Abstract: The irradiation of polymeric materials has received
much attention because it can produce diverse changes in chemical
structure and physical properties. Thus, studying the chemical and
structural changes of polymers is important in practice to achieve
optimal conditions for the modification of polymers. The effect of
gamma irradiation on the crystalline structure of poly(vinylidene
fluoride) (PVDF) has been investigated using differential scanning
calorimetry (DSC) and X-ray diffraction techniques (XRD). Gamma
irradiation was carried out in atmosphere air with doses between 100
kGy at 3,000 kGy with a Co-60 source. In the melting thermogram of
the samples irradiated can be seen a bimodal melting endotherm is
detected with two melting temperature. The lower melting
temperature is attributed to melting of crystals originally present and
the higher melting peak due to melting of crystals reorganized upon
heat treatment. These results are consistent with those obtained by
XRD technique showing increasing crystallinity with increasing
irradiation dose, although the melting latent heat is decreasing.
Abstract: The combination of multi–walled carbon nanotubes
(MWCNTs) with polymers offers an attractive route to reinforce the
macromolecular compounds as well as the introduction of new
properties based on morphological modifications or electronic
interactions between the two constituents. As they are only a few
nanometers in dimension, it offers ultra-large interfacial area per
volume between the nano-element and polymer matrix. Nevertheless,
the use of MWCNTs as a rough material in different applications has
been largely limited by their poor processability, insolubility, and
infusibility. Studies concerning the nanofiller reinforced polymer
composites are justified in an attempt to overcome these limitations.
This work presents one preliminary study of MWCNTs dispersion
into the PVDF homopolymer. For preparation, the composite
components were diluted in n,n-dimethylacetamide (DMAc) with
mechanical agitation assistance. After complete dilution, followed by
slow evaporation of the solvent at 60°C, the samples were dried.
Films of about 80 μm were obtained. FTIR and UV-Vis
spectroscopic techniques were used to characterize the
nanocomposites. The appearance of absorption bands in the FTIR
spectra of nanofilled samples, when compared to the spectrum of
pristine PVDF samples, are discussed and compared with the UV-Vis
measurements.
Abstract: This paper investigates the effects of breaks in bonds,
breaks in the earthing system and breaks in earth wire on the rise of
the earth potential (EPR) in a substation and at the transmission tower
bases using various models of an L6 tower. Different approaches
were adopted to examine the integrity of the earthing system and the
terminal towers. These effects were investigated to see the associated
difference in the EPR magnitudes with respect to a healthy system at
various locations. Comparisons of the computed EPR magnitudes
were then made between the healthy and unhealthy system to detect
any difference. The studies were conducted at power frequency for a
uniform soil with different soil resistivities. It was found that full
breaks in the double bond of the terminal towers increase the EPR
significantly at the fault location, while they reduce EPR at the
terminal tower bases. A fault on the isolated section of the grid can
result in EPR values up to 8 times of those on a healthy system at
higher soil resistivities, provided that the extended earthing system
stays connected to the grid.
Abstract: The adjoint method has been used as a successful tool to
obtain sensitivity gradients in aerodynamic design and optimisation
for many years. This work presents an alternative approach to the
continuous adjoint formulation that enables one to compute gradients
of a given measure of merit with respect to control parameters other
than those pertaining to geometry. The procedure is then applied to
the steady 2–D compressible Euler and incompressible Navier–Stokes
flow equations. Finally, the results are compared with sensitivities
obtained by finite differences and theoretical values for validation.
Abstract: This paper analyzes the institutionalization of social
protest in Spain. In the current crisis Podemos party seems to
represent the political positions of the most affected citizens by the
economic situation. It studies using quantitative techniques (statistical
bivariate analysis), focusing on the exploitation of several bases of
statistics data from the Center for Sociological and Research of
Spanish Government, 15M movement characterization to its
institutionalization in the Podemos party. Making a comparison
between the participant's profile by the 15M and the social bases of
Podemos votes. Data on the transformation of the socio-demographic
profile of the fans, connoisseurs and 15M participants and voters are
given.
Abstract: The aim of this paper is to develop an empirical
research on the nature and consequences of corporate governance on
Eurozone Insurance Industry risk taking attitude. More particularly,
we analyzed the effect of public ownership on risk taking with
respect to privately held Insurance Companies. We also analyzed the
effects on risk taking attitude of different degrees of ownership
concentration, directors compensation, and the dimension/diversity of
the Board of Directors. Our results provide quite strong evidence that,
coherently with the Agency Theory, publicly traded insurance
companies with more concentrated ownership are less risky than the
corresponding privately held.
Abstract: Large scale Indian manufacturers started
implementing Six Sigma to their supply core to fulfill the endless
need of high quality products. As well, they initiated encouraging
their suppliers to apply the well-ascertain SS management practice
and kept no resource for supplier enterprises, generally small midsized
enterprises to think for the admittance of Six Sigma as a quality
promotion drive. There are many issues to study for requisite changes
before the introduction of Six Sigma in auto SMEs. This paper
converges on impeding factors while implementing SS drive and also
pinpoints the gains achieved through successful implementation. The
result of this study suggest some operational guidelines for effective
implementation of Six Sigma from evidences acquired through
research questionnaire and interviews with industrial professionals,
apportioned to assort auto sector mid-sized enterprises (MSEs) in
India.
Abstract: Debts reconstruction under some of moratorium
projects is one of important method that highly benefits to both the
Banks and farmers. The method can reduce probabilities for nonprofits
loan. This paper discuss about debts reconstruction and career
development training for farmers in Thailand between 2011 and
2013. The research designed is mix-method between quantitative
survey and qualitative survey. Sample size for quantitative method is
1003 cases. Data gathering procedure is between October and
December 2013. Main results affirmed that debts reconstruction is
needed. And there are numerous benefits from farmers’ career
development training. Many of farmers who attend field school
activities able to bring knowledge learned to apply for the farms’
work. They can reduce production costs. Framers’ quality of life and
their household well-being also improve. This program should apply
in any countries where farmers have highly debts and highly risks for
not return the debts.
Abstract: Green chemistry for plant extraction of active principles is the main interest of many researchers concerned with climate change. While classical organic solvents are detrimental to our environment, greener alternatives to ionic liquids are very promising for sustainable organic chemistry. This study focused on the determination of functional groups observed in the main constituents from the ionic liquid extracts of Coleus aromaticus Benth leaves using FT-IR Spectroscopy. Moreover, this research aimed to determine the best ionic liquid that can separate functionalized plant constituents from the leaves Coleus aromaticus Benth using Fourier Transform Infrared Spectroscopy. Coleus aromaticus Benth leaf extract in different ionic liquids, elucidated pharmacologically important functional groups present in major constituents of the plant, namely, rosmarinic acid, caffeic acid and chlorogenic acid. In connection to distinctive appearance of functional groups in the spectrum and highest % transmittance, potassium chloride-glycerol is the best ionic liquid for green extraction.
Abstract: High double excitation of two-electron atoms has been
investigated using hyperpherical coordinates within a modified
adiabatic expansion technique. This modification creates a novel
fictitious force leading to a spontaneous exchange symmetry breaking
at high double excitation. The Pauli principle must therefore be
regarded as approximation valid only at low excitation energy.
Threshold electron scattering from high Rydberg states shows an
unexpected time reversal symmetry breaking. At threshold for double
escape we discover a broad (few eV) Cooper pair.
Abstract: Reinforced cement concrete is getting extensively used
for construction of different type of structures for the last one century.
During this period, we have constructed many structures like
buildings, bridges, industrial structures, pavement, water tanks etc.
using this construction material. These structures have been created
with huge investment of resources. It is essential to maintain those
structures in functional condition. Since deterioration in RCC
Structures is a common and natural phenomenon it is required to have
a detailed plan, methodology for structural repair and rehabilitation
shall be in place for dealing such issues. It is important to know exact
reason of distress, type of distress and correct method of repair
concrete structures. The different methods of repair are described in
paper according to distress category which can be refereed for repair.
Major finding of the study is that to protect our structure we need to
have maintenance frequency and correct material to be chosen for
repair. Also workmanship during repair needs to be taken utmost care
for quality repair.
Abstract: Ultrasonic metal welding has been the subject of ongoing research and development, most recently concentrating on metal joining in miniature devices, for example to allow solder-free wire bonding. As well as at the small scale, there are also opportunities to research the joining of thicker sheet metals and to widen the range of similar and dissimilar materials that can be successfully joined using this technology. This study presents the design, characterisation and test of a lateral-drive ultrasonic metal spot welding device. The ultrasonic metal spot welding horn is modelled using finite element analysis (FEA) and its vibration behaviour is characterised experimentally to ensure ultrasonic energy is delivered effectively to the weld coupon. The welding stack and fixtures are then designed and mounted on a test machine to allow a series of experiments to be conducted for various welding and ultrasonic parameters. Weld strength is subsequently analysed using tensile-shear tests. The results show how the weld strength is particularly sensitive to the combination of clamping force and ultrasonic vibration amplitude of the welding tip, but there are optimal combinations of these and also limits that must be clearly identified.
Abstract: This paper applies recursive cointegration analysis to
examine the dynamic changes in Feldstein-Horioka saving-investment
(S-I) coefficients across China and the ASEAN-5 countries over time.
To the extent that the S-I coefficients measure international capital
mobility, the main empirical results are as follows. The recursive trace
statistics show that the investment- savings nexus varies in these six
countries. There is no cointegration between investment and savings in
three countries (China, Malaysia, and Singapore), which means that
the mobility of the capital markets in the three is high and that
domestic investment in them will be financed by the global pool of
capital. As to the other three countries (Indonesia, Thailand, and
Philippines), there is cointegration between investment and savings for
part of the sample period in the three, including before 2002 for
Thailand, before 2001 for Indonesia, and before 2002 for Philippines.
This shows these three countries achieved highly mobile and open
capital markets later.
Abstract: Centrifugal-casting machine is used in manufacturing
special machine components like multi-layer journal bearing used in
all internal combustion engine, steam, gas turbine and air craft turboengine
where isotropic properties and high precisions are desired.
Moreover, this machine can be used in manufacturing thin wall hightech
machine components like cylinder liners and piston rings of IC
engine and other machine parts like sleeves, and bushes. Heavy-duty
machine component like railway wheel can also be prepared by
centrifugal casting. A lot of technological developments are required
in casting process for production of good casted machine body and
machine parts. Usually defects like blowholes, surface roughness,
chilled surface etc. are found in sand casted machine parts. But these
can be removed by centrifugal casting machine using rotating
metallic die. Moreover, die rotation, its temperature control, and good
pouring practice can contribute to the quality of casting because of
the fact that the soundness of a casting in large part depends upon
how the metal enters into the mold or dies and solidifies. Poor
pouring practice leads to variety of casting defects such as
temperature loss, low quality casting, excessive turbulence, over
pouring etc. Besides these, handling of molten metal is very
unsecured and dangerous for the workers. In order to get rid of all
these problems, the need of an automatic pouring device arises. In
this research work, a robot assisted pouring device and a centrifugal
casting machine are designed, developed constructed and tested
experimentally which are found to work satisfactorily. The robot
assisted pouring device is further modified and developed for using it
in actual metal casting process. Lot of settings and tests are required
to control the system and ultimately it can be used in automation of
centrifugal casting machine to produce high-tech machine parts with
desired precision.
Abstract: The objective of this research is to develop a general technique so that one may predict the dynamic behaviour of a three-dimensional scale crane model subjected to time-dependent moving point forces by means of conventional finite element computer packages. To this end, the whole scale crane model is divided into two parts: the stationary framework and the moving substructure. In such a case, the dynamic responses of a scale crane model can be predicted from the forced vibration responses of the stationary framework due to actions of the four time-dependent moving point forces induced by the moving substructure. Since the magnitudes and positions of the moving point forces are dependent on the relative positions between the trolley, moving substructure and the stationary framework, it can be found from the numerical results that the time histories for the moving speeds of the moving substructure and the trolley are the key factors affecting the dynamic responses of the scale crane model.
Abstract: In this paper, autonomous performance of a small
manufactured unmanned helicopter is tried to be increased. For this
purpose, a small unmanned helicopter is manufactured in Erciyes
University, Faculty of Aeronautics and Astronautics. It is called as
ZANKA-Heli-I. For performance maximization, autopilot parameters
are determined via minimizing a cost function consisting of flight
performance parameters such as settling time, rise time, overshoot
during trajectory tracking. For this purpose, a stochastic optimization
method named as simultaneous perturbation stochastic approximation
is benefited. Using this approach, considerable autonomous
performance increase (around %23) is obtained.
Abstract: In this paper, it is aimed to improve autonomous flight
performance of a load-carrying (payload: 3 kg and total: 6kg)
unmanned aerial vehicle (UAV) through active wing and horizontal
tail active morphing and also integrated autopilot system parameters
(i.e. P, I, D gains) and UAV parameters (i.e. extension ratios of wing
and horizontal tail during flight) design. For this purpose, a loadcarrying
UAV (i.e. ZANKA-II) is manufactured in Erciyes
University, College of Aviation, Model Aircraft Laboratory is
benefited. Optimum values of UAV parameters and autopilot
parameters are obtained using a stochastic optimization method.
Using this approach autonomous flight performance of UAV is
substantially improved and also in some adverse weather conditions
an opportunity for safe flight is satisfied. Active morphing and
integrated design approach gives confidence, high performance and
easy-utility request of UAV users.
Abstract: The boundary layer separation and new active flow control of a NACA 0025 airfoil were studied experimentally. This new flow control is sometimes known as a co-flow jet (cfj) airfoil. This paper presents the fluctuating velocity in a wall jet over the co-flow jet airfoil subjected to an adverse pressure gradient and a curved surface. In these results, the fluctuating velocity at the inner part increasing by increased the angle of attack up to 12o and this has due to the jet energized, while the angle of attack 20o has different. The airfoil cord based Reynolds number has 105.
Abstract: A composite material with carbon fiber and polymer
matrix has been used as adherent for manufacturing adhesive joints.
In order to evaluate different fiber orientations on joint performance,
the adherents with the 0°, ±15°, ±30°, ±45° fiber orientations were
used in the single lap joint configuration. The joints with an overlap
length of 25 mm were prepared according to the ASTM 1002
specifications and subjected to tensile loadings. The structural
adhesive used was a two-part epoxy to be cured at 70°C for an hour.
First, mechanical behaviors of the adherents were measured using
three point bending test. In the test, considerations were given to
stress to failure and elastic modulus. The results were compared with
theoretical ones using rule of mixture. Then, the joints were
manufactured in a specially prepared jig, after a proper surface
preparation. Experimental results showed that the fiber orientations
of the adherents affected the joint performance considerably; the
joints with ±45° adherents experienced the worst shear strength, half
of those with 0° adherents, and in general, there was a great
relationship between the fiber orientations and failure mechanisms.
Delamination problems were observed for many joints, which were
thought to be due to peel effects at the ends of the overlap. It was
proved that the surface preparation applied to the adherent surface
was adequate. For further explanation of the results, a numerical
work should be carried out using a possible non-linear analysis.
Abstract: This paper investigates the application of metallic
coatings on high fiber volume fraction carbon/epoxy polymer matrix
composites. For the grip of the metallic layer, a method of modifying
the surface of the composite by introducing a mixture of copper and
steel powder (filler powders) which can reduce the impact of thermal
spray particles. The powder was introduced to the surface at the time
of the forming. Arc spray was used to project the zinc coating layer.
The substrate was grit blasted to avoid poor adherence. The porosity, microstructure, and morphology of layers are
characterized by optical microscopy, SEM and image analysis. The
samples were studied also in terms of hardness and erosion resistance.
This investigation did not reveal any visible evidence damage to the
substrates. The hardness of zinc layer was about 25.94 MPa and the
porosity was around (∼6.70%). The erosion test showed that the zinc
coating improves the resistance to erosion. Based on the results
obtained, we can conclude that thermal spraying allows the production
of protective coating on PMC. Zinc coating has been identified as a
compatible material with the substrate. The filler powders layer
protects the substrate from the impact of hot particles and allows
avoiding the rupture of brittle carbon fibers.