Abstract: The freezing point of milk is in important indicator of
the milk quality. The freezing point of milk is determined primarily
to prove milk adulteration with water and to determine the amount of
water in it. Chemical composition and properties of milk, thermal
treatment and presence of any substance can influence freezing point
of product. There are different substances, which can be added to
milk with main purpose to prolong shelf-life of raw milk. There are
detergent, preservatives, formaldehyde, hydrogen peroxide,
antibiotics, sodium carbonate, and hydrogen peroxide. Therefore the
aim of the present study was to determine freezing point of milk,
skimmed milk, pasteurized milk and milk with different substances
(formaldehyde, antibiotics, sodium carbonate, hydrogen peroxide,
disinfectant, and detergent) in different concentrations. The thermal
treatment and different undesirable substances presence in milk have
significant influence on freezing point of it.
Abstract: The porous silicon (PS), formed from the anodization
of a p+ type substrate silicon, consists of a network organized in a
pseudo-column as structure of multiple side ramifications. Structural
micro-topology can be interpreted as the fraction of the interconnected
solid phase contributing to thermal transport. The
reduction of dimensions of silicon of each nanocristallite during the
oxidation induced a reduction in thermal conductivity. Integration of
thermal sensors in the Microsystems silicon requires an effective
insulation of the sensor element. Indeed, the low thermal conductivity
of PS consists in a very promising way in the fabrication of integrated
thermal Microsystems.In this work we are interesting in the
measurements of thermal conductivity (on the surface and in depth)
of PS by the micro-Raman spectroscopy. The thermal conductivity is
studied according to the parameters of anodization (initial doping and
current density. We also, determine porosity of samples by
spectroellipsometry.
Abstract: Preparation of hydrogel based on carrageenan
extracted from Kappaphycus alvarezii was conducted with film
immersion in glutaraldehyde solution (GA 4%w/w) for 2min and
then followed by thermal curing at 110°C for 25min. The method of
carrageenan recovery strongly determines the properties of
crosslinked carrageenan. Hydrogel obtained from alkali treated
carrageenan showed higher swelling ability compared to hydrogel
from nonalkali treated carrageenan. Hydrogel from alkali treated
showed the ability of sensitive to pH media.
Abstract: The aim of this research was to calculate the
mechanical properties of Pd3Rh and PdRh3 ordered alloys. The
molecular dynamics (MD) simulation technique was used to obtain
temperature dependence of the energy, the Yong modulus, the shear
modulus, the bulk modulus, Poisson-s ratio and the elastic stiffness
constants at the isobaric-isothermal (NPT) ensemble in the range of
100-325 K. The interatomic potential energy and force on atoms were
calculated by Quantum Sutton-Chen (Q-SC) many body potential.
Our MD simulation results show the effect of temperature on the
cohesive energy and mechanical properties of Pd3Rh as well as
PdRh3 alloys. Our computed results show good agreement with the
experimental results where they have been available.
Abstract: An explicit axisymmetrical FE methodology is
developed here to study the particle temperature arising in WC-Co
particle on an AISI 1045 steel substrate. Parameters of constitutive
Johnson-cook model were used for simulation. The results show that
particle velocity and kinetic energy have important role in
temperature arising of particles.
Abstract: Enzymatic hydrolysis is one of the major steps involved in the conversion from sugarcane bagasse to yield ethanol. This process offers potential for yields and selectivity higher, lower energy costs and milder operating conditions than chemical processes. However, the presence of some factors such as lignin content, crystallinity degree of the cellulose, and particle sizes, limits the digestibility of the cellulose present in the lignocellulosic biomasses. Pretreatment aims to improve the access of the enzyme to the substrate. In this study sugarcane bagasse was submitted chemical pretreatment that consisted of two consecutive steps, the first with dilute sulfuric acid (1 % (v/v) H2SO4), and the second with alkaline solutions with different concentrations of NaOH (1, 2, 3 and 4 % (w/v)). Thermal Analysis (TG/ DTG and DTA) was used to evaluate hemicellulose, cellulose and lignin contents in the samples. Scanning Electron Microscopy (SEM) was used to evaluate the morphological structures of the in natura and chemically treated samples. Results showed that pretreatments were effective in chemical degradation of lignocellulosic materials of the samples, and also was possible to observe the morphological changes occurring in the biomasses after pretreatments.
Abstract: A vertical SOI-based MOSFET with trench body
structure operated as 1T DRAM cell at various temperatures has been
studied and investigated. Different operation temperatures are
assigned for the device for its performance comparison, thus the
thermal stability is carefully evaluated for the future memory device
applications. Based on the simulation, the vertical SOI-based
MOSFET with trench body structure demonstrates the electrical
characteristics properly and possess conspicuous kink effect at
various operation temperatures. Transient characteristics were also
performed to prove that its programming window values and
retention time behaviors are acceptable when the new 1T DRAM cell
is operated at high operation temperature.
Abstract: The objective of this work was to examine the
changes in the microstructure and macro physical properties caused
by the carbonation of normalised CEM II mortar. Samples were
prepared and subjected to accelerated carbonation at 20°C, 65%
relative humidity and 20% CO2 concentration. On the microstructure
scale, the evolutions of the cumulative pore volume, pore size
distribution, and specific surface area during carbonation were
calculated from the adsorption desorption isotherms of nitrogen. We
also examined the evolution of macro physical properties such as the
porosity accessible to water, the gas permeability, and thermal
conductivity. The conflict between the results of nitrogen porosity
and water porosity indicated that the porous domains explored using
these two techniques are different and help to complementarily
evaluate the effects of carbonation. This is a multi-scale study where
results on microstructural changes can help to explain the evolution
of macro physical properties.
Abstract: In all industries which are related to heat, suitable
thermal ranges are defined for each device to operate well.
Consideration of these limits requires a thermal control unit beside
the main system. The Satellite Thermal Control Unit exploits from
different methods and facilities individually or mixed. For enhancing
heat transfer between primary surface and the environment,
utilization of radiating extended surfaces are common. Especially for
large temperature differences; variable thermal conductivity has a
strong effect on performance of such a surface .In most literatures,
thermo-physical properties, such as thermal conductivity, are
assumed as constant. However, in some recent researches the
variation of these parameters is considered. This may be helpful for
the evaluation of fin-s temperature distribution in relatively large
temperature differences. A new method is introduced to evaluate
temperature-dependent thermal conductivity values. The finite
volume method is employed to simulate numerically the temperature
distribution in a space radiating fin. The present modeling is carried
out for Aluminum as fin material and compared with previous
method. The present results are also compared with those of two
other analytical methods and good agreement is shown.
Abstract: Non-isothermal stagnation-point flow with consideration of thermal radiation is studied numerically. A set of partial differential equations that governing the fluid flow and energy is converted into a set of ordinary differential equations which is solved by Runge-Kutta method with shooting algorithm. Dimensionless wall temperature gradient and temperature boundary layer thickness for different combinaton of values of Prandtl number Pr and radiation parameter NR are presented graphically. Analyses of results show that the presence of thermal radiation in the stagnation-point flow is to increase the temperature boundary layer thickness and decrease the dimensionless wall temperature gradient.
Abstract: This article is presented an experimental and modeling
study of a four-bed pressure swing adsorption process using
zeolite13X to provide oxygen-enriched air. The binary mixture N2/O2
(79/21 vol %) was used as a feed stream. The effects of purge/feed
ratio (P/F), adsorption pressure, cyclic time and product flow rate on
product purity and recovery under nonisothermal condition were
studied. The adsorption dynamics of process were determined using
a mathematical model incorporated mass and energy balances. A
Mathlab code using finite difference method was developed to solve
the set of coupled differential-algebraic equations, and the simulation
results are agreed well with experimental results.
Abstract: Pure phase gallosilicate nitrite sodalite has been synthesized in a single step by low temperature (373 oK) hydrothermal technique. The product obtained was characterized using a combination of techniques including X-ray powder diffraction, IR, Raman spectroscopy, SEM, MAS NMR spectroscopy as well as thermogravimetry. Sodalite with an ideal composition was obtained after synthesis at 3730K and seven days duration using alkaline medium. The structural features of the Na8[GaSiO4]6(NO2)2 sodalite were investigated by IR, MAS NMR spectroscopy of 29Si and 23Na nuclei and by Reitveld refinement of X-ray powder diffraction data. The crystal structure of this sodalite has been refined in the space group P 4 3n; with a cell parameter 8.98386Å, V= 726.9 Å, (Rwp= 0.077 and Rp=0.0537) and Si-O-Ga angle is found to be 132.920 . MAS NMR study confirms complete ordering of Si and Ga in the gallosilicate framework. The surface area of single entity with stoichiometry Na8[GaSiO4]6(NO2)2 was found to be 8.083 x10-15 cm2/g.
Abstract: The deficit of power supply in Macedonia is almost 30% or reached up to 3000 GWh in a year. The existing thermal and hydro power plants are not enough to cover the power and energy, so the import increases every year. Therefore, in order to have more domestic energy supply, the new trends in renewable and energy efficiency should be implemented in power sector. The paper gives some perspectives for development of the power system in Macedonia, taking into account the growth of electricity demand and in the same time with implementation of renewable and energy efficiency. The development of power system is made for the period up to 2030 with the period of every 5 years.
Abstract: In space during functioning, a satellite will be heated
up due to the behavior of its components such as power electronics.
In order to prevent problems in the satellite, this heat has to be
released in space thanks to the cooling system. This system consists
of a loop heat pipe (LHP), in which a fluid streams through an
evaporator and a condenser. In the evaporator, the fluid captures the
heat from the satellite and evaporates. Then it flows to the condenser
where it releases the heat and it condenses. In this project, the two
mains parts of a cooling system are studied: the evaporator and the
condenser. The study of the diphasic loop was done starting from
digital simulations carried out under Matlab and Femlab.
Abstract: A novel biomass composite inspired from wood porous
structure was manufactured by impregnating vinyl monomer into
wood cellular structure under vacuum conditions, and initiating the
monomer for in situ polymerization through a thermal treatment. The
vacuum condition was studied, and the mechanical properties of the
composite were also tested. SEM observation shows that polymer
generated in the wood porous structure, and strongly interacted with
wood matrix; and the polymer content increased with vacuum value
increasing. FTIR indicates that polymer grafted onto wood matrix,
resulting chemical complex between them. The rate of monomer
loading increased with increasing vacuum value and time, accordance
with rate of polymer loading. The compression strength and modulus
of elasticity linearly increased with the increasing rate of polymer
loading. Results indicate that the novel biomass composite possesses
good mechanical properties capable of applying in the fields of
construction, traffic and so forth.
Abstract: The use of plastic materials in agriculture causes
serious hazards to the environment. The introduction of biodegradable materials, which can be disposed directly into the soil
can be one possible solution to this problem. In the present research results of experimental tests carried out on biodegradable film
fabricated from natural waste (corn husk) are presented. The film was
characterized by Fourier transform infrared spectroscopy (FTIR),
differential scanning calorimeter (DSC), thermal gravimetric analysis
(TGA) and atomic force microscope (AFM) observation. The film is
shown to be readily degraded within 7-9 months under controlled soil
conditions, indicating a high biodegradability rate. The film
fabricated was use to produce biodegradable pot (BioPot) for
seedlings plantation. The introduction and the expanding use of
biodegradable materials represent a really promising alternative for
enhancing sustainable and environmentally friendly agricultural
activities.
Abstract: The objective of this study is to present the test
results of variable air volume (VAV) air conditioning system
optimized by two objective genetic algorithm (GA). The objective
functions are energy savings and thermal comfort. The optimal set
points for fuzzy logic controller (FLC) are the supply air temperature
(Ts), the supply duct static pressure (Ps), the chilled water
temperature (Tw), and zone temperature (Tz) that is taken as the
problem variables. Supply airflow rate and chilled water flow rate are
considered to be the constraints. The optimal set point values are
obtained from GA process and assigned into fuzzy logic controller
(FLC) in order to conserve energy and maintain thermal comfort in
real time VAV air conditioning system. A VAV air conditioning
system with FLC installed in a software laboratory has been taken for
the purpose of energy analysis. The total energy saving obtained in
VAV GA optimization system with FLC compared with constant air
volume (CAV) system is expected to achieve 31.5%. The optimal
duct static pressure obtained through Genetic fuzzy methodology
attributes to better air distribution by delivering the optimal quantity
of supply air to the conditioned space. This combination enhanced
the advantages of uniform air distribution, thermal comfort and
improved energy savings potential.
Abstract: Increased energy demand and the concern about
environment friendly technology, renewable bio-fuels are better
alternative to petroleum products. In the present study linseed oil was
used as alternative source for diesel engine fuel and the results were
compared with baseline data of neat diesel. Performance parameters
such as brake thermal efficiency (BTE) and brake specific fuel
consumption (BSFC) and emissions parameters such as CO,
unburned hydro carbon (UBHC), NOx, CO2 and exhaust temperature
were compared. BTE of the engine was lower and BSFC was higher
when the engine was fueled with Linseed oil compared to diesel fuel.
Emission characteristics are better than diesel fuel. NOx formation by
using linseed oil during the experiment was lower than diesel fuel.
Linseed oil is non edible oil, so it can be used as an extender of diesel
fuel energy source for small and medium energy needs.
Abstract: The periodic mixed convection of a water-copper
nanofluid inside a rectangular cavity with aspect ratio of 3 is
investigated numerically. The temperature of the bottom wall of the
cavity is assumed greater than the temperature of the top lid which
oscillates horizontally with the velocity defined as u = u0 sin (ω t).
The effects of Richardson number, Ri, and volume fraction of
nanoparticles on the flow and thermal behavior of the nanofluid are
investigated. Velocity and temperature profiles, streamlines and
isotherms are presented. It is observed that when Ri < 1, heat transfer
rate is much greater than when Ri > 1. The higher value of Ri
corresponds to a lower value of the amplitude of the oscillation of
Num in the steady periodic state. Moreover, increasing the volume
fraction of the nanoparticles increases the heat transfer rate.
Abstract: Dehydration behavior gives a hint about thermal properties of materials. It is important for the usage areas and transportation of minerals. Magnesium borates can be used as additive materials in areas such as in the production of superconducting materials, in the composition of detergents, due to the content of boron in the friction-reducing additives in oils and insulating coating compositions due to their good mechanic and thermal properties.
In this study, thermal dehydration behavior of admontite (MgO(B2O3)3.7(H2O)), which is a kind of magnesium borate mineral, is experimented by microwave energy at 360W. Structure of admontite is suitable for the investigation of dehydration behavior by microwave because of its seven moles of crystal water. It is seen that admontite lost its 28.7% of weight at the end of the 120 minutes heating in microwave furnace.