Abstract: Industries produce millions of cubic meters of effluent
every year and the wastewater produced may be released into the
surrounding water bodies, treated on-site or at municipal treatment
plants. The determination of organic matter in the wastewater
generated is very important to avoid any negative effect on the
aquatic ecosystem. The scope of the present work is to assess the
physicochemical composition of the wastewater produced from one
of the brewery industry in South Africa. This is to estimate the
environmental impact of its discharge into the receiving water bodies
or the municipal treatment plant. The parameters monitored for the
quantitative analysis of brewery wastewater include biological
oxygen demand (BOD5), chemical oxygen demand (COD), total
suspended solids, volatile suspended solids, ammonia, total oxidized
nitrogen, nitrate, nitrite, phosphorus and alkalinity content. In
average, the COD concentration of the brewery effluent was 5340.97
mg/l with average pH values of 4.0 to 6.7. The BOD5 and the solids
content of the wastewater from the brewery industry were high. This
means that the effluent is very rich in organic content and its
discharge into the water bodies or the municipal treatment plant could
cause environmental pollution or damage the treatment plant. In
addition, there were variations in the wastewater composition
throughout the monitoring period. This might be as a result of
different activities that take place during the production process, as
well as the effects of peak period of beer production on the water
usage.
Abstract: Grains, including oats (Avena sativa L.), have been
recognized functional foods, because provide beneficial effect on the
health of the consumer and decrease the risk of various diseases. Oats
are good source of soluble fibre, essential amino acids, unsaturated
fatty acids, vitamins and minerals. Oat breeders have developed oat
varieties and improved yielding ability potential of oat varieties.
Therefore, the aim of investigation was to analyze the composition of
perspective oat varieties and breeding lines grains grown in different
conditions and evaluate functional properties. In the studied samples
content of protein, starch, β-glucans, total dietetic fibre, composition
of amino acids and vitamin E were determined. The results of
analysis showed that protein content depending of varieties ranged
9.70% to 17.30% total dietary fibre 13.66 g100g-1 to 30.17 g100g-1,
content of β-glucans 2.7 g100g-1 to 3.5 g100g-1, amount of
vitamin E (α-tocopherol) determined from 4 mgkg-1 to 9.9 mgkg-1.
The sums of essential amino acids in oat grain samples were
determined from 31.63 gkg-1 to 54.90 gkg-1. It is concluded that
amino acids composition of husked and naked oats grown in organic
or conventional conditions is close to optimal for human health.
Abstract: Crops diversity and maintaining and enhancing the
fertility of agricultural lands are basic principles of organic farming.
With a wider range of crops in agroecosystem can improve the ability
to control weeds, pests and diseases, and the performance of crops
rotation and food safety. In this sense, the main objective of the
research was to study the productivity and chemical composition of
some alternative crops and their adaptability to soil and climatic
conditions of the agricultural area in Southern Romania and to
cultivation in the organic farming system. The alternative crops were:
lentil (7 genotypes); five species of grain legumes (5 genotypes); four
species of oil crops (5 genotypes). The seed production was, on
average: 1343 kg/ha of lentil; 2500 kg/ha of field beans; 2400 kg/ha
of chick peas and blackeyed peas; more than 2000 kg/ha of atzuki
beans, over 1250 kg/ha of fenugreek; 2200 kg/ha of safflower; 570
kg/ha of oil pumpkin; 2150 kg/ha of oil flax; 1518 kg/ha of camelina.
Regarding chemical composition, lentil seeds contained: 22.18%
proteins, 3.03% lipids, 33.29% glucides, 4.00% minerals, and 259.97
kcal energy values. For field beans: 21.50% proteins, 4.40% lipids,
63.90% glucides, 5.85% minerals, 395.36 kcal energetic value. For
chick peas: 21.23% proteins, 4.55% lipids, 53.00% glucides, 3.67%
minerals, 348.22 kcal energetic value. For blackeyed peas: 23.30%
proteins, 2.10% lipids, 68.10% glucides, 3.93% minerals, 350.14 kcal
energetic value. For adzuki beans: 21.90% proteins, 2.60% lipids,
69.30% glucides, 4.10% minerals, 402.48 kcal energetic value. For
fenugreek: 21.30% proteins, 4.65% lipids, 63.83% glucides, 5.69%
minerals, 396.54 kcal energetic value. For safflower: 12.60%
proteins, 28.37% lipids, 46.41% glucides, 3.60% minerals, 505.78
kcal energetic value. For camelina: 20.29% proteins, 31.68% lipids,
36.28% glucides, 4.29% minerals, 526.63 kcal energetic value. For
oil pumpkin: 29.50% proteins, 36.92% lipids, 18.50% glucides,
5.41% minerals, 540.15 kcal energetic value. For oil flax: 22.56%
proteins, 34.10% lipids, 27.73% glucides, 5.25% minerals, 558.45
kcal energetic value.
Abstract: Typical load-bearing biological materials like bone,
mineralized tendon and shell, are biocomposites made from both
organic (collagen) and inorganic (biomineral) materials. This
amazing class of materials with intrinsic internally designed
hierarchical structures show superior mechanical properties with
regard to their weak components from which they are formed.
Extensive investigations concentrating on static loading conditions
have been done to study the biological materials failure. However,
most of the damage and failure mechanisms in load-bearing
biological materials will occur whenever their structures are exposed
to dynamic loading conditions. The main question needed to be
answered here is: What is the relation between the layout and
architecture of the load-bearing biological materials and their
dynamic behavior? In this work, a staggered model has been
developed based on the structure of natural materials at nanoscale and
Finite Element Analysis (FEA) has been used to study the dynamic
behavior of the structure of load-bearing biological materials to
answer why the staggered arrangement has been selected by nature to
make the nanocomposite structure of most of the biological materials.
The results showed that the staggered structures will efficiently
attenuate the stress wave rather than the layered structure.
Furthermore, such staggered architecture is effectively in charge of
utilizing the capacity of the biostructure to resist both normal and
shear loads. In this work, the geometrical parameters of the model
like the thickness and aspect ratio of the mineral inclusions selected
from the typical range of the experimentally observed feature sizes
and layout dimensions of the biological materials such as bone and
mineralized tendon. Furthermore, the numerical results validated with
existing theoretical solutions. Findings of the present work emphasize
on the significant effects of dynamic behavior on the natural
evolution of load-bearing biological materials and can help scientists
to design bioinspired materials in the laboratories.
Abstract: Distillery spentwash contains high chemical oxygen
demand (COD), biological oxygen demand (BOD), color, total
dissolved solids (TDS) and other contaminants even after biological
treatment. The effluent can’t be discharged as such in the surface
water bodies or land without further treatment. Reverse osmosis (RO)
treatment plants have been installed in many of the distilleries at
tertiary level in many of the distilleries in India, but are not properly
working due to fouling problem which is caused by the presence of
high concentration of organic matter and other contaminants in
biologically treated spentwash. In order to make the membrane
treatment a proven and reliable technology, proper pre-treatment is
mandatory. In the present study, ultra-filtration (UF) for pretreatment
of RO at tertiary stage has been performed. Operating
parameters namely initial pH (pHo: 2–10), trans-membrane pressure
(TMP: 4-20 bars) and temperature (T: 15-43°C) were used for
conducting experiments with UF system. Experiments were
optimized at different operating parameters in terms of COD, color,
TDS and TOC removal by using response surface methodology
(RSM) with central composite design. The results showed that
removal of COD, color and TDS was 62%, 93.5% and 75.5%
respectively, with UF, at optimized conditions with increased
permeate flux from 17.5 l/m2/h (RO) to 38 l/m2/h (UF-RO). The
performance of the RO system was greatly improved both in term of
pollutant removal as well as water recovery.
Abstract: In recent research copper and manganese systems
were found to be the most active in CO and organic compounds
oxidation among the base catalysts. The mixed copper manganese
oxide has been widely studied in oxidation reactions because of their
higher activity at low temperatures in comparison with single oxide
catalysts. The results showed that the formation of spinel
CuxMn3−xO4 in the oxidized catalyst is responsible for the activity
even at room temperature. That is why the most of the investigations
are focused on the hopcalite catalyst (CuMn2O4) as the best coppermanganese
catalyst. Now it’s known that this is true only for CO
oxidation, but not for mixture of CO and VOCs. The purpose of this
study is to investigate the alumina supported copper-manganese
catalysts with different Cu/Mn molar ratio in terms of oxidation of
CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of γ-Al2O3 with
copper and manganese nitrates and the catalytic activity
measurements were carried out in two stage continuous flow
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions closest possible to the industrial. Gas
mixtures on the input and output of the reactor were analyzed with a
gas chromatograph, equipped with FID and TCD detectors. The
texture characteristics were determined by low-temperature (- 196oС)
nitrogen adsorption in a Quantachrome Instruments NOVA 1200e
(USA) specific surface area & pore analyzer. Thermal, XRD and
TPR analyses were performed. It was established that the active component of the mixed Cu-
Mn/γ–alumina catalysts strongly depends on the Cu/Mn molar ratio.
Highly active alumina supported Cu-Mn catalysts for CO, methanol
and DME oxidation were synthesized. While the hopcalite is the best
catalyst for CO oxidation, the best compromise for simultaneous
oxidation of all components is the catalyst with Cu/Mn molar ratio
1:5.
Abstract: Present work deals with the possible use of fertigation
in agriculture and its impact on the availability of mineral nitrogen
(Nmin) in topsoil and subsoil horizons. The aim of the present study is
to demonstrate the effect of the organic matter presence in fertigation
on microbial transformation and availability of mineral nitrogen
forms. The main investigation reason is the potential use of pretreated
waste water, as a source of organic carbon (Corg) and residual
nutrients (Nmin) for fertigation. Laboratory experiment has been
conducted to demonstrate the effect of the arable land fertilization
method on the Nmin availability in different depths of the soil with
the usage of model experimental containers filled with soil from
topsoil and podsoil horizons that were taken from the precise area.
Tufted hairgrass (Deschampsia caespitosa) has been chosen as a
model plant. The water source protection zone Brezova nad Svitavou
has been a research area where significant underground reservoirs of
drinking water of the highest quality are located. From the second
half of the last century local sources of drinking water show
nitrogenous compounds increase that get here almost only from
arable lands. Therefore, an attention of the following text focuses on
the fate of mineral nitrogen in the complex plant-soil. Research
results show that the fertigation application with Corg in a
combination with mineral fertilizer can reduce the amount of Nmin
leached from topsoil horizon of agricultural soils. In addition, some
plants biomass production reduces may occur.
Abstract: The growth of organic farming practices in the last
few decades is continuing to stimulate the international debate about
this alternative food market. As a part of a PhD project research
about embeddedness in Alternative Food Networks (AFNs), this
paper focuses on the promotional aspects of organic farms websites
from the Madrid region. As a theoretical tool, some knowledge
categories drawn on the geographic studies literature are used to
classify the many ideas expressed in the web pages. By analysing
texts and pictures of 30 websites, the study aims to question how and
to what extent actors from organic world communicate to the
potential customers their personal beliefs about farming practices,
products qualities, and ecological and social benefits. Moreover, the
paper raises the question of whether organic farming laws and
regulations lack of completeness about the social and cultural aspects
of food.
Abstract: This work studies the effect of chemical composition
on the activity and selectivity of γ–alumina supported CuO/
MnO2/Cr2O3 catalysts toward deep oxidation of CO, dimethyl ether
(DME) and methanol. The catalysts were prepared by impregnation
of the support with an aqueous solution of copper nitrate, manganese
nitrate and CrO3 under different conditions. Thermal, XRD and TPR
analysis were performed. The catalytic measurements of single
compounds oxidation were carried out on continuous flow equipment
with a four-channel isothermal stainless steel reactor. Flow-line
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions that mimic closely the industrial
ones was used. The reactant and product gases were analyzed by
means of on-line gas chromatographs.
On the basis of XRD analysis it can be concluded that the active
component of the mixed Cu-Mn-Cr/γ–alumina catalysts consists of at
least six compounds – CuO, Cr2O3, MnO2, Cu1.5Mn1.5O4,
Cu1.5Cr1.5O4 and CuCr2O4, depending on the Cu/Mn/Cr molar ratio.
Chemical composition strongly influences catalytic properties, this
influence being quite variable with regards to the different processes.
The rate of CO oxidation rapidly decrease with increasing of
chromium content in the active component while for the DME was
observed the reverse trend. It was concluded that the best
compromise are the catalysts with Cu/(Mn + Cr) molar ratio 1:5 and
Mn/Cr molar ratio from 1:3 to 1:4.
Abstract: Currently, continuous two-phase decanter process
used for olive oil production is the more internationally widespread.
The wastewaters generated from this industry (OMW) are a real
environmental problem because of its high organic load. Among
proposed treatments for these wastewaters, advanced oxidation
technologies (Fenton, ozone, photoFenton, etc.) are the most
favourable. The direct application of these processes is somewhat
expensive. Therefore, the application of a previous stage based on a
flocculation-sedimentation operation is of high importance. In this
research five commercial flocculants (three cationic, and two anionic)
have been used to achieve the separation of phases (liquid clarifiedsludge).
For each flocculant, different concentrations (0-1000 mg/L)
have been studied. In these experiments, sludge volume formed and
the final water quality were determined. The final removal
percentages of total phenols (11.3-25.1%), COD (5.6-20.4%), total
carbon (2.3-26.5%), total organic carbon (1.50-23.8%), total nitrogen
(1.45-24.8%), and turbidity (27.9-61.4%) were determined. The
variation on electric conductivity reduction percentage (1-8%) was
also determined. Finally, the best flocculants with highest removal
percentages have been determined (QG2001 and Flocudex CS49).
Abstract: This paper represents the results of experimental work to investigate the suitability of a waste material (WM) for soft soil stabilisation. In addition, the effect of particle size distribution (PSD) of the waste material on its performance as a soil stabiliser was investigated. The WM used in this study is produced from the incineration processes in domestic energy power plant and it is available in two different grades of fineness (coarse waste material (CWM) and fine waste material (FWM)). An intermediate plasticity silty clayey soil with medium organic matter content has been used in this study. The suitability of the CWM and FWM to improve the physical and engineering properties of the selected soil was evaluated dependant on the results obtained from the consistency limits, compaction characteristics (optimum moisture content (OMC) and maximum dry density (MDD)); along with the unconfined compressive strength test (UCS). Different percentages of CWM were added to the soft soil (3, 6, 9, 12 and 15%) to produce various admixtures. Then the UCS test was carried out on specimens under different curing periods (zero, 7, 14, and 28 days) to find the optimum percentage of CWM. The optimum and other two percentages (either side of the optimum content) were used for FWM to evaluate the effect of the fineness of the WM on UCS of the stabilised soil. Results indicated that both types of the WM used in this study improved the physical properties of the soft soil where the index of plasticity (IP) was decreased significantly. IP was decreased from 21 to 13.64 and 13.10 with 12% of CWM and 15% of FWM respectively. The results of the unconfined compressive strength test indicated that 12% of CWM was the optimum and this percentage developed the UCS value from 202kPa to 500kPa for 28 days cured samples, which is equal, approximately 2.5 times the UCS value for untreated soil. Moreover, this percentage provided 1.4 times the value of UCS for stabilized soil-CWA by using FWM which recorded just under 700kPa after 28 days curing.
Abstract: For this study, a town based soil database created in
Gümüsçay District of Biga Town, Çanakkale, Turkey. Crop and
livestock production are major activities in the district. Nutrient
management is mainly based on commercial fertilizer application
ignoring the livestock manure. Within the boundaries of district, 122
soil sampling points determined over the satellite image. Soil samples
collected from the determined points with the help of handheld
Global Positioning System. Labeled samples were sent to a
commercial laboratory to determine 11 soil parameters including
salinity, pH, lime, organic matter, nitrogen, phosphorus, potassium,
iron, manganese, copper and zinc. Based on the test results soil maps
for mentioned parameters were developed using remote sensing, GIS,
and geostatistical analysis. In this study we developed a GIS database
that will be used for soil nutrient management. Methods were
explained and soil maps and their interpretations were summarized in
the study.
Abstract: Nowadays, the main goal for modern horticultural
production is an increase the quality. In recent years, the use of
organic fertilizers or biostimulants that can be applied in agriculture
to improve quali-quantitative crop yields has encountered increasing
interest. Biostimulants are gaining importance also for their possible
use in organic and sustainable agriculture, to avoid excessive
fertilizer applications. Consecutive experimental trials were carried
out in the Apulia region (southern Italy) on three herbaceous crops
(cauliflower, pepper, fennel) grown in pots under conventional and
organic fertilization systems without and with biostimulants. The aim
was to determine the effects of three biostimulants (Siapton®10L,
Micotech L, Lysodin Alga-Fert) on quali-quantitative yield
characteristics. At harvest, the quali-quantitative yield characteristics
of each crop were determined. All of the experimental data were
subjected to analysis of variance (ANOVA), and when significant
effects were detected, the means were compared using Tukey’s tests.
These data show large differences in these yield characteristics
between conventional and organic crops, particularly highlighting
higher yields for the conventional crops, while variable results were
generally observed when the biostimulants were applied. In this
context, there were no effects of the biostimulants on the quantitative
yield, whereas there were low positive effects on the qualitative
characteristics, as related to higher dry matter content of cauliflower,
and higher soluble solids content of pepper. Moreover, there were
evident positive effects of the biostimulants with fennel, due to the
lower nitrate content. These latter data are in line with most of the
published literature obtained for other herbaceous crops.
Abstract: Atmospheric carbon dioxide emissions are considered
as the greatest environmental challenge the world is facing today.
The tasks to control the emissions include the recovery of CO2 from
flue gas. This concern has been improved due to recent advances in
materials process engineering resulting in the development of
inorganic gas separation membranes with excellent thermal and
mechanical stability required for most gas separations. This paper,
therefore, evaluates the performance of a highly selective inorganic
membrane for CO2 recovery applications. Analysis of results
obtained is in agreement with experimental literature data. Further
results show the prediction performance of the membranes for gas
separation and the future direction of research. The materials
selection and the membrane preparation techniques are discussed.
Method of improving the interface defects in the membrane and its
effect on the separation performance has also been reviewed and in
addition advances to totally exploit the potential usage of this
innovative membrane.
Abstract: Extracting and determining chlorophyll pigments
(chlorophyll a and b) in green leaves are the procedures based on the
solvent extraction of pigments in samples using N,Ndimethylformamide
as the extractant. In this study, two species of
soluble inorganic selenium forms, selenite (SeIV) and selenate (SeVI)
at different concentrations were investigated on maize plants that
were growing in nutrient solutions during 2 weeks and at the end of
the experiment, amounts of chlorophyll a and b for first and second
leaves of maize were measured. In accordance with the results we
observed that our regarded Se concentrations in both forms of SeIV
and SeVI were not effective on maize plants’ chlorophyll a and b
significantly although high level of 3 mg.kg-1 SeIV had negative affect
on growth of the samples that had been treated by it but about SeVI
samples we did not observe this state and our different considered
SeVI concentrations were not toxic for maize plants.
Abstract: The separation of Hg (II) from produced water by
hollow fiber contactors (HFC) was investigation. This system
included of two hollow fiber modules in the series connecting. The
first module used for the extraction reaction and the second module
for stripping reaction. Aliquat336 extractant was fed from the organic
reservoirs into the shell side of the first hollow fiber module and
continuous to the shell side of the second module. The organic liquid
was continuously feed recirculate and back to the reservoirs. The feed
solution was pumped into the lumen (tube side) of the first hollow
fiber module. Simultaneously, the stripping solution was pumped in
the same way in tube side of the second module. The feed and
stripping solution was fed which had a countercurrent flow. Samples
were kept in the outlet of feed and stripping solution at 1 hour and
characterized concentration of Hg (II) by Inductively Couple Plasma
Atomic Emission Spectroscopy (ICP-AES). Feed solution was
produced water from natural gulf of Thailand. The extractant was
Aliquat336 dissolved in kerosene diluent. Stripping solution used was
nitric acid (HNO3) and thiourea (NH2CSNH2). The effect of carrier
concentration and type of stripping solution were investigated.
Results showed that the best condition were 10 % (v/v) Aliquat336
and 1.0 M NH2CSNH2. At the optimum condition, the extraction and
stripping of Hg (II) were 98% and 44.2%, respectively.
Abstract: The article presents a plasma chemical technology for
processing solid fuels, using examples of bituminous and brown
coals. Thermodynamic and experimental investigation of the
technology was made. The technology allows producing synthesis
gas from the coal organic mass and valuable components (technical
silicon, ferrosilicon, aluminum, and carbon silicon, as well as
microelements of rare metals, such as uranium, molybdenum,
vanadium, etc.) from the mineral mass. The thusly produced highcalorific
synthesis gas can be used for synthesis of methanol, as a
high-calorific reducing gas instead of blast-furnace coke as well as
power gas for thermal power plants.
Abstract: A field study was conducted to evaluate the efficacy of
safflower plant for phytoremediation of contaminated soils. The
experiment was performed on an agricultural fields contaminated by
the Non-Ferrous-Metal Works near Plovdiv, Bulgaria. Field
experiments with randomized complete block design with five
treatments (control, compost amendments added at 20 and 40 t/daa,
and vermicompost amendments added at 20 and 40 t/daa) were
carried out. The quality of safflower seeds and oil (heavy metals and
fatty acid composition) were determined. Tested organic amendments
significantly influenced the chemical composition of safflower seeds
and oil. The compost and vermicompost treatments significantly
reduced heavy metals concentration in safflower seeds and oils, but
the effect differed among them. Addition of vermicompost and
compost leads to an increase in the content of palmitic acid and
linoleic acid, and a decrease in the stearic and oleic acids compared
with the control. A significant increase in the quantity of saturated
acids was observed in the variants with 20 t/daa of compost and 20
t/daa of vermicompost (9.1 and 8.9% relative to the control).
Safflower is a plant which is tolerant to heavy metals and can be
successfully used in the phytoremediation of heavy metal
contaminated soils. The processing of seeds to oil and using the
obtained oil for nutritional purposes will greatly reduce the cost of
phytoremediation.
Abstract: In this work, two fermentations at different
temperatures (25 and 30ºC), with cell recycling, were accomplished
to produce ethanol, using a mix of commercial substrates, xylose
(70%) and glucose (30%), as organic source for Scheffersomyces
stipitis. Five consecutive fermentations of 80 g L-1 (1º, 2º and 3º
recycles), 96 g L-1 (4º recycle) and 120 g L-1 (5º recycle)reduced
sugars led to a final maximum ethanol concentration of 17.2 and 34.5
g L-1, at 25 and 30ºC, respectively. Glucose was the preferred
substrate; moreover xylose startup degradation was initiated after a
remaining glucose presence in the medium. Results showed that yeast
acid treatment, performed before each cycle, provided improvements
on cell viability, accompanied by ethanol productivity of 2.16 g L-1 h-
1 at 30ºC. A maximum 36% of xylose was retained in the
fermentation medium and after five-cycle fermentation an ethanol
yield of 0.43 g ethanol/g sugars was observed. S. stipitis fermentation
capacity and tolerance showed better results at 30ºC with 83.4% of
theoretical yield referenced on initial biomass.
Abstract: Pt/γ-Al2O3 membrane catalysts were prepared via an
evaporative-crystallization deposition method. The obtained Pt/γ-
Al2O3 catalyst activity was tested after characterization (SEM-EDAX
observation, BET measurement, permeability assessment) in the
catalytic oxidation of selected volatile organic compound (VOC) i.e.
propane, fed in mixture of oxygen. The VOC conversion (nearly
90%) obtained by varying the operating temperature showed that
flow-through membrane reactor might do better in the abatement of
VOCs.