Fabrication and Characterization of CdS Nanoparticles Annealed by using Different Radiations
The systematic manipulations of shapes and sizes of
inorganic compounds greatly benefit the various application fields
including optics, magnetic, electronics, catalysis and medicine.
However shape control has been much more difficult to achieve.
Hence exploration of novel method for the preparation of differently
shaped nanoparticles is challenging research area. II-VI group of
semiconductor cadmium sulphide (CdS) nanostructure with different
morphologies (such as, acicular like, mesoporous, spherical shapes)
and of crystallite sizes vary from 11 to 16 nm were successfully
synthesized by chemical aqueous precipitation of Cd2+ ions with
homogeneously released S2- ions from decomposition of cadmium
sulphate (CdSO4) and thioacetamide (CH3CSNH2) by annealing at
different radiations (microwave, ultrasonic and sunlight) with matter
and systematic research has been done for various factors affecting
the controlled growth rate of CdS nanoparticles. The obtained
nanomaterials have been characterized by X-ray Diffraction (XRD),
Fourier Transform Infrared Spectroscopy (FTIR),
Thermogravometric (DSC-TGA) analysis and Scanning Electron
Microscopy (SEM). The result indicates that on increasing the
reaction time particle size increases but on increasing the molar ratios
grain size decreases.
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[2] R. I. Dimitrov and B. S. Boyanov, Journal of Thermal Analysis and
Calorimetry. Vol 61, 2000, pp. 181-189.
[3] P. Raji, C. Sanjeeviraja and K. Ramachandran, Cryst. Res. Technol, vol
28, 2005, pp. 233-238.
[4] Pushpa Ann Kurian, C. Vijayan, K. Sathiyamoorthy, C. S. Suchand
Sandeep, Reji Philip Res, Lett. 2, 2007, pp. 561-568.
[5] J. Jakimavicious, A. Alisauskas and A. Sirvaitis, Materials Chemistry
and Physics, Vol. 11, 1971, pp. 493.
[6] J. Jakimavicious, A. Alisauskas and A. Sirvaitis, Chem, vol. 76, 1972,
pp. 38400.
[7] K. Matsumoto, K. Takagi and S. Kaneko, J. Electrochem. Soc, vol. 130,
1983, pp. 423.
[8] Clare R. Collins, K. Vala Ragnarsdottir, David M. Sherman,
Geochemical et Cosmochimica Acta, vol. 63, 1999, pp. 2989-3002.
[9] Murugan, Vadivel, Kale, B.B.Swaminathan, V.Sonawane, vol. 4594,
2001, pp. 440-446.
[10] Yonghong Ni, Fei Wang, Hongjiang liu, Gui Yin, Jianming Hong, Xiang
Ma, and Zheng Xu, J. Cryst. Growth, Vol. 262, 2004, pp. 399-402.
[11] Eugenio Caponetti, Delia Chillura Martino, Maurizio Leone, Lucia
Pedone, Maria Luisa Saladino and Valeria Vetri, Journal of Colloid and
Inteface Science, vol. 304, 2006, pp. 413A-418.
[12] R. Banerjee, R. Jayakrishnan and P. Ayyub, J. Phys. Condens. Matter.
Vol. 12, 2000, pp. 10647-10654.
[13] R.I.Dimitrov, N. Moldovanska and I. K. Bonev, vol. 385, 2002, pp. 41-
49.
[14] Jun Chen, Xinbo Wang and Zhicheng Zhang, Materials letters, vol. 62,
2008, pp. 787-790.
[15] J. Barman, J. P. Borah, K. C. Sarma, Chalcogenide Letters, vol. 5, 2008,
265 - 271.
[16] R. Devi, P. Purkayastha, P. K. Kalita and B. Sarma, Sci. vol. 30, 2007,
123-128.
[17] C. Yohannan Panicker, Hema Tresa Varghese and Daizy Philip,
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,
vol. 65, 2006, pp. 802-804.
[18] R. I. Dimitrov and B. S. Boyanov, Journal of Thermal Analysis and
Calorimetry, vol. 61, 2000, pp. 181-189.
[19] R. I. Dimitrov, N. Moldovanska and I. K. Bonev, Cadmium sulphide
oxidation, vol. 385, 2002, pp. 41-49.
[1] Efros AL, Rosen M Annu, Rev. Mater. Sci. vol. 30, 2003, pp. 475.
[2] R. I. Dimitrov and B. S. Boyanov, Journal of Thermal Analysis and
Calorimetry. Vol 61, 2000, pp. 181-189.
[3] P. Raji, C. Sanjeeviraja and K. Ramachandran, Cryst. Res. Technol, vol
28, 2005, pp. 233-238.
[4] Pushpa Ann Kurian, C. Vijayan, K. Sathiyamoorthy, C. S. Suchand
Sandeep, Reji Philip Res, Lett. 2, 2007, pp. 561-568.
[5] J. Jakimavicious, A. Alisauskas and A. Sirvaitis, Materials Chemistry
and Physics, Vol. 11, 1971, pp. 493.
[6] J. Jakimavicious, A. Alisauskas and A. Sirvaitis, Chem, vol. 76, 1972,
pp. 38400.
[7] K. Matsumoto, K. Takagi and S. Kaneko, J. Electrochem. Soc, vol. 130,
1983, pp. 423.
[8] Clare R. Collins, K. Vala Ragnarsdottir, David M. Sherman,
Geochemical et Cosmochimica Acta, vol. 63, 1999, pp. 2989-3002.
[9] Murugan, Vadivel, Kale, B.B.Swaminathan, V.Sonawane, vol. 4594,
2001, pp. 440-446.
[10] Yonghong Ni, Fei Wang, Hongjiang liu, Gui Yin, Jianming Hong, Xiang
Ma, and Zheng Xu, J. Cryst. Growth, Vol. 262, 2004, pp. 399-402.
[11] Eugenio Caponetti, Delia Chillura Martino, Maurizio Leone, Lucia
Pedone, Maria Luisa Saladino and Valeria Vetri, Journal of Colloid and
Inteface Science, vol. 304, 2006, pp. 413A-418.
[12] R. Banerjee, R. Jayakrishnan and P. Ayyub, J. Phys. Condens. Matter.
Vol. 12, 2000, pp. 10647-10654.
[13] R.I.Dimitrov, N. Moldovanska and I. K. Bonev, vol. 385, 2002, pp. 41-
49.
[14] Jun Chen, Xinbo Wang and Zhicheng Zhang, Materials letters, vol. 62,
2008, pp. 787-790.
[15] J. Barman, J. P. Borah, K. C. Sarma, Chalcogenide Letters, vol. 5, 2008,
265 - 271.
[16] R. Devi, P. Purkayastha, P. K. Kalita and B. Sarma, Sci. vol. 30, 2007,
123-128.
[17] C. Yohannan Panicker, Hema Tresa Varghese and Daizy Philip,
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,
vol. 65, 2006, pp. 802-804.
[18] R. I. Dimitrov and B. S. Boyanov, Journal of Thermal Analysis and
Calorimetry, vol. 61, 2000, pp. 181-189.
[19] R. I. Dimitrov, N. Moldovanska and I. K. Bonev, Cadmium sulphide
oxidation, vol. 385, 2002, pp. 41-49.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:52546", author = "Aneeqa Sabah and Saadat Anwar Siddiqi and Salamat Ali", title = "Fabrication and Characterization of CdS Nanoparticles Annealed by using Different Radiations", abstract = "The systematic manipulations of shapes and sizes of
inorganic compounds greatly benefit the various application fields
including optics, magnetic, electronics, catalysis and medicine.
However shape control has been much more difficult to achieve.
Hence exploration of novel method for the preparation of differently
shaped nanoparticles is challenging research area. II-VI group of
semiconductor cadmium sulphide (CdS) nanostructure with different
morphologies (such as, acicular like, mesoporous, spherical shapes)
and of crystallite sizes vary from 11 to 16 nm were successfully
synthesized by chemical aqueous precipitation of Cd2+ ions with
homogeneously released S2- ions from decomposition of cadmium
sulphate (CdSO4) and thioacetamide (CH3CSNH2) by annealing at
different radiations (microwave, ultrasonic and sunlight) with matter
and systematic research has been done for various factors affecting
the controlled growth rate of CdS nanoparticles. The obtained
nanomaterials have been characterized by X-ray Diffraction (XRD),
Fourier Transform Infrared Spectroscopy (FTIR),
Thermogravometric (DSC-TGA) analysis and Scanning Electron
Microscopy (SEM). The result indicates that on increasing the
reaction time particle size increases but on increasing the molar ratios
grain size decreases.", keywords = "CdS nanoparticles, Morphology, Oxidation,Radiations", volume = "4", number = "9", pages = "559-8", }