A Comparison between Heterogeneous and Homogeneous Gas Flow Model in Slurry Bubble Column Reactor for Direct Synthesis of DME
In the present study, a heterogeneous and
homogeneous gas flow dispersion model for simulation and
optimisation of a large-scale catalytic slurry reactor for the direct
synthesis of dimethyl ether (DME) from syngas and CO2, using a
churn-turbulent regime was developed. In the heterogeneous gas flow
model the gas phase was distributed into two bubble phases: small
and large, however in the homogeneous one, the gas phase was
distributed into only one large bubble phase. The results indicated
that the heterogeneous gas flow model was in more agreement with
experimental pilot plant data than the homogeneous one.
[1] K. L. Ng, D. Chadwick, and B. A. Toseland, "Kinetics and modelling of
dimethyl ether synthesis from synthesis gas," Chem. Eng. Sci., vol. 54,
pp. 3587-3592, 1999.
[2] Z. Chen, H. Zhang, W. Ying, and D. Fang, "Study on direct
alcohol/ether fuel synthesis process in bubble column slurry reactor,"
Fron. Chem. Eng. Chin., vol. 4, pp. 461-471, 2010.
[3] D. Liu, X. Hua, and D. Fang, "Mathematical Simulation and Design of
Three-Phase Bubble Column Reactor for Direct Synthesis of Dimethyl
Ether from Syngas," J. Nat. Gas Chem., vol. 16, pp. 193-199, 2007.
[4] C. Maretto, and R. Krishna, "Modelling of a bubble column slurry
reactor for Fischer-Tropsch synthesis," Catal. Today, vol. 52, pp. 279-
289, 1999.
[5] C. Maretto, and R. Krishna, "Design and optimisation of a multi-stage
bubble column slurry reactor for Fischer-Tropsch synthesis," Catal.
Today, vol. 66, pp. 241-248, 2001.
[6] I. G. Reilly, D. S. Scott, T. J. W Debruijn, and D. Macintyre, "A role of
gas phase momentum in determining gas holdup and hydrodynamic flow
regimes in bubble column operations," Can. J. Chem. Eng., vol. 72, pp.
3-12, 1994.
[7] R. Krishna, and J. W. A. de Swart, J. Ellenberger, G. B. Martina, and C.
Maretto, "Gas holdup in slurry bubble columns: effect of column
diameter and slurry concentrations," AIChE J., vol. 43, pp. 311-316,
1997.
[8] D. J. Vermeer, and R. Krishna, "Hydrodynamics and mass transfer in
bubble columns operating in the churn-turbulent regime," Ind. Eng.
Chem. Process Des. Dev., vol., 20, pp. 475-482, 1981.
[9] D. N. Smith, and J. A. Ruether, "Dispersed solid dynamics in a slurry
bubble column," Chem. Eng. Sci., vol. 40, pp. 741-775, 1985.
[10] J. W. A. De Swart, R. E. van Vliet, and R. Krishna, "Size, structure and
dynamics of "large" bubbles in a two-dimensional slurry bubble
column," Chem. Eng. Sci., vol. 51, pp. 4619-4629, 1996.
[11] R. W. Field, and J. F. Davidson, "Axial dispersion in bubble columns,"
Trans. Ins. Chem. Eng., vol. 58, pp. 228-235, 1980.
[12] W.-D. Deckwer, A. Schumpe, "Improved tools for bubble column
reactor design and scale-up," Chem. Eng. Sci., vol. 48, pp. 889-911,
1993.
[13] T. Wang, and J. Wang, "Numerical simulations of gas-liquid mass
transfer in bubble columns with a CFD-PBM coupled model," Chem.
Eng. Sci., vol. 62, pp. 7107-7118, 2007.
[14] H. Yagi, Y. Ohno, N. Inoue, K. Okuyama, and S. Aoki, "Slurry Phase
Reactor Technology for DME Direct Synthesis," Int. J. Chem. Reactor
Eng., vol. 8, pp. A109, 2010.
[1] K. L. Ng, D. Chadwick, and B. A. Toseland, "Kinetics and modelling of
dimethyl ether synthesis from synthesis gas," Chem. Eng. Sci., vol. 54,
pp. 3587-3592, 1999.
[2] Z. Chen, H. Zhang, W. Ying, and D. Fang, "Study on direct
alcohol/ether fuel synthesis process in bubble column slurry reactor,"
Fron. Chem. Eng. Chin., vol. 4, pp. 461-471, 2010.
[3] D. Liu, X. Hua, and D. Fang, "Mathematical Simulation and Design of
Three-Phase Bubble Column Reactor for Direct Synthesis of Dimethyl
Ether from Syngas," J. Nat. Gas Chem., vol. 16, pp. 193-199, 2007.
[4] C. Maretto, and R. Krishna, "Modelling of a bubble column slurry
reactor for Fischer-Tropsch synthesis," Catal. Today, vol. 52, pp. 279-
289, 1999.
[5] C. Maretto, and R. Krishna, "Design and optimisation of a multi-stage
bubble column slurry reactor for Fischer-Tropsch synthesis," Catal.
Today, vol. 66, pp. 241-248, 2001.
[6] I. G. Reilly, D. S. Scott, T. J. W Debruijn, and D. Macintyre, "A role of
gas phase momentum in determining gas holdup and hydrodynamic flow
regimes in bubble column operations," Can. J. Chem. Eng., vol. 72, pp.
3-12, 1994.
[7] R. Krishna, and J. W. A. de Swart, J. Ellenberger, G. B. Martina, and C.
Maretto, "Gas holdup in slurry bubble columns: effect of column
diameter and slurry concentrations," AIChE J., vol. 43, pp. 311-316,
1997.
[8] D. J. Vermeer, and R. Krishna, "Hydrodynamics and mass transfer in
bubble columns operating in the churn-turbulent regime," Ind. Eng.
Chem. Process Des. Dev., vol., 20, pp. 475-482, 1981.
[9] D. N. Smith, and J. A. Ruether, "Dispersed solid dynamics in a slurry
bubble column," Chem. Eng. Sci., vol. 40, pp. 741-775, 1985.
[10] J. W. A. De Swart, R. E. van Vliet, and R. Krishna, "Size, structure and
dynamics of "large" bubbles in a two-dimensional slurry bubble
column," Chem. Eng. Sci., vol. 51, pp. 4619-4629, 1996.
[11] R. W. Field, and J. F. Davidson, "Axial dispersion in bubble columns,"
Trans. Ins. Chem. Eng., vol. 58, pp. 228-235, 1980.
[12] W.-D. Deckwer, A. Schumpe, "Improved tools for bubble column
reactor design and scale-up," Chem. Eng. Sci., vol. 48, pp. 889-911,
1993.
[13] T. Wang, and J. Wang, "Numerical simulations of gas-liquid mass
transfer in bubble columns with a CFD-PBM coupled model," Chem.
Eng. Sci., vol. 62, pp. 7107-7118, 2007.
[14] H. Yagi, Y. Ohno, N. Inoue, K. Okuyama, and S. Aoki, "Slurry Phase
Reactor Technology for DME Direct Synthesis," Int. J. Chem. Reactor
Eng., vol. 8, pp. A109, 2010.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:53959", author = "Sadegh Papari and Mohammad Kazemeini and Moslem Fattahi", title = "A Comparison between Heterogeneous and Homogeneous Gas Flow Model in Slurry Bubble Column Reactor for Direct Synthesis of DME", abstract = "In the present study, a heterogeneous and
homogeneous gas flow dispersion model for simulation and
optimisation of a large-scale catalytic slurry reactor for the direct
synthesis of dimethyl ether (DME) from syngas and CO2, using a
churn-turbulent regime was developed. In the heterogeneous gas flow
model the gas phase was distributed into two bubble phases: small
and large, however in the homogeneous one, the gas phase was
distributed into only one large bubble phase. The results indicated
that the heterogeneous gas flow model was in more agreement with
experimental pilot plant data than the homogeneous one.", keywords = "Modelling, Slurry bubble column, Dimethyl ether
synthesis, Homogeneous gas flow, Heterogeneous gas flow", volume = "6", number = "3", pages = "194-5", }