Abstract: This is a study on numerical simulation of the convection-diffusion transport of a chemical species in steady flow through a small-diameter tube, which is lined with a very thin layer made up of retentive and absorptive materials. The species may be subject to a first-order kinetic reversible phase exchange with the wall material and irreversible absorption into the tube wall. Owing to the velocity shear across the tube section, the chemical species may spread out axially along the tube at a rate much larger than that given by the molecular diffusion; this process is known as dispersion. While the long-time dispersion behavior, well described by the Taylor model, has been extensively studied in the literature, the early development of the dispersion process is by contrast much less investigated. By early development, that means a span of time, after the release of the chemical into the flow, that is shorter than or comparable to the diffusion time scale across the tube section. To understand the early development of the dispersion, the governing equations along with the reactive boundary conditions are solved numerically using the Flux Corrected Transport Algorithm (FCTA). The computation has enabled us to investigate the combined effects on the early development of the dispersion coefficient due to the reversible and irreversible wall reactions. One of the results is shown that the dispersion coefficient may approach its steady-state limit in a short time under the following conditions: (i) a high value of Damkohler number (say Da ≥ 10); (ii) a small but non-zero value of absorption rate (say Γ* ≤ 0.5).
Abstract: Structural and UV/Visible optical properties can be
useful to describe a material for the CIGS solar cell active layer,
therefore, this work demonstrates the properties like surface
morphology, X-ray Photoelectron Spectroscopy (XPS) bonding
energy (EB) core level spectra, UV/Visible absorption spectra,
refractive index (n), optical energy band (Eg), reflection spectra for
the Cu25 (In16Ga9) Se40Te10 (CIGST-1) and Cu20 (In14Ga9) Se45Te12
(CIGST-2) chalcogenide compositions. Materials have been
exhibited homogenous surface morphologies, broading /-or diffusion
of bonding energy peaks relative elemental values and a high
UV/Visible absorption tendency in the wave length range 400 nm-
850 nm range with the optical energy band gaps 1.37 and 1.42
respectively. Subsequently, UV/Visible reflectivity property in the
wave length range 250 nm to 320 nm for these materials has also
been discussed.
Abstract: Arsenic in the sediments of the ash lagoons of the coal-fired power plant in Pagbilao, Quezon Province in the Philippines was sequentially extracted to determine its potential for leaching to the groundwater and the adjacent marine environment. Results show that 89% of the As is bound to the quasi-crystalline Fe/Mn oxides and hydroxide matrix in the sediments, whereas, the adsorbed and exchangeable As hosted by the clay minerals, representing those that are easiest to release from the sediment matrix, is below 10% of the acid leachable As. These As in these sediment matrices represent the possible maximum amount of As that can be released and supplied to the groundwater and the adjacent marine environment. Of the 89% reducible As, up to 4% is associated with the easily reducible variety, whereas, the rest is more strongly bonded by the moderately reducible variety. Based on the long-term As content of the lagoon water, the average desorption rate of As is calculated to be very low -- 0.3-0.5% on the average and 0.6% on the maximum. This indicates that As is well-fixed by its sediment matrices in the ash lagoon, attenuating the influx of As into the adjacent groundwater and marine environments.
Abstract: The experiments were performed in a batch set up
under different concentrations of Cu (II) (0.2 g.l-1 to 0.9 g.l-1), pH (4-
6), temperatures (20oC – 40oC) with varying teak leaves powder (as
biosorbent) dosage of 0.3 g.l-1 to 0.5 g.l-1. The kinetics of interactions
were tested with pseudo first order Lagergran equation and the value
for k1 was found to be 6.909 x 10-3 min-1. The biosorption data gave
a good fit with Langmuir and Fruendlich isotherms and the Langmuir
monolayer capacity (qm) was found to be 166.78 mg. g-1. Similarly
the Freundlich adsorption capacity (Kf) was estimated as 2.49 l g-1.
The mean values of the thermodynamic parameters ΔH, ΔS, and ΔG
were -62.42 KJ. mol-1, -0.219 KJ.mol-1 K-1 and -1.747 KJ.mol-1 at
293 K from a solution containing 0.4 g l-1 of Cu(II) showing the
biosorption to be thermodynamically favourable. These results show
good potentiality of using teak leaves as a biosorbent for the removal
of Cu(II) from aqueous solutions.
Abstract: Composite nanostructures of metal
core/semiconductor shell (Au/CdS) configuration were prepared
using organometalic method. UV-Vis spectra for the Au/CdS colloids
show initially two well separated bands, corresponding to surface
plasmon of the Au core, and the exciton of CdS shell. The absorption
of CdS shell is enhanced, while the Au plasmon band is suppressed
as the shell thickness increases. The shell sizes were estimated from
the optical spectra using the effective mass approximation model
(EMA), and compared to the sizes of the Au core and CdS shell
measured by high resolution transmission electron microscope
(HRTEM). The changes in the absorption features are discussed in
terms of gradual increase in the coupling strength of the Au core
surface plasmon and the exciton in the CdS. leading to charge
transfer and modification of electron oscillation in Au core.
Abstract: The use of solar control film on windows as one of
solar passive strategies for building have becoming important and is
gaining recognition. Malaysia located close to equator is having
warm humid climate with long sunshine hours and abundant solar
radiation throughout the year. Hence, befitting solar control on
windows is absolutely necessary to capture the daylight whilst
moderating thermal impact and eliminating glare problems. This is
one of the energy efficient strategies to achieve thermal and visual
comfort in buildings. Therefore, this study was carried out to
investigate the effect of window solar controls on thermal and visual
performance of naturally ventilated buildings. This was conducted via
field data monitoring using a test building facility. Four types of
window glazing systems were used with three types of solar control
films. Data were analysed for thermal and visual impact with
reference to thermal and optical characteristics of the films. Results
show that for each glazing system, the surface temperature of
windows are influenced by the Solar Energy Absorption property, the
indoor air temperature are influenced by the Solar Energy
Transmittance and Solar Energy Reflectance, and the daylighting by
Visible Light Transmission and Shading Coefficient. Further
investigations are underway to determine the mathematical relation
between thermal energy and visual performance with the thermal and
optical characteristics of solar control films.
Abstract: There are extensive applications of lithium
bromide-water absorption chillers in industry, but the heat exchangers
corrosion and refrigerating capacity loss are very difficult to be solved.
In this paper, an experiment was conducted by using plastic heat
transfer tubes instead of copper tubes. As an example, for a lithium
bromide-water absorption chiller of refrigerating capacity of 35kW,
the correlative performance of the lithium bromide-water absorption
chiller using plastic heat transfer tubes was compared with the
traditional lithium bromide-water absorption chiller. And then the
following three aspects, i.e., heat transfer area, pipe resistance, and
safety strength, are analyzed. The results show that plastic heat
transfer tubes can be used on lithium bromide-water absorption
chillers, and its prospect is very optimistic.
Abstract: ZnO nanocrystals with mean diameter size 14 nm
have been prepared by precipitation method, and examined as
photocatalyst for the UV-induced degradation of insecticide diazinon
as deputy of organic pollutant in aqueous solution. The effects of
various parameters, such as illumination time, the amount of
photocatalyst, initial pH values and initial concentration of
insecticide on the photocatalytic degradation diazinon were
investigated to find desired conditions. In this case, the desired
parameters were also tested for the treatment of real water containing
the insecticide. Photodegradation efficiency of diazinon was
compared between commercial and prepared ZnO nanocrystals. The
results indicated that UV/ZnO process applying prepared
nanocrystalline ZnO offered electrical energy efficiency and
quantum yield better than commercial ZnO. The present study, on the
base of Langmuir-Hinshelwood mechanism, illustrated a pseudo
first-order kinetic model with rate constant of surface reaction equal
to 0.209 mg l-1 min-1 and adsorption equilibrium constant of 0.124 l
mg-1.
Abstract: Effect of geometry on crushing behavior, energy absorption and failure mode of woven roving jute fiber/epoxy laminated composite tubes were experimentally studied. Investigations were carried out on three different geometrical types of composite tubes (circular, square and radial corrugated) subjected to axial compressive loading. It was observed in axial crushing study that the load bearing capability is significantly influenced by corrugation geometry. The influence of geometries of specimens was supported by the plotted load – displacement curves of the tests.
Abstract: In studying the possibility of using plants as
rhizoremediators, barley and grass mixture which showed resistance
to various concentrations of oil were selected. The minimum
inhibitory effect of oil on these plants by morphological parameters
such as survival of plants, length and biomass of shoot and root
compared with the control was showed. In determining physiological
parameters, a slight decrease in the number of chlorophyll a and b in
the leaves of plants was noted. The differences in the ratio of the total
surface of the roots to the work surface with the growth of plants in
soil with oil in the study of adsorption of the root surface were
showed.
Abstract: A new strategy for oriented immobilization of proteins was proposed. The strategy contains two steps. The first step is to search for a docking site away from the active site on the protein surface. The second step is trying to find a ligand that is able to grasp the targeted site of the protein. To avoid ligand binding to the active site of protein, the targeted docking site is selected to own opposite charges to those near the active site. To enhance the ligand-protein binding, both hydrophobic and electrostatic interactions need to be included. The targeted docking site should therefore contain hydrophobic amino acids. The ligand is then selected through the help of molecular docking simulations. The enzyme α-amylase derived from Aspergillus oryzae (TAKA) was taken as an example for oriented immobilization. The active site of TAKA is surrounded by negatively charged amino acids. All the possible hydrophobic sites on the surface of TAKA were evaluated by the free energy estimation through benzene docking. A hydrophobic site on the opposite side of TAKA-s active site was found to be positive in net charges. A possible ligand, 3,3-,4,4- – Biphenyltetra- carboxylic acid (BPTA), was found to catch TAKA by the designated docking site. Then, the BPTA molecules were grafted onto silica gels and measured the affinity of TAKA adsorption and the specific activity of thereby immobilized enzymes. It was found that TAKA had a dissociation constant as low as 7.0×10-6 M toward the ligand BPTA on silica gel. The increase in ionic strength has little effect on the adsorption of TAKA, which indicated the existence of hydrophobic interaction between ligands and proteins. The specific activity of the immobilized TAKA was compared with the randomly adsorbed TAKA on primary amine containing silica gel. It was found that the orderly immobilized TAKA owns a specific activity twice as high as the one randomly adsorbed by ionic interaction.
Abstract: The Chichiawan stream in the Wulin catchment in
Taiwan is the natural habitat of Formosan landlocked salmon. Human
and agriculture activities gradually worsen water quality and impact
the fish habitat negatively. To protect and manage Formosan
landlocked salmon habitat, it is important to understand a variety
land-uses affect on the watershed responses to storms. This study
discusses watershed responses to the dry-day before a storm event and
a variety of land-uses in the Wulin catchment. Under the land-use
planning in the Wulin catchment, the peak flows during typhoon
events do not have noticeable difference. However, the nutrient
exports can be highly reduced under the strategies of restraining
agriculture activities. Due to the higher affinity of P for soil than that
of N, the exports of TN from overall Wuling catchment were much
greater than Ortho-P. Agriculture mainly centralized in subbasin A,
which is the important source of nutrients in nonpoint source discharge.
The subbasin A supplied about 26% of the TN and 32% of the Ortho-P
discharge in 2004, despite the fact it only covers 19% area of the
Wuling catchment. The subbasin analysis displayed that the
agricultural subbasin A exports higher nutrients per unit area than
other forest subbasins. Additionally, the agricultural subbasin A
contributed a higher percentage to total Ortho-P exports compares to
TN. The results of subbasin analysis might imply the transport of
Ortho-P was similar to the particulate matter which was mainly
influenced by the runoff and affected by the desorption from soil
particles while the TN (dominated as nitrate-N) was mainly influenced
by base-flow.
Abstract: Synthetic juice clarification was done through spiral
wound ultrafiltration (UF) membrane module. Synthetic juice was
clarified at two different operating conditions, such as, with and
without permeates recycle at turbulent flow regime. The performance
of spiral wound ultrafiltration membrane was analyzed during
clarification of synthetic juice. Synthetic juice was the mixture of
deionized water, sucrose and pectin molecule. The operating
conditions are: feed flowrate of 10 lpm, pressure drop of 413.7 kPa
and Reynolds no of 5000. Permeate sample was analyzed in terms of
volume reduction factor (VRF), viscosity (Pa.s), ⁰Brix, TDS (mg/l),
electrical conductivity (μS) and turbidity (NTU). It was observe that
the permeate flux declined with operating time for both conditions of
with and without permeate recycle due to increase of concentration
polarization and increase of gel layer on membrane surface. For
without permeate recycle, the membrane fouling rate was faster
compared to with permeate recycle. For without permeate recycle,
the VRF rose up to 5 and for with recycle permeate the VRF is 1.9.
The VRF is higher due to adsorption of solute (pectin) molecule on
membrane surface and resulting permeateflux declined with VRF.
With permeate recycle, quality was within acceptable limit. Fouled
membrane was cleaned by applying different processes (e.g.,
deionized water, SDS and EDTA solution). Membrane cleaning was
analyzed in terms of permeability recovery.
Abstract: The implementation of Super-Ultra Low Emission
Vehicle standards requires more efficient exhaust gas purification. To
increase the efficiency of exhaust gas purification, an the adsorbent
capable of holding hydrocarbons up to 250-300 ОС should be
developed. The possibility to design such adsorbents by modification
of zeolites of mordenite type, ZSM-5 and NaY, using different
metals cations has been studied.
It has been shown that introducing Cr, Cs, Zn, Ni, Co, Li, Mn in
zeolites results in modification of the toluene TPD and toluene
sorption capacity.
5%LiZSM-5 zeolite exhibits the most attractive TPD curve, with
toluene desorption temperature ranging from 250 to 350ОС. The
sorption capacity of 5%Li-ZSM-5 is 0.4 mmol/g. NaY zeolite has the
highest sorption capacity, up to 2 mmol/g, and holds toluene up to
350ОС, but at 120ОС toluene desorption starts, which is not desirable,
since the adsorbent of cold start hydrocarbons should retain them
until 250-300ОС. Therefore 5%LiZSM-5 zeolite was found to be the
most promising to control the cold-start hydrocarbon emissions
among the samples studied.
Abstract: This paper presents a spectroscopic study on doping
of Vanadyl pathalocyanine (VOPc) by [6,6]-phenyl C61 butyric acid
methyl ester (PCBM). The films are characterized by UV/Vis/NIR
spectroscopy. A drastic increase in the absorption coefficient has
been observed with increasing dopant concentration. Optical
properties of VOPc:PCBM films deposited by spin coating technique
were studied in detail. Optical band gap decreased with the PCBM
incorporation in the VOPc film. Optical band gap calculated from the
absorption spectra decreased from 3.32 eV to 3.26 eV with a
variation of 0–75 % of PCBM concentration in the VOPC films.
Abstract: The abundance and availability of rice husk, an agricultural waste, make them as a good source for precursor of activated carbon. In this work, rice husk-based activated carbons were prepared via base treated chemical activation process prior the carbonization process. The effect of carbonization temperatures (400, 600 and 800oC) on their pore structure was evaluated through morphology analysis using scanning electron microscope (SEM). Sample carbonized at 800oC showed better evolution and development of pores as compared to those carbonized at 400 and 600oC. The potential of rice husk-based activated carbon as an alternative adsorbent was investigated for the removal of Ni(II), Zn(II) and Pb(II) from single metal aqueous solution. The adsorption studies using rice husk-based activated carbon as an adsorbent were carried out as a function of contact time at room temperature and the metal ions were analyzed using atomic absorption spectrophotometer (AAS). The ability to remove metal ion from single metal aqueous solution was found to be improved with the increasing of carbonization temperature. Among the three metal ions tested, Pb(II) ion gave the highest adsorption on rice husk-based activated carbon. The results obtained indicate the potential to utilize rice husk as a promising precursor for the preparation of activated carbon for removal of heavy metals.
Abstract: This study aims to investigate mechanical behavior of
deep-drawn cups consisting of aluminum (A1050)/ duralumin
(A2017) multi-layered clad structures with micro- and macro-scale
functional gradients. Such multi-layered clad structures are possibly
used for a new type of crash-boxes in automobiles to effectively
absorb the impact forces generated when automobiles having
collisions. The effect of heat treatments on microstructure,
compositional gradient, micro hardness in 2 and 6-layered aluminum/
duralumin clad structures, which were fabricated by hot rolling, have
been investigated. Impact compressive behavior of deep-drawn cups
consisting of such aluminum/ duralumin clad structures has been also
investigated in terms of energy absorption and maximum force.
Deep-drawn cups consisting of 6-layerd clad structures with microand
macro-scale functional gradients exhibit superior properties in
impact compressive tests.
Abstract: Aim of this work was to compare the efficacy of two
loading methods of proteins onto polymeric nanocarriers: adsorption
and encapsulation methods. Preliminary studies of protein loading
were done using Bovine Serum Albumin (BSA) as model protein.
Nanocarriers were prepared starting from polylactic co-glycolic acid
(PLGA) polymer; production methods used are two different variants
of emulsion evaporation method. Nanoparticles obtained were
analyzed in terms of dimensions by Dynamic Light Scattering and
Loading Efficiency of BSA by Bradford Assay. Loaded
nanoparticles were then submitted to in-vitro protein dissolution test
in order to study the effect of the delivery system on the release rate
of the protein.
Abstract: The literature has argued that firms based in industrial districts enjoy advantages for creating internal knowledge and absorbing external knowledge as a consequence of to the knowledge flows and spillovers that exist in the district. However, empirical evidence to show how belonging to an industrial district affects the business processes of creation and absorption of knowledge is scarce and, moreover, empirical research has not taken into account the influence of variations in the flows of knowledge circulating in each cluster. This study aims to extend empirical evidence on the effect that the stock of shared competencies in industrial districts has on the business processes of creation and absorption of knowledge, through data from an initial study on 952 firms and 35 industrial districts in Spain.
Abstract: Humic acids (HAs) have been shown to activate some
ion uptakes along with stimulating the lateral roots at effective
concentration of micronutrients. However, the effects of HA on ion
adsorption by plant roots are not easily explainable due to the
varieties of HAs that differ from origins. Therefore, this study was
aimed to investigate the effect of various concentrations of HA
obtained from the compost derived from mix manures and some
agricultural wastes on the growth of eggplant seedlings (Solanum
melongena L. cv. Chao Praya) in tissue cultures at low nutrient level.
Egg plant seeds were surfaced sterilized and germinated in ½
Murashige and Skoog medium (MS) without HA added or in ¼ MS
supplemented with 0, 25, 50, 75 and 100 ppm of HAs. Then, they
were cultured for 4 weeks under the controlled environment. The
results showed that seedlings grown on ¼MS supplemented with
HAs at the concentration of 25 and 50 ppm had the average plant
heights (2.49 and 2.28 cm, respectively) higher than the other
treatments. Both treatments also significantly showed the maximum
average fresh and dry weights (p