Abstract: Strong anion exchange resins with QN+OH-, have the
potential to be developed and employed as heterogeneous catalyst for
transesterification, as they are chemically stable to leaching of the
functional group. Nine different SIERs (SIER1-9) with QN+OH-were
prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene
(VBC-DVB) copolymers in the presence of n-heptane
(pore-forming agent). The amine group was successfully grafted into
the polymeric resin beads through functionalization with
trimethylamine. These SIERs are then used as a catalyst for the
transesterification of triacetin with methanol. A set of differential
equations that represents the Langmuir-Hinshelwood-Hougen-
Watson (LHHW) and Eley-Rideal (ER) models for the
transesterification reaction were developed. These kinetic models of
LHHW and ER were fitted to the experimental data. Overall, the
synthesized ion exchange resin-catalyzed reaction were welldescribed
by the Eley-Rideal model compared to LHHW models,
with sum of square error (SSE) of 0.742 and 0.996, respectively.
Abstract: Currently, thorium fuel has been especially noticed
because of its proliferation resistance than long half-life alpha emitter
minor actinides, breeding capability in fast and thermal neutron flux
and mono-isotopic naturally abundant. In recent years, efficiency of
minor actinide burning up in PWRs has been investigated. Hence, a
minor actinide-contained thorium based fuel matrix can confront both
proliferation resistance and nuclear waste depletion aims. In the
present work, minor actinide depletion rate in a CANDU-type nuclear
core modeled using MCNP code has been investigated. The obtained
effects of minor actinide load as mixture of thorium fuel matrix on
the core neutronics has been studied with comparing presence and
non-presence of minor actinide component in the fuel matrix.
Depletion rate of minor actinides in the MA-contained fuel has been
calculated using different power loads. According to the obtained
computational data, minor actinide loading in the modeled core
results in more negative reactivity coefficients. The MA-contained
fuel achieves less radial peaking factor in the modeled core. The
obtained computational results showed 140 kg of 464 kg initial load
of minor actinide has been depleted in during a 6-year burn up in 10
MW power.
Abstract: Liposome plays an important role in medical and
pharmaceutical science as e.g. nano scale drug carriers. Liposomes
are vesicles of varying size consisting of a spherical lipid bilayer and
an aqueous inner compartment. Magnet-driven liposome used for the
targeted delivery of drugs to organs and tissues. These liposome
preparations contain encapsulated drug components and finely
dispersed magnetic particles.
Liposomes are vesicles of varying size consisting of a spherical
lipid bilayer and an aqueous inner compartment that are generated in
vitro. These are useful in terms of biocompatibility, biodegradability,
and low toxicity, and can control biodistribution by changing the size,
lipid composition, and physical characteristics. Furthermore,
liposomes can entrap both hydrophobic and hydrophilic drugs and are
able to continuously release the entrapped substrate, thus being useful
drug carriers. Magnetic liposomes (MLs) are phospholipid vesicles
that encapsulate magneticor paramagnetic nanoparticles. They are
applied as contrast agents for magnetic resonance imaging (MRI).
The biological synthesis of nanoparticles using plant extracts plays
an important role in the field of nanotechnology. Green-synthesized
magnetite nanoparticles-protein hybrid has been produced by treating
Iron (III) / Iron (II) chloride with the leaf extract of Datura inoxia.
The phytochemicals present in the leaf extracts act as a reducing as
well stabilizing agents preventing agglomeration, which include
flavonoids, phenolic compounds, cardiac glycosides, proteins and
sugars.
The magnetite nanoparticles-protein hybrid has been trapped
inside the aqueous core of the liposome prepared by reversed phase
evaporation (REV) method using oleic and linoleic acid which has
been shown to be driven under magnetic field confirming the
formation magnetic liposome (ML). Chemical characterization of
stealth magnetic liposome has been performed by breaking the
liposome and release of magnetic nanoparticles. The presence iron
has been confirmed by colour complex formation with KSCN and
UV-Vis study using spectrophotometer Cary 60, Agilent.
This magnet driven liposome using nanoparticles-protein hybrid
can be a smart vesicles for the targeted drug delivery.
Abstract: The paper focus on robotic telepresence system build
around humanoid robot operated with controller-less Wizard of Oz
technique. Proposed solution gives possibility to quick start acting as
a operator with short, if any, initial training.
Abstract: In this research, waterglass based aerogel powder was
prepared by sol–gel process and ambient pressure drying. Inspired by
limited dust releasing, aerogel powder was introduced to the PET
electrospinning solution in an attempt to create required bulk and
surface structure for the nanofibers to improve their hydrophobic and
insulation properties. The samples evaluation was carried out by
measuring density, porosity, contact angle, heat transfer, FTIR, BET,
and SEM. According to the results, porous silica aerogel powder was
fabricated with mean pore diameter of 24 nm and contact angle of
145.9º. The results indicated the usefulness of the aerogel powder
confined into nanofibers to control surface roughness for
manipulating superhydrophobic nanowebs with water contact angle
of 147º. It can be due to a multi-scale surface roughness which was
created by nanowebs structure itself and nanofibers surface
irregularity in presence of the aerogels while a layer of fluorocarbon
created low surface energy. The wettability of a solid substrate is an
important property that is controlled by both the chemical
composition and geometry of the surface. Also, a decreasing trend in
the heat transfer was observed from 22% for the nanofibers without
any aerogel powder to 8% for the nanofibers with 4% aerogel
powder. The development of thermal insulating materials has become
increasingly more important than ever in view of the fossil energy
depletion and global warming that call for more demanding energysaving
practices.
Abstract: The computational fluid dynamics (CFD) study of
stirred tank with the air-water interface are carried out in the presence
of different types of the impeller and with or without baffles. A
multiple reference frame (MRF) approach with the volume of fluid
(VOF) method is used to capture the air-water interface. The RANS
(Reynolds Averaged Navier-Stokes) equations with k-ε turbulence
model are solved to predict the flow behavior of water and air phase
which are treated as a different phases. The predicted results have
shown that the VOF method is able to capture the interface in the
unbaffled tank. While, the VOF method is showing an unfeasible
results in the baffled tank with high rotational impeller speed. For
continuous stirred tank, the air-water interface is disturbed by the
inflow and the level of water is also increased with time.
Abstract: This paper investigates the joint effect of the
interconnected (n,k)-star network topology and Multi-Agent
automated control on restoration and reconfiguration of power
systems. With the increasing trend in development in Multi-Agent
control technologies applied to power system reconfiguration
in presence of faulty components or nodes. Fault tolerance is
becoming an important challenge in the design processes of the
distributed power system topology. Since the reconfiguration of a
power system is performed by agent communication, the (n,k)-star
interconnected network topology is studied and modeled in this
paper to optimize the process of power reconfiguration. In this paper,
we discuss the recently proposed (n,k)-star topology and examine its
properties and advantages as compared to the traditional multi-bus
power topologies. We design and simulate the topology model for
distributed power system test cases. A related lemma based on the
fault tolerance and conditional diagnosability properties is presented
and proved both theoretically and practically. The conclusion is
reached that (n,k)-star topology model has measurable advantages
compared to standard bus power systems while exhibiting fault
tolerance properties in power restoration, as well as showing
efficiency when applied to power system route discovery.
Abstract: The present study was conducted to evaluate the
potential applicability of biological trickling filter system for the
treatment of simulated textile wastewater containing reactive azo
dyes with bacterial consortium under non-sterile conditions. The
percentage decolorization for the treatment of wastewater containing
structurally different dyes was found to be higher than 95% in all
trials. The stable bacterial count of the biofilm on stone media of the
trickling filter during the treatment confirmed the presence,
proliferation, dominance and involvement of the added microbial
consortium in the treatment of textile wastewater. Results of
physicochemical parameters revealed the reduction in chemical
oxygen demand (58.5-75.1%), sulphates (18.9-36.5%), and
phosphates (63.6-73.0%). UV-Visible and FTIR spectroscopy
confirmed decolorization of dye containing wastewater was ultimate
consequence of biodegradation. Toxicological studies revealed the
nontoxic nature of degradative metabolites.
Abstract: In this work, a polyaniline/Iron oxide (PANI/Fe2O3)
composite was chemically prepared by oxidative polymerization of
aniline in acid medium, in presence of ammonium persulphate as an
oxidant and amount of Fe2O3. The composite was characterized by a
scanning electron microscopy (SEM). The prepared composite has
been used as adsorbent to remove Tartrazine dye form aqueous
solutions.
The effects of initial dye concentration and temperature on the
adsorption capacity of PANI/Fe2O3 for Tartrazine dye have been
studied in this paper.
The Langmuir and Freundlich adsorption models have been used
for the mathematical description of adsorption equilibrium data. The
best fit is obtained using the Freundlich isotherm with an R2 value of
0.998. The change of Gibbs energy, enthalpy, and entropy of
adsorption has been also evaluated for the adsorption of Tartrazine
onto PANI/ Fe2O3. It has been proved according the results that the
adsorption process is endothermic in nature.
Abstract: This paper proposes the designing direct adaptive
neural controller to apply for a class of a nonlinear pendulum
dynamic system. The radial basis function (RBF) neural adaptive
controller is robust in presence of external and internal uncertainties.
Both the effectiveness of the controller and robustness against
disturbances are importance of this paper. The simulation results
show the promising performance of the proposed controller.
Abstract: In this paper, the influence of upstream structures on the flow patternaround and inside the wind-catcher is experimentally investigated by smoke flow visualization techniques. Wind-catchers are an important part of natural ventilation in residential buildings or public places such as shopping centers, libraries, etc. Wind-catchers might be also used in places of high urban densities; hence their potential to provide natural ventilation is dependent on the presence of upstream structures. In this study, the two-sided wind-catcher model was based on a real wind-catcher observed in the city of Yazd, Iran. The present study focuses on the flow patterns around and inside the isolated two-sided wind-catcher, and on a two-sided wind-catcher in the presence of an upstream structure. The results show that the presence of an upstream structure influences the airflow pattern force and direction. Placing a high upstream structure reverses the airflow direction inside the wind-catcher.
Abstract: Marine Protected Areas can benefit from nature based
tourism, monitoring environmental impacts and also become target
for human presence. From more than 3 million tourists visiting
Cozumel Island every year, an average of 2,8 million arrive by cruise
ship, and 41% are estimated to have motivation for water activities.
The destination is relying so much on the tourism activity, that scuba
diving and snorkeling in the National Park Reef of Cozumel sustain
the major economic activity. In order to achieve the sustainable
development indicator designed for regional environmental
development, the PNAC offers a training course to tourism providers
to access the protected area. This way, the update of the last 5 years
of such training is directed to diving staff, boat crew and
professionals, making them able to assist in managing the natural
resource. Moreover, the case study is an example to be used for
raising awareness among tourists visiting protected areas.
Abstract: The influence of three different types of halloysite
nanotubes (HNTs) with different dimensions, namely as camel lake
(CLA), Jarrahdale (JA) and Matauri Bay (MB), on their reinforcing
ability of ethylene propylene dine monomer (EPDM) were
investigated by varying the HNTs loading (from 0-15 phr).
Mechanical properties of the nanocomposites improved with addition
of all three HNTs, but CLA based nanocomposites exhibited a
significant enhancement compared to the other HNTs. For instance,
tensile properties of EPDM nanocomposites increased by 120%,
256% and 340% for MB, JA and CLA, respectively, with addition of
15 phr of HNTs. This could be due to the higher aspect ratio and
higher surface area of CLA compared to others. Scanning electron
microscopy (SEM) of nanocomposites at 15 phr of HNT loadings
showed low amounts of pulled-out nanotubes which confirmed the
presence of more embedded nanotubes inside the EPDM matrix, as
well as aggregates within the fracture surface of EPDM/HNT
nanocomposites
Abstract: This work presents the result of investigations aimed
at determining the hardness of the welded Chromoly (A 4130) steel
plate of 2” thickness. Multi pass welding for the thick sections was
carried out and analyzed for the Chromoly alloy steel plates. The
study of hardness at the weld metal reveals that there is the presence
of different micro structure products which yields diverse properties.
The welding carried out using GMAW with ER70s-2 electrode.
Single V groove design was selected for the butt joint configuration.
The presence of hydrogen has been suppressed by selecting low
hydrogen electrode. Preheating of the plate prior to welding reduces
the cooling rate which also affects the weld metal microstructure. The
shielding gas composition used in this analysis is 80% Ar-20% CO2.
The experimental analysis gives the detailed study of the hardness of
the material.
Abstract: The biosynthesis of nanoparticles by microorganisms,
on the contrary to chemical synthesis, is an environmentally-friendly
process which has low energy requirements. In this investigation, we
used the microorganism Geobacillus wiegelii, strain GWE1, an
aerobic thermophile belonging to genus Geobacillus, isolated from a
drying oven. This microorganism has the ability to reduce selenite
evidenced by the change of color from colorless to red in the culture.
Elemental analysis and composition of the particles were verified
using transmission electron microscopy and energy-dispersive X-ray
analysis. The nanoparticles have a defined spherical shape and a
selenium elemental state. Previous experiments showed that the
presence of the whole microorganism for the reduction of selenite
was not necessary. The results strongly suggested that an intracellular
NADPH/NADH-dependent reductase mediates selenium
nanoparticles synthesis under aerobic conditions. The enzyme was
purified and identified by mass spectroscopy MALDI-TOF TOF
technique. The enzyme is a 1-pyrroline-5-carboxylate dehydrogenase.
Histograms of nanoparticles sizes were obtained. Size distribution
ranged from 40-160 nm, where 70% of nanoparticles have less than
100 nm in size. Spectroscopic analysis showed that the nanoparticles
are composed of elemental selenium. To analyse the effect of pH in
size and morphology of nanoparticles, the synthesis of them was
carried out at different pHs (4.0, 5.0, 6.0, 7.0, 8.0). For
thermostability studies samples were incubated at different
temperatures (60, 80 and 100 ºC) for 1 h and 3 h. The size of all
nanoparticles was less than 100 nm at pH 4.0; over 50% of
nanoparticles have less than 100 nm at pH 5.0; at pH 6.0 and 8.0 over
90% of nanoparticles have less than 100 nm in size. At neutral pH
(7.0) nanoparticles reach a size around 120 nm and only 20% of them
were less than 100 nm. When looking at temperature effect,
nanoparticles did not show a significant difference in size when they
were incubated between 0 and 3 h at 60 ºC. Meanwhile at 80 °C the
nanoparticles suspension lost its homogeneity. A change in size was
observed from 0 h of incubation at 80ºC, observing a size range
between 40-160 nm, with 20% of them over 100 nm. Meanwhile
after 3 h of incubation at size range changed to 60-180 nm with 50%
of them over 100 nm. At 100 °C the nanoparticles aggregate forming
nanorod structures. In conclusion, these results indicate that is
possible to modulate size and shape of biologically synthesized
nanoparticles by modulating pH and temperature.
Abstract: The presence of endocrine-disrupting compounds,
such as bisphenol A (BPA), in the environment can cause serious
health problems. However, there are controversial opinions. This
study investigated the reproductive, metabolic, oxidative and
immunologic-disrupting effects of bisphenol A in male rabbits.
Rabbits were divided into five groups. The first four rabbit groups
were administered oral BPA (1, 10, 50, or 100 mg/kg/day) for ten
weeks. The fifth group was administered corn oil as the vehicle. BPA
significantly decreased serum testosterone, estradiol and the free
androgen index (FAI) and significantly increased sex hormone
binding globulin (SHBG) compared with the placebo group. The
higher doses of BPA showed a significant decrease in follicular
stimulating hormone (FSH) and luteinizing hormone (LH). A
significant increase in blood glucose levels was identified in the BPA
groups. The non-significant difference in insulin levels is a novel
finding. The cumulative testicular toxicity of BPA was clearly
demonstrated by the dose-dependent decrease in absolute testes
weight, primary measures of semen quality and a significant increase
in testicular malonaldehyde (MDA). Moreover, BPA significantly
decreased total antioxidant capacity (TAC) and significantly
increased immunoglobulin G (IgG) at the highest concentration. Our
results suggest that BPA, especially at higher doses, is associated
with many adverse effects on metabolism, oxidative stress, immunity,
sperm quality and markers of androgenic action.
Abstract: Cement-based grouts has been used successfully to
repair cracks in many concrete structures such as bridges, tunnels,
buildings and to consolidate soils or rock foundations. In the present
study the rheological characterization of cement grout with
water/binder ratio (W/B) is fixed at 0.5. The effect of the replacement
of cement by bentonite (2 to 10% wt) in presence of superplasticizer
(0.5% wt) was investigated. Several rheological tests were carried out
by using controlled-stress rheometer equipped with vane geometry in
temperature of 20°C. To highlight the influence of bentonite and
superplasticizer on the rheological behavior of grout cement, various
flow tests in a range of shear rate from 0 to 200 s-1 were observed.
Cement grout showed a non-Newtonian viscosity behavior at all
concentrations of bentonite. Three parameter model Herschel-
Bulkley was chosen for fitting of experimental data. Based on the
values of correlation coefficients of the estimated parameters, The
Herschel-Bulkley law model well described the rheological behavior
of the grouts. Test results showed that the dosage of bentonite
increases the viscosity and yield stress of the system and introduces
more thixotropy. While the addition of both bentonite and
superplasticizer with cement grout improve significantly the fluidity
and reduced the yield stress due to the action of dispersion of SP.
Abstract: Natural gas, as one of the most important sources of
energy for many of the industrial and domestic users all over the
world, has a complex, huge supply chain which is in need of heavy
investments in all the phases of exploration, extraction, production,
transportation, storage and distribution. The main purpose of supply
chain is to meet customers’ need efficiently and with minimum cost.
In this study, with the aim of minimizing economic costs, different
levels of natural gas supply chain in the form of a multi-echelon,
multi-period fuzzy linear programming have been modeled. In this
model, different constraints including constraints on demand
satisfaction, capacity, input/output balance and presence/absence of a
path have been defined. The obtained results suggest efficiency of the
recommended model in optimal allocation and reduction of supply
chain costs.
Abstract: The aim of present study was to monitor the presence
of Trichodina sp. in Rainbow trout, Oncorhynchus mykiss collected
from various fish farms in the western provinces of Iran during
January, 2013- January, 2014. Out of 675 sampled fish 335, (49.16%)
were infested with Trichodina. The highest prevalence was observed
in the spring and winter followed by autumn and summer. In general,
the intensity of infection was low except in cases where outbreaks of
Trichodiniasis endangered the survival of fish in some ponds. In light
infestation Trichodina is usually present on gills, fins and skin of
apparently healthy fish. Clinical signs of Trichodiniasis only appear
on fish with heavy infections and cases of moderate ones that are
usually exposed to one or more stress factors including, rough
handling during transportation from ponds, overcrowdness,
malnutrition, high of free ammonia and low of oxygen concentration.
Clinical signs of Trichodiniasis in sampled fish were sluggish
movement, loss of appetite, black coloration, necrosis and ulcer on
different parts of the body, detached scales and excessive
accumulation of mucous in gill pouches. The most obvious
histopathological changes in diseased fish were sloughing of the
epidermal layer, aggregation of leucocytes and melanine-carrying
cells (between the dermis and hypodermis) and proliferative changes
including hyperplasia and hypertrophy of the epithelial lining cells of
gill filaments which resulted in fusion of secondary lamellae. Control
of Trichodiniasis, has been achieved by formalin bath treatment at a
concentration of 250 ppm for one hour.
Abstract: A study was conducted to determine the diversity and
abundance of shorebird species habituating the mudflat area of Jeram
Beach and Remis Beach, Selangor, Peninsular Malaysia. Direct
observation technique (using binoculars and video camera) was
applied to record the presence of bird species in the sampling sites
from August 2013 until July 2014. A total of 32 species of shorebird
were recorded during both migratory and non-migratory seasons. Of
these, eleven species (48%) are migrants, six species (26%) have both
migrant and resident populations, four species (17%) are vagrants and
two species (9%) are residents. The compositions of the birds
differed significantly in all months (χ2 = 84.35, p < 0.001). There is a
significant difference in avian abundance between migratory and
non-migratory seasons (Mann-Whitney, t = 2.39, p = 0.036). The
avian abundance were differed significantly in Jeram and Remis
Beaches during migratory periods (t = 4.39, p = 0.001) but not during
non-migratory periods (t = 0.78, p = 0.456). Shorebird diversity was
also affected by tidal cycle. There is a significance difference
between high tide and low tide (Mann-Whitney, t = 78.0, p < 0.005).
Frequency of disturbance also affected the shorebird distribution
(Mann-Whitney, t = 57.0, p = 0.0134). Therefore, this study
concluded that tides and disturbances are two factors that affecting
temporal distribution of shorebird in mudflats area.