a manufacturing process encourages the use of certain
measures to reduce health, safety and environmental (HSE) risks on
the shop floor, the PDP concentrates on the use of Geometric
Dimensioning and Tolerancing (GD&T) to develop a flawless design.
Furthermore, PDP distributes and coordinates activities between
different departments such as marketing, purchasing, and
manufacturing. However, it is seldom realized that PDP makes a
significant contribution to developing a product that reduces HSE
risks by encouraging the Technology group to use effective GD&T.
The GD&T is a precise communication tool that uses a set of
symbols, rules, and definitions to mathematically define parts to be
manufactured. It is a quality assurance method widely used in the oil
and gas sector. Traditionally it is used to ensure the
interchangeability of a part without affecting its form, fit, and
function. Parts that do not meet these requirements are rejected
during quality audits.
This paper discusses how the Technology group integrates this
quality assurance tool into the PDP and how the tool plays a major
role in helping the HSE department in its goal towards eliminating
HSE incidents. The PDP involves a thorough risk assessment and
establishes a method to address those risks during the design stage.
An illustration shows how GD&T helped reduce safety risks by
ergonomically improving assembling operations. A brief discussion
explains how tolerances provided on a part help prevent finger injury.
This tool has equipped Technology to produce fixtures, which are
used daily in operations as well as manufacturing. By applying
GD&T to create good fits, HSE risks are mitigated for operating
personnel. Both customers and service providers benefit from
reduced safety risks.