Abstract: In this study, the sorption of Malachite green (MG) on Hydrilla verticillata biomass, a submerged aquatic plant, was investigated in a batch system. The effects of operating parameters such as temperature, adsorbent dosage, contact time, adsorbent size, and agitation speed on the sorption of Malachite green were analyzed using response surface methodology (RSM). The proposed quadratic model for central composite design (CCD) fitted very well to the experimental data that it could be used to navigate the design space according to ANOVA results. The optimum sorption conditions were determined as temperature - 43.5oC, adsorbent dosage - 0.26g, contact time - 200min, adsorbent size - 0.205mm (65mesh), and agitation speed - 230rpm. The Langmuir and Freundlich isotherm models were applied to the equilibrium data. The maximum monolayer coverage capacity of Hydrilla verticillata biomass for MG was found to be 91.97 mg/g at an initial pH 8.0 indicating that the optimum sorption initial pH. The external and intra particle diffusion models were also applied to sorption data of Hydrilla verticillata biomass with MG, and it was found that both the external diffusion as well as intra particle diffusion contributes to the actual sorption process. The pseudo-second order kinetic model described the MG sorption process with a good fitting.
Abstract: The aim of this study was to synthesize the single
walled carbon nanotubes (SWCNTs) and determine their hydrogen
storage capacities. SWCNTs were firstly synthesized by chemical
vapor deposition (CVD) of acetylene (C2H2) on a magnesium oxide
(MgO) powder impregnated with an iron nitrate (Fe(NO3)3·9H2O)
solution. The synthesis parameters were selected as: the synthesis
temperature of 800°C, the iron content in the precursor of 5% and the
synthesis time of 30 min. Purification process of SWCNTs was
fulfilled by microwave digestion at three different temperatures (120,
150 and 200 °C), three different acid concentrations (0.5, 1 and 1.5
M) and for three different time intervals (15, 30 and 60 min). Nitric
acid (HNO3) was used in the removal of the metal catalysts. The
hydrogen storage capacities of the purified materials were measured
using volumetric method at the liquid nitrogen temperature and gas
pressure up to 100 bar. The effects of the purification conditions such
as temperature, time and acid concentration on hydrogen adsorption
were investigated.
Abstract: Snow cover is an important phenomenon in
hydrology, hence modeling the snow accumulation and melting is an
important issue in places where snowmelt significantly contributes to
runoff and has significant effect on water balance. The physics-based
models are invariably distributed, with the basin disaggregated into
zones or grid cells. Satellites images provide valuable data to verify
the accuracy of spatially distributed model outputs. In this study a
spatially distributed physically based model (WetSpa) was applied to
predict snow cover and melting in the Latyan dam watershed in Iran.
Snowmelt is simulated based on an energy balance approach. The
model is applied and calibrated with one year of observed daily
precipitation, air temperature, windspeed, and daily potential
evaporation. The predicted snow-covered area is compared with
remotely sensed images (MODIS). The results show that simulated
snow cover area SCA has a good agreement with satellite image
snow cover area SCA from MODIS images. The model performance
is also tested by statistical and graphical comparison of simulated and
measured discharges entering the Latyan dam reservoir.
Abstract: We developed a method based on quasi-molecular
modelling to simulate the fall of water drops on horizontally smooth
and rough surfaces. Each quasi-molecule was a group of particles
that interacted in a fashion entirely analogous to classical Newtonian
molecular interactions. When a falling water droplet was simulated at
low impact velocity on both smooth and rough surfaces, the droplets
moved periodically (i.e. the droplets moved up and down for a
certain period, finally they stopped moving and reached a steady
state), spreading and recoiling without splash or break-up. Spreading
rates of falling water droplets increased rapidly as time increased
until the spreading rate reached its steady state at time t ~ 0.25 s for
rough surface and t ~ 0.40 s for smooth surface. The droplet height
above both surfaces decreased as time increased, remained constant
after the droplet diameter attained a maximum value and reached its
steady state at time t ~ 0.4 s. However, rough surface had higher
spreading rates of falling water droplets and lower height on the
surface than smooth one.
Abstract: Helical milling operations are used to generate or
enlarge boreholes by means of a milling tool. The bore diameter can be
adjusted through the diameter of the helical path. The kinematics of
helical milling on a three axis machine tool is analysed firstly. The
relationships between processing parameters, cutting tool geometry
characters with machined hole feature are formulated. The feed motion
of the cutting tool has been decomposed to plane circular feed and
axial linear motion. In this paper, the time varying cutting forces acted
on the side cutting edges and end cutting edges of the flat end cylinder
miller is analysed using a discrete method separately. These two
components then are combined to produce the cutting force model
considering the complicated interaction between the cutters and
workpiece. The time varying cutting force model describes the
instantaneous cutting force during processing. This model could be
used to predict cutting force, calculate statics deflection of cutter and
workpiece, and also could be the foundation of dynamics model and
predicting chatter limitation of the helical milling operations.
Abstract: The rate of production of main products of the Fischer-Tropsch reactions over Fe/HZSM5 bifunctional catalyst in a fixed bed reactor is investigated at a broad range of temperature, pressure, space velocity, H2/CO feed molar ratio and CO2, CH4 and water flow rates. Model discrimination and parameter estimation were performed according to the integral method of kinetic analysis. Due to lack of mechanism development for Fisher – Tropsch Synthesis on bifunctional catalysts, 26 different models were tested and the best model is selected. Comprehensive one and two dimensional heterogeneous reactor models are developed to simulate the performance of fixed-bed Fischer – Tropsch reactors. To reduce computational time for optimization purposes, an Artificial Feed Forward Neural Network (AFFNN) has been used to describe intra particle mass and heat transfer diffusion in the catalyst pellet. It is seen that products' reaction rates have direct relation with H2 partial pressure and reverse relation with CO partial pressure. The results show that the hybrid model has good agreement with rigorous mechanistic model, favoring that the hybrid model is about 25-30 times faster.
Abstract: A self-association model has been used to understand
the concentration dependence of free energy of mixing (GM), heat of
mixing (HM), entropy of mixing (SM), activity (a) and microscopic
structures, such as concentration fluctuation in long wavelength limit
(Scc(0)) and Warren-Cowley short range order parameter ( 1
α )for Cu-
Tl molten alloys at 1573K. A comparative study of surface tension of
the alloys in the liquid state at that temperature has also been carried
out theoretically as function of composition in the light of Butler-s
model, Prasad-s model and quasi-chemical approach. Most of the
computed thermodynamic properties have been found in agreement
with the experimental values. The analysis reveals that the Cu-Tl
molten alloys at 1573K represent a segregating system at all
concentrations with moderate interaction. Surface tensions computed
from different approaches have been found to be comparable to each
other showing increment with the composition of copper.
Abstract: In this study, the conversion of n-pentane to aromatics is investigated on HZSM-5 zeolites modified by Ga ion-exchange and silylation using tetraethyl orthosilicate (TEOS) via chemical liquid deposition (CLD). The effect of SiO2/Al2O3 ratios of HZSM-5 was also studied. Parameters in preparing catalysts i.e. TEOS loading and cycles of deposition were varied to obtain the optimal condition for enhancing p-xylene selectivity. The highest p-xylene selectivity 99.7% was achieved when the amount of TEOS was 20 vol.%.The catalysts were characterized by TPD, TPO, XRF, and BET. Results show that the conversion of n-pentane was influenced remarkably by the SiO2/Al2O3 ratios of HZSM-5. The highest p-xylene selectivity 99.7% was achieved when the amount of TEOS was 20 vol.%. And cycles of deposition greatly improves HZSM-5 shape-selectivity.
Abstract: The implementations of green roof have been widely
used in the developed countries such as Germany, United Kingdom,
United States and Canada. Green roof have many benefits such as
aesthetic and economic value, ecological gain which are optimization
of storm water management, urban heat island mitigation and energy
conservation. In term of pollution, green roof can control the air and
noise pollution in urban cities. The application of green roof in
Malaysian building has been studied with the previous work of green
roof either in Malaysia or other Asian region as like Indonesia,
Singapore, Thailand, Taiwan and several other countries that have
similar climate and environment as in Malaysia. These technologies
of adapting green roof have been compared to the Green Building
Index (GBI) of Malaysian buildings. The study has concentrated on
the technical aspect of green roof system having focused on i) waste
& recyclable materials ii) types of plants and method of planting and
iii) green roof as tool to reduce storm water runoff. The finding of
these areas will be compared to the suitability in achieving good
practice of the GBI in Malaysia. Results show that most of the
method are based on the countries own climate and environment.
This suggests that the method of using green roof must adhere to the
tropical climate of Malaysia. Suggestion of this research will be
viewed in term of the sustainability of the green roof. Further
research can be developed to implement the best method and
application in Malaysian climate especially in urban cities and
township.
Abstract: This paper is concerned with an improved algorithm
based on the piecewise-smooth Mumford and Shah (MS) functional
for an efficient and reliable segmentation. In order to speed up
convergence, an additional force, at each time step, is introduced
further to drive the evolution of the curves instead of only driven by
the extensions of the complementary functions u + and u - . In our
scheme, furthermore, the piecewise-constant MS functional is
integrated to generate the extra force based on a temporary image that
is dynamically created by computing the union of u + and u - during
segmenting. Therefore, some drawbacks of the original algorithm,
such as smaller objects generated by noise and local minimal problem
also are eliminated or improved. The resulting algorithm has been
implemented in Matlab and Visual Cµ, and demonstrated efficiently
by several cases.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: A novel interpolation scheme to extend usable spectrum
and upconvert in high performance D/A converters is addressed in this
paper. By adjusting the pulse width of cycle and the production circuit
of code, the expansion code is a null code or complementary code that
is interpolation process. What the times and codes of interpolation
decide DAC works in one of a normal mode or multi-mixer mode
so that convert the input digital data signal into normal signal or a
mixed analog signal having a mixer frequency that is higher than the
data frequency. Simulation results show that the novel scheme and
apparatus most extend the usable frequency spectrum into fifth to
sixth Nyquist zone beyond conventional DACs.
Abstract: An experiment was performed with a 24.5 MeV 14N
beam on a 12C target in the cyclotron DC-60 located in Astana,
Kazakhstan, to study the elastic scattering of 14N on 12C; the
scattering was also analyzed at different energies for tracking the
phenomenon of remarkable structure at large angles. Its aims were to
extend the measurements to very large angles, and attempt to
uniquely identify the elastic scattering potential. Good agreement
between the theoretical and experimental data has been obtained with
suitable optical potential parameters. Optical model calculations with
l -dependent imaginary potentials were also applied to the data and
relatively good agreement was found.
Abstract: In the current age, retrieval of relevant information
from massive amount of data is a challenging job. Over the years,
precise and relevant retrieval of information has attained high
significance. There is a growing need in the market to build systems,
which can retrieve multimedia information that precisely meets the
user's current needs. In this paper, we have introduced a framework
for refining query results before showing it to the user, using ambient
intelligence, user profile, group profile, user location, time, day, user
device type and extracted features. A prototypic tool was also
developed to demonstrate the efficiency of the proposed approach.
Abstract: Composting is the process in which municipal solid
waste (MSW) and other organic waste materials such as biosolids
and manures are decomposed through the action of bacteria and other
microorganisms into a stable granular material which, applied to
land, as soil conditioner. Microorganisms, especially those that are
able to degrade polymeric organic material have a key role in speed
up this process. The aim of this study has been established to
isolation of microorganisms with high ability to production
extracellular enzymes for degradation of natural polymers that are
exists in MSW for decreasing time of degradation phase. Our
experimental study for isolation designed in two phases: in first
phase we isolated degrading microorganism with selected media that
consist a special natural polymer such as cellulose, starch, lipids and
etc as sole source of carbon. In second phase we selected
microorganism that had high degrading enzyme production with
enzymatic assay for seed production. However, our findings in pilot
scale have indicated that usage of this microbial consortium had high
efficiency for decreasing degradation phase.
Abstract: Multicast transmissions allow an host (the source) to send only one flow bound for a group of hosts (the receivers). Any equipment eager to belong to the group may explicitly register itself to that group via its multicast router. This router will be given the responsibility to convey all information relating to the group to all registered hosts. However in an environment in which the final receiver or the source frequently moves, the multicast flows need particular treatment. This constitutes one of the multicast transmissions problems around which several proposals were made in the Mobile IPv6 case in general. In this article, we describe the problems involved in this IPv6 multicast mobility and the existing proposals for their resolution. Then architecture will be proposed aiming to satisfy and optimize these transmissions in the specific case of a mobile multicast receiver in NC-HMIPv6 environment.
Abstract: If science is supposed to gain greater social
relevance and acceptance, researchers must not only relate to
the broader public, but also promote intercourse within the
ivory tower itself. The latter process has been under way
successfully for a number of years in the form of
transdisciplinary research initiatives. What is still lacking is a
broad debate about the necessity to look around properly and
face up to opposing views on one and the same topic within
our own discipline.
Abstract: Two indica varieties, IR36 and ‘Suweon 258’ (“S”)
are middle-heading in southern Japan. 36U, also middle-heading, is
an isogenic line of IR36 carrying Ur1 (Undulate rachis-1) gene.
However, late-heading plants segregated in the F2 population from
the F1 of S × 36U, and so did in the following generations. The
concerning lateness gene is designated as Ex. From the F8 generation,
isogenic-line pair of early-heading and late-heading lines, denoted by
“E” (ex/ex) and “L” (Ex/Ex), were developed. Genetic analyses of
heading time were conducted, using F1s and F2s among L, E, S and
36U. The following inferences were drawn from the experimental
results: 1) L, and both of E and 36U harbor Ex and ex, respectively;
2) Besides Ex, S harbors an inhibitor gene to it, i.e. I-Ex which is a
novel finding of the present study. 3) Ex is a dominant allele at the
E1 locus.
Abstract: The notions of intuitionistic fuzzy h-ideal and normal
intuitionistic fuzzy h-ideal in Γ-hemiring are introduced and some
of the basic properties of these ideals are investigated. Cartesian
product of intuitionistic fuzzy h-ideals is also defined. Finally a
characterization of intuitionistic fuzzy h-ideals in terms of fuzzy
relations is obtained.
Abstract: The daily increase of organic waste materials resulting
from different activities in the country is one of the main factors for
the pollution of environment. Today, with regard to the low level of
the output of using traditional methods, the high cost of disposal
waste materials and environmental pollutions, the use of modern
methods such as anaerobic digestion for the production of biogas has
been prevailing. The collected biogas from the process of anaerobic
digestion, as a renewable energy source similar to natural gas but
with a less methane and heating value is usable. Today, with the help
of technologies of filtration and proper preparation, access to biogas
with features fully similar to natural gas has become possible. At
present biogas is one of the main sources of supplying electrical and
thermal energy and also an appropriate option to be used in four
stroke engine, diesel engine, sterling engine, gas turbine, gas micro
turbine and fuel cell to produce electricity. The use of biogas for
different reasons which returns to socio-economic and environmental
advantages has been noticed in CHP for the production of energy in
the world. The production of biogas from the technology of anaerobic
digestion and its application in CHP power plants in Iran can not only
supply part of the energy demands in the country, but it can
materialize moving in line with the sustainable development. In this
article, the necessity of the development of CHP plants with biogas
fuels in the country will be dealt based on studies performed from the
economic, environmental and social aspects. Also to prove the
importance of the establishment of these kinds of power plants from
the economic point of view, necessary calculations has been done as
a case study for a CHP power plant with a biogas fuel.