Abstract: A study was carried out to determine the effect of water quality on flotation performance. The experimental test work comprised of batch flotation tests using Denver lab cell for a period of 10 minutes. Nine different test runs were carried out in triplicates to ensure reproducibility using different water types from different thickener overflows, return and sewage effluent water (process water) and portable water. The water sources differed in pH, total dissolved solids, total suspended solids and conductivity. Process water was found to reduce the concentrate recovery and mass pull, while portable water increased the concentrate recovery and mass pull. Portable water reduced the concentrate grade while process water increased the concentrate grade. It is proposed that a combination of process water and portable water supply be used in flotation circuits to balance the different effects that the different water types have on the flotation efficiency.
Abstract: As the fossil fuels kept on depleting, intense research in developing hydrogen (H2) as the alternative fuel has been done to cater our tremendous demand for fuel. The potential of H2 as the ultimate clean fuel differs with the fossil fuel that releases significant amounts of carbon dioxide (CO2) into the surrounding and leads to the global warming. The experimental work was carried out to study the production of H2 from palm kernel shell steam gasification at different variables such as heating rate, steam to biomass ratio and adsorbent to biomass ratio. Maximum H2 composition which is 61% (volume basis) was obtained at heating rate of 100oCmin-1, steam/biomass of 2:1 ratio, and adsorbent/biomass of 1:1 ratio. The commercial adsorbent had been modified by utilizing the alcoholwater mixture. Characteristics of both adsorbents were investigated and it is concluded that flowability and floodability of modified CaO is significantly improved.
Abstract: In this paper, fabrication and study of electronic properties of Au/methyl-red/Ag surface type Schottky diode by current-voltage (I-V) method has been reported. The I-V characteristics of the Schottky diode showed the good rectifying behavior. The values of ideality factor n and barrier height b of Au/methyl-red/Ag Schottky diode were calculated from the semi-log I-V characteristics and by using the Cheung functions. From semi-log current-voltage characteristics the values of n and b were found 1.93 and 0.254 eV, respectively, while by using Cheung functions their values were calculated 1.89 and 0.26 eV, respectively. The effect of series resistance was also analyzed by Cheung functions. The series resistance RS values were determined from dV/d(lnI)–I and H(I)–I graphs and were found to be 1.1 k and 1.3 k, respectively.
Abstract: This study was carried out to develop a flotation
procedure for an oxide copper ore from a Region in Central Africa
for producing an 18% copper concentrate for downstream processing
at maximum recovery from a 4% copper feed grade. The copper
recoveries achieved from the test work were less than 50% despite
changes in reagent conditions (multistage sulphidisation, use of RCA
emulsion and mixture, use of AM 2, etc). The poor recoveries were
attributed to the mineralogy of the ore from which copper silicates
accounted for approximately 70% (mass) of the copper minerals in
the ore. These can be complex and difficult to float using
conventional flotation methods. Best results were obtained using
basic sulphidisation procedures, a high flotation temperature and
extended flotation residence time.
Abstract: In this paper, the energy performance of a selected
UHDE Ammonia plant is optimized by conducting heat integration through waste heat recovery and the synthesis of a heat exchange
network (HEN). Minimum hot and cold utility requirements were estimated through IChemE spreadsheet. Supporting simulation was
carried out using HYSYS software. The results showed that there is
no need for heating utility while the required cold utility was found to
be around 268,714 kW. Hence a threshold pinch case was faced. Then, the hot and cold streams were matched appropriately. Also,
waste heat recovered resulted with savings in HP and LP steams of
approximately 51.0% and 99.6%, respectively. An economic analysis
on proposed HEN showed very attractive overall payback period not
exceeding 3 years. In general, a net saving approaching 35% was
achieved in implementing heat optimization of current studied UHDE Ammonia process.
Abstract: Factor analysis was applied to two stages biogas
production from banana stem waste allowing a screening of the
experimental variables second stage temperature (T), organic loading
rates (OLR) and hydraulic retention times (HRT). Biogas production
was found to be strongly influenced by all the above experimental
variables. Results from factorial analysis have shown that all
variables which were HRT, OLR and T have significant effect to
biogas production. Increased in HRT and OLR could increased the
biogas yield. The performance was tested under the conditions of
various T (35oC-60oC), OLR (0.3 g TS/l.d–1.9 gTS/l.d), and HRT (3
d–15 d). Conditions for temperature, OLR and HRT in this study
were based on the best range obtained from literature review.
Abstract: Fuller’s earth is a fine-grained, naturally occurring substance that has a substantial ability to adsorb impurities. In the present study Fuller’s earth has been characterized and used for the removal of Pb(II) from aqueous solution. The effect of various physicochemical parameters such as pH, adsorbent dosage and shaking time on adsorption were studied. The result of the equilibrium studies showed that the solution pH was the key factor affecting the adsorption. The optimum pH for adsorption was 5. Kinetics data for the adsorption of Pb(II) was best described by pseudo-second order model. The effective diffusion co-efficient for Pb(II) adsorption was of the order of 10-8 m2/s. The adsorption data for metal adsorption can be well described by Langmuir adsorption isotherm. The maximum uptake of metal was 103.3 mg/g of adsorbent. Mass transfer analysis was also carried out for the adsorption process. The values of mass transfer coefficients obtained from the study indicate that the velocity of the adsorbate transport from bulk to the solid phase was quite fast. The mean sorption energy calculated from Dubinin-Radushkevich isotherm indicated that the metal adsorption process was chemical in nature.
Abstract: Coal fly ash (CFA) generated by coal-based thermal
power plants is mainly composed of some oxides having high
crystallinity, like quartz and mullite. In this study, the effect of CFA
crystallinity toward lead adsorption capacity was investigated. To get
solid with various crystallinity, the solution of sodium hydroxide
(NaOH) of 1-7 M was used to treat CFA at various temperature and
reflux time. Furthermore, to evaluate the effect of NaOH-treated CFA
with respect to adsorption capacity, the treated CFA were examine as
adsorbent for removing lead in the solution. The result shows that
using NaOH to treat CFA causes crystallinity of quartz and mullite
decrease. At higher NaOH concentration (>3M), in addition the
damage of quartz and mullite crystallinity is followed by crystal
formation called hydroxysodalite. The lower crystalllinity, the higher
adsorption capacity.
Abstract: This paper studied the synthesis of monoacylglycerol (monolaurin) by glycerolysis of coconut oil and crude glycerol, catalyzed by Carica papaya lipase. Coconut oil obtained from cold pressed extraction method and crude glycerol obtained from the biodiesel plant in Department of Chemistry, Uttaradit Rajabhat University, Thailand which used oils were used as raw materials for biodiesel production through transesterification process catalyzed by sodium hydroxide. The influences of the following variables were studied: (i) type of organic solvent, (ii) molar ratio of substrate, (iii) reaction temperature, (iv) reaction time, (v) lipase dosage, and (vi) initial water activity of enzyme. High yields in monoacylglycerol (58.35%) were obtained with molar ratio of glycerol to oil at 8:1 in ethanol, temperature was controlled at 45oC for 36 hours, the amount of enzyme used was 20 wt% of oil and initial water activity of enzyme at 0.53.
Abstract: Bladder carcinoma is an important worldwide health problem. Both cystoscopy and urine cytology used in detecting bladder cancer suffer from drawbacks where cystoscopy is an invasive method and urine cytology shows low sensitivity in low grade tumors. This study validates easier and less time-consuming techniques to evaluate the value of combined use of angiogenin and clusterin in comparison and combination with voided urine cytology in the detection of bladder cancer patients. This study includes malignant (bladder cancer patients, n= 50), benign (n=20) and healthy (n=20) groups. The studied groups were subjected to cystoscopic examination, detection of bilharzial antibodies, urine cytology, and estimation of urinary angiogenin and clusterin by ELISA. The overall sensitivity and specificity were 66% and 75% for angiogenin, 70% and 82.5% for clusterin and 46% and 80% for voided urine cytology. Combined sensitivity of angiogenin and clusterin with urine cytology increased from 82 to 88%.
Abstract: Soy polyol obtained from hydroxylation of soy
epoxide with ethylene glycol were prepared as pre-polyurethane. The
two step process method were applied in the polyurethane synthesis.
The blending of soy polyol with synthetic polyol then simultaneously
carried out to TDI (2,4): MDI (4,4-) (80:20), blowing agent, and
surfactant. Ethylene glycol were not taking part in the polyurethane
synthesis. The inclusion of ethylene glycol were used as a control.
Characterization of polyurethane foam through impact resillience,
indentation deflection, and density can visualize the polyurethane
classifications.
Abstract: Rice husk is a lignocellulosic source that can be
converted to ethanol. Three hundreds grams of rice husk was mixed
with 1 L of 0.18 N sulfuric acid solutions then was heated in an
autoclave. The reaction was expected to be at constant temperature
(isothermal), but before that temperature was achieved, reaction has
occurred. The first liquid sample was taken at temperature of 140 0C
and repeated every 5 minute interval. So the data obtained are in the
regions of non-isothermal and isothermal. It was observed that the
degradation has significant effects on the ethanol production. The
kinetic constants can be expressed by Arrhenius equation with the
frequency factors for hydrolysis and sugar degradation of 1.58 x 105
1/min and 2.29 x 108 L/mole/min, respectively, while the activation
energies are 64,350 J/mole and 76,571 J/mole. The highest ethanol
concentration from fermentation is 1.13% v/v, attained at 220 0C.
Abstract: Poly-β-hydroxybutyrate (PHB) is one of the most
famous biopolymers that has various applications in production of
biodegradable carriers. The most important strategy for enhancing
efficiency in production process and reducing the price of PHB, is the
accurate expression of kinetic model of products formation and
parameters that are effective on it, such as Dry Cell Weight (DCW)
and substrate consumption. Considering the high capabilities of
artificial neural networks in modeling and simulation of non-linear
systems such as biological and chemical industries that mainly are
multivariable systems, kinetic modeling of microbial production of
PHB that is a complex and non-linear biological process, the three
layers perceptron neural network model was used in this study.
Artificial neural network educates itself and finds the hidden laws
behind the data with mapping based on experimental data, of dry cell
weight, substrate concentration as input and PHB concentration as
output. For training the network, a series of experimental data for
PHB production from Hydrogenophaga Pseudoflava by glucose
carbon source was used. After training the network, two other
experimental data sets that have not intervened in the network
education, including dry cell concentration and substrate
concentration were applied as inputs to the network, and PHB
concentration was predicted by the network. Comparison of predicted
data by network and experimental data, indicated a high precision
predicted for both fructose and whey carbon sources. Also in present
study for better understanding of the ability of neural network in
modeling of biological processes, microbial production kinetic of
PHB by Leudeking-Piret experimental equation was modeled. The
Observed result indicated an accurate prediction of PHB
concentration by artificial neural network higher than Leudeking-
Piret model.
Abstract: In this paper, four carbazole-based D-D-π-A organic
dyes code as CCT2A, CCT3A, CCT1PA and CCT2PA were reported.
A series of these organic dyes containing identical donor and
acceptor group but different π-system. The effect of replacing of
thiophene by phenyl thiophene as π-system on the physical
properties has been focused. The structural, energetic properties and
absorption spectra were theoretically investigated by means of
Density Functional Theory (DFT) and Time-Dependent Density
Functional Theory (TD-DFT). The results show that nonplanar
conformation due to steric hindrance in donor part (cabazolecarbazole
unit) of dye molecule can prevent unfavorable dye
aggregation. By means of the TD-DFT method, the absorption
spectra were calculated by B3LYP and BHandHLYP to study the
affect of hybrid functional on the excitation energy (Eg). The results
revealed the increasing of thiophene units not only resulted in
decreasing of Eg, but also found the shifting of absorption spectra to
higher wavelength. TD-DFT/BHandHLYP calculated results are
more strongly agreed with the experimental data than B3LYP
functions. Furthermore, the adsorptions of CCT2A and CCT3A on the
TiO2 anatase (101) surface were carried out by mean of the chemical
periodic calculation. The result exhibit the strong adsorption energy.
The calculated results provide our new organic dyes can be
effectively used as dye for Dye Sensitized Solar Cell (DSC).
Abstract: Two Amphiphilic catalysts, iron (III) dodecylbenzene
sulfonate and nickel (II) dodecylbenzene sulfonate, were synthesized
and used in the catalytic aquathermolysis of heavy crude oil to reduce
its viscosity. The prepared catalysts exhibited good performance in
the aquathermolysis and the viscosity is reduced by ~ 78.9 % for
Egyptian heavy crude oil. The chemical and physical properties of
heavy oil both before and after reaction were investigated by FT-IR,
dynamic viscosity, molecular weight and SARA analysis. The results
indicated that the content of resin, asphaltene, average molecular
weight and sulfur content of heavy oil is reduced after the catalytic
aquathermolysis.
Abstract: Heat pipes are two-phase heat transfer devices with
high effective thermal conductivity. Due to the high heat transport
capacity, heat exchanger with heat pipes has become much smaller
than traditional heat exchangers in handling high heat fluxes. With
the working fluid in a heat pipe, heat can be absorbed on the
evaporator region and transported to the condenser region where the
vapour condenses releasing the heat to the cooling media. Heat pipe
technology has found increasing applications in enhancing the
thermal performance of heat exchangers in microelectranics, energy
saving in HVAC systems for operating rooms,surgery centers, hotels,
cleanrooms etc, temperature regulation systems for the human body
and other industrial sectors. Development activity in heat pipe and
thermosyphon technology in asia in recent years is surveyed. Some
new results obtained in Australia and other countries are also
included.
Abstract: Four phenylurea herbicides (isoproturon, chlortoluron, diuron and linuron) were dissolved in different water matrices in order to study their chemical degradation by using UV radiation, ozone and some advanced oxidation processes (UV/H2O2, O3/H2O2, Fenton reagent and the photo- Fenton system). The waters used were: ultra-pure water, a commercial mineral water, a groundwater and a surface water taken from a reservoir. Elimination levels were established for each herbicide and for several global quality parameters, and a kinetic study was performed in order to determine basic kinetic parameters of each reaction between the target phenylureas and these oxidizing systems.
Abstract: Liquid-liquid extraction is a process using two immiscible
liquids to extract compounds from one phase without high
temperature requirement. Mostly, the technical implementation of
this process is carried out in mixer-settlers or extraction columns. In
real chemical processes, chemicals may have high viscosity and
contain impurities. These impurities may change the settling behavior
of the process without measurably changing the physical properties
of the phases. In the current study, the settling behavior and the affected
parameters in a high-viscosity system were observed. Batchsettling
experiments were performed to experimentally quantify the
settling behavior and the mixer-settler model of Henschke [1] was
used to evaluate the behavior of the toluene + water system. The
viscosity of the system was increased by adding polyethylene glycol
4000 to the aqueous phase. NaCl and Na2SO4 were used to study the
influence of electrolytes. The results from this study show that increasing
the viscosity of water has a higher influence on the settling
behavior in comparison to the effects of the electrolytes. It can be
seen from the experiments that at high salt concentrations, there was
no effect on the settling behavior.
Abstract: Separation of propylene-propane mixture using
immobilized liquid membrane was investigated. The effect of transmembrane
pressure and carrier concentration on membrane
separation performance was studied. It was observed that for 30:70
(vol. %) propylene-propane mixture, at pressure of 120kPa and
carrier concentration of 20wt. %, a separation factor of 474 was
obtained.
Abstract: Ethanol has become more attractive in fuel industry
either as fuel itself or an additive that helps enhancing the octane
number and combustibility of gasoline. This research studied a
pressure swing adsorption using cassava-based adsorbent prepared
from mixture of cassava starch and cassava pulp for dehydration of
ethanol vapor. The apparatus used in the experiments consisted of
double adsorption columns, an evaporator, and a vacuum pump. The
feed solution contained 90-92 %wt of ethanol. Three process
variables: adsorption temperatures (110, 120 and 130°C), adsorption
pressures (1 and 2 bar gauge) and feed vapor flow rate (25, 50 and 75
% valve opening of the evaporator) were investigated. According to
the experimental results, the optimal operating condition for this
system was found to be at 2 bar gauge for adsorption pressure, 120°C
for adsorption temperature and 25% valve opening of the evaporator.
Production of 1.48 grams of ethanol with concentration higher than
99.5 wt% per gram of adsorbent was obtained. PSA with cassavabased
adsorbent reported in this study could be an alternative method
for production of nearly anhydrous ethanol. Dehydration of ethanol
vapor achieved in this study is due to an interaction between free
hydroxyl group on the glucose units of the starch and the water
molecules.