Abstract: Magnesium wastes are produced by many industrial activities. This waste problem is becoming a future problem for the world. Magnesium borates have many advantages such as; high corrosion resistance, heat resistance, high coefficient of elasticity and can also be used in the production of material against radiation. Addition, magnesium borates have great potential in sectors
including ceramic and detergents industry and superconducting materials.
In this study, using the starting materials of waste magnesium and H3BO3 the hydrothermal method was applied at a moderate
temperature of 70oC. Several mole ratios of waste magnesium to H3BO3 are selected as; 1:2, 1:4, 1:6, 1:8, 1:10. Reaction time was determined as 1 hour. After the synthesis, X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques are applied to products. As a result the forms of mcallisterite “Mg2(B6O7(OH)6)2.9(H2O)”, admontite “MgO(B2O3)3.7(H2O)” and magnesium boron hydrate (MgO(B2O3)3.6(H2O)” are obtained.
Abstract: Hybrid photovoltaic thermal (PV/T) solar system comprises a solar collector which is disposed on photovoltaic solar cells. The disadvantage of a conventional photovoltaic cell is that its performance decreases as the temperature increases. Indeed, part of the solar radiation is converted into electricity and is dissipated as heat, increasing the temperature of the photovoltaic cell with respect to the ambient temperature. The objective of this work is to study experimentally and implement a hybrid prototype to evaluate electrical and thermal performance. In this paper, an experimental study of two new configurations of hybrid collectors is exposed. The results are given and interpreted. The two configurations of absorber studied are a new combination with tubes and galvanized tank, the other is a tubes and sheet.
Abstract: This paper presents a cold flow simulation study of a small gas turbine combustor performed using laboratory scale test rig. The main objective of this investigation is to obtain physical insight of the main vortex, responsible for the efficient mixing of fuel and air. Such models are necessary for predictions and optimization of real gas turbine combustors. Air swirler can control the combustor performance by assisting in the fuel-air mixing process and by producing recirculation region which can act as flame holders and influences residence time. Thus, proper selection of a swirler is needed to enhance combustor performance and to reduce NOx emissions. Three different axial air swirlers were used based on their vane angles i.e., 30°, 45°, and 60°. Three-dimensional, viscous, turbulent, isothermal flow characteristics of the combustor model operating at room temperature were simulated via Reynolds- Averaged Navier-Stokes (RANS) code. The model geometry has been created using solid model, and the meshing has been done using GAMBIT preprocessing package. Finally, the solution and analysis were carried out in a FLUENT solver. This serves to demonstrate the capability of the code for design and analysis of real combustor. The effects of swirlers and mass flow rate were examined. Details of the complex flow structure such as vortices and recirculation zones were obtained by the simulation model. The computational model predicts a major recirculation zone in the central region immediately downstream of the fuel nozzle and a second recirculation zone in the upstream corner of the combustion chamber. It is also shown that swirler angles changes have significant effects on the combustor flowfield as well as pressure losses.
Abstract: one of the significant factors for improving the
accuracy of Land Surface Temperature (LST) retrieval is the correct
understanding of the directional anisotropy for thermal radiance. In
this paper, the multiple scattering effect between heterogeneous
non-isothermal surfaces is described rigorously according to the
concept of configuration factor, based on which a directional thermal
radiance model is built, and the directional radiant character for urban
canopy is analyzed. The model is applied to a simple urban canopy
with row structure to simulate the change of Directional Brightness
Temperature (DBT). The results show that the DBT is aggrandized
because of the multiple scattering effects, whereas the change range of
DBT is smoothed. The temperature difference, spatial distribution,
emissivity of the components can all lead to the change of DBT. The
“hot spot" phenomenon occurs when the proportion of high
temperature component in the vision field came to a head. On the other
hand, the “cool spot" phenomena occur when low temperature
proportion came to the head. The “spot" effect disappears only when
the proportion of every component keeps invariability. The model
built in this paper can be used for the study of directional effect on
emissivity, the LST retrieval over urban areas and the adjacency effect
of thermal remote sensing pixels.
Abstract: Structured catalysts formed from the growth of
zeolites on substrates is an area of increasing interest due to the
increased efficiency of the catalytic process, and the ability to
provide superior heat transfer and thermal conductivity for both
exothermic and endothermic processes.
However, the generation of structured catalysts represents a
significant challenge when balancing the relationship variables
between materials properties and catalytic performance, with the
Na2O, H2O and Al2O3 gel composition paying a significant role in
this dynamic, thereby affecting the both the type and range of
application.
The structured catalyst films generated as part of this
investigation have been characterised using a range of techniques,
including X-ray diffraction (XRD), Electron microscopy (SEM),
Energy Dispersive X-ray analysis (EDX) and Thermogravimetric
Analysis (TGA), with the transition from oxide-on-alloy wires to
hydrothermally synthesised uniformly zeolite coated surfaces being
demonstrated using both SEM and XRD. The robustness of the
coatings has been ascertained by subjecting these to thermal cycling
(ambient to 550oC), with the results indicating that the synthesis time
and gel compositions have a crucial effect on the quality of zeolite
growth on the FeCrAlloy wires.
Finally, the activity of the structured catalyst was verified by a
series of comparison experiments with standard zeolite Y catalysts in
powdered pelleted forms.
Abstract: Water borne polyurethane (PU) based on newly prepared hyperbranched poly (amine-ester) (HBPAE) was applied and evaluated as organic coating material. HBPAE was prepared through one-pot synthesis between trimethylol propane as a core and AB2 branched monomer which was obtained via Michal addition of methyl methacrylate (MMA) and diethanol amine (DEA). PU was prepared from HBPAE using different ratios of toluene diisocyanate (TDI) to form cured coating film. The prepared HBPAE was characterized using; GPC, FT-IR and 1H-NMR. The mechanical properties (impact, hardness, adhesion, and flexibility), thermal properties (DSC and TGA) and chemical resistance of the applied film were estimated. The results indicated 50% of TDI is the selected ratio. This formulation represents a promising candidate to be used as coating material.
Abstract: High-velocity oxygen fuel (HVOF) thermal spraying
uses a combustion process to heat the gas flow and coating material.
A computational fluid dynamics (CFD) model has been developed to
predict gas dynamic behavior in a HVOF thermal spray gun in which
premixed oxygen and propane are burnt in a combustion chamber
linked to a parallel-sided nozzle. The CFD analysis is applied to
investigate axisymmetric, steady-state, turbulent, compressible,
chemically reacting, subsonic and supersonic flow inside and outside
the gun. The gas velocity, temperature, pressure and Mach number
distributions are presented for various locations inside and outside
the gun. The calculated results show that the most sensitive
parameters affecting the process are fuel-to-oxygen gas ratio and
total gas flow rate. Gas dynamic behavior along the centerline of the
gun depends on both total gas flow rate and fuel-to-oxygen gas ratio.
The numerical simulations show that the axial gas velocity and Mach
number distribution depend on both flow rate and ratio; the highest
velocity is achieved at the higher flow rate and most fuel-rich ratio.
In addition, the results reported in this paper illustrate that the
numerical simulation can be one of the most powerful and beneficial
tools for the HVOF system design, optimization and performance
analysis.
Abstract: Pomegranate and pomegranate juices (PJs) have taken
great attention for their health benefits in the last years. As there is an
increasing concern about potential health benefits of ellagic acid, it is
of great interest to evaluate alterations in ellagic acid concentration of
commercial PJs. The purpose of this study is to analyze total
phenolic, free and total ellagic acid content of six commercial PJs
sold in Turkish markets using HPLC.
The results showed that some commercial PJs had markedly high
total phenolic and ellagic acid content. Total phenolic substances of
commercial PJs range from 796.71 to 4608.91 mg GAE/l. Free
amount of ellagic acid in commercial PJs range from 27.64 to 111.78
mg/l. Samples are hydrolyzed with concentrated HCl at 93oC for 2
and 24 hour and influences of temperature and time parameters on
hydrolization were investigated. Thermal processing for
pasteurization increased ellagic acid via ellagitannins hydrolysis.
Abstract: This paper reported an experimental research of
steady-state heat transfer behaviour of a gas flowing through a fixed
bed under the different operating conditions. Studies had been carried
out in a fixed-bed packed methanol synthesis catalyst percolated by air
at appropriate flow rate. Both radial and axial direction temperature
distribution had been investigated under the different operating
conditions. The effects of operating conditions including the reactor
inlet air temperature, the heating pipe temperature and the air flow rate
on temperature distribution was investigated and the experimental
results showed that a higher inlet air temperature was conducive to
uniform temperature distribution in the fixed bed. A large temperature
drop existed at the radial direction, and the temperature drop increased
with the heating pipe temperature increasing under the experimental
conditions; the temperature profile of the vicinity of the heating pipe
was strongly affected by the heating pipe temperature. A higher air
flow rate can improve the heat transfer in the fixed bed. Based on the
thermal distribution, heat transfer models of the fixed bed could be
established, and the characteristics of the temperature distribution in
the fixed bed could be finely described, that had an important practical
significance.
Abstract: In this work we present an efficient approach for face
recognition in the infrared spectrum. In the proposed approach
physiological features are extracted from thermal images in order to
build a unique thermal faceprint. Then, a distance transform is used
to get an invariant representation for face recognition. The obtained
physiological features are related to the distribution of blood vessels
under the face skin. This blood network is unique to each individual
and can be used in infrared face recognition. The obtained results are
promising and show the effectiveness of the proposed scheme.
Abstract: Oilsands bitumen is an extremely important source of
energy for North America. However, due to the presence of large
molecules such as asphaltenes, the density and viscosity of the
bitumen recovered from these sands are much higher than those of
conventional crude oil. As a result the extracted bitumen has to be
diluted with expensive solvents, or thermochemically upgraded in
large, capital-intensive conventional upgrading facilities prior to
pipeline transport. This study demonstrates that globally abundant
natural zeolites such as clinoptilolite from Saint Clouds, New Mexico
and Ca-chabazite from Bowie, Arizona can be used as very effective
reagents for cracking and visbreaking of oilsands bitumen. Natural
zeolite cracked oilsands bitumen products are highly recoverable (up
to ~ 83%) using light hydrocarbons such as pentane, which indicates
substantial conversion of heavier fractions to lighter components.
The resultant liquid products are much less viscous, and have lighter
product distribution compared to those produced from pure thermal
treatment. These natural minerals impart similar effect on industrially
extracted Athabasca bitumen.
Abstract: The presented work is motivated by a French law
regarding nuclear waste management. A new conceptual Accelerator
Driven System (ADS) designed for the Minor Actinides (MA)
transmutation has been assessed by numerical simulation. The
MUltiple Spallation Target (MUST) ADS combines high thermal power (up to 1.4 GWth) and high specific power. A 30 mA and 1
GeV proton beam is divided into three secondary beams transmitted on three liquid lead-bismuth spallation targets. Neutron and thermalhydraulic
simulations have been performed with the code MURE, based on the Monte-Carlo transport code MCNPX. A methodology has been developed to define characteristic of the MUST ADS concept according to a specific transmutation scenario. The reference
scenario is based on a MA flux (neptunium, americium and curium)
providing from European Fast Reactor (EPR) and a plutonium multireprocessing
strategy is accounted for. The MUST ADS reference
concept is a sodium cooled fast reactor. The MA fuel at equilibrium is mixed with MgO inert matrix to limit the core reactivity and
improve the fuel thermal conductivity. The fuel is irradiated over five
years. Five years of cooling and two years for the fuel fabrication are
taken into account. The MUST ADS reference concept burns about 50% of the initial MA inventory during a complete cycle. In term of
mass, up to 570 kg/year are transmuted in one concept. The methodology to design the MUST ADS and to calculate fuel
composition at equilibrium is precisely described in the paper. A detailed fuel evolution analysis is performed and the reference scenario is compared to a scenario where only americium transmutation is performed.
Abstract: Mixed convection in two-dimensional shallow rectangular enclosure is considered. The top hot wall moves with constant velocity while the cold bottom wall has no motion. Simulations are performed for Richardson number ranging from Ri = 0.001 to 100 and for Reynolds number keeping fixed at Re = 408.21. Under these conditions cavity encompasses three regimes: dominating forced, mixed and free convection flow. The Prandtl number is set to 6 and the effects of cavity inclination on the flow and heat transfer are studied for different Richardson number. With increasing the inclination angle, interesting behavior of the flow and thermal fields are observed. The streamlines and isotherm plots and the variation of the Nusselt numbers on the hot wall are presented. The average Nusselt number is found to increase with cavity inclination for Ri ³ 1 . Also it is shown that the average Nusselt number changes mildly with the cavity inclination in the dominant forced convection regime but it increases considerably in the regime with dominant natural convection.
Abstract: The LHP is a two-phase device with extremely high
effective thermal conductivity that utilizes the thermodynamic
pressure difference to circulate a cooling fluid. A thermodynamics
analytical model is developed to explore different parameters effects
on a Loop Heat Pipe (LHP).. The effects of pipe length, pipe
diameter, condenser temperature, and heat load are reported. As pipe
length increases and/or pipe diameter decreases, a higher temperature
is expected in the evaporator.
Abstract: The hydrothermal behavior of a bed consisting of
magnetic and shale oil particle admixtures under the effect of a
transverse magnetic field is investigated. The phase diagram, bed
void fraction are studied under wide range of the operating
conditions i.e., gas velocity, magnetic field intensity and fraction of
the magnetic particles. It is found that the range of the stabilized
regime is reduced as the magnetic fraction decreases. In addition, the
bed voidage at the onset of fluidization decreases as the magnetic
fraction decreases. On the other hand, Nusselt number and
consequently the heat transfer coefficient is found to increase as the
magnetic fraction decreases. An empirical equation is investigated to
relate the effect of the gas velocity, magnetic field intensity and
fraction of the magnetic particles on the heat transfer behavior in the
bed.
Abstract: A magnetohydrodynamic mixed convective flow in a
cavity was studied in this paper. The lower surface of cavity was
heated from below whereas other walls of the cavity were thermally
isolated. The governing two-dimensional flow equations have been
solved by using finite volume code. The effects of magnetic field
were studied on flow and temperature field and heat transfer
performance at a wide range of parameters, Such as Hartmann
(0≤Ha≤100) and Reynolds (1≤Re≤100) numbers. The results showed
that as Hartman number increases the Nusselt number, representing
heat transfer from the cavity decreases.
Abstract: The Pads have unique values of thermophysical
properties (THP) having important contribution over heat transfer
into the PCB structure.
Materials with high thermal diffusivity (TD) rapidly adjust their
temperature to that of their surroundings, because the HT is quick in
compare to their volumetric heat capacity (VHC).
In the paper is presenting the diffusivity tests (ASTM E1461 flash
method) for PCBs with different core materials. In the experiments,
the multilayer structure of PCBA was taken into consideration, an
equivalent property referring to each of experimental structure be
practically measured.
Concerning to entire structure, the THP emphasize the major
contribution of substrate in establishing of reflow soldering process
(RSP) heat transfer necessities. This conclusion offer practical
solution for heat transfer time constant calculation as function of
thickness and substrate material diffusivity with an acceptable error
estimation.
Abstract: Combined conduction-free convection heat transfer in
vertical eccentric annuli is numerically investigated using a finitedifference
technique. Numerical results, representing the heat transfer
parameters such as annulus walls temperature, heat flux, and heat
absorbed in the developing region of the annulus, are presented for a
Newtonian fluid of Prandtl number 0.7, fluid-annulus radius ratio 0.5,
solid-fluid thermal conductivity ratio 10, inner and outer wall
dimensionless thicknesses 0.1 and 0.2, respectively, and
dimensionless eccentricities 0.1, 0.3, 0.5, and 0.7. The annulus walls
are subjected to thermal boundary conditions, which are obtained by
heating one wall isothermally whereas keeping the other wall at inlet
fluid temperature. In the present paper, the annulus heights required
to achieve thermal full development for prescribed eccentricities are
obtained. Furthermore, the variation in the height of thermal full
development as function of the geometrical parameter, i.e.,
eccentricity is also investigated.
Abstract: Recently ORC(Organic Rankine Cycle) has attracted
much attention due to its potential in reducing consumption of fossil
fuels and its favorable characteristics to exploit low-grade heat sources.
In this work thermodynamic performance of ORC with superheating of
vapor is comparatively assessed for various working fluids. Special
attention is paid to the effects of system parameters such as the evaporating
temperature and the turbine inlet temperature on the characteristics
of the system such as maximum possible work extraction from
the given source, volumetric flow rate per 1 kW of net work and
quality of the working fluid at turbine exit as well as thermal and
exergy efficiencies. Results show that for a given source the thermal
efficiency increases with decrease of the superheating but exergy
efficiency may have a maximum value with respect to the superheating
of the working fluid. Results also show that in selection of working
fluid it is required to consider various criteria of performance characteristics
as well as thermal efficiency.
Abstract: Aerospace vehicles are subjected to non-uniform
thermal loading that may cause thermal buckling. A study was
conducted on the thermal post-buckling of shape memory alloy
composite plates subjected to the non-uniform tent-like temperature
field. The shape memory alloy wires were embedded within the
laminated composite plates to add recovery stress to the plates. The
non-linear finite element model that considered the recovery stress of
the shape memory alloy and temperature dependent properties of the
shape memory alloy and composite matrix along with its source
codes were developed. It was found that the post-buckling paths of
the shape memory alloy composite plates subjected to various tentlike
temperature fields were stable within the studied temperature
range. The addition of shape memory alloy wires to the composite
plates was found to significantly improve the post-buckling behavior
of laminated composite plates under non-uniform temperature
distribution.