Abstract: Natural hydrocarbon seepage has helped petroleum
exploration as a direct indicator of gas and/or oil subsurface
accumulations. Surface macro-seeps are generally an indication of a
fault in an active Petroleum Seepage System belonging to a Total
Petroleum System. This paper describes a case study in which
multiple analytical techniques were used to identify and characterize
trace petroleum-related hydrocarbons and other volatile organic
compounds in groundwater samples collected from Sousse aquifer
(Central Tunisia). The analytical techniques used for analyses of
water samples included gas chromatography-mass spectrometry (GCMS),
capillary GC with flame-ionization detection, Compound
Specific Isotope Analysis, Rock Eval Pyrolysis. The objective of the
study was to confirm the presence of gasoline and other petroleum
products or other volatile organic pollutants in those samples in order
to assess the respective implication of each of the potentially
responsible parties to the contamination of the aquifer. In addition,
the degree of contamination at different depths in the aquifer was also
of interest. The oil and gas seeps have been investigated using
biomarker and stable carbon isotope analyses to perform oil-oil and
oil-source rock correlations. The seepage gases are characterized by
high CH4 content, very low δ13CCH4 values (-71,9 ‰) and high
C1/C1–5 ratios (0.95–1.0), light deuterium–hydrogen isotope ratios (-
198 ‰) and light δ13CC2 and δ13CCO2 values (-23,8‰ and-23,8‰
respectively) indicating a thermogenic origin with the contribution of
the biogenic gas. An organic geochemistry study was carried out on
the more ten oil seep samples. This study includes light hydrocarbon
and biomarkers analyses (hopanes, steranes, n-alkanes, acyclic
isoprenoids, and aromatic steroids) using GC and GC-MS. The
studied samples show at least two distinct families, suggesting two
different types of crude oil origins: the first oil seeps appears to be
highly mature, showing evidence of chemical and/or biological
degradation and was derived from a clay-rich source rock deposited
in suboxic conditions. It has been sourced mainly by the lower
Fahdene (Albian) source rocks. The second oil seeps was derived
from a carbonate-rich source rock deposited in anoxic conditions,
well correlated with the Bahloul (Cenomanian-Turonian) source rock.
Abstract: Collection of storm water runoff and forcing it into the
groundwater is the need of the hour to sustain the ground water table.
However, the runoff entraps various types of sediments and other
floating objects whose removal are essential to avoid pollution of
ground water and blocking of pores of aquifer. However, it requires
regular cleaning and maintenance due to problem of clogging. To
evaluate the performance of filter system consisting of coarse sand
(CS), gravel (G) and pebble (P) layers, a laboratory experiment was
conducted in a rectangular column. The effect of variable thickness
of CS, G and P layers of the filtration unit of the recharge shaft on the
recharge rate and the sediment concentration of effluent water were
evaluated.
Medium sand (MS) of three particle sizes, viz. 0.150–0.300 mm
(T1), 0.300–0.425 mm (T2) and 0.425–0.600 mm of thickness 25 cm,
30 cm and 35 cm respectively in the top layer of the filter system and
having seven influent sediment concentrations of 250–3,000 mg/l
were used for experimental study. The performance was evaluated in
terms of recharge rates and clogging time. The results indicated that
100 % suspended solids were entrapped in the upper 10 cm layer of
MS, the recharge rates declined sharply for influent concentrations of
more than 1,000 mg/l. All treatments with higher thickness of MS
media indicated recharge rate slightly more than that of all treatment
with lower thickness of MS media respectively. The performance of
storm water infiltration systems was highly dependent on the
formation of a clogging layer at the filter. An empirical relationship
has been derived between recharge rates, inflow sediment load, size
of MS and thickness of MS with using MLR.
Abstract: The present paper summarizes the analysis of the
request for consultation of information and data on industrial
emissions made publicly available on the web site of the Ministry of
Environment, Land and Sea on integrated pollution prevention and
control from large industrial installations, the so called “AIA Portal”.
As a matter of fact, a huge amount of information on national
industrial plants is already available on internet, although it is usually
proposed as textual documentation or images.
Thus, it is not possible to access all the relevant information
through interoperability systems and also to retrieval relevant
information for decision making purposes as well as rising of
awareness on environmental issue.
Moreover, since in Italy the number of institutional and private
subjects involved in the management of the public information on
industrial emissions is substantial, the access to the information is
provided on internet web sites according to different criteria; thus, at
present it is not structurally homogeneous and comparable.
To overcome the mentioned difficulties in the case of the
Coordinating Committee for the implementation of the Agreement
for the industrial area in Taranto and Statte, operating before the
IPPC permit granting procedures of the relevant installation located
in the area, a big effort was devoted to elaborate and to validate data
and information on characterization of soil, ground water aquifer and
coastal sea at disposal of different subjects to derive a global
perspective for decision making purposes. Thus, the present paper
also focuses on main outcomes matured during such experience.
Abstract: Water a vital component for all living forms is derived from variety of sources, including surface water (rivers, lakes, reservoirs and ponds) and ground water (aquifers). Over the years of time, water bodies are subjected to human interference regularly resulting in deterioration of water quality. Therefore, pollution of water bodies has become matter of global concern. As the water quality closely relate to human health, water analysis before usage is of immense importance. Improper management of water bodies can cause serious problems in availability and quality of water. The quality of water may be described according to their physico-chemical and microbiological characteristics. For effective maintenance of water quality through appropriate control measures, continuous monitoring of metals, physico-chemical and biological parameter is essential for the establishment of baseline data for the water quality in any study area. The present study has focused on to explore the status of water pollution in various areas and to estimate the magnitude of its toxicity using different bioassay.
Abstract: The paper aims at evaluating the effects of heavy groundwater withdrawal and artificial groundwater recharge of an ex-mining pond to the aquifer system of the Langat Basin through the three-dimensional (3D) numerical modeling. Many mining sites have been left behind from the massive mining exploitations in Malaysia during the England colonization era and from the last few decades. These sites are able to accommodate more than a million cubic meters of water from precipitation, runoff, groundwater, and river. Most of the time, the mining sites are turned into ponds for recreational activities. In the current study, an artificial groundwater recharge from an ex-mining pond in the Langat Basin was proposed due to its capacity to store >50 million m3 of water. The location of the pond is near the Langat River and opposite a steel company where >4 million gallons of groundwater is withdrawn on a daily basis. The 3D numerical simulation was developed using the Groundwater Modeling System (GMS). The calibrated model (error about 0.7 m) was utilized to simulate two scenarios (1) Case 1: artificial recharge pond with no pumping and (2) Case 2: artificial pond with pumping. The results showed that in Case 1, the pond played a very important role in supplying additional water to the aquifer and river. About 90,916 m3/d of water from the pond, 1,173 m3/d from the Langat River, and 67,424 m3/d from the direct recharge of precipitation infiltrated into the aquifer system. In Case 2, due to the abstraction of groundwater from a company, it caused a steep depression around the wells, river, and pond. The result of the water budget showed an increase rate of inflow in the pond and river with 92,493m3/d and 3,881m3/d respectively. The outcome of the current study provides useful information of the aquifer behavior of the Langat Basin.
Abstract: The protection of groundwater resources is the great
important many semiarid and arid environments. Baghan watershed
is located in the north of Kangan in the Boshehr province in Iran. The
groundwater resources have a vital role in supplying agricultural,
drinking, domestic and industrial water demand in Baghan
watershed. For our investigation into the water quality we collected
30 samples to chemical and physical analysis. The result showed the
marl and evaporation deposits that contain anhydrite and gypsum is
the main source of groundwater pollution, and one part of the
groundwater was polluted by oil and gas industrial. Another part of
the groundwater was contaminated by urban waste water. The
electrical conductivity and captions and anions increased around of
towns and gas refinery. Although the negative impact of untreated
domestic wastewater is relatively low but the results showed strongly
the negative impact of wastewater refinery is very considerable. This
negative impact increased in downstream due to shallow aquifer.
Additionally, the agents that adversely affect the quality of
groundwater come from a variety of sources, including geology,
domestic wastewater and the Jam refinery in Baghan watershed.
Abstract: In-situ chemical oxidation (ISCO) has been widely
used for source zone remediation of Dense Nonaqueous Phase
Liquids (DNAPLs) in subsurface environments. DNAPL source
zones for karst aquifers are generally located in epikarst where the
DNAPL mass is trapped either in karst soil or at the regolith contact
with carbonate bedrock. This study aims to investigate the
performance of oxidation of residual trichloroethylene found in such
environments by potassium permanganate. Batch and flow cell
experiments were conducted to determine the kinetics and the mass
removal rate of TCE. pH change, Cl production, TCE and MnO4
destruction were monitored routinely during experiments. Nonreactive
tracer tests were also conducted prior and after the oxidation
process to determine the influence of oxidation on flow conditions.
The results show that oxidant consumption rate of the calcareous
epikarst soil was significant and the oxidant demand was determined
to be 20 g KMnO4/kg soil. Oxidation rate of residual TCE (1.26x10-3
s-1) was faster than the oxidant consumption rate of the soil (2.54 -
2.92x10-4 s-1) at only high oxidant concentrations (> 40 mM
KMnO4). Half life of TCE oxidation ranged from 7.9 to 10.7 min.
Although highly significant fraction of residual TCE mass in the
system was destroyed by permanganate oxidation, TCE
concentration in the effluent remained above its MCL. Flow
interruption tests indicate that efficiency of ISCO was limited by the
rate of TCE dissolution and the rate-limited desorption of TCE. The
residence time and the initial concentration of the oxidant in the
source zone also controlled the efficiency of ISCO in epikarst.
Abstract: Neural networks are well known for their ability to
model non linear functions, but as statistical methods usually does,
they use a no parametric approach thus, a priori knowledge is not
obvious to be taken into account no more than the a posteriori
knowledge. In order to deal with these problematics, an original way
to encode the knowledge inside the architecture is proposed. This
method is applied to the problem of the evapotranspiration inside
karstic aquifer which is a problem of huge utility in order to deal
with water resource.
Abstract: To make use of the limited amounts of water in arid
region, the Iranians developed man-made underground water
channels called qanats (kanats) .In fact, qanats may be considered as
the first long-distance water transfer system. Qanats are an ancient
water transfer system found in arid regions wherein groundwater
from mountainous areas, aquifers and sometimes from rivers, was
brought to points of re-emergence such as an oasis, through one or
more underground tunnels. The tunnels, many of which were
kilometers in length, had designed for slopes to provide gravitational
flow. The tunnels allowed water to drain out to the surface by gravity
to supply water to lower and flatter agricultural land.
Qanats have been an ancient, sustainable system facilitating the
harvesting of water for centuries in Iran, and more than 35 additional
countries of the world such as India, Arabia, Egypt, North Africa,
Spain and even to New world.
There are about 22000 qanats in Iran with 274000 kilometers of
underground conduits all built by manual labor. The amount of
water of the usable qanats of Iran produce is altogether 750 to
1000 cubic meter per second. The longest chain of qanat is
situated in Gonabad region in Khorasan province. It is 70
kilometers long. Qanats are renewable water supply systems that
have sustained agricultural settlement on the Iranian plateau for
millennia. The great advantages of Qanats are no evaporation
during transit, little seepage , no raising of the water- table and no
pollution in the area surrounding the conduits. Qanat systems
have a profound influence on the lives of the water users in Iran, and
conform to Iran-s climate. Qanat allows those living in a desert
environment adjacent to a mountain watershed to create a large oasis
in an otherwise stark environment.
This paper explains qanats structure designs, their history,
objectives causing their creation, construction materials, locations
and their importance in different times, as well as their present
sustainable role in Iran.
Abstract: The groundwater is one of the main sources for
sustainability in the United Arab Emirates (UAE). Intensive
developments in Al-Ain area lead to increase water demand, which
consequently reduced the overall groundwater quantity in major
aquifers. However, in certain residential areas within Al-Ain, it has
been noticed that the groundwater level is rising, for example in
Sha-ab Al Askher area. The reasons for the groundwater rising
phenomenon are yet to be investigated. In this work, twenty four
seismic refraction profiles have been carried out along the study
pilot area; as well as field measurement of the groundwater level in
a number of available water wells in the area. The processed
seismic data indicated the deepest and shallowest groundwater
levels are 15m and 2.3 meters respectively. This result is greatly
consistent with the proper field measurement of the groundwater
level. The minimum detected value may be referred to perched
subsurface water which may be associated to the infiltration from
the surrounding water bodies such as lakes, and elevated farms. The
maximum values indicate the accurate groundwater level within the
study area. The findings of this work may be considered as a
preliminary help to the decision makers.
Abstract: Geopolymer cement was evaluated as wellbore sealing material for carbon dioxide geosequestration application. Curing of cement system in saline water and strength testing in triaxial stress state condition under lateral confinement is relevant to primary cementing in CO2 geosequestration wellbore in saline aquifer. Geopolymer cement was cured in saline water (both at ambient conditions for 28 days and heated (60°C) conditions for 12 hours) and tested for triaxial strength at different levels of lateral confinement. Normal water and few other curing techniques were also studied both for geopolymer and API ‘G’ cement. Results reported were compared to evaluate the suitability of saline water for curing of geopolymer cement. Unconfined compression test results showed higher strength for curing in saline water than normal water. Besides, testing strength under lateral confinement demonstrated the material failure behavior from brittle to plastic.
Abstract: Groundwater is one of the most important water resources in Fars province. Based on this study, 95 percent of the total annual water consumption in Fars is used for agriculture, whereas the percentages for domestic and industrial uses are 4 and 1 percent, respectively. Population growth, urban and industrial growth, and agricultural development in Fars have created a condition of water stress. In this province, farmers and other users are pumping groundwater faster than its natural replenishment rate, causing a continuous drop in groundwater tables and depletion of this resource. In this research variation of groundwater level , their effects and ways to help control groundwater levels in some plains of Fars were evaluated .Excessive exploitation of groundwater in Darab, Jahrom, Estahban, Arsanjan, Khir and Niriz plains of Fars caused the groundwater levels fall too fast or to unacceptable levels. The average drawdown of the water table in Arsanjan, Khir. Estahban and Niriz plain plains were 12,8, 9 and 6 meters during 16,11,11 and 13 years ago respectively. This not only reduces available water resources and well yields but also can saline water intrusion, reductions in river flow and in wetland areas , drying springs, and ground subsidence, considerable increase in pumping costs and a significant decline in crop yields as a result of the increasing salinity. Finally based on situation and condition of the aquifer some suggestions are recommended.
Abstract: This study was conducted to evaluate factors
regulating groundwater quality in an area with agriculture as main
use. Under this study twelve groundwater samples have been
collected from Padra taluka, Dabhoi taluka and Savli taluka of
Vadodara district. Groundwater samples were chemically analyzed
for major physicochemical parameter in order to understand the
different geochemical processes affecting the groundwater quality.
The analytical results shows higher concentration of total dissolved
solids (16.67%), electrical conductivity (25%) and magnesium
(8.33%) for pre monsoon and total dissolved solids (16.67%),
electrical conductivity (33.3%) and magnesium (8.33%) for post
monsoon which indicates signs of deterioration as per WHO and BIS
standards. On the other hand, 50% groundwater sample is unsuitable
for irrigation purposes based on irrigation quality parameters. The
study revealed that application of fertilizer for agricultural
contributing the higher concentration of ions in aquifer of Vadodara
district.
Abstract: Groundwater is one of the most important water
resources in Fars province. Based on this study, 95 percent of the
total annual water consumption in Fars is used for agriculture,
whereas the percentages for domestic and industrial uses are 4 and 1
percent, respectively. Population growth, urban and industrial
growth, and agricultural development in Fars have created a
condition of water stress. In this province, farmers and other users are
pumping groundwater faster than its natural replenishment rate,
causing a continuous drop in groundwater tables and depletion of this
resource. In this research variation of groundwater level, their effects
and ways to help control groundwater levels in aquifer of the Kavar-
Maharloo plains in Fars plain were evaluated .Excessive
exploitation of groundwater in this aquifer caused the groundwater
levels fall too fast or to unacceptable levels. The average drawdown
of the groundwater level in this plain were 17 meters during
1995 to 2006. The purpose of this study is to evaluate water level
changes in the Kavar-Maharloo Aquifer in the Fars province in order
to determine the areas of greatest depletion, the cause of depletion,
and predict the remaining life of the aquifer.
Abstract: The development of entrepreneurial competences of
farmers has been pointed out as a necessary condition for the
modernization of land in facing the phenomenon of globalization.
However, the educational processes involved in such a development
have been studied little, especially in emerging economies. This
research aims to enlighten some of the critical issues behind the early
stages of the transformation of farmers into entrepreneurs, through in
depth interviews with farmers, entrepreneurial promoters and public
officials participating in a public pilot project in Mexico. Although
major impacts were expected only in the long run, important positive
changes in the mind set of farmers and other participants were found
in early stages of the intervention. Apparently, the farmers started a
process of becoming more conscious about the importance of
preserving the aquiferous resources, as well as more market and
entrepreneurial oriented.
Abstract: The Yazd-Ardakan basin in Central Iran has two separated aquifers. The shallow unconfined aquifer is supplies 40 Qanats. The deep saturated confined aquifer is the main water storage. Due to over-withdrawal, water table has been decreasing during last 25 years. Recent study shows that the shortage of the aquifer is about 16 meters and land subsidence is 0.5 - 1.2 meters. Long deep cracks are found just above the aquifer and devour the irrigation water and floods. Although the most cracks direction is NW-SE and could be compared to the main direction of YA basin, there is no direct evidence for relation between land subsidence and the huge cracks. Large-scale water pumping has been decreased the water pressure in aquifer. The pressure decline disturbed the balance and increased the pressure of overlying sediments. So porosity decreased and compaction started. Then, sediments compaction developed and made land subsidence and some huge cracks slowly.
Abstract: Groundwater resources in Arsanjan plain provide
water for agriculture, industry, and human consumption. Continued
agricultural development in this area needs to additional groundwater
resources for, particularly during of drought periods, and effects on
the quantity and quality of ground water available. The purpose of
this study is to evaluate water level changes in the aquifer of
Arsanjan plain in the Fars province in order to determine the areas of
greatest depletion and the causes of depletion. In this plain, farmers
and other users are pumping groundwater faster than its natural
replenishment rate, causing a continuous drop in groundwater tables
and depletion of this resource. In this research variation of
groundwater level, their effects and ways to help control groundwater
levels in aquifer of the Arsanjan plains were evaluated .Excessive
exploitation of groundwater in this aquifer caused the groundwater
levels fall too fast or to unacceptable levels. The average drawdown
of the groundwater level in this plain were 19.66 meters during
1996 to 2003.
Abstract: This research was conducted in the Lower Namkam
Irrigation Project situated in the Namkam River Basin in Thailand.
Degradation of groundwater quality in some areas is caused by saline
soil spots beneath ground surface. However, the tail regulated gate
structure on the Namkam River, a lateral stream of the Mekong
River. It is aimed for maintaining water level in the river at +137.5 to
+138.5 m (MSL) and flow to the irrigation canals based on a gravity
system since July 2009. It might leach some saline soil spots from
underground to soil surface if lack of understanding of the
conjunctive surface water and groundwater behaviors. This research
has been conducted by continuously the observing of both shallow
and deep groundwater level and quality from existing observation
wells. The simulation of surface water was carried out using a
hydrologic modeling system (HEC-HMS) to compute the ungauged
side flow catchments as the lateral flows for the river system model
(HEC-RAS). The constant water levels in the upstream of the
operated gate caused a slight rising up of shallow groundwater level
when compared to the water table. However, the groundwater levels
in the confined aquifers remained less impacted than in the shallow
aquifers but groundwater levels in late of wet season in some wells
were higher than the phreatic surface. This causes salinization of the
groundwater at the soil surface and might affect some crops. This
research aims for the balance of water stage in the river and efficient
groundwater utilization in this area.
Abstract: In order to monitor the water table depth on soil profile
salinity buildup, a field study was carried out during 2006-07. Wheat
(Rabi) and Sorghum (Kharif) fodder were sown in with three
treatments. The results showed that watertable depth lowered from
1.15m to 2.89 m depth at the end of experiment. With lower of
watertable depth, pH, ECe and SAR decreased under crops both
without and with gypsum and increased in fallowing. Soil moisture
depletion was directly proportional to lowering of watertable. With the
application of irrigation water (58cm) pH, ECe and SAR were reduced
in cropped plots, reduction was higher in gypsum applied plots than
non-gypsum plots. In case of fallowing, there was increase in pH, EC,
while slight reduction occurred in SAR values. However, soil salinity
showed an increasing upward trend under fallowing and its value in
0-30 cm soil layer was the highest amongst the treatments.
Abstract: Groundwater is an essential and vital component of our life support system. The groundwater resources are being utilized for drinking, irrigation and industrial purposes. There is growing concern on deterioration of groundwater quality due to geogenic and anthropogenic activities. Groundwater, being a fragile must be carefully managed to maintain its purity within standard limits. So, quality assessment and management are to be carried out hand-in-hand to have a pollution free environment and for a sustainable use. In order to assess the quality for consumption by human beings and for use in agriculture, the groundwater from the shallow aquifers (dug well) in the Palakkad and Chittur taluks of Bharathapuzha river basin - a paddy dominated agricultural basin (order=8th; L= 209 Km; Area = 6186 Km2), Kerala, India, has been selected. The water samples (n= 120) collected for various seasons, viz., monsoon-MON (August, 2005), postmonsoon-POM (December, 2005) and premonsoon-PRM (April, 2006), were analyzed for important physico-chemical attributes. Spatial and temporal variation of attributes do exist in the study area, and based on major cations and anions, different hydrochemical facies have been identified. Using Gibbs'diagram, rock dominance has been identified as the mechanism controlling groundwater chemistry. Further, the suitability of water for irrigation was determined by analyzing salinity hazard indicated by sodium adsorption ratio (SAR), residual sodium carbonate (RSC) and sodium percent (%Na). Finally, stress zones in the study area were delineated using Arc GIS spatial analysis and various management options were recommended to restore the ecosystem.