Abstract: The outstanding mechanical properties of Carbon
nanotubes (CNTs) have generated great interest for their potential as
reinforcements in high performance cementitious composites. The
main challenge in research is the proper dispersion of carbon
nanotubes in the cement matrix. The present work discusses the role
of dispersion of multiwalled carbon nanotubes (MWCNTs) on the
compressive strength characteristics of hydrated Portland IS 1489
cement paste. Cement-MWCNT composites with different mixing
techniques were prepared by adding 0.2% (by weight) of MWCNTs
to Portland IS 1489 cement. Rectangle specimens of size
approximately 40mm × 40mm ×160mm were prepared and curing of
samples was done for 7, 14, 28 and 35days. An appreciable increase
in compressive strength with both techniques; mixture of MWCNTs
with cement in powder form and mixture of MWCNTs with cement
in hydrated form 7 to 28 days of curing time for all the samples was
observed.
Abstract: This paper introduces selected composition of conventional concretes and their resulting mechanical properties at different ages of concrete. With respect to utilization of mineral admixtures, fly ash and ground limestone agents were included in addition to pure Portland binder. The proposal of concrete composition remained constant in basic concrete components such as cement and representation of individual contents of aggregate fractions; weight dosing of admixtures and water dose were only modified. Water dose was chosen in order to achieve identical consistence by settlement for all proposals of concrete composition. Mechanical properties monitored include compression strength, static and dynamic modulus of concrete elasticity, at ages of 7, 28, 90, and 180 days.
Abstract: Floating tablets of Marichyadi Vati were developed with an aim to prolong its gastric residence time and increase the bioavailability of drug. Rapid gastrointestinal transit could result in incomplete drug release from the drug delivery system above the absorption zone leading to diminished efficacy of the administered dose. The tablets were prepared by wet granulation technique, using HPMC E50 LV act as Matrixing agent, Carbopol as floating enhancer, microcrystalline cellulose as binder, Sodium bi carbonate as effervescent agent with other excipients. The simplex lattice design was used for selection of variables for tablets formulation. Formulation was optimized on the basis of floating time and in vitro drug release. The results showed that the floating lag time for optimized formulation was found to be 61 second with about 97.32 % of total drug release within 3 hours. The vitro release profiles of drug from the formulation could be best expressed zero order with highest linearity r2 = 0.9943. It was concluded that the gastroretentive drug delivery system can be developed for Marichyadi Vati containing Piperine to increase the residence time of the drug in the stomach and thereby increasing bioavailability.
Abstract: Several review papers exist in literature related to the concrete containing mineral admixtures; however this paper reviews the durability characteristics of the concrete containing fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GGBS), metakaolin (MK) and rice husk ash (RHA). Durability related properties reviewed include permeability, resistance to sulfate attack, alkali-silica reaction (ASR), carbonation, chloride ion penetration, freezing and thawing, abrasion, fire, acid and efflorescence. From review of existing literature, it is found that permeability of concrete depends upon the content of alumina in mineral admixtures, i.e. higher the alumina content, lesser the permeability which results higher resistance to sulfate and chloride ion penetration. Highly reactive mineral admixtures prevent more ASR and reduce efflorescence. The carbonation increases with the mineral admixtures because higher water binder ratio and lesser content of portlandite in concrete due to pozzolanic reaction. Mineral admixtures require air entrainment except MK and RHA for better resistance to freezing and thawing.
Abstract: Non-woven fibrous filter media from empty fruit bunches were fabricated by using chitosan as a binder. Chitosan powder was dissolved in a 1 wt% aqueous acetic acid, and 1 wt% to 4 wt% of chitosan solutions was prepared. Chitosan-filled empty fruit bunches filter media have been prepared via wet-layup method. Thermogravimetric analysis (TGA) was performed to study various thermal properties of the fibrous filter media. It was found that the fibrous filter media have undergone several decomposition stages over a range of temperatures as revealed by TGA thermo-grams, where the temperature for 10% weight loss for chitosan-filled EFB filter media and binder-less filter media was at 150oC and 300oC, respectively.
Abstract: In the present work the internal sulfate attack on
pastes made from pure clinker phases was studied. Two binders were
produced: (a) a binder with 2% C3A and 18% C4AF content; (b) a
binder with 10% C3A and C4AF content each. Gypsum was used as
the sulfate bearing compound, while calcium carbonate added to
differentiate the binders produced. The phases formed were identified
by XRD analysis. The results showed that ettringite was the
deterioration phase detected in the case of the low C3A content
binder. Carbonation occurred in the specimen without calcium
carbonate addition, while portlandite was observed in the one
containing calcium carbonate. In the case of the high C3A content
binder, traces of thaumasite were detected when calcium carbonate
was not incorporated in the binder. A solid solution of thaumasite and
ettringite was found when calcium carbonate was added. The amount
of C3A had not fully reacted with sulfates, since its corresponding
peaks were detected.
Abstract: In this study, the theoretical relationship between pressure and density was investigated on cylindrical hollow fuel briquettes produced of a mixture of fibrous biomass material using a screw press without any chemical binder. The fuel briquettes were made of biomass and other waste material such as spent coffee beans, mielie husks, saw dust and coal fines under pressures of 0.878-2.2 Mega Pascals (MPa). The material was densified into briquettes of outer diameter of 100mm, inner diameter of 35mm and 50mm long. It was observed that manual screw compression action produces briquettes of relatively low density as compared to the ones made using hydraulic compression action. The pressure and density relationship was obtained in the form of power law and compare well with other cylindrical solid briquettes made using hydraulic compression action. The produced briquettes have a dry density of 989 kg/m3 and contain 26.30% fixed carbon, 39.34% volatile matter, 10.9% moisture and 10.46% ash as per dry proximate analysis. The bomb calorimeter tests have shown the briquettes yielding a gross calorific value of 18.9MJ/kg.
Abstract: Mechanical and water transport properties of high
performance concrete (HPC) containing natural zeolite as partial
replacement of Portland cement are studied. Experimental results
show that in the investigated mixes the use of natural zeolite leads to
an increase of porosity, decrease of compressive strength and
increase of moisture diffusivity and water vapor diffusion coefficient,
as compared with the reference HPC. However, for the replacement
level up to 20% of the mass of Portland cement the concretes still
maintain their high performance character and exhibit acceptable
water transport properties. Therefore, natural zeolite can be
considered an environmental friendly binder with a potential to
replace a part of Portland cement in concrete in building industry.
Abstract: In this paper, the effect of addition the dune sand powder (DSP) on development of compressive strength and hydration of cement pastes was investigated as a function of water/binder ratio, was varied, on the one hand, the percentage of DSP and on the other, the fineness of DSP. In order to understand better the pozzolanic effect of dune sand powder in cement pastes, we followed the mixtures hydration (50% Pure Lime + 50% DSP) by X-ray diffraction. These mixtures the pastes present a hydraulic setting which is due to the formation of a C-S-H phase (calcium silicate hydrate). The latter is semi-crystallized. This study is a simplified approach to that of the mixtures (80% ordinary Portland cement + 20% DSP), in which the main reaction is the fixing of the lime coming from the cement hydration in the presence of DSP, to form calcium silicate hydrate semi-crystallized of second generation. The results proved that up to (20% DSP) as Portland cement replacement could be used with a fineness of 4000 cm²/g without affecting adversely the compressive strength. After 28 days, the compressive strength at 5, 10 and 15% DSP is superior to Portland cement, with an optimum effect for a percentage of the order of 5% to 10% irrespective of the w/b ratio and fineness of DSP.
Abstract: Binder drainage test is widely used to set an upper
limit to the design binder content of porous asphalt. However, the
presence of high amount of fine particles in the drained binder may
affect the accuracy of the test result. This paper presents a study to
characterize the composition and particle size distribution of fine
particles accumulated in the drained binder. Fine aggregates and filler
in the drained binder were extracted using a suitable solvent. Then,
wet and dry sieve analysis was carried out to identify the actual
composition of the extracted fine aggregates and filler. From the
results, almost half of the drained binder consisted of fine aggregates
and this significantly affects the accuracy of the design binder content
of porous asphalt mix. This simple finding highlights the importance
of taking into account the presence of fine aggregates in the
calculation of drained binder.
Abstract: Utilization of waste material in asphalt pavement
would be beneficial in order to find an alternative solution to increase
service life of asphalt pavement and reduce environmental pollution
as well. One of these waste materials is Polyethylene Terephthalate
(PET) which is a type of polyester material and is produced in a large
extent. This research program is investigating the effects of adding
waste PET particles into the asphalt mixture with a maximum size of
2.36 mm. Different percentages of PET were added into the mixture
during dry process. Gap-graded mixture (SMA 14) and PG 80-100
asphalt binder have been used for this study. To evaluate PET
reinforced asphalt mixture different laboratory investigations have
been conducted on specimens. Marshall Stability test was carried
out. Besides, stiffness modulus test and indirect tensile fatigue test
were conducted on specimens at optimum asphalt content. It was
observed that in many cases PET reinforced SMA mixture had better
mechanical properties in comparison with control mixture.
Abstract: Pyrite (FeS2) is a promising candidate for cathode
materials in batteries because of it`s high theoretical capacity, low
cost and non-toxicity. In this study, nano size iron disulfide thin film
was prepared on graphite substrate through a new method as battery
cathode. In this way, acetylene black and poly vinylidene fluoride
were used as electron conductor and binder, respectively. Fabricated
thin films were analyzed by XRD and SEM. These results and
electrochemical data confirm improvement of battery discharge
capacity in comparison with commercial type of pyrite.
Abstract: In this study two series of self compacting concrete
mixtures were prepared with 100% coarse recycled concrete
aggregates and different percentages of 0%, 20%, 40%, 60%, 80%
and 100% fine recycled concrete aggregates. In series I and II the
water to binder ratios were 0.50 and 0.45, respectively. The cement
content was kept 350
3 m
kg for those mixtures that don't have any
Nano-Silica. To improve the compressive strength of samples, Nano-
Silica replaced with 10% of cement weight in concrete mixtures. By
doing the tests, the results showed that, adding Nano-silica to the
samples with less percentage of fine recycled concrete aggregates,
lead to more increase on the compressive strength.
Abstract: Limited infrastructure development on peats and
organic soils is a serious geotechnical issues common to many
countries of the world especially Malaysia which distributed 1.5 mill
ha of those problematic soil. These soils have high water content and
organic content which exhibit different mechanical properties and
may also change chemically and biologically with time. Constructing
structures on peaty ground involves the risk of ground failure and
extreme settlement. Nowdays, much efforts need to be done in
making peatlands usable for construction due to increased landuse.
Deep mixing method employing cement as binders, is generally used
as measure again peaty/ organic ground failure problem. Where the
technique is widely adopted because it can improved ground
considerably in a short period of time. An understanding of
geotechnical properties as shear strength, stiffness and compressibility
behavior of these soils was requires before continues construction on
it. Therefore, 1- 1.5 meter peat soil sample from states of Johor and
an organic soil from Melaka, Malaysia were investigated. Cement
were added to the soil in the pre-mixing stage with water cement ratio
at range 3.5,7,14,140 for peats and 5,10,30 for organic soils,
essentially to modify the original soil textures and properties. The
mixtures which in slurry form will pour to polyvinyl chloride (pvc)
tube and cured at room temperature 250C for 7,14 and 28 days.
Laboratory experiments were conducted including unconfined
compressive strength and bender element , to monitor the improved
strength and stiffness of the 'stabilised mixed soils'. In between,
scanning electron miscroscopic (SEM) were observations to
investigate changes in microstructures of stabilised soils and to
evaluated hardening effect of a peat and organic soils stabilised
cement. This preliminary effort indicated that pre-mixing peat and
organic soils contributes in gaining soil strength while help the
engineers to establish a new method for those problematic ground
improvement in further practical and long term applications.
Abstract: The composite materials were prepared by sawdust, cassava starch and natural rubber latex (NR). The mixtures of 15%w/v gelatinized cassava starch and 15%w/v PVOH were used as the binder of these composite materials. The concentrated rubber latex was added to the mixtures. They were mixed rigorously to the treated sawdust in the ratio of 70:30 until achive uniform dispersion. The batters were subjected to the hot compression moulding at the temperature of 160°C and 3,000 psi pressure for 5 min. The experimental results showed that the mechanical properties of composite materials, which contained the gelatinized cassava starch and PVOH in the ratio of 2:1, 20% NR latex by weight of the dry starch and treated sawdust with 5%NaOH or 1% BPO, were the best. It contributed the maximal compression strength (341.10 + 26.11 N), puncture resistance (8.79 + 0.98 N/mm2) and flexural strength (3.99 + 0.72N/mm2). It is also found that the physicochemical and mechanical properties of composites strongly depends on the interface quality of sawdust, cassava starch and NR latex.
Abstract: Inconel718 has been widely used as a super alloy in aerospace application due to the high strength at elevated temperatures, satisfactory oxidation resistance and heat corrosion resistance. In this study, the Inconel718 has been fabricated using high technology of Metal Injection Molding (MIM) process due to the cost effective technique for producing small, complex and precision parts in high volume compared with conventional method through machining. Through MIM, the binder system is one of the most important criteria in order to successfully fabricate the Inconel718. Even though, the binder system is a temporary, but failure in the selection and removal of the binder system will affect on the final properties of the sintered parts. Therefore, the binder system based on palm oil derivative which is palm stearin has been formulated and developed to replace the conventional binder system. The rheological studies of the mixture between the powder and binders system have been determined properly in order to be successful during injection into injection molding machine. After molding, the binder holds the particles in place. The binder system has to be removed completely through debinding step. During debinding step, solvent debinding and thermal pyrolysis has been used to remove completely of the binder system. The debound part is then sintered to give the required physical and mechanical properties. The results show that the properties of the final sintered parts fulfill the Standard Metal Powder Industries Federation (MPIF) 35 for MIM parts.
Abstract: This paper presents a research conducted to investigate the effect of mixing process on polypropylene (PP) modified bitumen mixed with well graded aggregate to form modified bituminous concrete mix. Two mode of mixing, namely dry and wet with different concentration of polymer polypropylene was used with 80/100 pen bitumen, to evaluate the bituminous concrete mix properties. Three percentages of polymer varying from 1-3% by the weight of bitumen was used in this study. Three mixes namely control mix, wet mix and dry mix were prepared. Optimum binder content was calculated considering Marshall Stability, flow, air voids and Marshall Quotient at different bitumen content varying from 4% - 6.5% for control, dry and wet mix. Engineering properties thus obtained at the calculated optimum bitumen content revealed that wet mixing process is advantageous in comparison to dry mixing as it increases the stiffness of the mixture with the increase in polymer content in bitumen. Stiffness value for wet mix increases with the increase in polymer content which is beneficial in terms of rutting. 1% PP dry mix also shows enhanced stiffness, with the air void content limited to 4%.The flow behaviour of dry mix doesn't indicate any major difference with the increase in polymer content revealing that polymer acting as an aggregate only without affecting the viscosity of the binder in the mix. Polypropylene (PP) when interacted with 80 pen base bitumen enhances its performance characteristics which were brought about by altered rheological properties of the modified bitumen. The decrease in flow with the increase in binder content reflects the increase in viscosity of binder which induces the plastic flow in the mix. Workability index indicates that wet mix were easy to compact up to desired void ratio in comparison to dry mix samples.
Abstract: High Strength Concrete (HSC) is defined as concrete
that meets special combination of performance and uniformity
requirements that cannot be achieved routinely using conventional
constituents and normal mixing, placing, and curing procedures. It is
a highly complex material, which makes modeling its behavior a very
difficult task. This paper aimed to show possible applicability of
Neural Networks (NN) to predict the slump in High Strength
Concrete (HSC). Neural Network models is constructed, trained and
tested using the available test data of 349 different concrete mix
designs of High Strength Concrete (HSC) gathered from a particular
Ready Mix Concrete (RMC) batching plant. The most versatile
Neural Network model is selected to predict the slump in concrete.
The data used in the Neural Network models are arranged in a format
of eight input parameters that cover the Cement, Fly Ash, Sand,
Coarse Aggregate (10 mm), Coarse Aggregate (20 mm), Water,
Super-Plasticizer and Water/Binder ratio. Furthermore, to test the
accuracy for predicting slump in concrete, the final selected model is
further used to test the data of 40 different concrete mix designs of
High Strength Concrete (HSC) taken from the other batching plant.
The results are compared on the basis of error function (or
performance function).
Abstract: This work presents a low-cost and eco-friendly
building material named Agrostone panel. Africa-s urban population
is growing at an annual rate of 2.8% and 62% of its population will
live in urban areas by 2050. As a consequence, many of the least
urbanized and least developed African countries- will face serious
challenges in providing affordable housing to the urban dwellers.
Since the cost of building materials accounts for the largest
proportion of the overall construction cost, innovating low-cost
building material is vital. Agrostone panel is used in housing projects
in Ethiopia. It uses raw materials of agricultural/industrial wastes
and/or natural minerals as a filler, magnesium-based chemicals as a
binder and fiberglass as reinforcement. Agrostone panel reduces the
cost of wall construction by 50% compared with the conventional
building materials. The pros and cons of Agrostone panel as well as
the use of other waste materials as a raw material to make the panel
more sustainable, low-cost and better properties are discussed.
Abstract: Natural pozzolan (NP) is one of the potential
prehistoric alternative binders in the construction industry. It has
been investigated as cement replacement in ordinary concrete by
several researchers for many purposes. Various supplementary
cementitious materials (SCMs) such as fly ash, limestone dust and
silica fume are widely used in the production of SCC; however,
limited studies to address the effect of NP on the properties of SCC
are documented. The current research is composed of different SCC
paste and concrete mixtures containing different replacement levels
of local NP as an alternative SCM. The effect of volume of paste
containing different amounts of local NP related to W/B ratio and
cement content on SCC fresh properties was assessed. The variations
in the fresh properties of SCC paste and concrete represented by
slump flow (flowability) and the flow rate were determined and
discussed. The results indicated that the flow properties of SCC paste
and concrete mixtures, at their optimized superplasticizer dosages,
were affected by the binder content of local NP and the total volume
fraction of SCC paste.