Abstract: The pulp and paper mill effluent is one of the high
polluting effluent amongst the effluents obtained from polluting
industries. All the available methods for treatment of pulp and paper
mill effluent have certain drawbacks. The coagulation is one of the
cheapest process for treatment of various organic effluents. Thus, the
removal of chemical oxygen demand (COD) and colour of paper mill
effluent is studied using coagulation process. The batch coagulation
process was performed using various coagulants like: aluminium
chloride, poly aluminium chloride and copper sulphate. The initial
pH of the effluent (Coagulation pH) has tremendous effect on COD
and colour removal. Poly aluminium chloride (PAC) as coagulant
reduced COD to 84 % and 92 % of colour was removed at an
optimum pH 5 and coagulant dose of 8 ml l-1. With aluminium
chloride at an optimum pH = 4 and coagulant dose of 5 g l-1, 74 %
COD and 86 % colour removal were observed. The results using
copper sulphate as coagulant (a less commercial coagulant) were
encouraging. At an optimum pH 6 and mass loading of 5 g l-1, 76 %
COD reduction and 78 % colour reduction were obtained. It was also
observed that after addition of coagulant, the pH of the effluent
decreases. The decrease in pH was highest for AlCl3, which was
followed by PAC and CuSO4. Significant amount of COD reductions
was obtained by coagulation process. Since the coagulation process
is the first stage for treatment of effluent and some of the coagulant
cations usually remain in the treated effluents. Thus, cation like
copper may be one of the good catalyst for second stage of treatment
process like wet oxidation. The copper has been found to be good
oxidation catalyst then iron and aluminum.
Abstract: Investigations of the unimolecular decomposition of
vinyl ethyl ether (VEE), vinyl propyl ether (VPE) and vinyl butyl
ether (VBE) have shown that activation of the molecule of a ether
results in formation of a cyclic construction - the transition state (TS),
which may lead to the displacement of the thermodynamic
equilibrium towards the reaction products. The TS is obtained by
applying energy minimization relative to the ground state of an ether
under the program MM2 when taking into account the hydrogen bond
formation between a hydrogen atom of alkyl residue and the extreme
atom of carbon of the vinyl group. The dissociation of TS up to the
products is studied by energy minimization procedure using the
mathematical program Gaussian. The obtained calculation data for
VEE testify that the decomposition of this ether may be conditioned
by hydrogen bond formation for two possible versions: when α- or β-
hydrogen atoms of the ethyl group are bound to carbon atom of the
vinyl group. Applying the same calculation methods to other ethers
(VPE and VBE) it is shown that only in the case of hydrogen bonding
between α-hydrogen atom of the alkyl residue and the extreme atom
of carbon of the vinyl group (αH---C) results in decay of theses
ethers.
Abstract: In the gas refineries of Iran-s South Pars Gas
Complex, Sulfrex demercaptanization process is used to remove
volatile and corrosive mercaptans from liquefied petroleum gases by
caustic solution. This process consists of two steps. Removing low
molecular weight mercaptans and regeneration exhaust caustic. Some
parameters such as LPG feed temperature, caustic concentration and
feed-s mercaptan in extraction step and sodium mercaptide content in
caustic, catalyst concentration, caustic temperature, air injection rate
in regeneration step are effective factors. In this paper was focused on
temperature factor that play key role in mercaptans extraction and
caustic regeneration. The experimental results demonstrated by
optimization of temperature, sodium mercaptide content in caustic
because of good oxidation minimized and sulfur impurities in
product reduced.
Abstract: In this work we investigated the behavior of methane
hydrates dispersed in crude oils from different fields at temperatures
below 0°C. In case of crude oil emulsion the size of water droplets is
in the range of 50e100"m. The size of hydrate particles formed from
droplets is the same. The self-preservation is not expected in this
field. However, the self-preservation of hydrates with the size of
particles 24±18"m (electron microscopy data) in suspensions is
observed. Similar results were obtained for four different kinds of
crude oil and model system such as asphaltenes, resins and wax in ndecane.
This result can allow developing effective methods to prevent
the formation and elimination of gas-hydrate plugs in pipelines under
low temperature conditions (e. g. in Eastern Siberia). There is a
prospective to use experiment results for working out the technology
of associated petroleum gas recovery.
Abstract: The equilibrium chemical reactions taken place in a converter reactor of the Khorasan Petrochemical Ammonia plant was studied using the minimization of Gibbs free energy method. In the minimization of the Gibbs free energy function the Davidon– Fletcher–Powell (DFP) optimization procedure using the penalty terms in the well-defined objective function was used. It should be noted that in the DFP procedure along with the corresponding penalty terms the Hessian matrices for the composition of constituents in the Converter reactor can be excluded. This, in fact, can be considered as the main advantage of the DFP optimization procedure. Also the effect of temperature and pressure on the equilibrium composition of the constituents was investigated. The results obtained in this work were compared with the data collected from the converter reactor of the Khorasan Petrochemical Ammonia plant. It was concluded that the results obtained from the method used in this work are in good agreement with the industrial data. Notably, the algorithm developed in this work, in spite of its simplicity, takes the advantage of short computation and convergence time.
Abstract: In this research a mathematical model for direct
oxidization of hydrogen sulfide into elemental sulfur in a fluidized
bed reactor with external circulation was developed. As the catalyst
is deactivated in the fluidized bed, it might be placed in a reduction
tank in order to remove sulfur through heating above its dew point.
The reactor model demonstrated via MATLAB software. It was
shown that variations of H2S conversion as well as; products formed
were reasonable in comparison with corresponding results of a fixed
bed reactor. Through analyzing results of this model, it became
possible to propose the main optimized operating conditions for the
process considered. These conditions included; the temperature range
of 100-130ºC and utilizing the catalyst as much as possible providing
the highest bed density respect to dimensions of bed, economical
aspects that the bed ever remained in fluidized mode. A high active
and stable catalyst under the optimum conditions exhibited 100%
conversion in a fluidized bed reactor.
Abstract: The Iranian bentonite was first characterized by
Scanning Electron Microscopy (SEM), Inductively Coupled Plasma
mass spectrometry (ICP-MS), X-ray fluorescence (XRF), X-ray
Diffraction (XRD) and BET. The bentonite was then treated
thermally between 150°C-250°C at 15min, 45min and 90min and
also was activated chemically with different concentration of
sulphuric acid (3N, 5N and 10N). Although the results of thermal
activated-bentonite didn-t show any considerable changes in specific
surface area and Cation Exchange Capacity (CEC), but the results of
chemical treated bentonite demonstrated that such properties have
been improved by acid activation process.
Abstract: Durian husk (DH), a fruit waste, was studied for its ability to remove Basic blue 3 (BB3) from aqueous solutions. Batch kinetic studies were carried out to study the sorption characteristics under various experimental conditions. The optimum pH for the dye removal occurred in the pH range of 3-10. Sorption was found to be concentration and agitation dependent. The kinetics of dye sorption fitted a pseudo-second order rate expression. Both Langmuir and Freundlich models appeared to provide reasonable fittings for the sorption data of BB3 on durian husk. Maximum sorption capacity calculated from the Langmuir model is 49.50 mg g-1.
Abstract: A feasibility study for the design and construction of a
pilot plant for the extraction of castor oil in South Africa was
conducted. The study emphasized the four critical aspects of project
feasibility analysis, namely technical, financial, market and
managerial aspects. The technical aspect involved research on
existing oil extraction technologies, namely: mechanical pressing and
solvent extraction, as well as assessment of the proposed production
site for both short and long term viability of the project. The site is
on the outskirts of Nkomazi village in the Mpumalanga province,
where connections for water and electricity are currently underway,
potential raw material supply proves to be reliable since the province
is known for its commercial farming. The managerial aspect was
evaluated based on the fact that the current producer of castor oil will
be fully involved in the project while receiving training and technical
assistance from Sasol Technology, the TSC and SEDA. Market and
financial aspects were evaluated and the project was considered
financially viable with a Net Present Value (NPV) of R2 731 687 and
an Internal Rate of Return (IRR) of 18% at an annual interest rate of
10.5%. The payback time is 6years for analysis over the first 10
years with a net income of R1 971 000 in the first year. The project
was thus found to be feasible with high chance of success while
contributing to socio-economic development. It was recommended
for lab tests to be conducted to establish process kinetics that would
be used in the initial design of the plant.
Abstract: The textile industry produces highly coloured
effluents containing polar and non-polar compounds. The textile mill
run by the Assam Polyester Co-operative Society Limited (APOL) is
situated at Rangia, about 55 km from Guwahati (26011' N, 91047' E)
in the northern bank of the river Brahmaputra, Assam (India). This
unit was commissioned in June 1988 and started commercial
production in November 1988. The installed capacity of the weaving
unit was 8000 m/day and that of the processing unit was 20,000
m/day. The mill has its own dyeing unit with a capacity of 1500-2000
kg/day. The western side of the mill consists of vast agricultural land
and the far northern and southern side of the mill has scattered human
population. The eastern side of the mill has a major road for
thoroughfare. The mill releases its effluents into the agricultural land
in the western side of the mill. The present study was undertaken to
assess the impact of the textile mill on surface soil quality in and
around the mill with particular reference to Cr, Mn, Ni and Zn.
Surface soil samples, collected along different directions at 200, 500
and 1000 m were digested and the metals were estimated with
Atomic Absorption Spectrophotometer. The metals were found in the
range of: Cr 50.9 – 105.0 mg kg-1, Mn 19.2- 78.6 mg kg-1, Ni 41.9 –
50.6 mg kg-1 and Zn 187.8 – 1095.8 mg kg-1. The study reveals
enrichment of Cr, Mn, Ni and Zn in the soil near the textile mill.
Abstract: Thermodynamics characterization Sesame oil
extraction by Acetone, Hexane and Benzene has been evaluated. The
120 hours experimental Data were described by a simple
mathematical model. According to the simulation results and the
essential criteria, Acetone is superior to other solvents but under
certain conditions where oil extraction takes place Hexane is superior
catalyst.
Abstract: In this work, the results of mixing study by a jet mixer in a tank have been investigated in the laboratory scale. The tank dimensions are H/D=1 and the jet entrance have been considered in
the center of upper surface of tank. RNG-k-ε model is used as the
turbulent model for the prediction of the pattern of turbulent flow
inside the tank. For this purpose, a tank with volume of 110 liter is
simulated and it has been divided into 410,000 tetrahedral control
cells for performing the calculations. The grids at the vicinity of the
nozzle and suction pare are finer to get more accurate results. The
experimental results showed that in a vertical jet, the lowest mixing
time takes place at 35 degree. In addition, mixing time decreased by
increasing the Reynolds number. Furthermore, the CFD simulation
predicted the items as well a flow patterns precisely that validates the
experiments.
Abstract: In this paper 2D Simulation of catalytic Fixed Bed Reactor in Fischer-Tropsch Synthesis of GTL technology has been performed utilizing computational fluid dynamics (CFD). Synthesis gas (a mixture of carbon monoxide and hydrogen) has been used as feedstock. The reactor was modeled and the model equations were solved employing finite volume method. The model was validated against the experimental data reported in literature. The comparison showed a good agreement between simulation results and the experimental data. In addition, the model was applied to predict the concentration contours of the reactants and products along the length of reactor.
Abstract: In order to obtaining the dynamic evolution image of Tungsten array for foam padding, and to research the form of interaction between Tungsten plasma and foam column, a shadow imaging system of four-frame ultraviolet probe laser (266nm)has been designed on 1MA pulse power device. The time resolution of the system is 2.5ns, and static space resolution is superior to 70μm. The radial shadowgraphy image reveals the whole process from the melting and expansion of solid wire to the interaction of the precursor plasma and the foam, from the pinch to rebound inflation. The image shows the continuous interaction of Tungsten plasma and foam in a form of “Raining" within a time of about 50ns, the plasma shell structure has not been found in the whole period of pinch. The quantitative analysis indicates the minimum pinching speed of the foam column is 1.0×106cm/s, and maximum pinching speed is 6.0×106cm/s, and the axial stagnation diameter is approx 1mm.
Abstract: The optimal operation of proton exchange membrane fuel cell (PEMFC) requires good water management which is presented under two forms vapor and liquid. Moreover, fuel cells have to reach higher output require integration of some accessories which need electrical power. In order to analyze fuel cells operation and different species transport phenomena a biphasic mathematical model is presented by governing equations set. The numerical solution of these conservation equations is calculated by Matlab program. A multi-criteria optimization with weighting between two opposite objectives is used to determine the compromise solutions between maximum output and minimal stack size. The obtained results are in good agreement with available literature data.
Abstract: Iodine radionuclides in accident releases under severe
accident conditions at NPP with VVER are the most radiationimportant
with a view to population dose generation at the beginning
of the accident. To decrease radiation consequences of severe
accidents the technical solutions for severe accidents management
have been proposed in MIR.1200 project, with consideration of the
measures for suppression of volatile iodine forms generation in the
containment. Behavior dynamics of different iodine forms in the
containment under severe accident conditions has been analyzed for
the purpose of these technical solutions justification.
Abstract: This work investigated the steady state and dynamic
simulation of a fixed bed industrial naphtha reforming reactors. The
performance of the reactor was investigated using a heterogeneous
model. For process simulation, the differential equations are solved
using the 4th order Runge-Kutta method .The models were validated
against measured process data of an existing naphtha reforming plant.
The results of simulation in terms of components yields and
temperature of the outlet were in good agreement with empirical data.
The simple model displays a useful tool for dynamic simulation,
optimization and control of naphtha reforming.
Abstract: Natural gas usually includes H2S component which is
very toxic, hazardous and corrosive to environment, human being and
process equipments, respectively. Therefore, sweetening of the gas
(separation of H2S) is inevitable. To achieve this purpose, using
packed-bed columns with liquid absorbents such as MEA or DEA is
very common. Due to some problems of usual packed columns
especially high pressure drop of gas phase, a novel kind of them
called wetted-wire column (WWC) has been invented. The column
decreases the pressure drop significantly and improves the absorption
efficiency. The packings are very thin rods (like wire) and as long as
column. The column has 100 wires with a triangular arrangement and
counter current flows of gas and liquid phases. The observation
showed that at the same conditions, the absorption performance was
quite comparable to conventional packed-bed towers and a very low
pressure drop.
Abstract: Coal tar is a liquid by-product of the process of coal
gasification and carbonation. This liquid oil mixture contains various
kinds of useful compounds such as phenol, o-cresol, and p-cresol.
These compounds are widely used as raw material for insecticides,
dyes, medicines, perfumes, coloring matters, and many others.
This research needed to be done that given the optimum conditions
for the separation of phenol, o-cresol, and p-cresol from the coal tar
by solvent extraction process. The aim of the present work was to
study the effect of two kinds of aqueous were used as solvents:
methanol and acetone solutions, the effect of temperature (298, 306,
and 313K) and mixing (30, 35, and 40rpm) for the separation of
phenol, o-cresol, and p-cresol from coal tar by solvent extraction.
Results indicated that phenol, o-cresol, and p-cresol in coal tar
were selectivity extracted into the solvent phase and these
components could be separated by solvent extraction. The aqueous
solution of methanol, mass ratio of solvent to feed, Eo/Ro=1,
extraction temperature 306K and mixing 35 rpm were the most
efficient for extraction of phenol, o-cresol, and p-cresol from coal tar.
Abstract: In this article, we synthesize a novel chitosan -based
superabsorbent hydrogel via graft copolymerization of mixtures
acrylic acid (AA) and N-vinyl pyrollidon onto chitosan backbones.
The polymerization reaction was carried out in an aqueous medium
and in the presence of ammonium persulfate (APS) as an initiator and
N,N'-methylene bisacrylamide (MBA) as a crosslinker.The hydrogel
structures were confirmed by FTIR spectroscopy. The swelling
behavior of these absorbent polymers was also investigated in
various salt solutions. Results indicated that the swelling capacity
decreased with an increase in the ionic strength of the swelling
medium. Furthermore, the swelling of superabsorbing hydrogels was
examined in solutions with pH values ranging between 1.0 and 13.0.
It showed a reversible pH-responsive behavior at pHs 2.0 and 8.0.
This on-off switching behavior makes the synthesized hydrogels as
an excellent candidate for controlled delivery of bioactive agents.