Abstract: Soil microbial activity is adversely affected by pollutants such as heavy metals, antibiotics and pesticides. Organic amendments including sewage sludge, municipal compost and vermicompost are recently used to improve soil structure and fertility. But, these materials contain heavy metals including Pb, Cd, Zn, Ni and Cu that are toxic to soil microorganisms and may lead to occurrence of more tolerant microbes. Among these, Pb is the most abundant and has more negative effect on soil microbial ecology. In this study, Pb levels of 0, 100, 200, 300, 400 and 500 mg Pb [as Pb(NO3)2] per kg soil were added to the pots containing 2 kg of a loamy soil and incubated for 6 months at 25°C with soil moisture of - 0.3 MPa. Dehydrogenase activity of soil as a measure of microbial activity was determined on 15, 30, 90 and 180 days after incubation. Triphenyl tetrazolium chloride (TTC) was used as an electron acceptor in this assay. PICTs (IC50 values) were calculated for each Pb level and incubation time. Soil microbial activity was decreased by increasing Pb level during 30 days of incubation but the induced tolerance appeared on day 90 and thereafter. During 90 to 180 days of incubation, the PICT was gradually developed by increasing Pb level up to 200 mg kg-1, but the rate of enhancement was steeper at higher concentrations.
Abstract: The Beshar River is one aquatic ecosystem,which is
affected by pollutants. This study was conducted to evaluate the
effects of human activities on the water quality of the Beshar river.
This river is approximately 190 km in length and situated at the
geographical positions of 51° 20' to 51° 48' E and 30° 18' to 30° 52'
N it is one of the most important aquatic ecosystems of Kohkiloye
and Boyerahmad province next to the city of Yasuj in southern Iran.
The Beshar river has been contaminated by industrial, agricultural
and other activities in this region such as factories, hospitals,
agricultural farms, urban surface runoff and effluent of wastewater
treatment plants. In order to evaluate the effects of these pollutants
on the quality of the Beshar river, five monitoring stations were
selected along its course. The first station is located upstream of
Yasuj near the Dehnow village; stations 2 to 4 are located east, south
and west of city; and the 5th station is located downstream of Yasuj.
Several water quality parameters were sampled. These include pH,
dissolved oxygen, biological oxygen demand (BOD), temperature,
conductivity, turbidity, total dissolved solids and discharge or flow
measurements. Water samples from the five stations were collected
and analysed to determine the following physicochemical
parameters: EC, pH, T.D.S, T.H, No2, DO, BOD5, COD during 2008
to 2009. The study shows that the BOD5 value of station 1 is at a
minimum (1.5 ppm) and increases downstream from stations 2 to 4 to
a maximum (7.2 ppm), and then decreases at station 5. The DO
values of station 1 is a maximum (9.55 ppm), decreases downstream
to stations 2 - 4 which are at a minimum (3.4 ppm), before increasing
at station 5. The amount of BOD and TDS are highest at the 4th
station and the amount of DO is lowest at this station, marking the
4th station as more highly polluted than the other stations. The
physicochemical parameters improve at the 5th station due to
pollutant degradation and dilution. Finally the point and nonpoint
pollutant sources of Beshar river were determined and compared to
the monitoring results.
Abstract: Intermittent aeration process can be easily applied on
the existing activated sludge system and is highly reliable against the loading changes. It can be operated in a relatively simple way as well.
Since the moving-bed biofilm reactor method processes pollutants by attaching and securing the microorganisms on the media, the process
efficiency can be higher compared to the suspended growth biological
treatment process, and can reduce the return of sludge. In this study,
the existing intermittent aeration process with alternating flow being
applied on the oxidation ditch is applied on the continuous flow stirred tank reactor with advantages from both processes, and we would like
to develop the process to significantly reduce the return of sludge in the clarifier and to secure the reliable quality of treated water by
adding the moving media. Corresponding process has the appropriate
form as an infrastructure based on u- environment in future u- City and
is expected to accelerate the implementation of u-Eco city in conjunction with city based services. The system being conducted in a
laboratory scale has been operated in HRT 8hours except for the final
clarifier and showed the removal efficiency of 97.7 %, 73.1 % and 9.4
% in organic matters, TN and TP, respectively with operating range of
4hour cycle on system SRT 10days. After adding the media, the removal efficiency of phosphorus showed a similar level compared to
that before the addition, but the removal efficiency of nitrogen was
improved by 7~10 %. In addition, the solids which were maintained in
MLSS 1200~1400 at 25 % of media packing were attached all onto the
media, which produced no sludge entering the clarifier. Therefore, the
return of sludge is not needed any longer.
Abstract: Estimation of stormwater pollutants is a pre-requisite
for the protection and improvement of the aquatic environment and
for appropriate management options. The usual practice for the
stormwater quality prediction is performed through water quality
modeling. However, the accuracy of the prediction by the models
depends on the proper estimation of model parameters. This paper
presents the estimation of model parameters for a catchment water
quality model developed for the continuous simulation of stormwater
pollutants from a catchment to the catchment outlet. The model is
capable of simulating the accumulation and transportation of the
stormwater pollutants; suspended solids (SS), total nitrogen (TN) and
total phosphorus (TP) from a particular catchment. Rainfall and water
quality data were collected for the Hotham Creek Catchment (HTCC),
Gold Coast, Australia. Runoff calculations from the developed model
were compared with the calculated discharges from the widely used
hydrological models, WBNM and DRAINS. Based on the measured
water quality data, model water quality parameters were calibrated
for the above-mentioned catchment. The calibrated parameters are
expected to be helpful for the best management practices (BMPs)
of the region. Sensitivity analyses of the estimated parameters were
performed to assess the impacts of the model parameters on overall
model estimations of runoff water quality.
Abstract: The efficient operation of any biological treatment
process requires pre-treatment of incompatible pollutants such as
acids, bases, oil, toxic substances, etc. which hamper the treatment
of other major components which are otherwise degradable. The
pre-treatment of alkaline waste-waters, generated from various
industries like textile, paper & pulp, potato-processing industries,
etc., having a pH of 10 or higher, is essential. The pre-treatment,
i.e., neutralization of such alkaline waste-waters can be achieved by
chemical as well as biological means. However, the biological pretreatment
offers better package over the chemical means by being
safe and economical. The biological pre-treatment can be
accomplished by using a blend of microorganisms able to withstand
such harsh alkaline conditions. In the present study, for the proper
pre-treatment of alkaline waste-waters, a package of alkalophilic
bacteria is formulated to neutralise the alkaline pH of the industrial
waste-waters. The developed microbial package is cost-effective as
well as environmental friendly.
Abstract: The reduction in vehicle exhaust emissions achieved
in the last two decades is offset by the growth in traffic, as well as by
changes in the composition of emitted pollutants. The present
investigation illustrates the emissions of in-use gasoline and diesel
passenger cars using the official European driving cycle and the
ARTEMIS real-world driving cycle. It was observed that some of the
vehicles do not comply with the corresponding regulations.
Significant differences in emissions were observed between driving
cycles. Not all pollutants showed a tendency to decrease from Euro 3
to Euro 5.
Abstract: A 7-step method (with 25 sub-steps) to assess risk of
air pollutants is introduced. These steps are: pre-considerations,
sampling, statistical analysis, exposure matrix and likelihood, doseresponse
matrix and likelihood, total risk evaluation, and discussion
of findings. All mentioned words and expressions are wellunderstood;
however, almost all steps have been modified, improved,
and coupled in such a way that a comprehensive method has been
prepared. Accordingly, the SADRA (Statistical Analysis-Driven Risk
Assessment) emphasizes extensive and ongoing application of
analytical statistics in traditional risk assessment models. A Sulfur
Dioxide case study validates the claim and provides a good
illustration for this method.
Abstract: In Southeast Asia, during the dry season (August to
October) forest fires in Indonesia emit pollutants into the atmosphere.
For two years during this period, a total of 67 samples of 2.5 μm
particulate matters were collected and analyzed for total mass and
elemental composition with ICP - MS after microwave digestion. A
study of 60 elements measured during these periods suggest that the
concentration of most of elements, even those usually related to
crustal source, are extremely high and unpredictable during the haze
period. In By contrast, trace element concentration in non - haze
months is more stable and covers a lower range. Other unexpected
events and their effects on the findings are discussed.
Abstract: Catalytic converters are used for minimizing the release of pollutants to the atmosphere. It is during the warm-up period that hydrocarbons are seen to be released in appreciable quantities from these converters. In this paper the conversion of a fast oxidizing hydrocarbon propylene is analysed using two numerical methods. The quasi steady state method assumes the accumulation terms to be negligible in the gas phase mass and energy balance equations, however this term is present in the solid phase energy balance. The unsteady state model accounts for the accumulation term to be present in the gas phase mass and energy balance and in the solid phase energy balance. The results derived from the two models for gas concentration, gas temperature and solid temperature are compared.
Abstract: Water hyacinth has been used in aquatic systems for
wastewater purification in many years worldwide. The role of water
hyacinth (Eichhornia crassipes) species in polishing nitrate and
phosphorus concentration from municipal wastewater treatment plant
effluent by phytoremediation method was evaluated. The objective
of this project is to determine the removal efficiency of water
hyacinth in polishing nitrate and phosphorus, as well as chemical
oxygen demand (COD) and ammonia. Water hyacinth is considered
as the most efficient aquatic plant used in removing vast range of
pollutants such as organic matters, nutrients and heavy metals. Water
hyacinth, also referred as macrophytes, were cultivated in the
treatment house in a reactor tank of approximately 90(L) x 40(W) x
25(H) in dimension and built with three compartments. Three water
hyacinths were placed in each compartments and water sample in
each compartment were collected in every two days. The plant
observation was conducted by weight measurement, plant uptake and
new young shoot development. Water hyacinth effectively removed
approximately 49% of COD, 81% of ammonia, 67% of phosphorus
and 92% of nitrate. It also showed significant growth rate at starting
from day 6 with 0.33 shoot/day and they kept developing up to 0.38
shoot/day at the end of day 24. From the studies conducted, it was
proved that water hyacinth is capable of polishing the effluent of
municipal wastewater which contains undesirable amount of nitrate
and phosphorus concentration.
Abstract: Environmental impact assessment (EIA) is a procedure tool of environmental management for identifying, predicting, evaluating and mitigating the adverse effects of development proposals. EIA reports usually analyze how the amounts or concentrations of pollutants obey the relevant standards. Actually, many analytical tools can deepen the analysis of environmental impacts in EIA reports, such as life cycle assessment (LCA) and environmental risk assessment (ERA). Life cycle impact assessment (LCIA) is one of steps in LCA to introduce the causal relationships among environmental hazards and damage. Incorporating the LCIA concept into ERA as an integrated tool for EIA can extend the focus of the regulatory compliance of environmental impacts to determine of the significance of environmental impacts. Sometimes, when using integrated tools, it is necessary to consider fuzzy situations due to insufficient information; therefore, ERA should be generalized to fuzzy risk assessment (FRA). Finally, the use of the proposed methodology is demonstrated through the study case of the expansion plan of the world-s largest plastics processing factory.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: Polymeric microreactors have emerged as a new
generation of carriers that hold tremendous promise in the areas of
cancer therapy, controlled delivery of drugs, for removal of
pollutants etc. Present work reports a simple and convenient
methodology for synthesis of polystyrene and poly caprolactone
microreactors. An aqueous suspension of carboxylated (1μm)
polystyrene latex particles was mixed with toluene solution followed
by freezing with liquid nitrogen. Freezed particles were incubated at
-20°C and characterized for formation of voids on the surface of
polymer microspheres by Field Emission Scanning Electron
Microscope. The hollow particles were then overnight incubated at
40ºC with unfunctionalized quantum dots (QDs) in 5:1 ratio. QDs
Encapsulated polystyrene microcapsules were characterized by
fluorescence microscopy.
Likewise Poly ε-caprolactone microreactors were prepared by
micro-volcanic rupture of freeze dried microspheres synthesized
using emulsification of polymer with aqueous Poly vinyl alcohol and
freezed with liquid nitrogen. Microreactors were examined with Field
Emission Scanning Electron Microscope for size and morphology.
Current study is an attempt to create hollow polymer particles which
can be employed for microencapsulation of nanoparticles and drug
molecules.
Abstract: Thailand is one of the world-s leaders of rice
producers and exporters. Farmers have to increase the rice cultivation
frequency for serving the national increasing of export-s demand. It
leads to an elimination of rice residues by open burning which is the
quickest and costless management method. The open burning of rice
residue is one of the major causes of air pollutants and greenhouse
gas (GHG) emission. Under ASEAN agreement on trans-boundary
haze, Thailand set the master plan to mitigate air pollutant emission
from open burning of agricultural residues. In this master plan,
residues incorporation is promoted as alternative management
method to open burning. However, the assessment of both options in
term of GHG emission in order to investigate their contribution to
long-term global warming is still scarce or inexistent. In this study, a
method on rice residues assessment was first developed in order to
estimate and compare GHG emissions from rice cultivation under
rice residues open burning and the case with incorporation of the
same amount of rice residues, using 2006 IPCC guidelines for
emission estimation and Life Cycle Analysis technique. The
emission from rice cultivation in different preparing area practice
was also discussed.
Abstract: The modified Claus process is the major technology
for the recovery of elemental sulfur from hydrogen sulfide. The
chemical reactions that can occur in the reaction furnace are
numerous and many byproducts such as carbon disulfide and carbon
carbonyl sulfide are produced. These compounds can often contribute
from 20 to 50% of the pollutants and therefore, should be hydrolyzed
in the catalytic converter. The inlet temperature of the first catalytic
reactor should be maintained over than 250 °C, to hydrolyze COS
and CS2. In this paper, the various configurations for the first
converter reheating of sulfur recovery unit are investigated. As a
result, the performance of each method is presented for a typical
clause unit. The results show that the hot gas method seems to be
better than the other methods.
Abstract: Road industry has challenged the prospect of ecoconstruction. Pavements may fit within the framework of sustainable development. Hence, research implements assessments of conventional pavements impacts on environment in use of life cycle approach. To meet global, and often national, targets on pollution control, newly introduced pavement designs are under study. This is the case of Cyprus demonstration, which occurred within EcoLanes project work. This alternative pavement differs on concrete layer reinforced with tire recycling product. Processing of post-consumer tires produces steel fibers improving strength capacity against cracking. Thus maintenance works are relevantly limited in comparison to flexible pavement. This enables to be more ecofriendly, referenced to current study outputs. More specific, proposed concrete pavement life cycle processes emits 15 % less air pollutants and consumes 28 % less embodied energy than those of the asphalt pavement. In addition there is also a reduction on costs by 0.06 %.
Abstract: The present work was conducted for Arsenic (III)
removal, which one of the most poisonous groundwater pollutants, by
synthetic nano size zerovalent iron (nZVI). Batch experiments were
performed to investigate the influence of As (III), nZVI
concentration, pH of solution and contact time on the efficiency of As
(III) removal. nZVI was synthesized by reduction of ferric chloride
by sodium borohydrid. SEM and XRD were used to determine
particle size and characterization of produced nanoparticles. Up to
99.9% removal efficiency for arsenic (III) was obtained by nZVI
dosage of 1 g/L at time equal to 10 min. and pH=7. It could be
concluded that the removal efficiency were enhanced with increasing
of ZVI dosage and reaction time, but decreased with increasing of
arsenic concentration and pH for nano sized ZVI. nZVI presented an
outstanding ability to remove As (III) due to not only a high surface
area and low particle size but also to high inherent activity.
Abstract: The use of bioindicators plants (lichens, bryophytes
and Sphagnum....) in monitoring pollution by heavy metals has been
the subject of several works. However, few studies have addressed
the impact of specific type-s pollutants (fertilizers, pesticides.) on
these organisms.
We propose in this work to make the highlighting effect of NPKs
(NPK: nitrogen-phosphate-potassium-sulfate (NP2O5K2O) (15,15,15),
at concentrations of 10, 20, 30 , 40 and 50mM/L) on the activity of
detoxification enzymes (GSH/GST, CAT, APX and MDA) of plant
bioindicators (mosses and lichens) after treatment for 3 and 7 days.
This study shows the important role of the defense system in the
accumulation and tolerance to chemical pollutants through the
activation of enzymatic (GST (glutathione-S-transferase, APX
(ascorbat peroxidase), CAT (catalase)) and nonenzymatic biomarkers
(GSH (glutathione), MDA (malondialdehyde)) against oxidative
stress generated by the NPKs.
Abstract: Air pollution is a major environmental health
problem, affecting developed and developing countries around the
world. Increasing amounts of potentially harmful gases and
particulate matter are being emitted into the atmosphere on a global
scale, resulting in damage to human health and the environment.
Petroleum-related air pollutants can have a wide variety of adverse
environmental impacts. In the crude oil production sectors, there is a
strong need for a thorough knowledge of gaseous emissions resulting
from the flaring of associated gas of known composition on daily
basis through combustion activities under several operating
conditions. This can help in the control of gaseous emission from
flares and thus in the protection of their immediate and distant
surrounding against environmental degradation.
The impacts of methane and non-methane hydrocarbons emissions
from flaring activities at oil production facilities at Kuwait Oilfields
have been assessed through a screening study using records of flaring
operations taken at the gas and oil production sites, and by analyzing
available meteorological and air quality data measured at stations
located near anthropogenic sources. In the present study the
Industrial Source Complex (ISCST3) Dispersion Model is used to
calculate the ground level concentrations of methane and nonmethane
hydrocarbons emitted due to flaring in all over Kuwait
Oilfields.
The simulation of real hourly air quality in and around oil
production facilities in the State of Kuwait for the year 2006,
inserting the respective source emission data into the ISCST3
software indicates that the levels of non-methane hydrocarbons from
the flaring activities exceed the allowable ambient air standard set by
Kuwait EPA. So, there is a strong need to address this acute problem
to minimize the impact of methane and non-methane hydrocarbons
released from flaring activities over the urban area of Kuwait.
Abstract: Since injection engines have a considerable portion, in
consumption of energy and environmental pollution, using an
alternative source of energy with lower pollutant effects in this
regard is necessary.
Biodiesel fuel is a suitable alternative for gasoline in diesel
engines.
In this research the property of biodiesel, the function and the
pollution effects of diesel engine, when using 100% biodiesel, using
100% gasoline and mixing ratio of both fuels for comparing them,
have been investigated.
The researches have shown, using biodiesel fuel in prevalent
diesel engine, will reduce the pollutants such as Co, half burned
carbohydrate and suspended particles and a little increase in
oxidation will achieve while power consumption, particularly fuel
and thermal efficiency of diesel fuel has the same.