Abstract: Five palm oil ether monoesters utilized as novel
biodiesels were synthesized and structurally identified in the paper.
The investigation was made on the effect of ether species on
physicochemical properties of the palm oil ether monoesters. The
results showed that density, kinematic viscosity, smoke point, and
solidifying point increase linearly with their –CH2 group number in
certain relationships. Cetane number is enhanced whereas heat value
decreases linearly with –CH2 group number. In addition, the
influencing regularities of the volumetric content of the palm oil ether
monoesters on the fuel properties were also studied when the ether
monoesters are used as diesel fuel additives.
Abstract: In contrast with literal meaning of nano, researchers
have been achieved mega adventures in this area and every day more
nanomaterials are being introduced to the market. After long time
application of fossil-based plastics, nowadays accumulation of their
waste seems to be a big problem to the environment. On the other
hand, mankind has more attention to safety and living environment.
Replacing common plastic packaging materials with degradable ones
that degrade faster and convert to non-dangerous components like
water and carbon dioxide have more attractions; these new materials
are based on renewable and inexpensive sources of starch and
cellulose. However, the functional properties of them do not suitable
for packaging. At this point, nanotechnology has an important role.
Utilizing of nanomaterials in polymer structure will improve
mechanical and physical properties of them; nanocrystalline cellulose
(NCC) has this ability. This work has employed a chemical method to
produce NCC and starch bio nanocomposite containing NCC. X-Ray
Diffraction technique has characterized the obtained materials.
Results showed that applied method is a suitable one as well as
applicable one to NCC production.
Abstract: WO3/SiO2 catalysts were modified by an ion exchange
method with sodium hydroxide or potassium hydroxide solution. The
performance of the modified catalysts was tested in the metathesis of
ethylene and trans-2-butene to propylene. During ion exchange,
sodium and potassium ions played different roles. Sodium modified
catalysts revealed constant trans-2-butene conversion and propylene
selectivity when the concentrations of sodium in the solution were
varied. In contrast, potassium modified catalysts showed reduction of
the conversion and increase of the selectivity. From these results,
potassium hydroxide may affect the transformation of tungsten oxide
active species, resulting in the decrease in conversion whereas
sodium hydroxide did not. Moreover, the modification of catalysts by
this method improved the catalyst stability by lowering the amount of
coke deposited on the catalyst surface.
Abstract: Atmospheric carbon dioxide emissions are considered
as the greatest environmental challenge the world is facing today.
The tasks to control the emissions include the recovery of CO2 from
flue gas. This concern has been improved due to recent advances in
materials process engineering resulting in the development of
inorganic gas separation membranes with excellent thermal and
mechanical stability required for most gas separations. This paper,
therefore, evaluates the performance of a highly selective inorganic
membrane for CO2 recovery applications. Analysis of results
obtained is in agreement with experimental literature data. Further
results show the prediction performance of the membranes for gas
separation and the future direction of research. The materials
selection and the membrane preparation techniques are discussed.
Method of improving the interface defects in the membrane and its
effect on the separation performance has also been reviewed and in
addition advances to totally exploit the potential usage of this
innovative membrane.
Abstract: This study is aiming at establishing the relationship
between the optical signal of flame and an equivalent ratio of flame. In
this experiment, flame optical signal in a furnace is measured using
photodiode. The combustion system is composed of metal fiber burner
and vertical furnace, and flame chemiluminescence is measured at
various experimental conditions. In this study, the flame
chemiluminescence of laminar premixed flame is measured using
commercially available photodiode. It is experimentally investigated
the relationship between equivalent ratio and photodiode signal. In
addition, the strategy of combustion control method is proposed using
the optical signal and fuel pressure.
The results showed that certain relationship between optical data of
photodiode and equivalence ratio exists, and this leads to the
successful application of this system for instantaneous measurement of
equivalence ration of the combustion system.
Abstract: Copper (I) oxide microparticles with the morphology
of cubic and hollow sphere were synthesized with the assistance of
surfactant as the shape controller. Both particles were then subjected
to study the catalytic activity and observed the results of shape effects
of catalysts on rate of catalytic reaction. The decolorizing reaction of
crystal violet and sodium hydroxide was chosen and measured the
decreasing of reactant with respect to times using spectrophotometer.
The result revealed that morphology of crystal had no effect on the
catalytic activity for crystal violet reaction but contributed to total
surface area predominantly.
Abstract: Biomass briquette gasification is regarded as a
promising route for efficient briquette use in energy generation, fuels
and other useful chemicals. However, previous research has been
focused on briquette gasification in fixed bed gasifiers such as
updraft and downdraft gasifiers. Fluidised bed gasifier has the
potential to be effectively sized to medium or large scale. This study
investigated the use of fuel briquettes produced from blends of rice
husks and corn cobs biomass, in a bubbling fluidised bed gasifier.
The study adopted a combination of numerical equations and Aspen
Plus simulation software, to predict the product gas (syngas)
composition base on briquette density and biomass composition
(blend ratio of rice husks to corn cobs). The Aspen Plus model was
based on an experimentally validated model from the literature. The
results based on a briquette size 32 mm diameter and relaxed density
range of 500 to 650kg/m3, indicated that fluidisation air required in
the gasifier increased with increase in briquette density, and the
fluidisation air showed to be the controlling factor compared with the
actual air required for gasification of the biomass briquettes. The
mass flowrate of CO2 in the predicted syngas composition increased
with an increase in air flow, in the gasifier, while CO decreased and
H2 was almost constant. The ratio of H2 to CO for various blends of
rice husks and corn cobs did not significantly change at the designed
process air, but a significant difference of 1.0 was observed between
10/90 and 90/10 % blend of rice husks and corn cobs.
Abstract: In this study, we demonstrate the production of natural gas hydrates from permeable marine sediments with simultaneous mechanisms for methane recovery and methane-air or methane-air/carbon dioxide replacement. The simultaneous melting happens until the chemical potentials become equal in both phases as natural gas hydrate depletion continues and self-regulated methane-air replacement occurs over an arbitrary point. We observed certain point between dissociation and replacement mechanisms in the natural gas hydrate reservoir, and we call this boundary as critical methane concentration. By the way, when carbon dioxide was added, the process of chemical exchange of methane by air/carbon dioxide was observed in the natural gas hydrate. The suggested process will operate well for most global natural gas hydrate reservoirs, regardless of the operating conditions or geometrical constraints.
Abstract: Doxorubicin (DOX) is an anthracycline drug used to treat many cancer diseases. Similarly to other cytostatic drugs, DOX has serious side effects; the biggest obstacle is the cardiotoxicity. With the aim of lowering the negative side effects and to target the DOX into the tumor tissue, the different nanoparticles (NPs) are studied. The aim of this work was to synthetized different NPs and conjugated them with DOX and determine the binding capacity of the NPs. For this experiment, carbon nanotubes (CNTs), graphene oxide (GO), fullerene (FUL) and liposomes (LIP) were used. The highest binding capacity was observed in GO (85%). Subsequently the toxicity of NPs and NPs-DOX conjugates was analyzed in in vivo system (chicken embryos). Some NPs (GO) can increase the toxicity of DOX, whereas other NPs (LIP, CNTs) decrease DOX toxicity.
Abstract: Biodiesel as an alternative diesel fuel is steadily gaining more attention and significance. However, there are some drawbacks while using biodiesel regarding its properties that requires it to be blended with petrol based diesel and/or additives to improve the fuel characteristics. This study analyses thermal cracking as an alternative technology to improve biodiesel characteristics in which, FAME based biodiesel produced by transesterification of castor oil is fed into a continuous thermal cracking reactor at temperatures range of 450-500°C and flowrate range of 20-40 g/hr. Experiments designed by response surface methodology and subsequent statistical studies show that temperature and feed flowrate significantly affect the products yield. Response surfaces were used to study the impact of temperature and flowrate on the product properties. After each experiment, the produced crude bio-oil was distilled and diesel cut was separated. As shorter chain molecules are produced through thermal cracking, the distillation curve of the diesel cut fitted more with petrol based diesel curve in comparison to the biodiesel. Moreover, the produced diesel cut properties adequately pose within property ranges defined by the related standard of petrol based diesel. Cold flow properties, high heating value as the main drawbacks of the biodiesel are improved by this technology. Thermal cracking decreases kinematic viscosity, Flash point and cetane number.
Abstract: Experimental investigations of the DC electric field effect on thermal decomposition of biomass, formation of the axial flow of volatiles (CO, H2, CxHy), mixing of volatiles with swirling airflow at low swirl intensity (S ≈ 0.2-0.35), their ignition and on formation of combustion dynamics are carried out with the aim to understand the mechanism of electric field influence on biomass gasification, combustion of volatiles and heat energy production. The DC electric field effect on combustion dynamics was studied by varying the positive bias voltage of the central electrode from 0.6 kV to 3 kV, whereas the ion current was limited to 2 mA. The results of experimental investigations confirm the field-enhanced biomass gasification with enhanced release of volatiles and the development of endothermic processes at the primary stage of thermochemical conversion of biomass determining the field-enhanced heat energy consumption with the correlating decrease of the flame temperature and heat energy production at this stage of flame formation. Further, the field-enhanced radial expansion of the flame reaction zone correlates with a more complete combustion of volatiles increasing the combustion efficiency by 3% and decreasing the mass fraction of CO, H2 and CxHy in the products, whereas by 10% increases the average volume fraction of CO2 and the heat energy production downstream the combustor increases by 5-10%
Abstract: Radial profiles of particle velocities were investigated
in a 6.1m high methanol-to-olefins cold model experimental device
using a TSI laser Doppler velocimeter. The effect of axial height on
flow development was not obvious in fully developed region under the
same operating condition. Superficial gas velocity and solid
circulating rate had significant influence on particle velocity in the
center region of the riser. Besides, comparisons among rising,
descending and average particle velocity were conducted. The particle
average velocity was similar to the rising particle velocity and higher
than the descending particle velocity in radial locations except the wall
region of riser.
Abstract: Mobil Producing Nigeria Unlimited (MPNU), a
subsidiary of ExxonMobil and the highest crude oil & condensate
producer in Nigeria has its operational base and an oil terminal, the
Qua Iboe terminal (QIT) located at Ibeno, Nigeria. Other oil
companies like Network Exploration and Production Nigeria Ltd,
Frontier Oil Ltd; Shell Petroleum Development Company Ltd; Elf
Petroleum Nigeria Ltd and Nigerian Agip Energy, a subsidiary of the
Italian ENI E&P operate onshore, on the continental shelf and in deep
offshore of the Atlantic Ocean, respectively with the coastal waters of
Ibeno, Nigeria as the nearest shoreline. This study was designed to
delineate the oil-polluted sites in Ibeno, Nigeria using
microbiological and physico-chemical characterization of soils,
sediments and ground and surface water samples from the study area.
Results obtained revealed that there have been significant recent
hydrocarbon inputs into this environment as observed from the high
counts of hydrocarbonoclastic microorganisms in excess of 1% at all
the stations sampled. Moreover, high concentrations of THC, BTEX
and heavy metals contents in all the samples analyzed corroborate the
high recent crude oil input into the study area. The results also
showed that the pollution of the different environmental media
sampled were of varying degrees, following the trend: ground water
> surface water > sediments > soils.
Abstract: Let us consider that the entire universe is composed of
a single hydrogen atom within which the electron is moving around
the proton. In this case, according to classical theories of physics,
radiation, photons respectively, should be absorbed by the electron.
Depending on the number of photons absorbed, the electron radius of
rotation around the proton is established. Until now, the principle of
photons absorption by electrons and the electron transition to a new
energy level, namely to a higher radius of rotation around the proton,
is not clarified in physics. This paper aims to demonstrate that
radiation, photons respectively, have mass and negative electrostatic
charge similar to electrons but infinitely smaller. The experiments
which demonstrate this theory are simple: thermal expansion,
photoelectric effect and thermonuclear reaction.
Abstract: The Chair of Thermal Engineering at Poznan
University of Technology has been conducted research works on the
possibilities of using carbon nanostructures in energy and mechanics
applications for a couple of years. Those studies have provided results in a form of co-operation with foreign research centres, numerous publications and patent
applications.
Authors of this paper have studied the influence of multi-walled
carbon nanostructures on changes in static friction arising when steel
surfaces were moved. Tests were made using the original test stand
consisting of automatically controlled inclined plane driven by
precise stepper motors. Computer program created in the LabView
environment was responsible for monitoring of the stand operation,
accuracy of measurements and archiving the obtained results. Such a
solution enabled to obtain high accuracy and repeatability of all
conducted experiments.
Tests and analysis of the obtained results allowed us to determine
how additional layers of carbon nanostructures influenced on changes
of static friction coefficients. At the same time, we analyzed the
potential possibilities of applying nanostructures under consideration
in mechanics.
Abstract: This paper presents a rheological model for producing
shape-memory thermoplastic polymers. Shape-memory occurs as a
result of internal rearrangement of the structural elements of a
polymer. A non-linear viscoelastic model was developed that allows
qualitative and quantitative prediction of the stress-strain behavior of
shape-memory polymers during heating. This research was done to
develop a technique to determine the maximum possible change in
size of shape-memory products during heating. The rheological
model used in this work was particularly suitable for defining process
parameters and constructive parameters of the processing equipment.
Abstract: In this work new macroporous Ni electrodes modified
with Au nanoparticles for hydrogen production have been developed.
The supporting macroporous Ni electrodes have been obtained by
means of the electrodeposition at high current densities. Then, the Au
nanoparticles were synthesized and added to the electrode surface.
The electrocatalytic behaviour of the developed electrocatalysts was
studied by means of pseudo-steady-state polarization curves,
electrochemical impedance spectroscopy (EIS) and hydrogen
discharge curves. The size of the Au synthetized nanoparticles shows
a monomodal distribution, with a very sharp band between 10 and 50
nm. The characteristic parameters d10, d50 and d90 were 14, 20 and
31 nm respectively. From Tafel polarization data has been concluded
that the Au nanoparticles improve the catalytic activity of the
developed electrodes towards the HER respect to the macroporous Ni
electrodes. EIS permits to obtain the electrochemically active area by
means of the roughness factor value. All the developed electrodes
show roughness factor values in the same order of magnitude. From
the activation energy results it can be concluded that the Au
nanoparticles improve the intrinsic catalytic activity of the
macroporous Ni electrodes.
Abstract: Amoxicillin is an antibiotic which is widely used to
treat various infections in both human beings and animals. However,
when amoxicillin is released into the environment, it is a major
problem. Amoxicillin causes bacterial resistance to these drugs and
failure of treatment with antibiotics. Liquid membrane is of great
interest as a promising method for the separation and recovery of the
target ions from aqueous solutions due to the use of carriers for the
transport mechanism, resulting in highly selectivity and rapid
transportation of the desired metal ions. The simultaneous processes
of extraction and stripping in a single unit operation of liquid
membrane system are very interesting. Therefore, it is practical to
apply liquid membrane, particularly the HFSLM for industrial
applications as HFSLM is proved to be a separation process with
lower capital and operating costs, low energy and extractant with
long life time, high selectivity and high fluxes compared with solid
membranes. It is a simple design amenable to scaling up for industrial
applications. The extraction and recovery for (Amoxicillin) through
the hollow fiber supported liquid membrane (HFSLM) using
aliquat336 as a carrier were explored with the experimental data. The
important variables affecting on transport of amoxicillin viz.
extractant concentration and operating time were investigated. The
highest AMOX- extraction percentages of 85.35 and Amoxicillin
stripping of 80.04 were achieved with the best condition at 6 mmol/L
[aliquat336] and operating time 100 min. The extraction reaction
order (n) and the extraction reaction rate constant (kf) were found to
be 1.00 and 0.0344 min-1, respectively.
Abstract: Currently, continuous two-phase decanter process
used for olive oil production is the more internationally widespread.
The wastewaters generated from this industry (OMW) are a real
environmental problem because of its high organic load. Among
proposed treatments for these wastewaters, advanced oxidation
technologies (Fenton, ozone, photoFenton, etc.) are the most
favourable. The direct application of these processes is somewhat
expensive. Therefore, the application of a previous stage based on a
flocculation-sedimentation operation is of high importance. In this
research five commercial flocculants (three cationic, and two anionic)
have been used to achieve the separation of phases (liquid clarifiedsludge).
For each flocculant, different concentrations (0-1000 mg/L)
have been studied. In these experiments, sludge volume formed and
the final water quality were determined. The final removal
percentages of total phenols (11.3-25.1%), COD (5.6-20.4%), total
carbon (2.3-26.5%), total organic carbon (1.50-23.8%), total nitrogen
(1.45-24.8%), and turbidity (27.9-61.4%) were determined. The
variation on electric conductivity reduction percentage (1-8%) was
also determined. Finally, the best flocculants with highest removal
percentages have been determined (QG2001 and Flocudex CS49).
Abstract: A comparison of activity and stability of the as-formed
Pt/C, Pt-Co and Pt-Pd/C electrocatalysts, prepared by a combined
approach of impregnation and seeding, was performed. According to
the activity test in a single Proton Exchange Membrane (PEM) fuel
cell, the Oxygen Reduction Reaction (ORR) activity of the Pt-M/C
electrocatalyst was slightly lower than that of Pt/C. The j0.9 V and
E10 mA/cm2 of the as-prepared electrocatalysts increased in the order of
Pt/C > Pt-Co/C > Pt-Pd/C. However, in the medium-to-high current
density region, Pt-Pd/C exhibited the best performance. With regard to
their stability in a 0.5 M H2SO4 electrolyte solution, the
electrochemical surface area decreased as the number of rounds of
repetitive potential cycling increased due to the dissolution of the
metals within the catalyst structure. For long-term measurement, Pt-
Pd/C was the most stable than the other three electrocatalysts.