Abstract: The transesterification of dimethyl malonate (DMM)
with phenol has been studied in vapour phase over cordierite
honeycomb coated with solid acid catalysts such as ZrO2,
Mo(VI)/ZrO2 and SO42-/ZrO2. The catalytic materials were prepared
honeycomb coated, powder forms, and characterized for their total
surface acidity by NH3-TPD and crystalinity by powder XRD
methods. Phenyl methyl malonate (PMM) and diphenyl malonate
(DPM) were obtained as the reaction products. A good conversion of
DMM (up to 82%) of MPM with 95% selectivity was observed when
the reactions were carried out at a catalyst bed temperature of 200 °C
and flow-rate of 10 mL/h in presence of Mo(VI)/ZrO2 as catalyst.
However, over SO4^2-/ZrO2 catalyst, the yield of DPM was found to be
higher. The results have been interpreted based on the variation of
acidic properties and powder XRD phases of zirconia on
incorporation of Mo(VI) or SO42– ions. Transesterification reactions
were also carried out over powder forms of the catalytic materials
and the yield of the desired phenyl ester products were compared
with that of the HC coated catalytic materials. The solid acids were
found to be reusable when used for at least 5 reaction cycles.
Abstract: This research was made during the 2015 growing
periods in the trial filed of "Research Station for Department of Field
Crops, Agricultural Faculty, Selcuk University" according to
“Randomized Blocks Design” with 3 replications. Research material
was the following pea lines; PS16, PS18, PS21, PS23, PS24, PS25,
PS36, PS47, PS49, PS51, PS54, PS58, PS67, PS69, PS71, PS73,
PS83, PS84, PS87 and PSKY and three cultivars and other 2
commercial varieties named as Bolero, Rondo and Ultrello. Some
agronomical characteristics such as plant height (cm) number of pod
per plant number of seed per pod number of seed per plant 100 seed
weight (g) and seed yield (kg ha-1) were determined. The highest seed
yield was obtained 2727.0 kg ha-1 in the PS71 line and the lowest
value was obtained 1238.0 kg ha-1 in the commercial variety of
Bolero. Results of the research implicated that the new developed
lines were superior compared with the control (commercial) varieties
by means of most of the characteristics. Nevertheless, similar
researches should be continued in different locations and years.
Abstract: Strong anthropogenic impact has uncontrolled
consequences on the nature of the soil. Hence, up-to-date sustainable
methods of soil state improvement are essential. Investigators provide
the evidence that biochar can positively effects physical, chemical,
and biological soil properties and the abundance of mycorrhizal fungi
which are in the focus of this study. The main aim of the present
investigation is to demonstrate the effect of two types of plant growth
promoting bacteria (PGPB) inoculums along with the beech wood
biochar and mineral N additives on mycorrhizal colonization.
Experiment has been set up in laboratory conditions with containers
filled with arable soil from the protection zone of the main water
source “Brezova nad Svitavou”. Lactuca sativa (lettuce) has been
selected as a model plant. Based on the obtained data, it can be
concluded that mycorrhizal colonization increased as the result of
combined influence of biochar and PGPB inoculums amendment. In
addition, correlation analyses showed that the numbers of main
groups of cultivated bacteria were dependent on the degree of
mycorrhizal colonization.
Abstract: With the increasing dependence of countries on the
critical infrastructure, it increases their vulnerability. Big threat is
primarily in the human factor (personnel of the critical infrastructure)
and in terrorist attacks. It emphasizes the development of
methodology for searching of weak points and their subsequent
elimination. This article discusses methods for the analysis of safety
in the objects of critical infrastructure. It also contains proposal for
methodology for training employees of security services in the
objects of the critical infrastructure and developing scenarios of
attacks on selected objects of the critical infrastructure.
Abstract: The 1:1 cocrystal of 2-amino-4-chloro-6-
methylpyrimidine (2A4C6MP) with 4-methylbenzoic acid (4MBA)
(I) has been prepared by slow evaporation method in methanol,
which was crystallized in monoclinic C2/c space group, Z = 8, and a
= 28.431 (2) Å, b = 7.3098 (5) Å, c = 14.2622 (10) Å and β =
109.618 (3)°. The presence of unionized –COOH functional group in
cocrystal I was identified both by spectral methods (1H and 13C
NMR, FTIR) and X-ray diffraction structural analysis. The
2A4C6MP molecule interact with the carboxylic group of the
respective 4MBA molecule through N—H⋯O and O—H⋯N
hydrogen bonds, forming a cyclic hydrogen–bonded motif R2
2(8).
The crystal structure was stabilized by Npyrimidine—H⋯O=C and
C=O—H⋯Npyrimidine types hydrogen bonding interactions.
Theoretical investigations have been computed by HF and density
function (B3LYP) method with 6–311+G (d,p)basis set. The
vibrational frequencies together with 1H and 13C NMR chemical
shifts have been calculated on the fully optimized geometry of
cocrystal I. Theoretical calculations are in good agreement with the
experimental results. Solvent–free formation of this cocrystal I is
confirmed by powder X-ray diffraction analysis.
Abstract: Background: Breast milk may impact early brain
development, with potentially important biological, medical and
social implications. There is an important discussion on which is the
adequate breastfeeding extension to the development consolidation
and how the children breastfeeding affects their psychomotor
development, in the first year of life, and in following periods as
well. Some special fats (LC PUFA) contained in breast milk play a
key role in the brain’s maturation and cognitive development or
social skills. These capacities created during breastfeeding time
would be unfolded throughout all lifespan. Aim of the study: In our research, we have studied the effect of
breastfeeding in preschooler's psychomotor assessment.
Method: This study was conducted in a sample of 158 preschool
children in Vlorë, Albania. We have measured the psychometric
parameters of preschoolers with ASQ-3 (Age&Stage Questionnaires-
3). The studied sample was divided in three groups according to their
breastfeeding duration (3, 6 and 12 months). Results: Children breastfed for only 3 months have definitely
lower psychometric scores compared to the ones with 6 or more
months of breastfeeding (respectively 217 to 239 ASQ-3 scores). Six
and twelvemonth breastfed children have progressively more odds to
have high levels of psychomotor development comparing to those
with only 3 months of breastfeeding. The most affected psychometric
domains by shortness of breastfeeding are Communication and
Global motor. Conclusion: This leads to conclusion that to ensure high
psychomotor parameters during childhood is necessary breastfeeding
for at least 6 months.
Abstract: The Petri nets are the first standard for business
process modeling. Most probably, it is one of the core reasons why
all new standards created afterwards have to be so reformed as to
reach the stage of mapping the new standard onto Petri nets. The paper presents a business process repository based on a
universal database. The repository provides the possibility the data
about a given process to be stored in three different ways. Business
process repository is developed with regard to the reformation of a
given model to a Petri net in order to be easily simulated. Two different techniques for business process simulation based on
Petri nets - Yasper and Woflan are discussed. Their advantages and
drawbacks are outlined. The way of simulating business process
models, stored in the Business process repository is shown.
Abstract: Within this paper, latest results on processing of energetic nanomaterials by means of the Spray Flash Evaporation technique are presented. This technology constitutes a highly effective and continuous way to prepare fascinating materials on the nano- and micro-scale. Within the process, a solution is set under high pressure and sprayed into an evacuated atomization chamber. Subsequent ultrafast evaporation of the solvent leads to an aerosol stream, which is separated by cyclones or filters. No drying gas is required, so the present technique should not be confused with spray dying. Resulting nanothermites, insensitive explosives or propellants and compositions are foreseen to replace toxic (according to REACH) and very sensitive matter in military and civil applications. Diverse examples are given in detail: nano-RDX (n-Cyclotrimethylentrinitramin) and nano-aluminum based systems, mixtures (n-RDX/n-TNT - trinitrotoluene) or even cocrystalline matter like n-CL-20/HMX (Hexanitrohexaazaisowurtzitane/ Cyclotetra-methylentetranitramin). These nanomaterials show reduced sensitivity by trend without losing effectiveness and performance. An analytical study for material characterization was performed by using Atomic Force Microscopy, X-Ray Diffraction, and combined techniques as well as spectroscopic methods. As a matter of course, sensitivity tests regarding electrostatic discharge, impact, and friction are provided.
Abstract: Multiprocessor task scheduling problem for dependent
and independent tasks is computationally complex problem. Many
methods are proposed to achieve optimal running time. As the
multiprocessor task scheduling is NP hard in nature, therefore, many
heuristics are proposed which have improved the makespan of the
problem. But due to problem specific nature, the heuristic method
which provide best results for one problem, might not provide good
results for another problem. So, Simulated Annealing which is meta
heuristic approach is considered. It can be applied on all types of
problems. However, due to many runs, meta heuristic approach takes
large computation time. Hence, the hybrid approach is proposed by
combining the Duplication Scheduling Heuristic and Simulated
Annealing (SA) and the makespan results of Simple Simulated
Annealing and Hybrid approach are analyzed.
Abstract: Machine visualization is an area of interest with fast
and progressive development. We present a method of machine
visualization which will be applicable in real industrial conditions
according to current needs and demands. Real factory data were
obtained in a newly built research plant. Methods described in this
paper were validated on a case study. Input data were processed and
the virtual environment was created. The environment contains
information about dimensions, structure, disposition, and function.
Hardware was enhanced by modular machines, prototypes, and
accessories. We added functionalities and machines into the virtual
environment. The user is able to interact with objects such as testing
and cutting machines, he/she can operate and move them. Proposed
design consists of an environment with two degrees of freedom of
movement. Users are in touch with items in the virtual world which
are embedded into the real surroundings. This paper describes development of the virtual environment. We
compared and tested various options of factory layout virtualization
and visualization. We analyzed possibilities of using a 3D scanner in
the layout obtaining process and we also analyzed various virtual
reality hardware visualization methods such as: Stereoscopic (CAVE)
projection, Head Mounted Display (HMD) and augmented reality
(AR) projection provided by see-through glasses.
Abstract: Anaerobic digestion is a well-known technique for
sustainable energy recovery from sewage sludge. However, sewage
sludge digestion is restricted due to certain factors. Pre-treatment
methods have been established in various publications as a promising
technique to improve the digestibility of the sewage sludge and to
enhance the biogas generated which can be used for energy recovery.
In this study, continuous flow microwave (MW) pre-treatment with
different intensities were compared by using 5 L semi-continuous
digesters at a hydraulic retention time of 27 days. We focused on the
effects of MW at different intensities on the sludge solubilization,
sludge digestibility, and biogas production of the untreated and MW
pre-treated sludge. The MW pre-treatment demonstrated an increase
in the ratio of soluble chemical oxygen demand to total chemical
oxygen demand (sCOD/tCOD) and volatile fatty acid (VFA)
concentration. Besides that, the total volatile solid (TVS) removal
efficiency and tCOD removal efficiency also increased during the
digestion of the MW pre-treated sewage sludge compared to the
untreated sewage sludge. Furthermore, the biogas yield also
subsequently increases due to the pre-treatment effect. A higher MW
power level and irradiation time generally enhanced the biogas
generation which has potential for sustainable energy recovery from
sewage treatment plant. However, the net energy balance tabulation
shows that the MW pre-treatment leads to negative net energy production.
Abstract: Anogeissus leiocarpus (Combretaceae) is well known
for its medicinal uses in African traditional medicine, for treating
many human diseases mainly skin diseases and infections. Mycetoma
disease is a fungal and/ or bacterial skininfection, mainly cause by
Madurella mycetomatis fungus. This study was carried out in vitro to
investigate the antifungal activity of Anogeissus leiocarpus leaf
extracts against the isolated pathogenic Madurella mycetomatis, by
using the NCCLS modified method compared to Ketoconazole
standard drug, and MTT assay. The bioactive fraction was subjected
to chemical analysis implementing different chromatographic
analytical methods (TLC, HPLC, and LC-MS/MS). The results
showed significance antifungal activity of A. leiocarpus leaf extracts
against the isolated pathogenic M. mycetomatis, compared to negative
and positive controls. The chloroform fraction showed the highest
antifungal activity. The chromatographic analysis of the chloroform
fraction with the highest activity showed the presence of important
bioactive compounds such as ellagic and flavellagic acids derivatives,
flavonoids and stilbenoid, which are well known for their antifungal
activity.
Abstract: The aim of the study is to describe and analyze design
of mobile teaching for students collaborative learning in distance
higher education with a focus on mobile technologies as online
webinars (web-based seminars or conferencing) by using laptops,
smart phones, or tablets. These multimedia tools can provide face-toface
interactions, recorded flipped classroom videos and parallel chat
communications. The data collection consists of interviews with 22
students and observations of online face-to-face webinars, as well
two surveys. Theoretically, the study joins the research tradition of
Computer Supported Collaborative learning, CSCL, as well as
Computer Self-Efficacy, CSE concerned with individuals’ media and
information literacy. Important conclusions from the study
demonstrated mobile interactions increased student centered
learning. As the students were appreciating the working methods,
they became more engaged and motivated. The mobile technology
using among student also contributes to increased flexibility between
space and place, as well as media and information literacy.
Abstract: Diets high in processed foods have been found to lack
essential micro-nutrients for optimum human development and
overall health. Some micro-nutrients such as copper (Cu) have been
found to enhance the inflammatory response through its oxidative
functions, thereby having a role in cardiovascular disease, metabolic
syndrome, diabetes and related complications. This research study
was designed to determine if food crops could be bio-fortified with
micro-nutrients by growing sprouts on mineral fortified fiber mats. In
the feasibility study described in this contribution, recycled cellulose
fibers and clay, saturated with either micro-nutrient copper ions or
copper nanoparticles, were converted to a novel mineral-cellulose
fiber carrier of essential micro-nutrient and of antimicrobial
properties. Seeds of Medicago sativa (alfalfa), purchased from a
commercial, organic supplier were germinated on engineered
cellulose fiber mats. After the appearance of the first leaves, the
sprouts were dehydrated and analyzed for Cu content. Nutrient
analysis showed ~2 increase in Cu of the sprouts grown on the fiber
mats with copper particles, and ~4 increase on mats with ionic copper
as compared to the control samples. This study illustrates the
potential for the use of engineered mats as a viable way to increase
the micro-nutrient composition of locally-grown food crops and the
need for additional research to determine the uptake, nutritional
implications and risks of micro-nutrient bio-fortification.
Abstract: The objective of this work is to carryout critical
comparison of different actuation mechanisms like electrostatic,
thermal, piezoelectric, and magnetic with reference to a micro
cantilever. The relevant parameters like force generated,
displacement are compared in actuation methods. With these results,
helps in choosing the best actuation method for a particular
application. In this study, Comsol/Multiphysics software is used.
Modeling and simulation is done by considering the micro cantilever
of same dimensions as an actuator using all the above mentioned
actuation techniques. In addition to their small size, micro actuators
consume very little power and are capable of accurate results. In this
work, a comparison of actuation mechanisms is done to decide the
efficient system in micro domain.
Abstract: The paper discusses the problem of load transport
using farm tractors and road tractor units. This type of carriage of
goods is often done with farm vehicles. The tests were performed
with the PEMS equipment (Portable Emission Measurement System)
under actual traffic conditions. The vehicles carried a load of 20000
kg. This research method is one of the most desired because it
provides reliable information on the actual vehicle emissions and fuel
consumption (carbon balance method). For the tests, a route was
selected that simulated a trip from a small town to a food-processing
facility located in a city. The analysis of the obtained results gave a
clear answer as to what vehicles need to be used for carriage of this
type of cargo in terms of exhaust emissions and fuel consumption.
Abstract: Cooperative groups through much research have been
recognized to churn remarkable achievements instead of solitary or
individualistic efforts. Based on Johnson and Johnson’s model of
cooperative learning, the five key components of cooperation are
positive interdependence, face-to-face promotive interaction,
individual accountability, social skills, and group processing. In
2011, the Malaysian Ministry of Higher Education (MOHE)
introduced the Holistic Student Development policy with the aim to
develop morally sound individuals equipped with lifelong learning
skills. The Community Service project was included in the
improvement initiative. The purpose of this study is to assess the
relationship of team-based learning in facilitating particularly
students’ positive interdependence and face-to-face promotive
interaction. The research methods involve in-depth interviews with
the team leaders and selected team members, and a content analysis
of the undergraduate students’ reflective journals. A significant
positive relationship was found between students’ progressive
outlook towards teamwork and the highlighted two components. The
key findings show that students have gained in their individual
learning and work results through teamwork and interaction with
other students. The inclusion of Community Service as a MOHE
subject resonates with cooperative learning methods that enhances
supportive relationships and develops students’ social skills together
with their professional skills.
Abstract: This paper discusses the thematic structure of Yoruba
popular music of Southwest Nigeria. It examines the use of themes
and variations in early and contemporary Juju music. The work is an
outcome of a research developed by the author in his doctoral studies
at the University of Lagos, Nigeria, with the aim of analyzing the
thematic and motivic developments in Yoruba popular genres.
Observations, interviews, live recordings and CDs were used as
methods for eliciting information. Field recordings and CDs of
selected musical samples were also transcribed and notated. The
research established the prevalent use of string of themes by Juju
musicians as a compositional technique in moving from one musical
section to another, as they communicate the verbal messages in their
song. These themes consist of the popular ‘call and response’ form
found in most African music, analogous to the western ‘subject and
answer’ style of the fugue or sonata form, although without the tonic–
dominant relations. Due to the short and repetitive form of African
melodies and rhythms, a theme is restated as a variation, where its
rhythmic and melodic motifs are stylistically developed and repeated,
but still retaining its recognizable core musical structure. The
findings of this study showed that Juju musicians generally often
employ a thematic plan where new themes are used to arrange the
songs into sections, and each theme is developed into variations in
order to further expand the music, eliminate monotony, and create
musical aesthetics, serving as hallmark of its musical identity. The
study established the musical and extra-musical attributes of the
genre, while recommending further research towards analyzing the
various compositional techniques employed in African popular
genres.
Abstract: The increase of technogenic and natural accidents,
accompanied by air pollution, for example, by combustion products,
leads to the necessity of respiratory protection. This work is devoted to the development of a calorimetric method
and a device which allows investigating quickly the kinetics of
carbon dioxide sorption by chemisorbents on the base of potassium
superoxide in order to assess the protective properties of respiratory
protective closed circuit apparatus. The features of the traditional approach for determining the
sorption properties in a thin layer of chemisorbent are described, as
well as methods and devices, which can be used for the sorption
kinetics study. The authors developed an approach (as opposed to the traditional
approach) based on the power measurement of internal heat sources
in the chemisorbent layer. The emergence of the heat sources is a
result of exothermic reaction of carbon dioxide sorption. This
approach eliminates the necessity of chemical analysis of samples
and can significantly reduce the time and material expenses during
chemisorbents testing. Error of determining the volume fraction of adsorbed carbon
dioxide by the developed method does not exceed 12%. Taking into
account the efficiency of the method, we consider that it is a good
alternative to traditional methods of chemical analysis under the
assessment of the protection sorbents quality.
Abstract: Intermediate cities which also called medium size
cities have an important role in the process of globalization. It is
argued that, in some cases this type of cities may be depopulated or in
otherwise may be transformed as the periphery of metropolitans, so
that the personal identity of the city and its local cultural heritage
could suffer from its neighbor metropolitan. Over the last decades,
the role of tourism in the development process and the cultural
heritage has increased. The impact of tourism on socioeconomic
growth makes motivation for the study of tourism development in
regional and urban planning process. There are evidences that
tourism has a positive impact in local development and makes
economic motivations for cultural heritage protection. In this study,
by considering the role of tourism in local development, especially by
its economic and socio-cultural impacts, it is tried to introduce a
strategy for tourism development through a method of urban planning
for intermediate cities called as Base plan. Damavand is an
intermediate city located in Tehran province, Iran with a high
potential in tourism by its local specific characteristic like social
structure, antiquities and natural attractions. It’s selected as a suitable
case study for intended strategy which is a combination of urban
planning and tourism development methods. Focusing on recognition
of the historical and cultural heritage of Damavand, in this paper
through “base plan methodology” a strategy of urban planning
toward tourism development is prepared in order to make tourism
development as a support for cultural heritage of this city.