The Role of Halloysite’s Surface Area and Aspect Ratio on Tensile Properties of Ethylene Propylene Diene Monomer Nanocomposites

The influence of three different types of halloysite
nanotubes (HNTs) with different dimensions, namely as camel lake
(CLA), Jarrahdale (JA) and Matauri Bay (MB), on their reinforcing
ability of ethylene propylene dine monomer (EPDM) were
investigated by varying the HNTs loading (from 0-15 phr).
Mechanical properties of the nanocomposites improved with addition
of all three HNTs, but CLA based nanocomposites exhibited a
significant enhancement compared to the other HNTs. For instance,
tensile properties of EPDM nanocomposites increased by 120%,
256% and 340% for MB, JA and CLA, respectively, with addition of
15 phr of HNTs. This could be due to the higher aspect ratio and
higher surface area of CLA compared to others. Scanning electron
microscopy (SEM) of nanocomposites at 15 phr of HNT loadings
showed low amounts of pulled-out nanotubes which confirmed the
presence of more embedded nanotubes inside the EPDM matrix, as
well as aggregates within the fracture surface of EPDM/HNT
nanocomposites





References:
[1] H. Ismail, P. Pasbakhsh, M. A. Fauzi, A. A. Bakar. Morphological,
thermal and tensile properties of halloysite nanotubes filled ethylene
propylene diene monomer (EPDM) nanocomposites. Polymer Testing.
27(7): 841–850, 2008.
[2] M. Du, B. Guo, D. Jia. Newly emerging applications of halloysite
nanotubes: a review. Polymer International. 59(5): 574-582, 2010.
[3] H. Zheng, Y. Zhang, Z. Peng, Y. Zhang. Influence of clay modification
on the structure and mechanical properties of EPDM/montmorillonite
nanocomposites. Polymer Testing. 23(2): 217-223, 2004.
[4] P. Pasbakhsh, J. Churchman, J. Keeling. Characterisation of properties
of various halloysites relevant to their use as nanotubes and microfibre
fillers. Applied Clay Science. 74: 47-57, 2013.
[5] X. Sun, Y. Zhang, H. Shen, N. Jia. Direct electrochemistry and
electrocatalysis of horseradish peroxidase based on halloysite
nanotubes/chitosan nanocomposite film. Electrochimica Acta. 56(2):
700-705, 2010.
[6] A. S. Deuri, A. K. Bhowmick. Aging of EPDM rubber. Journal of
Applied Polymer Science. 34(6):2205-2222, 1987.
[7] Y. –W. Chang, Y. Yang, S. Ryu, C. Nah. Preparation and properties of
EPDM/organomontmorillonite hybrid nanocomposites. Polymer
International. 51(4):319-324, 2002.