Abstract: Hydrogen is an important chemical in many industries and it is expected to become one of the major fuels for energy generation in the future. Unfortunately, hydrogen does not exist in its elemental form in nature and therefore has to be produced from hydrocarbons, hydrogen-containing compounds or water.
Above its critical point (374.8oC and 22.1MPa), water has lower density and viscosity, and a higher heat capacity than those of ambient water. Mass transfer in supercritical water (SCW) is enhanced due to its increased diffusivity and transport ability. The reduced dielectric constant makes supercritical water a better solvent for organic compounds and gases. Hence, due to the aforementioned desirable properties, there is a growing interest toward studies regarding the gasification of organic matter containing biomass or model biomass solutions in supercritical water.
In this study, hydrogen and biofuel production by the catalytic gasification of 2-Propanol in supercritical conditions of water was investigated. Ru/Al2O3 was the catalyst used in the gasification reactions. All of the experiments were performed under a constant pressure of 25 MPa. The effects of five reaction temperatures (400, 450, 500, 550 and 600oC) and five reaction times (10, 15, 20, 25 and 30 s) on the gasification yield and flammable component content were investigated.
Abstract: Recently, a growing interest has emerged on the development of new and efficient energy sources, due to the inevitable extinction of the nonrenewable energy reserves. One of these alternative sources which have a great potential and sustainability to meet up the energy demand is biomass energy. This significant energy source can be utilized with various energy conversion technologies, one of which is biomass gasification in supercritical water.
Water, being the most important solvent in nature, has very important characteristics as a reaction solvent under supercritical circumstances. At temperatures above its critical point (374.8oC and 22.1MPa), water becomes more acidic and its diffusivity increases. Working with water at high temperatures increases the thermal reaction rate, which in consequence leads to a better dissolving of the organic matters and a fast reaction with oxygen. Hence, supercritical water offers a control mechanism depending on solubility, excellent transport properties based on its high diffusion ability and new reaction possibilities for hydrolysis or oxidation.
In this study the gasification of a real biomass, namely olive mill wastewater (OMW), in supercritical water conditions is investigated with the use of Ru/Al2O3 catalyst. OMW is a by-product obtained during olive oil production, which has a complex nature characterized by a high content of organic compounds and polyphenols. These properties impose OMW a significant pollution potential, but at the same time, the high content of organics makes OMW a desirable biomass candidate for energy production.
The catalytic gasification experiments were made with five different reaction temperatures (400, 450, 500, 550 and 600°C) and five reaction times (30, 60, 90, 120 and 150s), under a constant pressure of 25MPa. Through these experiments, the effects of reaction temperature and time on the gasification yield, gaseous product composition and OMW treatment efficiency were investigated.
Abstract: This paper presents a new compact analytical model of
the gate leakage current in high-k based nano scale MOSFET by
assuming a two-step inelastic trap-assisted tunneling (ITAT) process
as the conduction mechanism. This model is based on an inelastic
trap-assisted tunneling (ITAT) mechanism combined with a semiempirical
gate leakage current formulation in the BSIM 4 model. The
gate tunneling currents have been calculated as a function of gate
voltage for different gate dielectrics structures such as HfO2, Al2O3
and Si3N4 with EOT (equivalent oxide thickness) of 1.0 nm. The
proposed model is compared and contrasted with santaurus
simulation results to verify the accuracy of the model and excellent
agreement is found between the analytical and simulated data. It is
observed that proposed analytical model is suitable for different highk
gate dielectrics simply by adjusting two fitting parameters. It was
also shown that gate leakages reduced with the introduction of high-k
gate dielectric in place of SiO2.
Abstract: In the context of introduction of deregulatory policy measures and subsequent wave of mergers and acquisitions (M&A) in Indian corporate sector since 1991, the present paper attempts to examine the welfare implications of this wave. It is found that M&A do not have any significant impact on consumers- welfare. Instead, consumers- welfare is significantly influenced by exports intensity, imports intensity, advertising intensity, technology related efforts, and past profitability of the firms. While the industries with higher exports orientation or greater product differentiation or better financial performance experience greater loss in consumers- welfare, it is less in the industries with greater competition from imports or better technology. Hence, the wave of M&A in Indian manufacturing sector in the post-liberalization era may not be a matter of serious concern from consumers- welfare point of view. Instead, in many cases, M&A can help the firms in consolidating their business and enhancing competitiveness, and this may benefit the consumers in the form of greater efficiency and lower prices.
Abstract: Structured catalysts formed from the growth of
zeolites on substrates is an area of increasing interest due to the
increased efficiency of the catalytic process, and the ability to
provide superior heat transfer and thermal conductivity for both
exothermic and endothermic processes.
However, the generation of structured catalysts represents a
significant challenge when balancing the relationship variables
between materials properties and catalytic performance, with the
Na2O, H2O and Al2O3 gel composition paying a significant role in
this dynamic, thereby affecting the both the type and range of
application.
The structured catalyst films generated as part of this
investigation have been characterised using a range of techniques,
including X-ray diffraction (XRD), Electron microscopy (SEM),
Energy Dispersive X-ray analysis (EDX) and Thermogravimetric
Analysis (TGA), with the transition from oxide-on-alloy wires to
hydrothermally synthesised uniformly zeolite coated surfaces being
demonstrated using both SEM and XRD. The robustness of the
coatings has been ascertained by subjecting these to thermal cycling
(ambient to 550oC), with the results indicating that the synthesis time
and gel compositions have a crucial effect on the quality of zeolite
growth on the FeCrAlloy wires.
Finally, the activity of the structured catalyst was verified by a
series of comparison experiments with standard zeolite Y catalysts in
powdered pelleted forms.
Abstract: The integration between technology of remote
sensing, information from the data of digital image, and modeling
technology for the simulation of water quality will provide easiness
during the observation on the quality of water changes on the river
surface. For example, Ciliwung River which is contaminated with
non-point source pollutant from household wastes, particularly on its
downstream. This fact informed that the quality of water in this river
is getting worse. The land use for settlements and housing ranges
between 62.84% - 81.26% on the downstream of Ciliwung River,
give a significant picture in seeing factors that affected the water
quality of Ciliwung River.
Abstract: In this study, the effect of mechanical activation on the synthesis of Fe3Al/Al2O3 nanocomposite has been investigated by using mechanochemical method. For this purpose, Aluminum powder and hematite as precursors, with stoichiometric ratio, have been utilized and other effective parameters in milling process were kept constant. Phase formation analysis, crystallite size measurement and lattice strain were studied by X-ray diffraction (XRD) by using Williamson-Hall method as well as microstructure and morphology were explored by Scanning electron microscopy (SEM). Also, Energy-dispersive X-ray spectroscopy (EDX) analysis was used in order to probe the particle distribution. The results showed that after 30-hour milling, the reaction was started, combustibly done and completed.
Abstract: Zirconium diamine and triamine complexes can possess biological activities. These complexes were synthesised via the reaction of equimolar quantities of 1,10-phenanthroline {NC3H3(C6H2)NC3H3} (L1) or 4-4-amino phenazone {ONC6H5(NH)CH(NH2} (L2) or diphenyl carbizon {HNNCO(NH)2(C6H5)} (L3) with a Zirconium Salt {ZrOCl2} in a 1:1 ratio to form complexes [{NC3H3(C6H2)NC3H3}ZrOCl2}] [ZrOCl2L1], [{(O2NC6H4(NH)(NH2)}ZrOCl2] [ZrOCl2L2] and [{HNNCO(NH)2(C6H5)ZrOCl2}] [ZrOCl2L3] respectively. They were characterised using Fourier Transform Infrared (FT-IR) and UV-Visible spectroscopy. Also a variable temperature study of these complexes was completed, using UV-Visible spectroscopy to observe electronic transitions under temperature control. Also a DFT study was done on these complexes via the information from FT-IR and UV-Visible spectroscopy.
These complexes were found to show different inhibition to the growth of bacterial strains of Bacillus spp. & Klebsiella spp. & E. coli & Proteus spp. & Pseudomona spp. at different concentrations (0.001, 0.2 and 1M). For better understanding these complexes were examined by using a Density Functional Theory (DFT) calculation.
Abstract: This paper deals with a high-order accurate Runge
Kutta Discontinuous Galerkin (RKDG) method for the numerical
solution of the wave equation, which is one of the simple case of a
linear hyperbolic partial differential equation. Nodal DG method is
used for a finite element space discretization in 'x' by discontinuous
approximations. This method combines mainly two key ideas which
are based on the finite volume and finite element methods. The
physics of wave propagation being accounted for by means of
Riemann problems and accuracy is obtained by means of high-order
polynomial approximations within the elements. High order accurate
Low Storage Explicit Runge Kutta (LSERK) method is used for
temporal discretization in 't' that allows the method to be nonlinearly
stable regardless of its accuracy. The resulting RKDG
methods are stable and high-order accurate. The L1 ,L2 and L∞ error
norm analysis shows that the scheme is highly accurate and effective.
Hence, the method is well suited to achieve high order accurate
solution for the scalar wave equation and other hyperbolic equations.
Abstract: The Shortest Approximate Common Superstring
(SACS) problem is : Given a set of strings f={w1, w2, ... , wn},
where no wi is an approximate substring of wj, i ≠ j, find a shortest
string Sa, such that, every string of f is an approximate substring of
Sa. When the number of the strings n>2, the SACS problem becomes
NP-complete. In this paper, we present a greedy approximation
SACS algorithm. Our algorithm is a 1/2-approximation for the SACS
problem. It is of complexity O(n2*(l2+log(n))) in computing time,
where n is the number of the strings and l is the length of a string.
Our SACS algorithm is based on computation of the Length of the
Approximate Longest Overlap (LALO).
Abstract: In industrial scale of Gas to Liquid (GTL) process in
Fischer-Tropsch (FT) synthesis, a part of reactor outlet gases such as
CO2 and CH4 as side reaction products, is usually recycled. In this
study, the influence of CO2 and CH4 on the performance and
selectivity of Co-Ru/Al2O3 catalyst is investigated by injection of
these gases (0-20 vol. % of feed) to the feed stream. The effect of
temperature and feed flow rate, are also inspected. The results show
that low amounts of CO2 in the feed stream, doesn`t change the
catalyst activity significantly but increasing the amount of CO2 (more
than 10 vol. %) cause the CO conversion to decrease and the
selectivity of heavy components to increase. Methane acts as an inert
gas and doesn`t affect the catalyst performance. Increasing feed flow
rate has negative effect on both CO conversion and heavy component
selectivity. By raising the temperature, CO conversion will increase
but there are more volatile components in the product. The effect of
CO2 on the catalyst deactivation is also investigated carefully and a
mechanism is suggested to explain the negative influence of CO2 on
catalyst deactivation.
Abstract: Selective oxidation of H2S to elemental sulfur in a
fixed bed reactor over newly synthesized alumina nanocatalysts was
physio-chemically investigated and results compared with a
commercial Claus catalyst. Amongst these new materials, Al2O3-
supported sodium oxide prepared with wet chemical technique and
Al2O3 nanocatalyst prepared with spray pyrolysis method were the
most active catalysts for selective oxidation of H2S to elemental
sulfur. Other prepared nanocatalysts were quickly deactivated,
mainly due to the interaction with H2S and conversion into sulfides.
Abstract: In this paper we are to find the optimum multiwavelet for compression of electrocardiogram (ECG) signals and then, selecting it for using with SPIHT codec. At present, it is not well known which multiwavelet is the best choice for optimum compression of ECG. In this work, we examine different multiwavelets on 24 sets of ECG data with entirely different characteristics, selected from MIT-BIH database. For assessing the functionality of the different multiwavelets in compressing ECG signals, in addition to known factors such as Compression Ratio (CR), Percent Root Difference (PRD), Distortion (D), Root Mean Square Error (RMSE) in compression literature, we also employed the Cross Correlation (CC) criterion for studying the morphological relations between the reconstructed and the original ECG signal and Signal to reconstruction Noise Ratio (SNR). The simulation results show that the Cardinal Balanced Multiwavelet (cardbal2) by the means of identity (Id) prefiltering method to be the best effective transformation. After finding the most efficient multiwavelet, we apply SPIHT coding algorithm on the transformed signal by this multiwavelet.
Abstract: Minimum Quantity Lubrication (MQL) technique
obtained a significant attention in machining processes to reduce
environmental loads caused by usage of conventional cutting fluids.
Recently nanofluids are finding an extensive application in the field
of mechanical engineering because of their superior lubrication and
heat dissipation characteristics. This paper investigates the use of a
nanofluid under MQL mode to improve grinding characteristics of
Ti-6Al-4V alloy. Taguchi-s experimental design technique has been
used in the present investigation and a second order model has been
established to predict grinding forces and surface roughness.
Different concentrations of water based Al2O3 nanofluids were
applied in the grinding operation through MQL setup developed in
house and the results have been compared with those of conventional
coolant and pure water. Experimental results showed that grinding
forces reduced significantly when nano cutting fluid was used even at
low concentration of the nano particles and surface finish has been
found to improve with higher concentration of the nano particles.
Abstract: A fully implicit finite-difference method has been proposed for the numerical solutions of one dimensional coupled nonlinear Burgers’ equations on the uniform mesh points. The method forms a system of nonlinear difference equations which is to be solved at each iteration. Newton’s iterative method has been implemented to solve this nonlinear assembled system of equations. The linear system has been solved by Gauss elimination method with partial pivoting algorithm at each iteration of Newton’s method. Three test examples have been carried out to illustrate the accuracy of the method. Computed solutions obtained by proposed scheme have been compared with analytical solutions and those already available in the literature by finding L2 and L∞ errors.
Abstract: The effect of chemical treatment in CdCl2 on the
compositional changes and defect structures of potentially useful ZnS
solar cell thin films prepared by vacuum deposition method was
studied using the complementary Rutherford backscattering (RBS)
and Thermoluminesence (TL) techniques. A series of electron and
hole traps are found in the various as deposited samples studied.
After treatment, perturbation on the intensity is noted; mobile defect
states and charge conversion and/or transfer between defect states are
found.
Abstract: This paper focuses on a critical component of the situational awareness (SA), the control of autonomous vertical flight for tactical unmanned aerial vehicle (TUAV). With the SA strategy, we proposed a two stage flight control procedure using two autonomous control subsystems to address the dynamics variation and performance requirement difference in initial and final stages of flight trajectory for an unmanned helicopter model with coaxial rotor and ducted fan configuration. This control strategy for chosen model of TUAV has been verified by simulation of hovering maneuvers using software package Simulink and demonstrated good performance for fast stabilization of engines in hovering, consequently, fast SA with economy in energy can be asserted during search-and-rescue operations.
Abstract: The steady mixed convection boundary layer flow from
a vertical cone in a porous medium filled with a nanofluid is
numerically investigated using different types of nanoparticles as Cu
(copper), Al2O3 (alumina) and TiO2 (titania). The boundary value
problem is solved by using the shooting technique by reducing it
into an ordinary differential equation. Results of interest for the local
Nusselt number with various values of the constant mixed convection
parameter and nanoparticle volume fraction parameter are evaluated.
It is found that dual solutions exist for a certain range of mixed
convection parameter.
Abstract: Thermal conductivity is an important characteristic of
a nanofluid in laminar flow heat transfer. This paper presents an
improved model for the prediction of the effective thermal
conductivity of nanofluids based on dimensionless groups. The
model expresses the thermal conductivity of a nanofluid as a function
of the thermal conductivity of the solid and liquid, their volume
fractions and particle size. The proposed model includes a parameter
which accounts for the interfacial shell, brownian motion, and
aggregation of particle. The validation of the model is verified by
applying the results obtained by the experiments of Tio2-water and
Al2o3-water nanofluids.
Abstract: In this paper we are to find the optimum
multiwavelet for compression of electrocardiogram (ECG)
signals. At present, it is not well known which multiwavelet is
the best choice for optimum compression of ECG. In this
work, we examine different multiwavelets on 24 sets of ECG
data with entirely different characteristics, selected from MITBIH
database. For assessing the functionality of the different
multiwavelets in compressing ECG signals, in addition to
known factors such as Compression Ratio (CR), Percent Root
Difference (PRD), Distortion (D), Root Mean Square Error
(RMSE) in compression literature, we also employed the
Cross Correlation (CC) criterion for studying the
morphological relations between the reconstructed and the
original ECG signal and Signal to reconstruction Noise Ratio
(SNR). The simulation results show that the cardbal2 by the
means of identity (Id) prefiltering method to be the best
effective transformation.