Abstract: Liquid-Liquid Equilibrium (LLE) data are measured
for the ternary mixtures of water + 1-butanol + butyl acetate and
quaternary mixtures of water + 1-butanol + butyl acetate + glycerol at
atmospheric pressure at 313.15 K. In addition, isothermal
vapor–liquid–liquid equilibrium (VLLE) data are determined
experimentally at 333.15 K. The region of heterogeneity is found to
increase as the hydrophilic agent (glycerol) is introduced into the
aqueous mixtures. The experimental data are correlated with the
NRTL model. The predicted results from the solution model with the
model parameters determined from the constituent binaries are also
compared with the experimental values.
Abstract: Crops diversity and maintaining and enhancing the
fertility of agricultural lands are basic principles of organic farming.
With a wider range of crops in agroecosystem can improve the ability
to control weeds, pests and diseases, and the performance of crops
rotation and food safety. In this sense, the main objective of the
research was to study the productivity and chemical composition of
some alternative crops and their adaptability to soil and climatic
conditions of the agricultural area in Southern Romania and to
cultivation in the organic farming system. The alternative crops were:
lentil (7 genotypes); five species of grain legumes (5 genotypes); four
species of oil crops (5 genotypes). The seed production was, on
average: 1343 kg/ha of lentil; 2500 kg/ha of field beans; 2400 kg/ha
of chick peas and blackeyed peas; more than 2000 kg/ha of atzuki
beans, over 1250 kg/ha of fenugreek; 2200 kg/ha of safflower; 570
kg/ha of oil pumpkin; 2150 kg/ha of oil flax; 1518 kg/ha of camelina.
Regarding chemical composition, lentil seeds contained: 22.18%
proteins, 3.03% lipids, 33.29% glucides, 4.00% minerals, and 259.97
kcal energy values. For field beans: 21.50% proteins, 4.40% lipids,
63.90% glucides, 5.85% minerals, 395.36 kcal energetic value. For
chick peas: 21.23% proteins, 4.55% lipids, 53.00% glucides, 3.67%
minerals, 348.22 kcal energetic value. For blackeyed peas: 23.30%
proteins, 2.10% lipids, 68.10% glucides, 3.93% minerals, 350.14 kcal
energetic value. For adzuki beans: 21.90% proteins, 2.60% lipids,
69.30% glucides, 4.10% minerals, 402.48 kcal energetic value. For
fenugreek: 21.30% proteins, 4.65% lipids, 63.83% glucides, 5.69%
minerals, 396.54 kcal energetic value. For safflower: 12.60%
proteins, 28.37% lipids, 46.41% glucides, 3.60% minerals, 505.78
kcal energetic value. For camelina: 20.29% proteins, 31.68% lipids,
36.28% glucides, 4.29% minerals, 526.63 kcal energetic value. For
oil pumpkin: 29.50% proteins, 36.92% lipids, 18.50% glucides,
5.41% minerals, 540.15 kcal energetic value. For oil flax: 22.56%
proteins, 34.10% lipids, 27.73% glucides, 5.25% minerals, 558.45
kcal energetic value.
Abstract: The design of high pressure water jet based polishing
equipment and its fabrication conducted in this study is reported
herein, together with some preliminary test results for assessing its
applicability for HMA surface polishing. This study also provides
preliminary findings concerning the test variables, such as the
rotational speed, the water jet pressure, the abrasive agent used, and
the impact angel that were experimentally investigated in this study. The preliminary findings based on four trial tests (two on large
slab specimens and two on small size gyratory compacted
specimens), however, indicate that both friction and texture values
tend to increase with the polishing durations for two combinations of
pressure and rotation speed of the rotary deck. It seems that the more
polishing action the specimen is subjected to; the aggregate edges are
created such that the surface texture values are increased with the
accompanied increase in friction values. It may be of interest (but
which is outside the scope of this study) to investigate if the similar
trend exist for HMA prepared with aggregate source that is sand and
gravel.
Abstract: The economic use and ease of construction of profiled
deck composite slab is marred with the complex and un-economic
strength verification required for the serviceability and general safety
considerations. Beside these, albeit factors such as shear span length,
deck geometries and mechanical frictions greatly influence the
longitudinal shear strength, that determines the ultimate strength of
profiled deck composite slab, and number of methods available for its
determination; partial shear and slope-intercept are the two methods
according to Euro-code 4 provision. However, the complexity
associated with shear behavior of profiled deck composite slab, the
use of these methods in determining the load carrying capacities of
such slab yields different and conflicting values. This couple with the
time and cost constraint associated with the strength verification is a
source of concern that draws more attentions nowadays, the issue is
critical. Treating some of these known shear strength influencing
factors as random variables, the load carrying capacity violation of
profiled deck composite slab from the use of the two-methods
defined according to Euro-code 4 are determined using reliability
approach, and comparatively studied. The study reveals safety values
from the use of m-k method shows good standing compared with that
from the partial shear method.
Abstract: Numerical investigations were conducted to study the
influence of flexural reinforcement ratio on the diagonal cracking
strength and ultimate shear strength of reinforced concrete (RC)
beams without stirrups. Three-dimensional nonlinear finite element
analyses (FEAs) of the beams with flexural reinforcement ratios
ranging from 0.58% to 2.20% subjected to a mid-span concentrated
load were carried out. It is observed that the load-deflection and loadstrain
curves obtained from the numerical analyses agree with those
obtained from the experiments. It is concluded that flexural
reinforcement ratio has a significant effect on the shear strength and
deflection capacity of RC beams without stirrups. The predictions of
diagonal cracking strength and ultimate shear strength of beams
obtained by using the equations defined by a number of codes and
researchers are compared with each other and with the experimental
values.
Abstract: Zn alloy and composite coatings are widely used in
buildings and structures, automobile and fasteners industries to
protect steel component from corrosion. In this paper, Zn-Ni-Al2O3
nanocomposite coatings were electrodeposited on mild steel using a
novel sol enhanced electroplating method. In this method, transparent
Al2O3 sol was added into the acidic Zn-Ni bath to produced Zn-Ni-
Al2O3 nanocomposite coatings. The effect of alumina sol on the
electrodeposition process, and coating properties was investigated
using cyclic voltammetry, XRD, ESEM and Tafel test. Results from
XRD tests showed that the structure of all coatings was single γ-
Ni5Zn21 phase. Cyclic voltammetry results showed that the
electrodeposition overpotential was lower in the presence of alumina
sol in the bath, and caused the reduction potential of Zn-Ni to shift to
more positive values. Zn-Ni-Al2O3 nanocomposite coatings produced
more uniform and compact deposits, with fine grained microstructure
when compared to Zn-Ni coatings. The corrosion resistance of Zn-Ni
coatings was improved significantly by incorporation of alumina
nanoparticles into the coatings.
Abstract: The rapid growth of multimedia technology demands
the secure and efficient access to information. This fast growing lose
the confidence of unauthorized duplication. Henceforth the protection
of multimedia content is becoming more important. Watermarking
solves the issue of unlawful copy of advanced data. In this paper,
blind video watermarking technique has been proposed. A luminance
layer of selected frames is interlaced into two even and odd rows of
an image, further it is deinterlaced and equalizes the coefficients of
the two shares. Color watermark is split into different blocks, and the
pieces of block are concealed in one of the share under the wavelet
transform. Stack the two images into a single image by introducing
interlaced even and odd rows in the two shares. Finally, chrominance
bands are concatenated with the watermarked luminance band. The
safeguard level of the secret information is high, and it is
undetectable. Results show that the quality of the video is not
changed also yields the better PSNR values.
Abstract: The paper is focused on monitoring of dependencies
of different composition concretes on elastic modulus values.
To obtain a summary of elastic modulus development in dependence
of concrete composition design variability was the objective
of the experiment. Essential part of this work was initiated
as a reaction to building practice when questions of elastic moduli
arose at the same time and which mostly did not obtain the required
and expected values from concrete constructions.
Abstract: To construct the lumped spring-mass model
considering the occupants for the offset frontal crash, the SISAME
software and the NHTSA test data were used. The data on 56 kph 40%
offset frontal vehicle to deformable barrier crash test of a MY2007
Mazda 6 4-door sedan were obtained from NHTSA test database. The
overall behaviors of B-pillar and engine of simulation models agreed
very well with the test data. The trends of accelerations at the driver
and passenger head were similar but big differences in peak values.
The differences of peak values caused the large errors of the HIC36
and 3 ms chest g’s. To predict well the behaviors of dummies, the
spring-mass model for the offset frontal crash needs to be improved.
Abstract: There is not much effective guideline on development of design parameters selection on spring back for advanced high strength steel sheet metal in U-channel process during cold forming process. This paper presents the development of predictive model for spring back in U-channel process on advanced high strength steel sheet employing Response Surface Methodology (RSM). The experimental was performed on dual phase steel sheet, DP590 in Uchannel forming process while design of experiment (DoE) approach was used to investigates the effects of four factors namely blank holder force (BHF), clearance (C) and punch travel (Tp) and rolling direction (R) were used as input parameters using two level values by applying Full Factorial design (24 ). From a statistical analysis of variant (ANOVA), result showed that blank holder force (BHF), clearance (C) and punch travel (Tp) displayed significant effect on spring back of flange angle (β2 ) and wall opening angle (β1 ), while rolling direction (R) factor is insignificant. The significant parameters are optimized in order to reduce the spring back behavior using Central Composite Design (CCD) in RSM and the optimum parameters were determined. A regression model for spring back was developed. The effect of individual parameters and their response was also evaluated. The results obtained from optimum model are in agreement with the experimental values.
Abstract: More than 3000 plants of notable phyto-therapeutic
value grow in South Africa; these include Cissampelos capensis,
commonly known in Afrikaans as dawidjie or dawidjiewortel. C.
capensis is the most significant and popular medicinal plant used by
the Khoisan as well as other rural groups in the Western region of
South Africa. Its rhizomes are traditionally used to treat male fertility
problems. Yet, no studies have investigated the effects of this plant or
its extracts on human spermatozoa. Therefore, this study aimed at
investigating the effects of C. capensis rhizome extract (CRE)
fractions on ejaculated human spermatozoa in vitro. Spermatozoa
from a total of 77 semen samples were washed with human tubular
fluid medium supplemented with bovine serum albumin (HTF-BSA)
and incubated for 2 hours with 20 μg/ml progesterone (P4) followed
by incubation with different concentrations (0, 0.05, 0.5, 5, 50, 200
μg/ml) of fractionated CRE (F1=0% MeOH, F2=30% MeOH,
F3=60% MeOH and F4=100% MeOH) for 1.5 hours at 37°C. A
sample without addition of CRE fractions served as control. Samples
were analyzed for sperm motility, reactive oxygen species (ROS),
DNA-fragmentation, acrosome reaction and capacitation. Results
showed that F1 resulted in significantly higher values for ROS,
capacitation and hyper-activation compared to F2, F3, and F4 with
P4-stimulated samples generally having higher values. No significant
effect was found for the other parameters. In conclusion, alkaloids
present in F1 of CRE appear to have triggered sperm intrinsic ROS
production leading to sperm capacitation and acrosome reaction
induced by P4.
Abstract: One of the main challenges in using the Discrete
Element Method (DEM) is to specify the correct input parameter
values. In general, the models are sensitive to the input parameter
values and accurate results can only be achieved if the correct values
are specified. For the linear contact model, micro-parameters such as
the particle density, stiffness, coefficient of friction, as well as the
particle size and shape distributions are required. There is a need for
a procedure to accurately calibrate these parameters before any
attempt can be made to accurately model a complete bulk materials
handling system. Since DEM is often used to model applications in
the mining and quarrying industries, a calibration procedure was
developed for materials that consist of relatively large (up to 40 mm
in size) particles. A coarse crushed aggregate was used as the test
material. Using a specially designed large shear box with a diameter
of 590 mm, the confined Young’s modulus (bulk stiffness) and
internal friction angle of the material were measured by means of the
confined compression test and the direct shear test respectively. DEM
models of the experimental setup were developed and the input
parameter values were varied iteratively until a close correlation
between the experimental and numerical results was achieved. The
calibration process was validated by modelling the pull-out of an
anchor from a bed of material. The model results compared well with
experimental measurement.
Abstract: One of the crucial parameters of digital cryptographic
systems is the selection of the keys used and their distribution. The
randomness of the keys has a strong impact on the system’s security
strength being difficult to be predicted, guessed, reproduced, or
discovered by a cryptanalyst. Therefore, adequate key randomness
generation is still sought for the benefit of stronger cryptosystems.
This paper suggests an algorithm designed to generate and test
pseudo random number sequences intended for cryptographic
applications. This algorithm is based on mathematically manipulating
a publically agreed upon information between sender and receiver
over a public channel. This information is used as a seed for
performing some mathematical functions in order to generate a
sequence of pseudorandom numbers that will be used for
encryption/decryption purposes. This manipulation involves
permutations and substitutions that fulfill Shannon’s principle of
“confusion and diffusion”. ASCII code characters were utilized in the
generation process instead of using bit strings initially, which adds
more flexibility in testing different seed values. Finally, the obtained
results would indicate sound difficulty of guessing keys by attackers.
Abstract: Reliability of long-term storage products is related to
the availability of the whole system, and the evaluation of storage life
is of great necessity. These products are usually highly reliable and
little failure information can be collected. In this paper, an analytical
method based on data from accelerated storage life test is proposed to
evaluate the reliability index of the long-term storage products. Firstly,
singularities are eliminated by data normalization and residual
analysis. Secondly, with the preprocessed data, the degradation path
model is built to obtain the pseudo life values. Then by life distribution
hypothesis, we can get the estimator of parameters in high stress levels
and verify failure mechanism consistency. Finally, the life distribution
under the normal stress level is extrapolated via the acceleration model
and evaluation of the actual average life is available. An application
example with the camera stabilization device is provided to illustrate
the methodology we proposed.
Abstract: Experimental production methods of Chevreul’s salt
being an intermediate stage product in copper recovery were
investigated on this article. Chevreul’s salt, Cu2SO3.CuSO3.2H2O,
being a mixed valence copper sulphite compound, has been obtained
by using different methods and reagents. Chevreul’s salt has an
intense brick-red color. It is highly stable and expensive. The
production of Chevreul’s salt plays a key role in hydrometallurgy.
Thermodynamic tendency on precipitation of Chevreul’s salt is
related to pH and temperature. Besides, SO2 gaseous is a versatile
reagent for precipitating of copper sulphites, Using of SO2 for
selective precipitation can be made by appropriate adjustments of pH
and temperature. Chevreul’s salt does not form in acidic solutions if
those solutions contains considerable amount of sulfurous acid. It is
necessary to maintain between pH 2–4.5, because, solubility of
Chevreul’s salt increases with decreasing of pH values. Also, the
region which Chevreul’s salt is stable can be seen from the potentialpH
diagram.
Abstract: This work deals with parameter identification of
permanent magnet motors, a class of ac motor which is particularly
important in industrial automation due to characteristics like
applications high performance, are very attractive for applications
with limited space and reducing the need to eliminate because they
have reduced size and volume and can operate in a wide speed range,
without independent ventilation. By using experimental data and
genetic algorithm we have been able to extract values for both the
motor inductance and the electromechanical coupling constant, which
are then compared to measured and/or expected values.
Abstract: Chitosan has been an attractive biopolymer for
decades, but its processability is lowered by its poor solubility,
especially in physiological pH values. Freeze concentrated reactions
of chitosan with several organic acids including acrylic, citraconic,
itaconic, and maleic acid revealed improved solubility and
morphological properties. Solubility traits were assessed with a
modified ninhydrin test. Chitosan derivatives were characterized by
ATR-FTIR and morphological characteristics were determined by
SEM. This study is a unique approach to chemically modify chitosan
to enhance water solubility.
Abstract: Sustainability and eco-friendly requirement of
engineering materials are sort for in recent times, thus giving rise to
the development of bio-composites. However, the natural fibres to
matrix interface interactions remain a key issue in getting the desired
mechanical properties from such composites. Treatment of natural
fibres is essential in improving matrix to filler adhesion, hence
improving its mechanical properties. In this study, investigations
were carried out to determine the effect of sodium hydroxide
treatment on the tensile, flexural, impact and hardness properties of
crushed and uncrushed Luffa cylindrica fibre reinforced recycled low
density polyethylene composites. The LC (Luffa cylindrica) fibres
were treated with 0%, 2%, 4%, 6%, 8% and 10% wt. sodium
hydroxide (NaOH) concentrations for a period of 24 hours under
room temperature conditions. A formulation ratio of 80/20 g (matrix
to reinforcement) was maintained for all developed samples. Analysis
of the results showed that the uncrushed luffa fibre samples gave
better mechanical properties compared with the crushed luffa fibre
samples. The uncrushed luffa fibre composites had a maximum
tensile and flexural strength of 7.65 MPa and 17.08 Mpa respectively
corresponding to a young modulus and flexural modulus of 21.08
MPa and 232.22 MPa for the 8% and 4% wt. NaOH concentration
respectively. Results obtained in the research showed that NaOH
treatment with the 8% NaOH concentration improved the mechanical
properties of the LC fibre reinforced composites when compared with
other NaOH treatment concentration values.
Abstract: The Standard Penetration Test (SPT) is the most
common in situ test for soil investigations. On the other hand, the
Cone Penetration Test (CPT) is considered one of the best
investigation tools. Due to the fast and accurate results that can be
obtained it complaints the SPT in many applications like field
explorations, design parameters, and quality control assessments.
Many soil index and engineering properties have been correlated to
both of SPT and CPT. Various foundation design methods were
developed based on the outcome of these tests. Therefore it is vital to
correlate these tests to each other so that either one of the tests can be
used in the absence of the other, especially for preliminary evaluation
and design purposes.
The primary purpose of this study was to investigate the
relationships between the SPT and CPT for different type of sandy
soils in Florida. Data for this research were collected from number of
projects sponsored by the Florida Department of Transportation
(FDOT), six sites served as the subject of SPT-CPT correlations. The
correlations were established between the cone resistance (qc), sleeve
friction (fs) and the uncorrected SPT blow counts (N) for various
soils.
A positive linear relationship was found between qc, fs and N for
various sandy soils. In general, qc versus N showed higher
correlation coefficients than fs versus N. qc/N ratios were developed
for different soil types and compared to literature values, the results
of this research revealed higher ratios than literature values.
Abstract: Testing the first year students of Informatics at the
University of Debrecen revealed that students start their tertiary
studies in programming with a low level of programming knowledge
and algorithmic skills. The possible reasons which lead the students
to this very unfortunate result were examined. The results of the test
were compared to the students’ results in the school leaving exams
and to their self-assessment values. It was found that there is only a
slight connection between the students’ results in the test and in the
school leaving exams, especially at intermediate level. Beyond this,
the school leaving exams do not seem to enable students to evaluate
their own abilities.