A Comparison between Heterogeneous and Homogeneous Gas Flow Model in Slurry Bubble Column Reactor for Direct Synthesis of DME

In the present study, a heterogeneous and homogeneous gas flow dispersion model for simulation and optimisation of a large-scale catalytic slurry reactor for the direct synthesis of dimethyl ether (DME) from syngas and CO2, using a churn-turbulent regime was developed. In the heterogeneous gas flow model the gas phase was distributed into two bubble phases: small and large, however in the homogeneous one, the gas phase was distributed into only one large bubble phase. The results indicated that the heterogeneous gas flow model was in more agreement with experimental pilot plant data than the homogeneous one.




References:
[1] K. L. Ng, D. Chadwick, and B. A. Toseland, "Kinetics and modelling of
dimethyl ether synthesis from synthesis gas," Chem. Eng. Sci., vol. 54,
pp. 3587-3592, 1999.
[2] Z. Chen, H. Zhang, W. Ying, and D. Fang, "Study on direct
alcohol/ether fuel synthesis process in bubble column slurry reactor,"
Fron. Chem. Eng. Chin., vol. 4, pp. 461-471, 2010.
[3] D. Liu, X. Hua, and D. Fang, "Mathematical Simulation and Design of
Three-Phase Bubble Column Reactor for Direct Synthesis of Dimethyl
Ether from Syngas," J. Nat. Gas Chem., vol. 16, pp. 193-199, 2007.
[4] C. Maretto, and R. Krishna, "Modelling of a bubble column slurry
reactor for Fischer-Tropsch synthesis," Catal. Today, vol. 52, pp. 279-
289, 1999.
[5] C. Maretto, and R. Krishna, "Design and optimisation of a multi-stage
bubble column slurry reactor for Fischer-Tropsch synthesis," Catal.
Today, vol. 66, pp. 241-248, 2001.
[6] I. G. Reilly, D. S. Scott, T. J. W Debruijn, and D. Macintyre, "A role of
gas phase momentum in determining gas holdup and hydrodynamic flow
regimes in bubble column operations," Can. J. Chem. Eng., vol. 72, pp.
3-12, 1994.
[7] R. Krishna, and J. W. A. de Swart, J. Ellenberger, G. B. Martina, and C.
Maretto, "Gas holdup in slurry bubble columns: effect of column
diameter and slurry concentrations," AIChE J., vol. 43, pp. 311-316,
1997.
[8] D. J. Vermeer, and R. Krishna, "Hydrodynamics and mass transfer in
bubble columns operating in the churn-turbulent regime," Ind. Eng.
Chem. Process Des. Dev., vol., 20, pp. 475-482, 1981.
[9] D. N. Smith, and J. A. Ruether, "Dispersed solid dynamics in a slurry
bubble column," Chem. Eng. Sci., vol. 40, pp. 741-775, 1985.
[10] J. W. A. De Swart, R. E. van Vliet, and R. Krishna, "Size, structure and
dynamics of "large" bubbles in a two-dimensional slurry bubble
column," Chem. Eng. Sci., vol. 51, pp. 4619-4629, 1996.
[11] R. W. Field, and J. F. Davidson, "Axial dispersion in bubble columns,"
Trans. Ins. Chem. Eng., vol. 58, pp. 228-235, 1980.
[12] W.-D. Deckwer, A. Schumpe, "Improved tools for bubble column
reactor design and scale-up," Chem. Eng. Sci., vol. 48, pp. 889-911,
1993.
[13] T. Wang, and J. Wang, "Numerical simulations of gas-liquid mass
transfer in bubble columns with a CFD-PBM coupled model," Chem.
Eng. Sci., vol. 62, pp. 7107-7118, 2007.
[14] H. Yagi, Y. Ohno, N. Inoue, K. Okuyama, and S. Aoki, "Slurry Phase
Reactor Technology for DME Direct Synthesis," Int. J. Chem. Reactor
Eng., vol. 8, pp. A109, 2010.