Abstract: In situ modified cyclohexanone-formaldehyde resins
were prepared by addition of alendronic acid during resin
preparation. Clay nanocomposites in ketonic resins were achieved by
adding clay into the flask at the beginning of the resin preparation.
The prepared resins were used for the synthesis of fire resistant
polyurethanes foam. Both phosphorous containing modifier
compound alendronic acid and nanoclay increases fire resistance of
the cyclohexanone-formaldehyde resin thus polyurethane produced
from these resins. The effect of the concentrations of alendronic acid
and clay on the fire resistance and physical properties of
polyurethanes was studied.
Abstract: The purpose of this paper is to examine gas transport
behavior of mixed matrix membranes (MMMs) combined with
porous particles. Main existing models are categorized in two main
groups; two-phase (ideal contact) and three-phase (non-ideal contact).
A new coefficient, J, was obtained to express equations for estimating
effect of the particle porosity in two-phase and three-phase models.
Modified models evaluates with existing models and experimental
data using Matlab software. Comparison of gas permeability of
proposed modified models with existing models in different MMMs
shows a better prediction of gas permeability in MMMs.
Abstract: Adsorption of a boron nitride nanotube (BNNT) was
examined toward ethylacetylene (C4H6) molecule by using density
functional theory (DFT) calculations at the B3LYP/6-31G (d) level,
and it was found that the adsorption energy (Ead) of ethylacetylene
the pristine nanotubes is about -1.60kcal/mol. But when nanotube has
been doped with Si and Al atoms, the adsorption energy of
ethylacetylene molecule was increased. Calculation showed that
when the nanotube is doping by Al, the adsorption energy is about -
24.19kcal/mol and also the amount of HOMO/LUMO energy gap
(Eg) will reduce significantly. Boron nitride nanotube is a suitable
adsorbent for ethylacetylene and can be used in separation processes
ethylacetylene. It is seem that nanotube (BNNT) is a suitable
semiconductor after doping, and the doped BNNT in the presence of
ethylacetylene an electrical signal is generating directly and therefore
can potentially be used for ethylacetylene sensors.
Abstract: This study presents synthesis of novel block
copolymers of thienyl end capped ethoxylated nonyl phenol and
pyrrole via chemical oxidative polymerization. Ethoxylated nonyl
phenol (ENP) was reacted with 2-thiophenecarbonyl chloride in order
to synthesize a macromonomer containing thienyl end-group (ENPThC).
Then copolymers of ENP-ThC and pyrrole were synthesized
by chemical oxidative polymerization using iron (III) chloride as an
oxidant. ENP-ThC served both as a macromonomer and an emulsifier
for pyrrole with poor solubility in water.
The synthesized block copolymers (ENP-ThC-b-PPy) were
characterized by spectroscopic analysis and the electrical
conductivities were investigated with 4-point probe technique.
Abstract: Food is widely packaged with plastic materials to
prevent microbial contamination and spoilage. Ionizing radiation is
widely used to sterilize the food-packaging materials. Sterilization by
γ-radiation causes degradation such as embrittlement, stiffening,
softening, discoloration, odour generation, and decrease in molecular
weight. Many antioxidants can prevent γ-degradation but most of
them are toxic. The migration of antioxidants to its environment
gives rise to major concerns in case of food packaging plastics. In
this attempt, we have aimed to utilize synergistic mixtures of
stabilizers which are approved for food-contact applications.
Ethylene-propylene-diene terpolymer has been melt-mixed with
hindered amine stabilizers (HAS), phenolic antioxidants and organophosphites
(hydroperoxide decomposer). Results were discussed by
comparing the stabilizing efficiency of mixtures with and without
phenol system. Among phenol containing systems where we mostly
observed discoloration due to the oxidation of hindered phenol, the
combination of secondary HAS, tertiary HAS, organo-phosphite and
hindered phenol exhibited improved stabilization efficiency than
single or binary additive systems. The mixture of secondary HAS and
tertiary HAS, has shown antagonistic effect of stabilization.
However, the combination of organo-phosphite with secondary HAS,
tertiary HAS and phenol antioxidants have been found to give
synergistic even at higher doses of Gamma-irradiation. The effects
have been explained through the interaction between the stabilizers.
After γ-irradiation, the consumption of oligomeric stabilizer
significantly depends on the components of stabilization mixture. The
effect of the organo-phosphite antioxidant on the overall stability has
been discussed.
Abstract: Anthocyanins are natural pigments with effective UV
protection but their topical use could be limited due to their
physicochemical characteristics. An attempt to overcome such
limitations by complexation of 2 major anthocyanin-rich sources, C.
ternatea and Z. mays, has potentiated its use as topical antiinflammatory.
Cell studies indicate no cytotoxicity of the
anthocyanin complex (AC) up to 1 mg/ml tested in HaCaT and
human fore head fibroblasts by MTT. Croton oil-induced ear edema
in Wistar rats suggests an effective dose of 5 mg/cm2 of AC as a
topical anti-inflammatory in comparison to 0.5 mg/cm2 of
fluocinolone acetonide. Niosomal encapsulation of the AC
significantly prolonged the anti-inflammatory activity particularly at
8 h after topical application (p = 0.0001). The AC was not cytotoxic
and its anti-inflammatory and activity was dose-dependent and
prolonged by niosomal encapsulation. It has also shown to promote
collagen type 1 production in cell culture. Thus, AC could be a
potential candidate for topical anti-inflammatory agent from natural
resources.
Abstract: Complexation of anthocyanins to mimic natural
copigmentation process was investigated. Cyanidin-rich extracts from
Zea mays L. ceritina Kulesh. and delphinidin-rich extracts from
Clitoria ternatea L. were used to form 4 anthocyanin complexes,
AC1, AC2, AC3 and AC4, in the presence of several polyphenols and
a trace metal. Characterizations of the ACs were conducted by UV,
FTIR, DSC/TGA and morphological observations. Bathochromic
shifts of the UV spectra of 4 formulas of ACs were observed at peak
wavelengths of about 510-620 nm by 10 nm suggesting complex
formation. FTIR spectra of the ACs indicate shifts of peaks from
1,733 cm-1 to 1,696 cm-1 indicating interactions and a decrease in the
peak areas within the wavenumber of 3,400-3,500 cm-1 indicating
changes in hydrogen bonding. Thermal analysis of all of the ACs
suggests increases in melting temperature after complexation. AC
with the highest melting temperature was morphologically observed
by SEM and TEM to be crystal-like particles within a range of 50 to
200 nm. Particle size analysis of the AC by laser diffraction gave a
range of 50-600 nm, indicating aggregation. This AC was shown to
have no cytotoxic effect on cultured HGEPp0.5 and HGF (all p>
0.05) by MTT. Therefore, complexation of anthocyanins was simple
and self-assembly process, potentially resulting in nanosized particles
of anthocyanin complex.
Abstract: Pipe failure and leakage is a problematic issue and the
traditional solution of replacing the pipes is costly and time
consuming. Rehabilitation by relining materials based on polymer
composites is an alternative solution towards the degradation problem
of the old piping. This paper provides a brief summary of advances in
technology, methods and materials for relining as well as a summary
of the degradation analyses of the two main composite materials used
for relining, rubber filled epoxy and reinforced polyester baltoflake
when they are exposed in deionized water and elevated temperature
up to 80°C for a duration of 2-14 months in the laboratory.
Abstract: The aim of this work was to apply extractive
distillation for acetonitrile removal from water solutions, to validate
thermodynamic criterion based on excess Gibbs energy to entrainer
selection process for acetonitrile – water mixture separation and show
its potential efficiency at isothermal conditions as well as at isobaric
(conditions of real distillation process), to simulate and analyze an
extractive distillation process with chosen entrainers: optimize
amount of trays and feeds, entrainer/original mixture and reflux
ratios. Equimolar composition of the feed stream was chosen for the
process, comparison of the energy consumptions was carried out.
Glycerol was suggested as the most energetically and ecologically
suitable entrainer.
Abstract: An environmentally benign protocol for the one-pot,
three-component synthesis of Triazolo[1,2-a]indazole-1,3,8-trione
derivatives by condensation of dimedone, urazole and aromatic
aldehydes catalyzed by HClO4/SiO2 NPS as an ecofriendly catalyst
with high catalytic activity and reusability at 100ºC under solventfree
conditions is reported. The reaction proceeds to completion
within 20-30 min in 77-86% yield.
Abstract: Some regularities of formation of a new structural
state of the thermoplastic polymers - gradually oriented (stretched)
state (GOS) are discussed. Transition into GOS is realized by the
graded oriented stretching - by action of inhomogeneous mechanical
field on the isotropic linear polymers or by zone stretching that is
implemented on a standard tensile-testing machine with using a
specially designed zone stretching device (ZSD). Both technical
approaches (especially zone stretching method) allows to manage the
such quantitative parameters of gradually oriented polymers as a
range of change in relative elongation/orientation degree, length of
this change and profile (linear, hyperbolic, parabolic, logarithmic,
etc.). The possibility of obtaining functionally graded materials
(FGMs) by graded orientation method is briefly discussed. Uniaxial
graded stretching method should be considered as an effective
technological solution to create polymer materials with a
predetermined gradient of physical properties.
Abstract: A new method for determining the distribution of
birefringence and linear dichroism in optical polymer materials is
presented. The method is based on the use of polarizationholographic
diffraction grating that forms an orthogonal circular basis
in the process of diffraction of probing laser beam on the grating. The
intensities ratio of the orders of diffraction on this grating enables the
value of birefringence and linear dichroism in the sample to be
determined. The distribution of birefringence in the sample is
determined by scanning with a circularly polarized beam with a
wavelength far from the absorption band of the material. If the
scanning is carried out by probing beam with the wavelength near to
a maximum of the absorption band of the chromophore then the
distribution of linear dichroism can be determined. An appropriate
theoretical model of this method is presented. A laboratory setup was
created for the proposed method. An optical scheme of the laboratory
setup is presented. The results of measurement in polymer films with
two-dimensional gradient distribution of birefringence and linear
dichroism are discussed.
Abstract: Water contamination by toxic compound is one of the serious environmental problems today. These toxic compounds mostly originated from industrial effluents, agriculture, natural sources and human waste. These studies focus on modification of multiwalled carbon nanotube (MWCNTs) with nanoparticle of calixarene and explore the possibility of using this modification for the remediation of cadmium in water. The nanocomposites were prepared by dissolving calixarene in chloroform solution as solvent, followed by additional multiwalled carbon nanotube (MWCNTs) then sonication process for 3 hour and fabricated the nanocomposites on substrate by spin coating method. Finally, the nanocomposites were tested on cadmium ion (10 mg/ml). The morphology of nanocomposites was investigated by FESEM showing the formation of calixarene on the outer walls of carbon nanotube and cadmium ion also clearly seen from the micrograph. This formation was supported by using energy dispersive x-ray (EDX). The presence of cadmium ions in the films, leads to some changes in the surface potential and Fourier Transform Infrared spectroscopy (FTIR).The nanocomposites MWCNTs-calixarene have potential for development of sensor for pollutant monitoring and nanoelectronics devices applications.
Abstract: This work presents synthesis of α,ω-dithienyl
terminated poly(ethylene glycol) (PEGTh) capable for further chain
extension by either chemical or electrochemical polymeriztion.
PEGTh was characterized by FTIR and 1H-NMR. Further
copolymerization of PEGTh and pyrrole (Py) was performed by
chemical oxidative polymerization using ceric (IV) salt as an oxidant
(PPy-PEGTh). PEG without end group modification was used
directly to prepare copolymers with Py by Ce (IV) salt (PPy-PEG).
Block copolymers with mole ratio of pyrrole to PEGTh (PEG) 50:1
and 10:1 were synthesized. The electrical conductivities of
copolymers PPy-PEGTh and PPy-PEG were determined by four
point probe technique. Influence of the synthetic route and content of
the insulating segment on conductivity and yield of the copolymers
were investigated.
Abstract: The design and plantwide control of an integrated
plant where the endothermic 1,4-butanediol dehydrogenation and the
exothermic furfural hydrogenation is simultaneously performed in a
single reactor is studied. The reactions can be carried out in an
adiabatic reactor using small hydrogen excess and with reduced
parameter sensitivity. The plant is robust and flexible enough to
allow different production rates of γ-butyrolactone and 2-methyl
furan, keeping high product purities. Rigorous steady state and
dynamic simulations performed in AspenPlus and AspenDynamics to
support the conclusions.
Abstract: Polysulfone (PSU) is a specialty engineering polymer
having various industrial applications. PSU is especially used in
waste water treatment membranes due to its good mechanical
properties, structural and chemical stability. But it is a hydrophobic
material and therefore its surface aim to pollute easily. In order to
resolve this problem and extend the properties of membrane, PSU
surface is rendered hydrophilic by addition of the sepiolite
nanofibers. Sepiolite is one of the natural clays, which is a hydrate
magnesium silicate fiber, also one of the well known layered clays of
the montmorillonites where has several unique channels and pores
within. It has also moisture durability, strength and low price.
Sepiolite channels give great capacity of absorption and good surface
properties. In this study, nanocomposites of commercial PSU and
Sepiolite were prepared by solvent mixing method. Different organic
solvents and their mixtures were used. Rheological characteristics of
PSU-Sepiolite solvent mixtures were analyzed, the solubility of
nanocomposite content in those mixtures were studied.
Abstract: The industrial process adds to engineering wood
products features absent in solid wood, with homogeneous structure
and reduced defects, improved physical and mechanical properties,
bio-deterioration, resistance and better dimensional stability,
improving quality and increasing the reliability of structures wood.
These features combined with using fast-growing trees, make them
environmentally ecological products, ensuring a strong consumer
market. The wood I-joists are manufactured by the industrial profiles
bonding flange and web, an important aspect of the production of
wooden I-beams is the adhesive joint that bonds the web to the
flange. Adhesives can effectively transfer and distribute stresses,
thereby increasing the strength and stiffness of the composite. The
objective of this study is to evaluate different resins in a shear strain
specimens with the aim of analyzing the most efficient resin and
possibility of using national products, reducing the manufacturing
cost. First was conducted a literature review, where established the
geometry and materials generally used, then established and analyzed
8 national resins and produced six specimens for each.
Abstract: Thin ZnO films are deposited on glass substrates via
sol–gel method and dip-coating. The films are prepared from zinc
acetate dehydrate as a starting reagent. After that the as-prepared
ZnO sol is aged for different periods (0, 1, 3, 5, 10, 15 and 30 days).
Nanocrystalline thin films are deposited from various sols. The
effect ZnO sols aging time on the structural and photocatalytic
properties of the films is studied. The films surface is studied by
Scanning Electron Microscopy. The effect of the aging time of the
starting solution is studied in the photocatalytic degradation of
Reactive Black 5 (RB5) by UV-vis spectroscopy. The experiments
are conducted upon UV-light illumination and in complete darkness.
The variation of the absorption spectra shows the degradation of RB5
dissolved in water, as a result of the reaction, occurring on the surface
of the films and promoted by UV irradiation. The initial
concentrations of dye (5, 10 and 20 ppm) and the effect of the aging
time are varied during the experiments. The results show, that the
increasing aging time of starting solution with respect to ZnO
generally promotes photocatalytic activity. The thin films obtained
from ZnO sol, which is aged 30 days have best photocatalytic
degradation of the dye (97,22%) in comparison with the freshly
prepared ones (65,92%). The samples and photocatalytic
experimental results are reproducible. Nevertheless, all films exhibit
a substantial activity in both UV light and darkness, which is
promising for the development of new ZnO photocatalysts by sol-gel
method.
Abstract: The study examined the effect of Bonny Light whole
crude oil (WC) and its water soluble fraction (WSF) on the activities
of antioxidant enzymes (catalase (CAT) and superoxide dismutase
(SOD)) and crude mitochondria ATPases in the radicle of
germinating bean (Vigna unguiculata). The percentage germination,
level of lipid peroxidation, antioxidant enzyme and mitochondria
Ca2+ and Mg2+ ATPase activities were measured in the radicle of
bean after 7, 14 and 21 days post germination. Viable bean seeds
were planted in soils contaminated with 10ml, 25ml and 50ml of
whole crude oil (WC) and its water soluble fraction (WSF) to obtain
2, 5 and 10% v/w crude oil contamination. There was dose dependent
reduction of the number of bean seeds that germinated in the
contaminated soils compared with control (p
Abstract: PLA emerged as a promising polymer because of its
property as a compostable, biodegradable thermoplastic made from
renewable sources. PLA can be polymerized from monomers
(Lactide or Lactic acid) obtained by fermentation processes from
renewable sources such as corn starch or sugarcane. For PLA
synthesis, ring opening polymerization (ROP) of Lactide monomer is
one of the preferred methods. In the literature, the technique mainly
developed for ROP of PLA is based on metal/bimetallic catalyst (Sn,
Zn and Al) or other organic catalysts in suitable solvent. However,
the PLA synthesized using such catalysts may contain trace elements
of the catalyst which may cause toxicity. This work estimated the
usefulness and drawbacks of using different catalysts as well as effect
of alternative energies and future aspects for PLA production.