Abstract: Ionic liquids consisting of a phosphonium cationic
moiety and a saccharinate anion are synthesized and compared with
their precursors, phosphonium chlorides, in reference to their
extraction efficiency towards L-lactic acid. On the base of
measurements of the acid and the water partitioning in the
equilibrium biphasic systems, the molar ratios between acid, water
and ionic liquid are estimated which allows to deduce the lactic acid
extractive pathway. The effect of a salting-out addition that
strengthens hydrophobicity in both phases is studied in view to reveal
the best biphasic system with respect to IL low toxicity and high
extraction efficiency.
Abstract: Catalytic combustion of methane is imperative due to
stability of methane at low temperature. Methane (CH4), therefore,
remains unconverted in vehicle exhausts thereby causing greenhouse
gas GHG emission problem. In this study, heterogeneous catalysts of
palladium with bio-char (2 wt% Pd/Bc) and Al2O3 (2wt% Pd/ Al2O3)
supports were prepared by incipient wetness impregnation and then
subsequently tested for catalytic combustion of CH4. Support-porous
heterogeneous catalytic combustion (HCC) material were selected
based on factors such as surface area, porosity, thermal stability,
thermal conductivity, reactivity with reactants or products, chemical
stability, catalytic activity, and catalyst life. Sustainable and
renewable support-material of bio-mass char derived from palm shell
waste material was compared with those from the conventional
support-porous materials. Kinetic rate of reaction was determined for
combustion of methane on Palladium (Pd) based catalyst with Al2O3
support and bio-char (Bc). Material characterization was done using
TGA, SEM, and BET surface area. The performance test was
accomplished using tubular quartz reactor with gas mixture ratio of
3% methane and 97% air. The methane porous-HCC conversion was
carried out using online gas analyzer connected to the reactor that
performed porous-HCC. BET surface area for prepared 2 wt% Pd/Bc
is smaller than prepared 2wt% Pd/ Al2O3 due to its low porosity
between particles. The order of catalyst activity based on kinetic rate
on reaction of catalysts in low temperature was 2wt%
Pd/Bc>calcined 2wt% Pd/ Al2O3> 2wt% Pd/ Al2O3>calcined 2wt%
Pd/Bc. Hence agro waste material can successfully be utilized as an
inexpensive catalyst support material for enhanced CH4 catalytic
combustion.
Abstract: This article discusses ways to implement a
differentiated approach to developing academic motivation for
mathematical studies which relies on defining the primary structural
characteristics of motivation. The following characteristics are
considered: features of realization of cognitive activity, meaningmaking
characteristics, level of generalization and consistency of
knowledge acquired by personal experience. The assessment of the
present level of individual student understanding of each component
of academic motivation is the basis for defining the relevant
educational strategy for its further development.
Abstract: Adolescents with Autism Spectrum Disorders (ASD)
often experience social-communication difficulties that negatively
impact their social interactions with typical peers. However, unlike
other age and disability groups, there is little intervention research to
inform best practice for these students. One evidence-based strategy
for younger students with ASD is peer-mediated intervention (PMI).
PMI may be particularly promising for use with adolescents, as peers
are readily available and are natural experts for encouraging authentic
high school conversations. This paper provides a review of previous
research that evaluated the use of PMI to improve the socialcommunication
skills of students with ASD. Specific intervention
features associated with positive student outcomes are identified and
recommendations for future research are provided. Adolescents with
ASD are targeted due the critical importance of social conversation at
the high school level.
Abstract: Modern Portfolio Theory (MPT) according to
Markowitz states that investors form mean-variance efficient
portfolios which maximizes their utility. Markowitz proposed the
standard deviation as a simple measure for portfolio risk and the
lower semi-variance as the only risk measure of interest to rational
investors. This paper uses a third volatility estimator based on
intraday data and compares three efficient frontiers on the Croatian
Stock Market. The results show that range-based volatility estimator
outperforms both mean-variance and lower semi-variance model.
Abstract: In this work, we attempt to analyze the contribution of
innovative activities to firm performance and growth. We examine
economic data from some of the economies that were heavily
affected by current economic crisis: the countries of southern Europe
(Portugal, Italy, Greece and Spain) and Ireland. Following literature,
an appropriate econometric model is developed and several indicators
are tested in order to disclose possible relation with innovative
activity. Findings confirm the crucial effect of innovative process in
economic activity, in firm and country level.
Abstract: To determine the potential of a low cost Irish
engineered timber product to replace high cost solid timber for use in
bending active structures such as gridshells a single Irish engineered
timber product in the form of orientated strand board (OSB) was
selected. A comparative study of OSB and solid timber was carried
out to determine the optimum properties that make a material suitable
for use in gridshells. Three parameters were identified to be relevant
in the selection of a material for gridshells. These three parameters
are the strength to stiffness ratio, the flexural stiffness of
commercially available sections, and the variability of material and
section properties. It is shown that when comparing OSB against
solid timber, OSB is a more suitable material for use in gridshells that
are at the smaller end of the scale and that have tight radii of
curvature. Typically, for solid timber materials, stiffness is used as an
indicator for strength and engineered timber is no different. Thus, low
flexural stiffness would mean low flexural strength. However, when
it comes to bending active gridshells, OSB offers a significant
advantage. By the addition of multiple layers, an increased section
size is created, thus endowing the structure with higher stiffness and
higher strength from initial low stiffness and low strength materials
while still maintaining tight radii of curvature. This allows OSB to
compete with solid timber on large scale gridshells. Additionally, a
preliminary sustainability study using a set of sustainability indicators
was carried out to determine the relative sustainability of building a
large-scale gridshell in Ireland with a primary focus on economic
viability but a mention is also given to social and environmental
aspects. For this, the Savill garden gridshell in the UK was used as
the functional unit with the sustainability of the structural roof
skeleton constructed from UK larch solid timber being compared
with the same structure using Irish OSB. Albeit that the advantages of
using commercially available OSB in a bending active gridshell are
marginal and limited to specific gridshell applications, further study
into an optimised engineered timber product is merited.
Abstract: This paper proposes five level diode clamped Z source
Inverter. The existing PWM techniques used for ZSI are restricted for
two level. The two level Z Source Inverter have high harmonic
distortions which effects the performance of the grid connected PV
system. To improve the performance of the system the number of
voltage levels in the output waveform need to be increased. This
paper presents comparative analysis of a five level diode clamped Z
source Inverter with different carrier based Modified Pulse Width
Modulation techniques. The parameters considered for comparison
are output voltage, voltage gain, voltage stress across switch and total
harmonic distortion when powered by same DC supply. Analytical
results are verified using MATLAB.
Abstract: Array-based gene expression analysis is a powerful
tool to profile expression of genes and to generate information on
therapeutic effects of new anti-cancer compounds. Anti-apoptotic
effect of thymoquinone was studied in MCF7 breast cancer cell line
using gene expression profiling with cDNA microarray. The purity
and yield of RNA samples were determined using RNeasyPlus Mini
kit. The Agilent RNA 6000 NanoLabChip kit evaluated the quantity
of the RNA samples. AffinityScript RT oligo-dT promoter primer
was used to generate cDNA strands. T7 RNA polymerase was used to
convert cDNA to cRNA. The cRNA samples and human universal
reference RNA were labelled with Cy-3-CTP and Cy-5-CTP,
respectively. Feature Extraction and GeneSpring softwares analysed
the data. The single experiment analysis revealed involvement of 64
pathways with up-regulated genes and 78 pathways with downregulated
genes. The MAPK and p38-MAPK pathways were
inhibited due to the up-regulation of PTPRR gene. The inhibition of
p38-MAPK suggested up-regulation of TGF-ß pathway. Inhibition of
p38-MAPK caused up-regulation of TP53 and down-regulation of
Bcl2 genes indicating involvement of intrinsic apoptotic pathway.
Down-regulation of CARD16 gene as an adaptor molecule regulated
CASP1 and suggested necrosis-like programmed cell death and
involvement of caspase in apoptosis. Furthermore, down-regulation
of GPCR, EGF-EGFR signalling pathways suggested reduction of
ER. Involvement of AhR pathway which control cytochrome P450
and glucuronidation pathways showed metabolism of Thymoquinone.
The findings showed differential expression of several genes in
apoptosis pathways with thymoquinone treatment in estrogen
receptor-positive breast cancer cells.
Abstract: The check-in area of airport terminal is one of the
busiest sections at airports at certain periods. The passengers are
subjected to queues and delays during the check-in process. These
delays and queues are due to constraints in the capacity of service
facilities. In this project, the airport terminal is decomposed into
several check-in areas. The airport check-in scheduling problem
requires both a deterministic (integer programming) and stochastic
(simulation) approach. Integer programming formulations are
provided to minimize the total number of counters in each check-in
area under the realistic constraint that counters for one and the same
flight should be adjacent and the desired number of counters
remaining in each area should be fixed during check-in operations.
By using simulation, the airport system can be modeled to study the
effects of various parameters such as number of passengers on a
flight and check-in counter opening and closing time.
Abstract: We assessed the ecology of the organic and mineral soil
layers of laurel-leaved (BB-1) and Cryptomeria japonica (BB-2 and Pw)
forests in the Kasugayama Hill Primeval Forest (Nara, Japan). The soil
respiration rate was higher in the deeper horizons (F and H) of organic
layers than in those of mineral soil layers, suggesting organic layers
may be where active microbial metabolism occurs. Respiration rates in
the soil of BB-1, BB-2 and Pw forests were closely similar at 5 and 10°C.
However, the soil respiration rate increased in proportion to
temperatures of 15°C or above. We therefore consider the activity of
soil microorganisms to markedly decrease at temperatures below 10°C.
At a temperature of 15°C or above, the soil respiration rate in the BB-1
organic layers was higher than in those of the BB-2 and Pw organic
layers, due to differences in forest vegetation that appeared to
influence several salient soil properties, particularly pH and the carbon
(C) and nitrogen (N) content of the F and H horizons.
Abstract: Nitrogen fertilizer is the most used and often the most
mismanaged nutrient input. Nitrogen management has tremendous
implications on crop productivity, quality and environmental
stewardship. Sufficient nitrogen is needed to optimum yield and
quality. Soil and in-season plant tissue testing for nitrogen status are
a time consuming and expensive process. Real time sensing of plant
nitrogen status can be a useful tool in managing nitrogen inputs. The
objectives of this project were to assess the reliability of remotely
sensed non-destructive plant nitrogen measurements compared to wet
chemistry data from sampled plant tissue, develop in-season nitrogen
recommendations based on remotely sensed data for improved
nitrogen use efficiency and assess the potential for determining yield
and quality from remotely sensed data. Very good correlations were
observed between early-season remotely sensed crop nitrogen status
and plant nitrogen concentrations and subsequent in-season fertilizer
recommendations. The transmittance/absorbance type meters gave
the most accurate readings. Early in-season fertilizer recommendation
would be to apply 40 kg nitrogen per hectare plus 15 kg nitrogen per
hectare for each unit difference measured with the SPAD meter
between the crop and reference area or 25 kg plus 13 kg per hectare
for each unit difference measured with the CCM 200. Once the crop
was sufficiently fertilized meter readings became inconclusive and
were of no benefit for determining nitrogen status, silage yield and
quality and grain yield and protein.
Abstract: The Al-MoO3-P-CdTe-Al MOS sandwich structures
were fabricated by vacuum deposition method on cleaned glass
substrates. Capacitance versus voltage measurements were performed
at different frequencies and sweep rates of applied voltages for oxide
and semiconductor films of different thicknesses. In the negative
voltage region of the C-V curve a high differential capacitance of the
semiconductor was observed and at high frequencies (
Abstract: In its efforts to utilize the information and
communication technology to enhance the quality of public service
delivery, national and local governments around the world are
competing to introduce more ICT applications as tools to automate
processes related to law enforcement or policy execution, increase
citizen orientation, trust, and satisfaction, and create one-stop-shops
for public services. In its implementation, e-Government ICTs need
to maintain transparency, participation, and collaboration. Due to this
diverse of mixed goals and requirements, e-Government systems
need to be designed based on special design considerations in order
to eliminate the risks of failure to compliance to government
regulations, citizen dissatisfaction, or market repulsion.
In this article we suggest a framework with guidelines for
designing government information systems that takes into
consideration the special requirements of the public sector. Then we
introduce two case studies and show how applying those guidelines
would result in a more solid system design.
Abstract: Chemical vapor deposition (CVD) diamond coated
cutting tool has excellent cutting performance, it is the most ideal tool
for the processing of nonferrous metals and alloys, composites,
nonmetallic materials and other difficult-to-machine materials
efficiently and accurately. Depositing CVD diamond coating on the
cemented carbide with high cobalt content can improve its toughness
and strength, therefore, it is very important to research on the
preparation technology and cutting properties of CVD diamond coated
cemented carbide cutting tool with high cobalt content. The
preparation technology of boron-doped diamond (BDD) coating has
been studied and the coated drills were prepared. BDD coating were
deposited on the drills by using the optimized parameters and the SEM
results show that there are no cracks or collapses in the coating.
Cutting tests with the prepared drills against the silumin and aluminum
base printed circuit board (PCB) have been studied. The results show
that the wear amount of the coated drill is small and the machined
surface has a better precision. The coating does not come off during
the test, which shows good adhesion and cutting performance of the
drill.
Abstract: Solid waste management in steel industry is broadly
classified in “4 Rs” i.e. reduce, reuse, recycle and restore the
materials. Reuse and recycling the entire solid waste generated in the
process of steel making is a viable solution in targeting a clean, green
and zero waste technology leading to sustainable development of the
steel industry. Solid waste management has gained importance in
steel industry in view of its uncertainty, volatility and speculation due
to world competitive standards, rising input costs, scarcity of raw
materials and solid waste generated like in other sectors. The
challenges that the steel Industry faces today are the requirement of a
sustainable development by meeting the needs of our present
generation without compromising the ability of future generations.
Technologies are developed not only for gainful utilization of solid
wastes in manufacture of conventional products but also for
conversion of same in to completely new products.
Abstract: The main aim of the presented experiments is to
improve behaviour of sandwich structures under dynamic loading,
such as crash or explosion. This paper describes experimental
investigation on the response of new advanced materials to low and
high velocity load. Blast wave energy absorbers were designed using
two types of porous lightweight raw particle materials based on
expanded glass and ceramics with dimensions of 0.5-1 mm,
combined with polymeric binder. The effect of binder amount on the
static and dynamic properties of designed materials was observed.
Prism shaped specimens were prepared and loaded to obtain physicomechanical
parameters – bulk density, compressive and flexural
strength under quasistatic load, the dynamic response was determined
using Split Hopkinson Pressure bar apparatus. Numerical
investigation of the material behaviour in sandwich structure was
performed using implicit/explicit solver LS-Dyna. As the last step,
the developed material was used as the interlayer of blast resistant
litter bin, and it´s functionality was verified by real field blast tests.
Abstract: The purpose of the present work was to develop an
innovative food product with nutritional properties as well as
appealing organoleptic qualities. The product, a jam, was prepared
with the beans’ cooking water combined with fresh apple or carrot,
without the addition of any conservatives. Three different jams were
produced: bean and carrot, bean and apple and bean, apple and
cinnamon. The developed products underwent a sensorial analysis
that revealed that the bean, apple and cinnamon jam was globally
better accepted. However, with this study, the consumers determined
that the bean and carrot jam had the most attractive color and the
bean and apple jam the better consistency. Additionally, it was
possible to analyze the jams for their chemical components, namely
fat, fiber, protein, sugars and antioxidant activity. The obtained
results showed that the bean and carrot jam had the highest lipid
content, while the bean, apple and cinnamon jam had the highest
fiber content, when compared to the other two jams. Regarding the
sugar content, both jams with apple revealed similar sugar values,
which were higher than the sugar content of the bean and carrot jam.
The antioxidant activity was on average 10 mg TE/g.
Abstract: In this paper we present the efficient parallel
implementation of elastoplastic problems based on the TFETI (Total
Finite Element Tearing and Interconnecting) domain decomposition
method. This approach allow us to use parallel solution and compute
this nonlinear problem on the supercomputers and decrease the
solution time and compute problems with millions of DOFs. In
our approach we consider an associated elastoplastic model with
the von Mises plastic criterion and the combination of linear
isotropic-kinematic hardening law. This model is discretized by
the implicit Euler method in time and by the finite element
method in space. We consider the system of nonlinear equations
with a strongly semismooth and strongly monotone operator. The
semismooth Newton method is applied to solve this nonlinear
system. Corresponding linearized problems arising in the Newton
iterations are solved in parallel by the above mentioned TFETI. The
implementation of this problem is realized in our in-house MatSol
packages developed in MatLab.
Abstract: In this work, we begin with the presentation of the
Tθ family of usual similarity measures concerning multidimensional
binary data. Subsequently, some properties of these measures are
proposed. Finally the impact of the use of different inter-elements
measures on the results of the Agglomerative Hierarchical Clustering
Methods is studied.