Abstract: Cs-type nanocomposite zeolite membrane was successfully synthesized on an alumina ceramic hollow fibre with a mean outer diameter of 1.7 mm; cesium cationic exchange test was carried out inside test module with mean wall thickness of 230 μm and an average crossing pore size smaller than 0.2 μm. Separation factor of n-butane/H2 obtained indicate that a relatively high quality closed to 20. Maxwell-Stefan modeling provides an equivalent thickness lower than 1 µm. To compare the difference an application to CO2/N2 separation has been achieved, reaching separation factors close to (4,18) before and after cation exchange on H-zeolite membrane formed within the pores of a ceramic alumina substrate.
Abstract: Vertical ZnO nanowire array films were synthesized
based on aqueous method for sensing applications. ZnO nanowires
were investigated structurally using X-ray diffraction (XRD) and
scanning electron microscopy (SEM). The gas-sensing properties of
ZnO nanowires array films are studied. It is found that the ZnO
nanowires array film sensor exhibits excellent sensing properties
towards O2 and CO2 at 100 °C with the response time shorter than 5
s. High surface area / volume ratio of vertical ZnO nanowire and high
mobility accounts for the fast response and recovery. The sensor
response was measured in the range from 100 to 500 ppm O2 and CO2
in this study.
Abstract: In this study, a 3D combustion chamber was simulated
using FLUENT 6.32. Aims to obtain accurate information about the
profile of the combustion in the furnace and also check the effect of
oxygen enrichment on the combustion process. Oxygen enrichment is
an effective way to reduce combustion pollutant. The flow rate of air
to fuel ratio is varied as 1.3, 3.2 and 5.1 and the oxygen enriched
flow rates are 28, 54 and 68 lit/min. Combustion simulations
typically involve the solution of the turbulent flows with heat
transfer, species transport and chemical reactions. It is common to
use the Reynolds-averaged form of the governing equation in
conjunction with a suitable turbulence model. The 3D Reynolds
Averaged Navier Stokes (RANS) equations with standard k-ε
turbulence model are solved together by Fluent 6.3 software. First
order upwind scheme is used to model governing equations and the
SIMPLE algorithm is used as pressure velocity coupling. Species
mass fractions at the wall are assumed to have zero normal
gradients.Results show that minimum mole fraction of CO2 happens
when the flow rate ratio of air to fuel is 5.1. Additionally, in a fixed
oxygen enrichment condition, increasing the air to fuel ratio will
increase the temperature peak. As a result, oxygen-enrichment can
reduce the CO2 emission at this kind of furnace in high air to fuel
rates.
Abstract: Understanding of how and where NOx formation
occurs in industrial burner is very important for efficient and clean
operation of utility burners. Also the importance of this problem is
mainly due to its relation to the pollutants produced by more burners
used widely of gas turbine in thermal power plants and glass and steel
industry.
In this article, a numerical model of an industrial burner operating
in MILD combustion is validated with experimental data.. Then
influence of air flow rate and air temperature on combustor
temperature profiles and NOX product are investigated. In order to
modification this study reports on the effects of fuel and air dilution
(with inert gases H2O, CO2, N2), and also influence of lean-premixed
of fuel, on the temperature profiles and NOX emission.
Conservation equations of mass, momentum and energy, and
transport equations of species concentrations, turbulence, combustion
and radiation modeling in addition to NO modeling equations were
solved together to present temperature and NO distribution inside the
burner.
The results shows that dilution, cause to a reduction in value of
temperature and NOX emission, and suppresses any flame
propagation inside the furnace and made the flame inside the furnace
invisible. Dilution with H2O rather than N2 and CO2 decreases further
the value of the NOX. Also with raise of lean-premix level, local
temperature of burner and the value of NOX product are decreases
because of premixing prevents local “hot spots" within the combustor
volume that can lead to significant NOx formation. Also leanpremixing
of fuel with air cause to amount of air in reaction zone is
reach more than amount that supplied as is actually needed to burn
the fuel and this act lead to limiting NOx formation
Abstract: Increasing concerns over climate change have limited
the liberal usage of available energy technology options. India faces
a formidable challenge to meet its energy needs and provide adequate
energy of desired quality in various forms to users in sustainable
manner at reasonable costs. In this paper, work carried out with an
objective to study the role of various energy technology options
under different scenarios namely base line scenario, high nuclear
scenario, high renewable scenario, low growth and high growth rate
scenario. The study has been carried out using Model for Energy
Supply Strategy Alternatives and their General Environmental
Impacts (MESSAGE) model which evaluates the alternative energy
supply strategies with user defined constraints on fuel availability,
environmental regulations etc. The projected electricity demand, at
the end of study period i.e. 2035 is 500490 MWYr. The model
predicted the share of the demand by Thermal: 428170 MWYr,
Hydro: 40320 MWYr, Nuclear: 14000 MWYr, Wind: 18000 MWYr
in the base line scenario. Coal remains the dominant fuel for
production of electricity during the study period. However, the
import dependency of coal increased during the study period. In
baseline scenario the cumulative carbon dioxide emissions upto 2035
are about 11,000 million tones of CO2. In the scenario of high nuclear
capacity the carbon dioxide emissions reduced by 10 % when nuclear
energy share increased to 9 % compared to 3 % in baseline scenario.
Similarly aggressive use of renewables reduces 4 % of carbon
dioxide emissions.
Abstract: Owing to the stringent environmental legislations,
CO2 capture and sequestration is one of the viable solutions to reduce
the CO2 emissions from various sources. In this context, Ionic liquids
(ILs) are being investigated as suitable absorption media for CO2
capture. Due to their non-evaporative, non-toxic, and non-corrosive
nature, these ILs have the potential to replace the existing solvents
like aqueous amine solutions for CO2 separation technologies. Thus,
the present work aims at studying the important aspects such as the
interactions of CO2 molecule with different anions (F-, Br-, Cl-, NO3
-,
BF4
-, PF6
-, Tf2N-, and CF3SO3
-) that are commonly used in ILs
through molecular modeling. In this, the minimum energy structures
have been obtained using Ab initio based calculations at MP2
(Moller-Plesset perturbation) level. Results revealed various degrees
of distortion of CO2 molecule (from its linearity) with the anions
studied, most likely due to the Lewis acid-base interactions between
CO2 and anion. Furthermore, binding energies for the anion-CO2
complexes were also calculated. The implication of anion-CO2
interactions to the solubility of CO2 in ionic liquids is also discussed.
Abstract: In the present study, a heterogeneous and
homogeneous gas flow dispersion model for simulation and
optimisation of a large-scale catalytic slurry reactor for the direct
synthesis of dimethyl ether (DME) from syngas and CO2, using a
churn-turbulent regime was developed. In the heterogeneous gas flow
model the gas phase was distributed into two bubble phases: small
and large, however in the homogeneous one, the gas phase was
distributed into only one large bubble phase. The results indicated
that the heterogeneous gas flow model was in more agreement with
experimental pilot plant data than the homogeneous one.
Abstract: Since the European renewable energy directives set the
target for 22.1% of electricity generation to be supplied by 2010
[1], there has been increased interest in using green technologies
also within the urban enviroment. The most commonly considered
installations are solar thermal and solar photovoltaics. Nevertheless,
as observed by Bahaj et al. [2], small scale turbines can reduce the
built enviroment related CO2 emissions. Thus, in the last few years,
an increasing number of manufacturers have developed small wind
turbines specifically designed for the built enviroment. The present
work focuses on the integration into architectural systems of such
installations and presents a survey of successful case studies.
Abstract: Experiments with pumpkin-rowanberry marmalade
candies were carried out at the Faculty of Food Technology of the
Latvia University of Agriculture. The objective of this investigation
was to evaluate the quality changes of pumpkin-rowanberry
marmalade candies packed in different packaging materials during
the storage of 15 weeks, and to find the most suitable packaging
material for prolongation of low sugar marmalade candies shelf-life.
An active packaging in combination with modified atmosphere
(MAP, CO2 100%) was examined and compared with traditional
packaging in air ambiance. Polymer Multibarrier 60 and paper bags
were used. Influence of iron based oxygen absorber in sachets of 500
cc obtained from Mitsubishi Gas Chemical Europe Ageless® on the
marmalade candies’ quality was tested during shelf life. Samples of
80±5 g were packaged in polymer pouches (110 mm x 110 mm),
hermetically sealed by MULTIVAC C300 vacuum chamber machine,
and stored in a room temperature +21±0.5 °C. The physiochemical
properties –moisture content, hardness, aw, pH, changes of
atmosphere content (CO2 and O2), ascorbic acid, total carotenoids,
total phenols in headspace of packs, and microbial conditions were
analysed before packaging and in the 1st, 3rd , 5th, 8th, 11th and 15th
weeks of storage.
Abstract: The present study conducted experimental investigation on combustion and emission characteristics of compression ignition engine using diesel as pilot fuel and methane, hydrogen and methane/hydrogen mixture as gaseous fuels at 1800 rev min-1. The effect of gaseous fuel on peak cylinder pressure and heat release is modest at low to medium loads. At high load, the high combustion temperature and high quantity of pilot fuel contribute to better combustion efficiency for all kinds of gaseous fuels and increases the peak cylinder pressure. Enrichment of hydrogen in methane gradually increases the peak cylinder pressure. The brake thermal efficiency increases with higher hydrogen fraction at lower loads. Hydrogen addition in methane contributed to a proportional reduction of CO/CO2/HC emission without penalty of NOx. For particulate emission, methane and hydrogen, could both suppress the particle emission. 30% hydrogen fraction in methane is observed to be best in reducing the particulate emission.
Abstract: The forest fires in Thailand are annual occurrence which is the cause of air pollutions. This study intended to estimate the emission from forest fire during 2005-2009 using MODerateresolution Imaging Spectro-radiometer (MODIS) sensor aboard the Terra and Aqua satellites, experimental data, and statistical data. The forest fire emission is estimated using equation established by Seiler and Crutzen in 1982. The spatial and temporal variation of forest fire emission is analyzed and displayed in the form of grid density map. From the satellite data analysis suggested between 2005 and 2009, the number of fire hotspots occurred 86,877 fire hotspots with a significant highest (more than 80% of fire hotspots) in the deciduous forest. The peak period of the forest fire is in January to May. The estimation on the emissions from forest fires during 2005 to 2009 indicated that the amount of CO, CO2, CH4, and N2O was about 3,133,845 tons, 47,610.337 tons, 204,905 tons, and 6,027 tons, respectively, or about 6,171,264 tons of CO2eq. They also emitted 256,132 tons of PM10. The year 2007 was found to be the year when the emissions were the largest. Annually, March is the period that has the maximum amount of forest fire emissions. The areas with high density of forest fire emission were the forests situated in the northern, the western, and the upper northeastern parts of the country.
Abstract: In recent years various types of electric vehicles
has gained again increasing attention as an environmentally
benign technology in transport. Especially for urban areas with
high local pollution this Zero-emission technology (at the point
of use) is considered to provide proper solutions. Yet, the bad
economics and the limited driving ranges are still major barriers
for a broader market penetration of battery electric vehicles
(BEV) and of fuel cell vehicles (FCV). The major result of our
analyses is that the most important precondition for a further
dissemination of BEV in urban areas are emission-free zones.
This is an instrument which allows the promotion of BEV
without providing excessive subsidies. In addition, it is
important to note that the full benefits of EV can only be
harvested if the electricity used is produced from renewable
energy sources. That is to say, it has to be ensured that the use of
BEV in urban areas is clearly linked to a green electricity
purchase model. And moreover, the introduction of a CO2-
emission-based tax system would support this requirement.
Abstract: In this study is presented a general methodology to
predict the performance of a continuous near-critical fluid extraction
process to remove compounds from aqueous solutions using hollow
fiber membrane contactors. A comprehensive 2D mathematical
model was developed to study Porocritical extraction process. The
system studied in this work is a membrane based extractor of ethanol
and acetone from aqueous solutions using near-critical CO2.
Predictions of extraction percentages obtained by simulations have
been compared to the experimental values reported by Bothun et al.
[5]. Simulations of extraction percentage of ethanol and acetone
show an average difference of 9.3% and 6.5% with the experimental
data, respectively. More accurate predictions of the extraction of
acetone could be explained by a better estimation of the transport
properties in the aqueous phase that controls the extraction of this
solute.
Abstract: This paper presents comparative emission study of
newly introduced gasoline/LPG bifuel automotive engine in Indian
market. Emissions were tested as per LPG-Bharat stage III driving
cycle. Emission tests were carried out for urban cycle and extra urban
cycle. Total time for urban and extra urban cycle was 1180 sec.
Engine was run in LPG mode by using conversion system. Emissions
were tested as per standard procedure and were compared. Corrected
emissions were computed by deducting ambient reading from sample
reading. Paper describes detail emission test procedure and results
obtained. CO emissions were in the range of38.9 to 111.3 ppm. HC
emissions were in the range of 18.2 to 62.6 ppm. Nox emissions were
08 to 3.9 ppm and CO2 emissions were from 6719.2 to 8051 ppm.
Paper throws light on emission results of LPG vehicles recently
introduced in Indian automobile market. Objectives of this
experimental study were to measure emissions of engines in gasoline
& LPG mode and compare them.
Abstract: Multi-energy systems will enhance the system
reliability and power quality. This paper presents an integrated
approach for the design and operation of distributed energy resources
(DER) systems, based on energy hub modeling. A multi-objective
optimization model is developed by considering an integrated view of
electricity and natural gas network to analyze the optimal design and
operating condition of DER systems, by considering two conflicting
objectives, namely, minimization of total cost and the minimization
of environmental impact which is assessed in terms of CO2
emissions. The mathematical model considers energy demands of the
site, local climate data, and utility tariff structure, as well as technical
and financial characteristics of the candidate DER technologies. To
provide energy demands, energy systems including photovoltaic, and
co-generation systems, boiler, central power grid are considered. As
an illustrative example, a hotel in Iran demonstrates potential
applications of the proposed method. The results prove that
increasing the satisfaction degree of environmental objective leads to
increased total cost.
Abstract: The research object was apple-black currant
marmalade candies. Experiments were carried out at the Faculty of
Food Technology of the Latvia University of Agriculture. An active
packaging in combination with modified atmosphere (MAP, CO2
100%) was examined and compared with traditional packaging in air
ambiance. Polymer Multibarrier 60 and paper bags were used.
Influence of iron based oxygen absorber in sachets of 500 cc
obtained from Mitsubishi Gas Chemical Europe Ageless® was tested
on the quality during the shelf of marmalade. Samples of 80±5 g
were packaged in polymer pouches (110 mm x 110 mm),
hermetically sealed by MULTIVAC C300 vacuum chamber machine,
and stored in room temperature +20.0±1.0 °C. The physiochemical
properties – weight losses, moisture content, hardness, aw, pH, colour,
changes of atmosphere content (CO2 and O2) in headspace of packs,
and microbial conditions were analysed before packaging and in the
1st, 3rd , 5th, 8th, 11th and 15th weeks of storage.
Abstract: The increasing industrialization and motorization of the world has led to a steep rise for the demand of petroleum-based fuels. Petroleum-based fuels are obtained from limited reserves. These finite reserves are highly concentrated in certain regions of the world. Therefore, those countries not having these resources are facing energy/foreign exchange crisis, mainly due to the import of crude petroleum. Hence, it is necessary to look for alternative fuels which can be produced from resources available locally within the country such as alcohol, biodiesel, vegetable oils etc. Biodiesel is a renewable, domestically produced fuel that has been shown to reduce particulate, hydrocarbon, and carbon monoxide emissions from combustion. In the present study an experimental investigation on emission characteristic of a liquid burner system operating on several percentage of biodiesel and gas oil is carried out. Samples of exhaust gas are analysed with Testo 350 Xl. The results show that biodiesel can lower some pollutant such as CO, CO2 and particulate matter emissions while NOx emission would increase in comparison with gas oil. The results indicate there may be benefits to using biodiesel in industrial processes.
Abstract: In this work, the precipitation of asphaltene from a Malaysian light oil reservoir was studies. A series of experiments were designed and carried out to examine the effect of CO2 injection on asphaltene precipitation. Different pressures of injections were used in Dynamic flooding experiment in order to investigate the effect of pressure versus injection pore volume of CO2. These dynamic displacement tests simulate reservoir condition. Results show that by increasing the pore volume of injected gas asphaltene precipitation will increases, also rise in injection pressure causes less precipitation. Sandstone core plug was used to represent reservoir formation during displacement test; therefore it made it possible to study the effect of present of asphaltene on formation. It is found out that the precipitated asphaltene can reduce permeability and porosity which is not favorable during oil production.
Abstract: In the present study, a steady-state simulation model
has been developed to evaluate the system performance of a
transcritical carbon dioxide heat pump system for simultaneous water
cooling and heating. Both the evaporator (including both two-phase
and superheated zone) and gas cooler models consider the highly
variable heat transfer characteristics of CO2 and pressure drop. The
numerical simulation model of transcritical CO2 heat pump has been
validated by test data obtained from experiments on the heat pump
prototype. Comparison between the test results and the model
prediction for system COP variation with compressor discharge
pressure shows a modest agreement with a maximum deviation of
15% and the trends are fairly similar. Comparison for other operating
parameters also shows fairly similar deviation between the test
results and the model prediction. Finally, the simulation results are
presented to study the effects of operating parameters such as,
temperature of heat exchanger fluid at the inlet, discharge pressure,
compressor speed on system performance of CO2 heat pump, suitable
in a dairy plant where simultaneous cooling at 4oC and heating at
73oC are required. Results show that good heat transfer properties of
CO2 for both two-phase and supercritical region and efficient
compression process contribute a lot for high system COPs.
Abstract: Using steelmaking slag as a raw material, aragonite superstructure product had been synthesized via an indirect CO2 mineral sequestration rout. It mainly involved two separate steps, in which the element of calcium is first selectively leached from steelmaking slag by a novel leaching media consisting of organic solvent Tributyl phosphate (TBP), acetic acid, and ultra-purity water, followed by enhanced carbonation in a separate step for aragonite superstructure production as well as efficiency recovery of leaching media. Based on the different leaching medium employed in the steelmaking slag leaching process, two typical products were collected from the enhanced carbonation step. The products were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM), respectively. It reveals that the needle-like aragonite crystals self-organized into aragonite superstructure particles including aragonite microspheres as well as dumbbell-like spherical particles, can be obtained from the steelmaking slag with the purity over 99%.