Abstract: The dynamics of a predator-prey model with continuous
threshold policy harvesting functions on the prey is studied. Theoretical
and numerical methods are used to investigate boundedness
of solutions, existence of bionomic equilibria, and the stability properties
of coexistence equilibrium points and periodic orbits. Several
bifurcations as well as some heteroclinic orbits are computed.
Abstract: Boron minerals are very useful for various industrial
activities, such as glass industry and detergent industry, due to its
mechanical and chemical properties. During the production of boron
compounds, many of these are introduced into the environment in the
form of waste. Boron is also an important micro nutrient for the
plants to vegetate but if it exists in high concentrations, it could have
toxic effects. The maximum boron level in drinking water for human
health is given as 0.3 mg/L in World Health Organization (WHO)
standards. The toxic effects of boron should be noted especially for
dry regions, thus, in recent years, increasing attention has been paid
to remove the boron from waste waters. In this study, boron removal
is implemented by ion exchange process using Amberlite IRA-743
resin. Amberlite IRA-743 resin is a boron specific resin and it
belongs to the polymerizate sorbent group within the aminopolyol
functional group. Batch studies were performed to investigate the
effects of various experimental parameters, such as adsorbent dose,
initial concentration and pH, on the removal of boron. It is found
that, when the adsorbent dose increases removal of boron from the
liquid phase increases. However, an increase in the initial
concentration decreases the removal of boron. The effective pH
values for removal of boron are determined between 8.5 and 9.
Equilibrium isotherms were also analyzed by Langmuir and
Freundlich isotherm models. The Langmuir isotherm is obeyed better
than the Freundlich isotherm.
Abstract: This study empirically examines the long run equilibrium relationship between South Africa’s exports and imports using quarterly data from 1985 to 2012. The theoretical framework used for the study is based on Johansen’s Maximum Likelihood cointegration technique which tests for both the existence and number of cointegration vectors that exists. The study finds that both the series are integrated of order one and are cointegrated. A statistically significant cointegrating relationship is found to exist between exports and imports. The study models this unique linear and lagged relationship using a Vector Error Correction Model (VECM). The findings of the study confirm the existence of a long run equilibrium relationship between exports and imports.
Abstract: The relation between taxation states and foreign direct
investment has been studied for several perspectives and with states
of different levels of development. Usually it's only considered the
impact of tax level on the foreign direct investment volume. This
paper enhances this view by assuming that multinationals companies
(MNC) can use transfer prices systems and have got investment
timing flexibility. Thus, it evaluates the impact of the use of
international transfer pricing systems on the states- policy and on the
investment timing of the multinational companies. In uncertain
business environments (with periodical release of news), the
investment can increase if MNC detain investment delay options.
This paper shows how tax differentials can attract foreign direct
investments (FDI) and influence MNC behavior. The equilibrium is
set in a global environment where MNC can shift their profits
between states depending on the corporate tax rates. Assuming the
use of transfer pricing schemes, this paper confirms the relationship
between MNC behavior and the release of new business news.
Abstract: Game theory could be used to analyze the conflicted
issues in the field of information hiding. In this paper, 2-phase game
can be used to build the embedder-attacker system to analyze the
limits of hiding capacity of embedding algorithms: the embedder
minimizes the expected damage and the attacker maximizes it. In the
system, the embedder first consumes its resource to build embedded
units (EU) and insert the secret information into EU. Then the attacker
distributes its resource evenly to the attacked EU. The expected
equilibrium damage, which is maximum damage in value from the
point of view of the attacker and minimum from the embedder against
the attacker, is evaluated by the case when the attacker attacks a
subset from all the EU. Furthermore, the optimal equilibrium capacity
of hiding information is calculated through the optimal number of EU
with the embedded secret information. Finally, illustrative examples
of the optimal equilibrium capacity are presented.
Abstract: The purpose of this study is to investigate the capacity
of natural Turkish zeolite for NH4-N removal from landfill leachate.
The effects of modification and initial concentration on the removal
of NH4-N from leachate were also investigated. The kinetics of
adsorption of NH4-N has been discussed using three kinetic models,
i.e., the pseudo-second order model, the Elovich equation, the
intraparticle diffuion model. Kinetic parameters and correlation
coefficients were determined. Equilibrium isotherms for the
adsorption of NH4-N were analyzed by Langmuir, Freundlich and
Tempkin isotherm models. Langmuir isotherm model was found to
best represent the data for NH4-N.
Abstract: This work was to study batch biosorption of Pb(II)
ions from aqueous solution by Luffa charcoal. The effect of operating
parameters such as adsorption contact time, initial pH solution and
different initial Pb(II) concentration on the sorption of Pb(II) were
investigated. The results showed that the adsorption of Pb(II) ions
was initially rapid and the equilibrium time was 10 h. Adsorption
kinetics of Pb(II) ions onto Luffa charcoal could be best described by
the pseudo-second order model. At pH 5.0 was favorable for the
adsorption and removal of Pb(II) ions. Freundlich adsorption
isotherm model was better fitted for the adsorption of Pb(II) ions than
Langmuir and Timkin isotherms, respectively. The highest monolayer
adsorption capacity obtained from Langmuir isotherm model was
51.02 mg/g. This study demonstrated that Luffa charcoal could be
used for the removal of Pb(II) ions in water treatment.
Abstract: Gas turbine systems with wet compression have a
potential for future power generation, since they can offer a high
efficiency and a high specific power with a relatively low cost. In this
study influence of ambient condition on the performance of the wet
compression process is investigated with a non-equilibrium analytical
modeling based on droplet evaporation. Transient behaviors of droplet
diameter and temperature of mixed air are investigated for various
ambient temperatures. Special attention is paid for the effects of
ambient temperature, pressure ratio, and water injection ratios on the
important wet compression variables including compressor outlet
temperature and compression work. Parametric studies show that
downing of the ambient temperature leads to lower compressor outlet
temperature and consequently lower consumption of compression
work even in wet compression processes.
Abstract: An iterative algorithm is proposed and tested in Cournot Game models, which is based on the convergence of sequential best responses and the utilization of a genetic algorithm for determining each player-s best response to a given strategy profile of its opponents. An extra outer loop is used, to address the problem of finite accuracy, which is inherent in genetic algorithms, since the set of feasible values in such an algorithm is finite. The algorithm is tested in five Cournot models, three of which have convergent best replies sequence, one with divergent sequential best replies and one with “local NE traps"[14], where classical local search algorithms fail to identify the Nash Equilibrium. After a series of simulations, we conclude that the algorithm proposed converges to the Nash Equilibrium, with any level of accuracy needed, in all but the case where the sequential best replies process diverges.
Abstract: Curing of paints by exposure to UV radiations is
emerging as one of the best film forming technique as an alternative
to traditional solvent borne oxidative and thermal curing coatings.
The composition and chemistry of UV curable coatings and role of
multifunctional and monofunctional monomers, oligomers, and
photoinitiators have been discussed. The limitations imposed by
thermodynamic equilibrium and tendency for acrylic double bond
polymerizations during synthesis of multifunctional acrylates have
been presented. Aim of present investigation was thus to explore the
reaction variables associated with synthesis of multifunctional
acrylates. Zirconium oxychloride was evaluated as catalyst against
regular acid functional catalyst. The catalyzed synthesis of glyceryl
acrylate and neopentyl glycol acrylate was conducted by variation of
following reaction parameters: two different reactant molar ratios-
1:4 and 1:6; catalyst usage in % by moles on polyol- 2.5, 5.0 and 7.5
and two different reaction temperatures- 45 and 75 0C. The reaction
was monitored by determination of acid value and hydroxy value at
regular intervals, besides TLC, HPLC, and FTIR analysis of
intermediates and products. On the basis of determination of reaction
progress over 1-60 hrs, the esterification reaction was observed to
follow 2nd order kinetics with rate constant varying from 1*10-4 to
7*10-4. The thermal and catalytic components of second order rate
constant and energy of activation were also determined. Uses of
these kinetic and thermodynamic parameters in design of reactor for
manufacture of multifunctional acrylate ester have been presented.
The synthesized multifunctional acrylates were used to formulate and
apply UV curable clear coat followed by determination of curing
characteristics and mechanical properties of cured film. The overall
curing rates less than 05 min. were easily attained indicating
economical viability of radiation curable system due to faster
production schedules
Abstract: This paper presents an experimental investigation of
transformer dielectric response and solid insulation water content.
The dielectric response was carried out on the base of Hybrid
Frequency Dielectric Spectroscopy and Polarization Current
measurements method (FDS &PC). The calculation of the water
content in paper is based on the water content in oil and the obtained
equilibrium curves. A reference measurements were performed at
equilibrium conditions for water content in oil and paper of
transformer at different stable temperatures (25, 50, 60 and 70°C) to
prepare references to evaluate the insulation behavior at the not
equilibrium conditions. Some measurements performed at the
different simulated normal working modes of transformer operation
at the same temperature where the equilibrium conditions. The
obtained results show that when transformer temperature is mach
more than the its ambient temperature, the transformer temperature
decreases immediately after disconnecting the transformer from the
network and this temperature reduction influences the transformer
insulation condition in the measuring process. In addition to the oil
temperature at the near places to the sensors, the temperature
uniformity in transformer which can be changed by a big change in
the load of transformer before the measuring time will influence the
result. The investigations have shown that the extremely influence of
the time between disconnecting the transformer and beginning the
measurements on the results. And the online monitoring for water
content in paper measurements, on the basis of the oil water content
on line monitoring and the obtained equilibrium curves. The
measurements where performed continuously and for about 50 days
without any disconnection in the prepared the adiabatic room.
Abstract: The potential of economically cheaper cellulose
containing natural materials like rice husk was assessed for nickel
adsorption from aqueous solutions. The effects of pH, contact time,
sorbent dose, initial metal ion concentration and temperature on the
uptake of nickel were studied in batch process. The removal of nickel
was dependent on the physico-chemical characteristics of the
adsorbent, adsorbate concentration and other studied process
parameters. The sorption data has been correlated with Langmuir,
Freundlich and Dubinin-Radush kevich (D-R) adsorption models. It
was found that Freundlich and Langmuir isotherms fitted well to the
data. Maximum nickel removal was observed at pH 6.0. The
efficiency of rice husk for nickel removal was 51.8% for dilute
solutions at 20 g L-1 adsorbent dose. FTIR, SEM and EDAX were
recorded before and after adsorption to explore the number and
position of the functional groups available for nickel binding on to
the studied adsorbent and changes in surface morphology and
elemental constitution of the adsorbent. Pseudo-second order model
explains the nickel kinetics more effectively. Reusability of the
adsorbent was examined by desorption in which HCl eluted 78.93%
nickel. The results revealed that nickel is considerably adsorbed on
rice husk and it could be and economic method for the removal of
nickel from aqueous solutions.
Abstract: Absorptive characteristics of polyaniline synthesized
in mixture of water and acetonitrile in 50/50 volume ratio was
studied. Synthesized polyaniline in powder shape is used as an
adsorbent to remove toxic hexavalent chromium from aqueous
solutions. Experiments were conducted in batch mode with different
variables such as agitation time, solution pH and initial concentration
of hexavalent chromium. Removal mechanism is the combination of
surface adsorption and reduction. The equilibrium time for removal
of Cr(T) and Cr(VI) was about 2 and 10 minutes respectively. The
optimum pH for total chromium removal occurred at pH 7 and
maximum hexavalent chromium removal took place under acidic
condition at pH 3. Investigating the isothermal characteristics showed
that the equilibrium adsorption data fitted both Freundlich-s and
Langmuir-s isotherms. The maximum adsorption of chromium was
calculated 36.1 mg/g for polyaniline
Abstract: In this paper, a predator-prey model with time delay and habitat complexity is investigated. By analyzing the characteristic equations, the local stability of each feasible equilibria of the system is discussed and the existence of a Hopf bifurcation at the coexistence equilibrium is established. By choosing the sum of two delays as a bifurcation parameter, we show that Hopf bifurcations can occur as crosses some critical values. By deriving the equation describing the flow on the center manifold, we can determine the direction of the Hopf bifurcations and the stability of the bifurcating periodic solutions. Numerical simulations are carried out to illustrate the main theoretical results.
Abstract: A well balanced numerical scheme based on
stationary waves for shallow water flows with arbitrary topography
has been introduced by Thanh et al. [18]. The scheme was
constructed so that it maintains equilibrium states and tests indicate
that it is stable and fast. Applying the well-balanced scheme for the
one-dimensional shallow water equations, we study the early shock
waves propagation towards the Phuket coast in Southern Thailand
during a hypothetical tsunami. The initial tsunami wave is generated
in the deep ocean with the strength that of Indonesian tsunami of
2004.
Abstract: In modern agriculture, polymeric hydrogels are
known as a component able to hold an amount of water due to their
3-dimensional network structure and their tendency to absorb water
in humid environments. In addition, these hydrogels are able to
controllably release the fertilisers and pesticides loaded in them.
Therefore, they deliver these materials to the plants' roots and help
them with growing. These hydrogels also reduce the pollution of
underground water sources by preventing the active components
from leaching. In this study, sIPN acrylamide based hydrogels are
synthesised by using acrylamide free radical, potassium acrylate, and
linear polyvinyl alcohol. Ammonium nitrate is loaded in the hydrogel
as the fertiliser. The effect of various amounts of monomers and
linear polymer, measured in molar ratio, on the swelling rate,
equilibrium swelling, and release of ammonium nitrate is studied.
Abstract: Hypersonic flows around spatial vehicles during their
reentry phase in planetary atmospheres are characterized by intense
aerothermal phenomena. The aim of this work is to analyze high
temperature flows around an axisymmetric blunt body taking into
account chemical and vibrational non-equilibrium for air mixture
species. For this purpose, a finite volume methodology is employed
to determine the supersonic flow parameters around the axisymmetric
blunt body, especially at the stagnation point and along the wall of
spacecraft for several altitudes. This allows the capture shock wave
before a blunt body placed in supersonic free stream. The numerical
technique uses the Flux Vector Splitting method of Van Leer. Here,
adequate time stepping parameter, along with CFL coefficient and
mesh size level are selected to ensure numerical convergence, sought
with an order of 10-8
Abstract: In this paper real money demand function is analyzed
within multivariate time-series framework. Cointegration approach is
used (Johansen procedure) assuming interdependence between
money demand determinants, which are nonstationary variables. This
will help us to understand the behavior of money demand in Croatia,
revealing the significant influence between endogenous variables in
vector autoregrression system (VAR), i.e. vector error correction
model (VECM). Exogeneity of the explanatory variables is tested.
Long-run money demand function is estimated indicating slow speed
of adjustment of removing the disequilibrium. Empirical results
provide the evidence that real industrial production and exchange
rate explains the most variations of money demand in the long-run,
while interest rate is significant only in short-run.
Abstract: Molecular dynamics simulation of annular flow
boiling in a nanochannel with 70000 particles is numerically
investigated. In this research, an annular flow model is developed to
predict the superheated flow boiling heat transfer characteristics in a
nanochannel. To characterize the forced annular boiling flow in a
nanochannel, an external driving force F ext ranging from 1to12PN
(PN= Pico Newton) is applied along the flow direction to inlet fluid
particles during the simulation. Based on an annular flow model
analysis, it is found that saturation condition and superheat degree
have great influences on the liquid-vapor interface. Also, the results
show that due to the relatively strong influence of surface tension in
small channel, the interface between the liquid film and vapor core is
fairly smooth, and the mean velocity along the stream-wise direction
does not change anymore.
Abstract: A thin layer on the component surface can be found
with high tensile residual stresses, due to turning operations, which
can dangerously affect the fatigue performance of the component. In
this paper an analytical approach is presented to reconstruct the
residual stress field from a limited incomplete set of measurements.
Airy stress function is used as the primary unknown to directly solve
the equilibrium equations and satisfying the boundary conditions. In
this new method there exists the flexibility to impose the physical
conditions that govern the behavior of residual stress to achieve a
meaningful complete stress field. The analysis is also coupled to a
least squares approximation and a regularization method to provide
stability of the inverse problem. The power of this new method is
then demonstrated by analyzing some experimental measurements
and achieving a good agreement between the model prediction and
the results obtained from residual stress measurement.