Abstract: Endemic Artemia franciscana populations can be found throughout the American continent and also as an introduced specie in several country all over the world, such as in the Mediterranean region where Artemia franciscana was identified as an invasive specie replacing native Artemia parthenogenetica and Artemia salina. In the present study, the characterization of the new invasive Artemia franciscana reported from Sabkhet Halk El-Menzel (Tunisia) was done based on the cysts biometry, nauplii instar-I length, Adult sexual dimorphism and fatty acid profile. The mean value of the diameter of non-decapsulated and decapsulated cysts, chorion thickness and naupliar length is 235.8, 226.3, 4.75 and 426.8 μm, respectively. Sexual dimorphism for adults specimen showed that maximal distance between compound eyes, diameter for compound eyes, length of first antenna and the abdomen length compared to the total body length ratio, are the most important variables for males and females discrimination with a total contribution of 62.39 %. The analysis of fatty acid methyl esters profile of decapsulated cysts resulted in low levels of linolenic acid (LLA, C18:3n-3) and high levels of eicosapentaenoic acid (EPA, C20:5n-3) with 3.11 and 11.10 %, respectively. Low quantity of docosahexaenoic acid (DHA, 22:6n-3) was also observed with 0.17 mg.g-1 dry weight.
Abstract: The systematic manipulations of shapes and sizes of
inorganic compounds greatly benefit the various application fields
including optics, magnetic, electronics, catalysis and medicine.
However shape control has been much more difficult to achieve.
Hence exploration of novel method for the preparation of differently
shaped nanoparticles is challenging research area. II-VI group of
semiconductor cadmium sulphide (CdS) nanostructure with different
morphologies (such as, acicular like, mesoporous, spherical shapes)
and of crystallite sizes vary from 11 to 16 nm were successfully
synthesized by chemical aqueous precipitation of Cd2+ ions with
homogeneously released S2- ions from decomposition of cadmium
sulphate (CdSO4) and thioacetamide (CH3CSNH2) by annealing at
different radiations (microwave, ultrasonic and sunlight) with matter
and systematic research has been done for various factors affecting
the controlled growth rate of CdS nanoparticles. The obtained
nanomaterials have been characterized by X-ray Diffraction (XRD),
Fourier Transform Infrared Spectroscopy (FTIR),
Thermogravometric (DSC-TGA) analysis and Scanning Electron
Microscopy (SEM). The result indicates that on increasing the
reaction time particle size increases but on increasing the molar ratios
grain size decreases.
Abstract: The remediation of water resources pollution in
developing countries requires the application of alternative
sustainable cheaper and efficient end-of-pipe wastewater treatment
technologies. The feasibility of use of South African cheap and
abundant pine tree (Pinus patula) sawdust for development of lowcost
AC of comparable quality to expensive commercial ACs in the
abatement of water pollution was investigated. AC was developed at
optimized two-stage N2-superheated steam activation conditions in a
fixed bed reactor, and characterized for proximate and ultimate
properties, N2-BET surface area, pore size distribution, SEM, pHPZC
and FTIR. The sawdust pyrolysis activation energy was evaluated by
TGA. Results indicated that the chars prepared at 800oC and 2hrs
were suitable for development of better quality AC at 800oC and 47%
burn-off having BET surface area (1086m2/g), micropore volume
(0.26cm3/g), and mesopore volume (0.43cm3/g) comparable to
expensive commercial ACs, and suitable for water contaminants
removal. The developed AC showed basic surface functionality at
pHPZC at 10.3, and a phenol adsorption capacity that was higher than
that of commercial Norit (RO 0.8) AC. Thus, it is feasible to develop
better quality low-cost AC from (Pinus patula) sawdust using twostage
N2-steam activation in fixed-bed reactor.
Abstract: n-CdO/p-Si heterojunction diode was fabricated using
sol-gel spin coating technique which is a low cost and easily scalable
method for preparing of semiconductor films. The structural and
morphological properties of CdO film were investigated. The X-ray
diffraction (XRD) spectra indicated that the film was of
polycrystalline nature. The scanning electron microscopy (SEM)
images indicate that the surface morphology CdO film consists of the
clusters formed with the coming together of the nanoparticles. The
electrical characterization of Au/n-CdO/p–Si/Al heterojunction diode
was investigated by current-voltage. The ideality factor of the diode
was found to be 3.02 for room temperature. The reverse current of
the diode strongly increased with illumination intensity of 100
mWcm-2 and the diode gave a maximum open circuit voltage Voc of
0.04 V and short-circuits current Isc of 9.92×10-9 A.
Abstract: Quantitative characterization of nonlinear directional
couplings between stochastic oscillators from data is considered. We
suggest coupling characteristics readily interpreted from a physical
viewpoint and their estimators. An expression for a statistical
significance level is derived analytically that allows reliable coupling
detection from a relatively short time series. Performance of the
technique is demonstrated in numerical experiments.
Abstract: The progress of concentrations of particular heavy metals was assessed in chosen localities in region Moravia, the Czech Republic, from 2007 to 2009. Particular metals were observed in localities with various types and characterization of zone. Pb, Ni, As and Cd were emphasized as a result of their toxicity and potential adverse health effect to the exposed population. The progress of metal concentrations and their health effects in the most polluted localities were examined. According to the results, the air pollution limit values were not exceeded. Based on the health risk assessment, the probability of developing tumorous diseases is acceptable, except for the increased probability of cancer risk from long-term exposure to As.
Abstract: In this paper, the requirement for Coke quality
prediction, its role in Blast furnaces, and the model output is
explained. By applying method of Artificial Neural Networking
(ANN) using back propagation (BP) algorithm, prediction model has
been developed to predict CSR. Important blast furnace functions
such as permeability, heat exchanging, melting, and reducing
capacity are mostly connected to coke quality. Coke quality is further
dependent upon coal characterization and coke making process
parameters. The ANN model developed is a useful tool for process
experts to adjust the control parameters in case of coke quality
deviations. The model also makes it possible to predict CSR for new
coal blends which are yet to be used in Coke Plant. Input data to the
model was structured into 3 modules, for tenure of past 2 years and
the incremental models thus developed assists in identifying the
group causing the deviation of CSR.
Abstract: In this work some characterizations of semi Riemannian curvature tensor on almost split quaternion Kaehler manifolds and some characterizations of Ricci tensor on almost split quaternion Kaehler manifolds are given.
Abstract: The objective of this research is to study principal
component analysis for classification of 67 soil samples collected from
different agricultural areas in the western part of Thailand. Six soil
properties were measured on the soil samples and are used as original
variables. Principal component analysis is applied to reduce the
number of original variables. A model based on the first two
principal components accounts for 72.24% of total variance. Score
plots of first two principal components were used to map with
agricultural areas divided into horticulture, field crops and wetland.
The results showed some relationships between soil properties and
agricultural areas. PCA was shown to be a useful tool for agricultural
areas classification based on soil properties.
Abstract: Fermented beverages have high expression in the
market for beverages in general, is increasingly valued in situations
where the characteristic aroma and flavor of the material that gave
rise to them are kept after processing. This study aimed to develop a
distilled beverage from passion fruit, and assess, by sensory tests and
chromatographic profile, the influence of different treatments (FM1-
spirit with pulp addiction and FM2 – spirit with bigger ratio of pulp
in must) in the setting of volatiles in the fruit drink, and performing
chemical characterization taking into account the main parameters of
quality established by the legislation. The chromatograms and the
first sensorial tests had indicated that sample FM1 possess better
characteristics of aroma, as much of how much quantitative the
qualitative point of view. However, it analyzes it sensorial end
(preference test) disclosed the biggest preference of the cloth provers
for sample FM2-2 (note 7.93), being the attributes of decisive color
and flavor in this reply, confirmed for the observed values lowest of
fixed and total acidity in the samples of treatment FM2.
Abstract: Phase locked loops for data links operating at 10 Gb/s
or faster are low phase noise devices designed to operate with a low
jitter reference clock. Characterization of their jitter transfer function
is difficult because the intrinsic noise of the device is comparable to
the random noise level in the reference clock signal. A linear model
is proposed to account for the intrinsic noise of a PLL. The intrinsic
noise data of a PLL for 10 Gb/s links is presented. The jitter transfer
function of a PLL in a test chip for 12.8 Gb/s data links was
determined in experiments using the 400 MHz reference clock as the
source of simultaneous excitations over a wide range of frequency.
The result shows that the PLL jitter transfer function can be
approximated by a second order linear model.
Abstract: An innovative approach utilizing highly alkaline oil
shale waste ash and carbon dioxide gas (CO2), associated with power
production, as a resource for production of precipitated calcium
carbonate (PCC) is introduced in this paper. The specifics and
feasibility of the integrated ash valorization and CO2 sequestration
process by indirect aqueous carbonation of lime-consisting ash were
elaborated and the main parameters established. Detailed description
of the formed precipitates was included. Complimentary carbonation
experiments with commercial CaO fine powder were conducted for
comparative characterization of the final products obtained on the
basis of two different raw materials. Finally, the expected CO2
uptake was evaluated.
Abstract: Adsorption of Toluidine blue dye from aqueous solutions onto Neem Leaf Powder (NLP) has been investigated. The surface characterization of this natural material was examined by Particle size analysis, Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FTIR) spectroscopy and X-Ray Diffraction (XRD). The effects of process parameters such as initial concentration, pH, temperature and contact duration on the adsorption capacities have been evaluated, in which pH has been found to be most effective parameter among all. The data were analyzed using the Langmuir and Freundlich for explaining the equilibrium characteristics of adsorption. And kinetic models like pseudo first- order, second-order model and Elovich equation were utilized to describe the kinetic data. The experimental data were well fitted with Langmuir adsorption isotherm model and pseudo second order kinetic model. The thermodynamic parameters, such as Free energy of adsorption (AG"), enthalpy change (AH') and entropy change (AS°) were also determined and evaluated.
Abstract: Commercial hydroxyapatite (HA) was reinforced by
adding 2, 5, and 10 wt % of 28.5%CaO-28.5%P2O5-38%Na2 O-
5%CaF2 based glass and then sintered. Although HA shows good
biocompatibility with the human body, its applications are limited to
non load-bearing areas and coatings due to its poor mechanical
properties. These mechanical properties can be improved
substantially with addition of glass ceramics by sintering. In this
study, the effects of sintering hydroxyapatite with above specified
phosphate glass additions are quantified. Each composition was
sintered over a range of temperatures. Scanning electron microscopy
and x-ray diffraction were used to characterize the microstructure and
phases of the composites. The density, microhardness, and
compressive strength were measured using Archimedes Principle,
Vickers Microhardness Tester (at 0.98 N), and Instron Universal
Testing Machine (cross speed of 0.5 mm/min) respectively. These
results were used to indicate which composition provided suitable
material for use in hard tissue replacement. Composites containing 10
wt % glass additions formed dense HA/TCP (tricalcium phosphate)
composite materials possessing good compressive strength and
hardness than HA. In-vitro bioactivity was assessed by evaluating
changes in pH and Ca2+ ion concentration of SBF-simulated body
fluid on immersion of these composites in it for two weeks.
Abstract: Considering toxicity of heavy metals and their
accumulation in domestic wastes, immobilization of lead and
cadmium is envisaged inside glass-ceramics. We particularly
focused this work on calcium-rich phases embedded in a
glassy matrix.
Glass-ceramics were synthesized from glasses doped with
12 wt% and 16 wt% of PbO or CdO. They were observed and
analyzed by Electron MicroProbe Analysis (EMPA) and
Analytical Scanning Electron Microscopy (ASEM). Structural
characterization of the samples was performed by powder XRay
Diffraction.
Diopside crystals of CaMgSi2O6 composition are shown to
incorporate significant amounts of cadmium (up to 9 wt% of
CdO). Two new crystalline phases are observed with very
high Cd or Pb contents: about 40 wt% CdO for the cadmiumrich
phase and near 60 wt% PbO for the lead-rich phase. We
present complete chemical and structural characterization of
these phases. They represent a promising way for the
immobilization of toxic elements like Cd or Pb since glass
ceramics are known to propose a “double barrier" protection
(metal-rich crystals embedded in a glass matrix) against metal
release in the environment.
Abstract: This paper reports the tensile fracture location
characterizations of dissimilar friction stir welds between 5754
aluminium alloy and C11000 copper. The welds were produced using
three shoulder diameter tools; namely, 15, 18 and 25 mm by varying
the process parameters. The rotational speeds considered were 600,
950 and 1200 rpm while the feed rates employed were 50, 150 and
300 mm/min to represent the low, medium and high settings
respectively. The tensile fracture locations were evaluated using the
optical microscope to identify the fracture locations and were
characterized. It was observed that 70% of the tensile samples failed
in the Thermo Mechanically Affected Zone (TMAZ) of copper at the
weld joints. Further evaluation of the fracture surfaces of the pulled
tensile samples revealed that welds with low Ultimate Tensile
Strength either have defects or intermetallics present at their joint
interfaces.
Abstract: The methanolic extracts from seeds of tamarind
(Tamarindus indica) was prepared by Soxhlet apparatus extraction
and evaluated for total phenolic content by Folin-Ciocalteu method.
Then, methanolic extract was screened biological activities (In vitro)
for anti-melanogenic activity by tyrosinase inhibition test, antiinflammation
activity by cyclooxygenase 1 (COX-1) and
cyclooxygenase 2 (COX-2) inhibition test, and cytotoxic screening
test with Vero cells. The results showed that total phenolic content,
which contained in extract, was contained 27.72 mg of gallic acid
equivalent per g of dry weight. The ability to inhibit tyrosinase
enzyme, which exerted by Tamarind seed extracts (1 mg/ml) was
52.13 ± 0.42 %. The extract was not possessed inhibitory effect to
COX-1 and COX-2 enzymes and cytotoxic effect to Vero cells. The
finding is concludes that tested seed extract was possessed
antimelanogenic activity with non-toxic effects. However, there was
not exhibited anti-inflammatory activity. Further studies include the
use of advance biological models to confirm this biological activity,
as well as, the isolation and characterization of the purified
compounds that it was contained.
Abstract: Controlled release urea has become popular in agricultural industry as it helps to solve environmental issues and increase crop yield. Recently biomass was identified to replace the polymer used as a coating material in the conventional coated urea. In this paper spreading and contact angle of biomass droplet (lignin, cellulose and clay) on urea surface are investigated experimentally. There were two tests were conducted, sessile drop for contact angle measurement and pendant drop for contact angle measurement. A different concentration of biomass droplet was released from 30 mm above a substrate. Glass was used as a controlled substrate. Images were recorded as soon as the droplet impacted onto the urea before completely adsorb into the urea. Digitized droplets were then used to identify the droplet-s surface tension and contact angle. There is large difference observed between the low surface tension and high surface tension liquids, where the wetting and spreading diameter is higher for lower surface tension. From the contact angle results, the data showed that the biomass coating films were possible as wetting liquid (θ < 90º). Contact angle of biomass coating material gives good indication for the wettablity of a liquid on urea surface.
Abstract: Decomposition processes take place in landfill
generate leachates that can be categorized mainly of acetogenic and
methanogenic in nature. BOD:COD ratio computed in this study for a
landfill site over a 3 years duration revealed as a good indicator to
identify acetogenic leachate from methanogenic leachate. Correlation
relationships to predict pollutant level taking into consideration of
climatic condition are derived.
Abstract: In recent years, scanning probe atomic force
microscopy SPM AFM has gained acceptance over a wide spectrum
of research and science applications. Most fields focuses on physical,
chemical, biological while less attention is devoted to manufacturing
and machining aspects. The purpose of the current study is to assess
the possible implementation of the SPM AFM features and its
NanoScope software in general machining applications with special
attention to the tribological aspects of cutting tool. The surface
morphology of coated and uncoated as-received carbide inserts is
examined, analyzed, and characterized through the determination of
the appropriate scanning setting, the suitable data type imaging
techniques and the most representative data analysis parameters
using the MultiMode SPM AFM in contact mode. The NanoScope
operating software is used to capture realtime three data types
images: “Height", “Deflection" and “Friction". Three scan sizes are
independently performed: 2, 6, and 12 μm with a 2.5 μm vertical
range (Z). Offline mode analysis includes the determination of three
functional topographical parameters: surface “Roughness", power
spectral density “PSD" and “Section". The 12 μm scan size in
association with “Height" imaging is found efficient to capture every
tiny features and tribological aspects of the examined surface. Also,
“Friction" analysis is found to produce a comprehensive explanation
about the lateral characteristics of the scanned surface. Configuration
of many surface defects and drawbacks has been precisely detected
and analyzed.