Abstract: The present research focus on the processing of mullite-based ceramics from oil refinery industrial wastes and byproducts of agricultural industry and on the investigating of silane modified surface of ceramics. Two waste products were used as initial material – waste aluminum oxide and waste rice husk. The burning - out additives used were waste rise husk. It is known that the oxide ceramics surface is hydrophilic due to the presence of – OH groups in it. The nature of ceramic surface regarding permeation of water and hydrocarbons can be changed by further treatment with silanes. The samples were studied mainly by X-ray analysis, FT-IR absorbance measurements and microscopic analysis. The X-ray analyses showed the phase composition depends on the firing temperature and on the purity of the starting alumina. Two kind of silanes were used for the transformation of surface from hydrophilic to hydrophobic – trimethoxymethylsilane (TMMS) and trimethylclorsilane (TMCS).
Abstract: In this article the investigation about installation heat
recovery steam generation (HRSG) on the exhaust of turbo generators of phases 2&3 at South Pars Gas Complex is presented.
The temperature of exhaust gas is approximately 665 degree centigrade, Installation of heat recovery boiler was simulated in
ThermoFlow 17.0.2 software, based on test operation data and the
equipments site operation conditions in Pars exclusive economical energy area, the affect of installation HRSG package on the available
gas turbine and its operation parameters, ambient temperature, the
exhaust temperatures steam flow rate were investigated. Base on the results recommended HRSG package should have the capacity for 98
ton per hour high pressure steam generation this refinery, by use of
exhaust of three gas turbines for each package in operation condition of each refinery at 30 degree centigrade. Besides saving energy this
project will be an Environment-Friendly project. The Payback Period
is estimated approximately 1.8 year, with considering Clean Development Mechanism.
Abstract: Anaerobic treatment has many advantages over other
biological method particularly when used to treat complex
wastewater such as petroleum refinery wastewater. In this study two
Up-flow Anaerobic Sludge Blanket (UASB) reactors were operated
in parallel to treat six volumetric organic loads (0.58, 1.21, 0.89,
2.34, 1.47 and 4.14 kg COD/m3·d) to evaluate the chemical oxygen
demand (COD) removal efficiency. The reactors were continuously
adapting to the changing of operation condition with increase in the
removal efficiency or slight decrease until the last load which was
more than two times the load, at which the reactor stressed and the
removal efficiency decreased to 75% with effluent concentration of
1746 mg COD/L. Other parameters were also monitored such as pH,
alkalinity, volatile fatty acid and gas production rate. The UASB
reactor was suitable to treat petroleum refinery wastewater and the
highest COD removal rate was 83% at 1215 kg/m3·d with COD
concentration about 356 mg/L in the effluent.
Abstract: Heterogeneous catalysis is vital for a number of
chemical, refinery and pollution control processes. The use of
catalyst pellets of hollow cylindrical shape provide several distinct
advantages over other common shapes, and can therefore help to
enhance conversion levels in reactors. A better utilization of the
catalytic material is probably most notable of these features due to
the absence of the pellet core, which helps to significantly lower the
effect of the internal transport resistance. This is reflected in the
enhancement of the effectiveness factor. For the case of the first order
irreversible kinetics, a substantial increase in the effectiveness factor
can be obtained by varying shape parameters. Important shape
parameters of a finite hollow cylinder are the ratio of the inside to the
outside radii (κ) and the height to the diameter ratio (γ). A high value
of κ the generally helps to enhance the effectiveness factor. On the
other hand, lower values of the effectiveness factors are obtained
when the dimension of the height and the diameter are comparable.
Thus, the departure of parameter γ from the unity favors higher
effectiveness factor. Since a higher effectiveness factor is a measure
of a greater utilization of the catalytic material, higher conversion
levels can be achieved using the hollow cylindrical pellets possessing
optimized shape parameters.
Abstract: The recovery of metal values and safe disposal of
spent catalyst is gaining interest due to both its hazardous nature and
increased regulation associated with disposal methods. Prior to the
recovery of the valuable metals, removal of entrained deposits limit
the diffusion of lixiviate resulting in low recovery of metals must be
taken into consideration. Therefore, petroleum refinery spent catalyst
was subjected to acetone washing and roasting at 500oC. The treated
samples were investigated for metals bioleaching using
Acidithiobacillus ferrooxidans in batch reactors and the leaching
efficiencies were compared. It was found out that acetone washed
spent catalysts results in better metal recovery compare to roasted
spent. About 83% Ni, 20% Al, 50% Mo and 73% V were leached
using the acetone washed spent catalyst. In both the cases, Ni, V and
Mo was high compared to Al.
Abstract: Explosion occurs due to sudden release of energy.
Common examples of explosion include chemical, atomic, heat, and
pressure tank (due to ignition) explosions. Petroleum, gas, and
petrochemical industries operations are threatened by natural risks
and processes. Fires and explosions are the greatest process risks
which cause financial damages.
This study aims at designing a single-floor structure for the control
room of a petroleum refinery to be resistant against gas explosion
loads, and the information related to the structure specifications have
been provided regarding the fact that the structure is made on the
ground's surface. In this research, the lateral stiffness of single pile is
calculated by SPPLN.FOR computer program, and its value for
13624 KN/m single pile has been assessed. The analysis used due to
the loading conditions, is dynamic nonlinear analysis with direct
integration method.
Abstract: This study aimed to evaluate regional soil Borkhar of
the metals Lead has been made. In this field study fires visits to the
regions. The limit of this study located in the East refineries,
petrochemical and power plant to 20 km was selected. The 41 soil
samples from depths of 0 to 10 cm in area and were randomized. Soil
samples were transported to the laboratory and by air was dry and
passed through 2-mil thickness sieve. In the laboratory of physical
and chemical characteristics and concentrations of total absorption
was measured. The results showed that the amount of lead in soil in
many parts of the range higher than the standard limit. Survey maps
show that the lead spatial distribution of the region does not special
pattern.
Abstract: Analysis of reciprocating equipment piston rod leads
to nonlinear elastic-plastic deformation analysis of rod with initial
imperfection under axial dynamic load. In this paper a new and
effective model and analytical formulations are presented to evaluate
dynamic deformation and elastic-plastic stresses of reciprocating
machine piston rod. This new method has capability to account for
geometric nonlinearity, elastic-plastic deformation and dynamic
effects. Proposed method can be used for evaluation of piston rod
performance for various reciprocating machines under different
operation situations. Rod load curves and maximum allowable rod
load are calculated with presented method for a refinery type
reciprocating compressor. Useful recommendations and guidelines
for rod load, rod load reversal and rod drop monitoring are also
addressed.
Abstract: In this study, a reformer model simulation to use
refinery (Farashband refinery, Iran) waste natural gas. In the
petroleum and allied sectors where natural gas is being encountered
(in form of associated gas) without prior preparation for its positive
use, its combustion (which takes place in flares, an equipment through
which they are being disposed) has become a great problem because
of its associated environmental problems in form of gaseous emission.
The proposed model is used to product syngas from waste natural gas.
A detailed steady model described by a set of ordinary differential and
algebraic equations was developed to predict the behavior of the
overall process. The proposed steady reactor model was validated
against process data of a reformer synthesis plant recorded and a good
agreement was achieved. H2/CO ratio has important effect on Fischer-
Tropsch synthesis reactor product and we try to achieve this parameter
with best designing reformer reactor. We study different kind of
reformer reactors and then select auto thermal reforming process of
natural gas in a fixed bed reformer that adjustment H2/CO ratio with
CO2 and H2O injection. Finally a strategy was proposed for prevention
of extra natural gas to atmosphere.
Abstract: In this study, the ability of Aspergillus niger and
Penicillium simplicissimum to extract heavy metals from a spent
refinery catalyst was investigated. For the first step, a spent
processing catalyst from one of the oil refineries in Iran was
physically and chemically characterized. Aspergillus niger and
Penicillium simplicissimum were used to mobilize Al/Co/Mo/Ni from
hazardous spent catalysts. The fungi were adapted to the mixture of
metals at 100-800 mg L-1 with increments in concentration of 100 mg
L-1. Bioleaching experiments were carried out in batch cultures. To
investigate the production of organic acids in sucrose medium,
analyses of the culture medium by HPLC were performed at specific
time intervals after inoculation. The results obtained from Inductive
coupled plasma-optical emission spectrometry (ICP-OES) showed
that after the one-step bioleaching process using Aspergillus niger,
maximum removal efficiencies of 27%, 66%, 62% and 38% were
achieved for Al, Co, Mo and Ni, respectively. However, the highest
removal efficiencies using Penicillium simplicissimum were of 32%,
67%, 65% and 38% for Al, Co, Mo and Ni, respectively
Abstract: Methane is the second most important greenhouse gas
(GHG) after carbon dioxide. Amount of methane emission from
energy sector is increasing day by day with various activities. In
present work, various sources of methane emission from upstream,
middle stream and downstream of oil & gas sectors are identified and
categorised as per IPCC-2006 guidelines. Data were collected from
various oil & gas sector like (i) exploration & production of oil & gas
(ii) supply through pipelines (iii) refinery throughput & production
(iv) storage & transportation (v) usage. Methane emission factors for
various categories were determined applying Tier-II and Tier-I
approach using the collected data. Total methane emission from
Indian Oil & Gas sectors was thus estimated for the year 1990 to
2007.
Abstract: This work concerns the topological optimization
problem for determining the optimal petroleum refinery
configuration. We are interested in further investigating and
hopefully advancing the existing optimization approaches and
strategies employing logic propositions to conceptual process
synthesis problems. In particular, we seek to contribute to this
increasingly exciting area of chemical process modeling by
addressing the following potentially important issues: (a) how the
formulation of design specifications in a mixed-logical-and-integer
optimization model can be employed in a synthesis problem to enrich
the problem representation by incorporating past design experience,
engineering knowledge, and heuristics; and (b) how structural
specifications on the interconnectivity relationships by space (states)
and by function (tasks) in a superstructure should be properly
formulated within a mixed-integer linear programming (MILP)
model. The proposed modeling technique is illustrated on a case
study involving the alternative processing routes of naphtha, in which
significant improvement in the solution quality is obtained.
Abstract: Petroleum refineries discharged large amount of
wastewater -during the refining process- that contains hazardous
constituents that is hard to degrade. Anaerobic treatment process is
well known as an efficient method to degrade high strength
wastewaters. Up-flow Anaerobic Sludge Blanker (UASB) is a
common process used for various wastewater treatments. Two UASB
reactors were set up and operated in parallel to evaluate the treatment
efficiency of petroleum refinery wastewater. In this study four
organic volumetric loading rates were applied (i.e. 0.58, 0.89, 1.21
and 2.34 kg/m3·d), two loads to each reactor. Each load was applied
for a period of 60 days for the reactor to acclimatize and reach steady
state, and then the second load applied. The chemical oxygen demand
(COD) removals were satisfactory with the removal efficiencies at the
loadings applied were 78, 82, 83 and 81 % respectively.